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MSDS Material Safety Data Sheet
CAS

97-63-2
27813-02-1
1830-78-0
99-97-8
1843-05-6
81-48-1

File Name: transdesign_com---msds-002.asp
                                                                                                                            Page 1 of 7
MATERIAL SAFETY DATA SHEET MSDS-002
Prepared to OSHA, ACC, ANSI, WHMIS & 2001/58 EC Standards MSDS Revision: 2.1 MSDS Revision Date: 03/15/2005


1. PRODUCT IDENTIFICATION
1.1 Product Name:

ABSOLUTE LIQUID
1.2 Chemical Name:
METHACRYLATE SOLUTION
1.3 Synonyms:
NA
1.4 Trade Names:
AA1
1.5 Product Use:
PROFESSIONAL USE ONLY
1.6 Manufacturer鈥檚 Name:
OPI PRODUCTS, INC.
1.7 Manufacturer鈥檚 Address:
13034 SATICOY STREET, NO. HOLLYWOOD, CA 91605 USA
1.8 Emergency Phone:

CHEMTREC: (703) 527-3887
1.9 Business Phone:
(818) 759-2400


2. COMPOSITION & INGREDIENT INFORMATION
EXPOSURE LIMITS IN AIR (mg/m3)
ACGIH OSHA OTHER
TLV STEL PEL STEL IDLH
CHEMICAL NAME(S) CAS No. RTECS No. EINECS No. % ppm ppm ppm ppm ppm
ETHYL METHACRYLATE 鈮? 90.0
97-63-2 OZ4550000 202-597-5 (15) NE (10) NE NE
HYDROXYPROPYL 27813-02-1 UD3442500 248-666-3 鈮? 10.0 NE NE NE NE NE
METHACRYLATE
1830-78-0 NA 217-388-4
GLYCEROL DIMETHACRYLATE 鈮? 3.0 NE NE NE NE NE
DIMETHYLTOLYLAMINE 鈮? 1.0
99-97-8 XU5803000 202-805-4 NE NE NE NE NE
1843-05-6 DJ1595000 217-421-2
BENZOPHENONE-12 鈮? 1.0 NE NE NE NE NE
81-48-1 CB7700000 201-353-5 鈮? 1.0
CI 60725 (VIOLET 2) NE NE NE NE NE


NA = Not Available; ND = Not Determined; NE = Not Established; C = Ceiling Limit; See Section 16 for Additional Definitions of Terms Used
NOTE: all WHMIS required information is included. It is located in appropriate sections based on the ANSI Z400.1-2003 format.
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MATERIAL SAFETY DATA SHEET MSDS-002
Prepared to OSHA, ACC, ANSI, WHMIS & 2001/58 EC Standards MSDS Revision: 2.1 MSDS Revision Date: 03/15/2005


3. HAZARD IDENTIFICATION
3.1 Hazard Identification:
Flammable liquid.
3.2 Routes of Entry: Inhalation: YES Absorption: YES Ingestion: YES
3.3 Effects of Exposure:
INGESTION: If product is swallowed, may cause nausea, vomiting and/or diarrhea and central nervous system depression.
SKIN & EYES: Moderately irritating to the eyes. Symptoms of overexposure may include redness, itching, irritation and watering.
May be irritating to skin, especially after prolonged contact. The product can cause allergic skin reactions (e.g.,
rashes, welts, dermatitis) upon prolonged or repeated exposure.
INHALATION: Vapors of this product may be moderately irritating to the nose, throat and other tissues of the respiratory system.
Symptoms of overexposure can include coughing, wheezing, nasal congestion, and difficulty breathing. Inhalation of
concentrated vapors can cause central nervous system depression (e.g., drowsiness, dizziness, headaches, nausea).
3.4 Symptoms of Overexposure:
Symptoms of skin overexposure may include redness, itching, and irritation of affected areas. Overexposure in eyes may cause
redness, itching and watering. The product can cause allergic skin reactions (e.g., rashes, welts, dermatitis) upon prolonged or
repeated exposure.
3.5 Acute Health Effects:
Moderate irritation to eyes and skin near affected areas. Additionally, high concentrations of vapors can cause drowsiness, dizziness,
headaches and nausea.
3.6 Chronic Health Effects:
None known
3.7 Target Organs:
Eyes, skin & respiratory system.


4. FIRST AID MEASURES
4.1 First Aid:
INGESTION: If ingested, do not induce vomiting! If product has been swallowed, drink plenty of water or milk IMMEDIATELY. If the
patient is vomiting, continue to offer water or milk. Never give water or milk to an unconscious person. Contact the
nearest Poison Control Center or local emergency number. Provide an estimate of the time at which the material was
ingested and the amount of the substance that was swallowed.
EYES: If product gets in the eyes, flush with copious amounts of lukewarm water for at least 15 minutes. Open and close
eyelid(s) to ensure thorough irrigation. IF problem persists, seek immediate medical attention.
SKIN: If irritation occurs & product is on the skin, rinse thoroughly with lukewarm water, followed by a thorough washing of the
affected area with plenty of soap and water. Do not wear contaminated clothing until after it has been properly
cleaned. If irritation, redness or swelling persists, consult a physician immediately.
INHALATION: Remove victim to fresh air at once. If breathing stops, perform artificial respiration at once. Seek immediate medical
attention.

HEALTH 2
4.2 Medical Conditions Aggravated by Exposure:
Pre-existing dermatitis, other skin conditions, and disorders of the target organs (eyes,
FLAMMABILITY 3
skin, respiratory system).

REACTIVITY 2
PROTECTIVE EQUIPMENT B
EYES SKIN
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MATERIAL SAFETY DATA SHEET MSDS-002
Prepared to OSHA, ACC, ANSI, WHMIS & 2001/58 EC Standards MSDS Revision: 2.1 MSDS Revision Date: 03/15/2005


5. FIREFIGHTING MEASURES
5.1 Flashpoint & Method:
21掳C (70掳F)
5.2 Autoignition Temperature:
ND
5.3 Flammability Limits: Lower Explosive Limit (LEL): ND Upper Explosive Limit (UEL): ND
5.4 Fire & Explosion Hazards:
This product is a flammable liquid. When involved in a fire, this product may ignite and decompose to
form toxic gases (e.g., CO, CO2, NOx).
5.5 Extinguishing Methods:
Water, Foam, CO2, Dry Chemical
5.6 Firefighting Procedures:
First responders should wear eye protection. Structural fire fighters must wear full protective equipment
and MSHA/NIOSH-approved self-contained breathing apparatus. If possible, prevent runoff water from
entering storm drains, bodies of water, or other environmentally sensitive areas. If necessary, rinse
contaminated equipment with soapy water before returning to service.


6. ACCIDENTAL RELEASE MEASURES
6.1 Spills:
Before cleaning any spill or leak, individuals involved in spill cleanup must wear appropriate Personal Protective Equipment.
For small spills (e.g., <1 gallon) wear appropriate personal protective equipment (e.g., goggles, gloves). Maximize ventilation (open
doors and windows) and secure all sources of ignition. Remove spilled material with absorbent material and place into appropriate
closed container(s) for disposal. Dispose of properly in accordance with local, state and federal regulations. Wash all affected areas
and outside of container with plenty of warm water and soap. Remove any contaminated clothing and wash thoroughly before
reuse.
For spills 鈮? 1 gallon, deny entry to all unprotected individuals. Dike and contain spill with inert material (e.g., sand or earth). Use
ONLY non-sparking tools for recovery and cleanup. Transfer liquid to containers for recovery or disposal and solid diking material to
separate containers for proper disposal. Remove contaminated clothing promptly and wash affected skin areas with soap and
water. Keep spills and cleaning runoffs out of municipal sewers and open bodies of water.


7. HANDLING & STORAGE INFORMATION
7.1 Work & Hygiene Practices:
Avoid prolonged contact with this material. Avoid breathing the vapors generated by this product. Use in a well-ventilated location
(e.g., local exhaust ventilation, fans). Wash exposed skin thoroughly with plenty of soap & water after using this product. If
necessary, use a moisturizer after washing. Do not eat, drink, or smoke while handling this product.
7.2 Storage & Handling:
Use and store in a cool, dry, well-ventilated location (e.g., local exhaust ventilation, fans). Keep away from excessive heat, open
flames, sparks, and other possible sources of ignition. Keep away from incompatible materials listed in Section 10. Do not store in
damaged or unmarked containers or storage devices. Keep containers securely closed when not in use. Open slowly on a level,
stable surface. Empty containers may contain residual amounts of this product; therefore, empty containers should be handled with
care. As a precaution against exposure to the eyes, nose, throat and face, this product should not be stored higher than waist level.
Keep away from children at all times!
7.3 Special Precautions:
NA
Page 4 of 7
MATERIAL SAFETY DATA SHEET MSDS-002
Prepared to OSHA, ACC, ANSI, WHMIS & 2001/58 EC Standards MSDS Revision: 2.1 MSDS Revision Date: 03/15/2005


8. EXPOSURE CONTROLS & PERSONAL PROTECTION
8.1 Ventilation & Engineering Controls:
Use with adequate ventilation (e.g., open doors and windows, local exhaust ventilation). Ensure appropriate decontamination
equipment is available (e.g., sink, safety shower, eye-wash station).
8.2 Respiratory Protection:
No special respiratory protection is required under typical circumstances of use or handling. In instances where vapors or sprays of
this product are generated, and respiratory protection is needed, use only protection authorized by 29 CFR 搂1910.134, applicable U.S.
State regulations, or the Canadian CAS Standard Z94.4-93 and applicable standards of Canadian Provinces, EC member States, or
Australia.
8.3 Eye Protection:
Wear protective eyewear (e.g., safety glasses with side-shield) at all times when handling this product. Always use protective
eyewear when cleaning spills or leaks.
8.4 Hand Protection:
None required under normal conditions of use. However, may cause skin irritation in some sensitive individuals.
When handling large quantities (e.g., 鈮? 1 gallon), wear rubber or impervious plastic gloves.
8.5 Body Protection:
No apron required when handling small quantities.
When handling large quantities (e.g., 鈮? 1 gallon), eye wash stations and deluge showers should be available. Upon completion of
work activities involving large quantities of this product, wash any exposed areas thoroughly with soap and water.


9. PHYSICAL & CHEMICAL PROPERTIES
9.1 Density: 0.918
9.2 Boiling Point: 117 掳C (243 掳F)
9.3 Melting Point: NE
9.4 Evaporation Rate: NA
9.5 Vapor Pressure: NA
9.6 Molecular Weight: NE
9.7 Appearance & Color: Blue liquid with a mild acrylic odor.
9.8 Odor Threshold: NE
9.9 Solubility: Slightly soluble.
9.10 pH NA
9.11 Viscosity: NE
9.12 Other Information: Vapor density (air=1): > 1.0


10. STABILITY & REACTIVITY
10.1 Stability: Relatively stable under ambient conditions when stored properly.
10.2 Hazardous Decomposition Products: If exposed to extremely high temperatures, products of thermal decomposition may include irritating
vapors and toxic gases (e.g., oxides of carbon & nitrogen).
10.3 Hazardous Polymerization: May occur.
10.4 Conditions to Avoid: Exposure or contact to extreme temperatures, incompatible chemicals, strong light sources, sparks,
flame.
Strong oxidizers, peroxides, strong alkalis or acids.
10.5 Incompatible Substances:
Page 5 of 7
MATERIAL SAFETY DATA SHEET MSDS-002
Prepared to OSHA, ACC, ANSI, WHMIS & 2001/58 EC Standards MSDS Revision: 2.1 MSDS Revision Date: 03/15/2005


11. TOXICOLOGICAL INFORMATION
11.1 Toxicity Data:
This product has not been tested on animals to obtain toxicological data. There are toxicology data for the components of this
product, which are found in the scientific literature. These data have not been presented in this document.
11.2 Acute Toxicity:
See Section 3.5
11.3 Chronic Toxicity:
See Section 3.6
11.4 Suspected Carcinogen:
NE
11.5 Reproductive Toxicity:
This product is not reported to produce reproductive toxicity in humans.
Mutagenicity:
This product is not reported to produce mutagenic effects in humans. However, animal mutation data are available for the
components of this product.
Embryotoxicity:
This product is not reported to produce embryotoxic effects in humans.
Teratogenicity:
This product is not reported to produce teratogenic effects in humans.
Reproductive Toxicity:
This product is not reported to produce reproductive effects in humans.
11.6 Irritancy of Product:
See Section 3.3
11.7 Biological Exposure Indices:
NE
11.8 Physician Recommendations:
Treat symptomatically.


12. ECOLOGICAL INFORMATION
12.1 Environmental Stability:
This product will slowly volatile from soil. Components of this product will slowly decompose into organic compounds.
12.2 Effects on Plants & Animals:
There is no specific data available for this product.
12.3 Effects on Aquatic Life:
There is no specific data available for this product. Releases of large volumes may be harmful or fatal to overexposed aquatic life.
Aquatic toxicity data for components of this product are available, but are not presented in this MSDS.


13. DISPOSAL CONSIDERATIONS
13.1 Waste Disposal:
Dispose of in accordance with all Federal, state, and local regulations.
13.2 Special Considerations:
U.S. EPA Characteristic Waste: D001 (flammable)


14. TRANSPORTATION INFORMATION
The basic description (proper shipping name, hazard class & division, ID Number, packing group) is shown for each mode of transportation.
Additional descriptive information may be required by 49 CFR, IATA/ICAO, IMDG and the CTDGR.
14.1 49 CFR (GND):
CONSUMER COMMODITY, ORM-D (x 鈮? 1.0 L)
UN2277, ETHYL METHACRYLATE, STABILIZED, 3, II (x > 1.0 L)
14.2 IATA (AIR):
CONSUMER COMMODITY, 9, ID8000 (x 鈮? 0.5 L)
UN2277, ETHYL METHACRYLATE, STABILIZED, 3, II (x > 0.5 L)
14.3 IMDG (OCN):
UN2277, ETHYL METHACRYLATE, STABILIZED, 3, II, LTD QTY (x 鈮? 1.0 L)
UN2277, ETHYL METHACRYLATE, STABILIZED, 3, II (x > 1.0 L)
14.4 TDGR (Canadian GND):
MARK PACKAGE "LIMITED QUANTITY" or "QUANTIT脡 LIMIT脡E" or "LTD QTY" or "QUANT LT脡E" (x 鈮? 1.0 L)
UN2277, ETHYL METHACRYLATE, STABILIZED, 3, II (x > 1.0 L)
14.5 ADR/RID (EU):
UN2277, ETHYL METHACRYLATE, STABILIZED, 3, II, ADR, LTD QTY (x 鈮? 1.0 L)
14.6 MEXICO (SCT):
UN2277, ETIL METILACRILATO, STABILIZADA, 3, II, CANTIDAD LIMITADA (x 鈮? 1.0 L)
Page 6 of 7
MATERIAL SAFETY DATA SHEET MSDS-002
Prepared to OSHA, ACC, ANSI, WHMIS & 2001/58 EC Standards MSDS Revision: 2.1 MSDS Revision Date: 03/15/2005


15. REGULATORY INFORMATION
15.1 SARA Reporting Requirements:
SARA 304 (Ethyl Methacrylate)
15.2 SARA Threshold Planning Quantity:
NA
15.3 TSCA Inventory Status:
All components of this product are listed in the TSCA Inventory or are exempt.
15.4 CERCLA Reportable Quantity (RQ):
Ethyl Methacrylate: 1000 lbs
15.5 Other Federal Requirements:
This product complies with the appropriate sections of the Food and Drug Administration鈥檚 21 CFR Subchapter G, (Cosmetics).
15.6 Other Canadian Regulations
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of
the information required by the CPR. The components of this product are listed on the DSL/NDSL. None
of the components of this product are listed on the Priorities Substances List (PSL). Class B2 Flammable
Liquid.
15.7 State Regulatory Information:
Ethyl methacrylate is covered under specific state criteria. No components of this mixture are listed in the California Proposition 65
Lists.
15.8 67/548/EEC (European Union) Requirements:
The primary component of this product is not listed in Annex I of EU Directive 67/548/EEC:
Ethyl Methacrylate: Flammable, Irritant (F, Xi). R: 11-36/37/38-43 鈥? Highly flammable. Irritating to eyes,
respiratory system and skin. May cause sensitization by skin contact. S: 2-9-16-29-33 鈥? Keep out the
reach of children. Keep container in a well-ventilated place. Keep away from sources of ignition - No
smoking. Do not empty into drains. Take precautionary measures against static discharges.


16. OTHER INFORMATION
16.1 Other Information:
Precisely follow directions and MSDS (available through your supplier) for use. Avoid all skin contact. If redness or other signs of
adverse reaction occur, discontinue use immediately. Use only in a well ventilated area. A ventilation system that expels vapors to
the outdoors is recommended. Poisonous if swallowed! Keep out of reach of children. FLAMMABLE! Keep away from heat or flame. In
case of emergency, contact your physician or local Poison Control Center immediately. FOR PROFESSIONAL USE ONLY.
16.2 Terms & Definitions:
See page 7 of this MSDS.
16.3 Disclaimer:
This Material Safety Data Sheet is offered pursuant to OSHA鈥檚 Hazard Communication Standard, 29 CFR 搂1910.1200. Other
government regulations must be reviewed for applicability to this product. To the best of ShipMate's & OPI Products鈥? knowledge, the
information contained herein is reliable and accurate as of this date; however, accuracy, suitability or completeness are not
guaranteed and no warranties of any type, either expressed or implied, are provided. The information contained herein relates only
to the specific product(s). If this product(s) is combined with other materials, all component properties must be considered. Data
may be changed from time to time. Be sure to consult the latest edition.
16.4 Prepared for:
OPI Products, Inc.
13034 Saticoy Street
No. Hollywood, CA 91605 USA
(818) 759-2400 phone
(818) 759-5770 fax
http://www.opi.com/
16.5 Prepared by:
ShipMate, Inc.
18436 Hawthorne Boulevard, Suite 201
Torrance, CA 90504
310-370-3600 phone
310-370-5700 fax
http://www.shipmate.com/
Page 7 of 7
MATERIAL SAFETY DATA SHEET MSDS-002
Prepared to OSHA, ACC, ANSI, WHMIS & 2001/58 EC Standards MSDS Revision: 2.1 MSDS Revision Date: 03/15/2005
DEFINITION OF TERMS
A large number of abbreviations and acronyms appear on a MSDS. Some of these that are commonly used include the following:

GENERAL INFORMATION: NATIONAL FIRE PROTECTION ASSOCIATION: NFPA

CAS No. Chemical Abstract Service Number FLAMMABILITY LIMITS IN AIR:

EXPOSURE LIMITS IN AIR: Autoignition Minimum temperature required to initiate combustion
Temperature in air with no other source of ignition
ACGIH American Conference on Governmental Industrial Hygienists
LEL Lower Explosive Limit - lowest percent of vapor in air, by
TLV Threshold Limit Value
volume, that will explode or ignite in the presence of
OSHA U.S. Occupational Safety and Health Administration
an ignition source
PEL Permissible Exposure Limit
UEL Upper Explosive Limit - highest percent of vapor in air,
IDLH Immediately Dangerous to Life and Health by volume, that will explode or ignite in the presence of
an ignition source
FIRST AID MEASURES:

HAZARD RATINGS:
CPR Cardiopulmonary resuscitation - method in which a person
whose heart has stopped receives manual chest
0 Minimal Hazard
compressions and breathing to circulate blood and provide
oxygen to the body. 1 Slight Hazard
2 Moderate Hazard
HMIS庐

HAZARDOUS MATERIALS IDENTIFICATION 3 Severe Hazard
FLAMMABILITY
SYSTEM: HMIS REACTIVITY
4 Extreme Hazard
ACD Acidic
HEALTH
HEALTH, FLAMMABILITY & REACTIVITY RATINGS:
ALK Alkaline
0 Minimal Hazard COR Corrosive
FLAMMABILITY
1 Slight Hazard W Use No Water
2 Moderate Hazard OX Oxidizer
REACTIVITY SPECIAL
3 Severe Hazard HEALTH
PRECAUTIONS
4 Extreme Hazard PERSONAL PROTECTION TOXICOLOGICAL INFORMATION:
NCCHL44T 漏 NPCA Printed by Labelmaster, A, American Labelmark Co., Chicago, IL 60646 (800) 621-5808



PERSONAL PROTECTION RATINGS:
LD50 Lethal Dose (solids & liquids) which kills 50% of the
exposed animals s
A G LC50 Lethal concentration (gases) which kills 50% of the
exposed animal
ppm Concentration expressed in parts of material per
B H
million parts
TDlo Lowest dose to cause a symptom
C I TCLo Lowest concentration to cause a symptom
TDlo, LDlo, & LDo or Lowest dose (or concentration) to cause lethal or
D J TC, TCo, LClo, & LCo toxic effects
IARC International Agency for Research on Cancer
NTP National Toxicology Program
E K RTECS Registry of Toxic Effects of Chemical Substances
BCF Bioconcentration Factor
Consult your supervisor or S.O.P. for
F X TLm Median threshold limit
special handling directions.
log KOW or log KOC Coefficient of Oil/Water Distribution

REGULATORY INFORMATION:
Face Shield &
Safety Glasses Splash Goggles Gloves
Eye Protection WHMIS Canadian Workplace Hazardous Material Information System
DOT U.S. Department of Transportation
TC Transport Canada
EPA U.S. Environmental Protection Agency
Boots Synthetic Apron Full Suit Dust Respirator
DSL Canadian Domestic Substance List
NDSL Canadian Non-Domestic Substance List
PSL Canadian Priority Substances List
Dust & Vapor Full Face Airline Hood/Mask
Vapor Respirator Respirator
Respirator or SCBA TSCA U.S. Toxic Substance Control Act
EU European Union (European Union Directive 67/548/EEC)
Note: the dotted circle indicates that this respiratory protective
equipment is required for high concentrations or for large
EC INFORMATION:
volume spills or releases of product.

OTHER STANDARD ABBREVIATIONS:
NA Not Available
NR No Results
NE Not Established
C E F N O T+ Xi Xn
ND Not Determined
ML Maximum Limit Corrosive Explosive Flammable Harmful Oxidizing Toxic Irritant Harmful
SCBA Self-Contained Breathing Apparatus

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