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MSDS Material Safety Data Sheet
CAS

7085-85-0
9011-14-7
5858-81-1

File Name: transdesign_com---msds-049.asp
                                                                                                                                      Page 1 of 6
MATERIAL SAFETY DATA SHEET MSDS-049
Prepared to OSHA, ACC, ANSI, WHMIS & 2001/58 EC Standards MSDS Revision: 1.0 MSDS Revision Date: 01/01/2005


1. PRODUCT IDENTIFICATION
1.1 Product Name:

MICROWRAP THICKSET RESIN
1.2 Chemical Name:
CYANOACRYLATE MIXTURE
1.3 Synonyms:
NA
1.4 Trade Names:
MW151-174
1.5 Product Use:
PROFESSIONAL OR SUNDRY USE ONLY
1.6 Manufacturer鈥檚 Name:
OPI PRODUCTS, INC.
1.7 Manufacturer鈥檚 Address:
13034 SATICOY STREET, NO. HOLLYWOOD, CA 91605 USA
1.8 Emergency Phone:

CHEMTREC: (703) 527-3887
1.9 Business Phone:
(818) 759-2400


2. COMPOSITION & INGREDIENT INFORMATION
EXPOSURE LIMITS IN AIR (mg/m3)
ACGIH - ppm OSHA - ppm OTHER
%
CHEMICAL NAME(S) CAS No. RTECS No. EINECS No. TLV STEL PEL STEL IDLH
7085-85-0 UD3330050 230-391-5
ETHYL-2 CYANOACRYLATE 鈮? 75.0 (0.2) NE NE NE NE
9011-14-7 TR0400000 201-297-1
POLY (METHYLMETHACRYLATE) 鈮? 25.0 100 NE 100 NE NE
5858-81-1 NA 227-497-9 NE NE NE NE NE
CI 15850 (RED 7) 鈮? 1.0


NA = Not Available; ND = Not Determined; NE = Not Established; C = Ceiling Limit; See Section 16 for Additional Definitions of Terms Used
NOTE: all WHMIS required information is included. It is located in appropriate sections based on the ANSI Z400.1-2003 format.


3. HAZARD IDENTIFICATION
3.1 Hazard Identification:



YES YES YES
3.2 Routes of Entry: Inhalation: Absorption: Ingestion:
3.3 Effects of Exposure:
INGESTION: If product is swallowed, may cause nausea, vomiting and/or diarrhea and central nervous system depression.
SKIN & EYES: Warning! This product will bond skin instantly. Vapor of this product may be mildly to moderately irritating to the eyes.
Symptoms of overexposure may include redness, itching, irritation and watering. May be irritating to skin in some
sensitive individuals, especially after prolonged or repeated skin contact.
INHALATION: Vapors of this product may be slightly irritating to the nose, throat and other tissues of the respiratory system.
Symptoms of overexposure can include coughing, wheezing, nasal congestion, and difficulty breathing. Inhalation of
vapors can cause central nervous system depression (e.g., drowsiness, dizziness, headaches, nausea).
3.4 Symptoms of Overexposure:
Symptoms of skin overexposure in some sensitive individuals may include redness, itching, and irritation of affected areas.
Overexposure of vapor in eyes may cause redness, itching and watering.
3.5 Acute Health Effects:
Mild to moderate irritation to skin near affected areas.
Vapor of this product may be mildly to moderately irritating to the eyes and mucous membranes. Symptoms of overexposure may
include redness, itching, irritation and watering.
Additionally, high concentrations of vapors can cause drowsiness, dizziness, headaches and nausea.
3.6 Chronic Health Effects:
None known.
3.7 Target Organs:
Eyes, skin & respiratory system.
Page 2 of 6
MATERIAL SAFETY DATA SHEET MSDS-049
Prepared to OSHA, ACC, ANSI, WHMIS & 2001/58 EC Standards MSDS Revision: 1.0 MSDS Revision Date: 01/01/2005



4. FIRST AID MEASURES
4.1 First Aid:
INGESTION: If ingested, do not induce vomiting. If product has been swallowed, drink plenty of water or milk IMMEDIATELY. If the
patient is vomiting, continue to offer water or milk. Never give water or milk to an unconscious person. Contact the
nearest Poison Control Center or local emergency number. Provide an estimate of the time at which the material was
ingested and the amount of the substance that was swallowed.
SKIN: This product bonds skin immediately. Do not pull. Peel slowly under lukewarm water. If irritation occurs and product is
on the skin, rinse thoroughly with lukewarm water, followed by a thorough washing of the effected area with soap and
water. If irritation, redness or swelling persists, contact a physician immediately.
EYES: Contact a physician immediately. Do not try to open the eye. Flush with cool water for at least 15 minutes opening
and closing eyelids to ensure thorough irrigation. If irritation persists, contact a physician.
INHALATION: Remove victim to fresh air at once. If breathing stops, perform artificial respiration. Seek immediate medical attention.

HEALTH 2
4.2 Medical Conditions Aggravated by Exposure:
None known.
FLAMMABILITY 1
REACTIVITY 2
PROTECTIVE EQUIPMENT A
EYES

5. FIREFIGHTING MEASURES
5.1 Flashpoint & Method:
< 83掳C (181掳F), TCC
5.2 Autoignition Temperature:
ND
5.3 Flammability Limits: Lower Explosive Limit (LEL): ND Upper Explosive Limit (UEL): ND
5.4 Fire & Explosion Hazards:
Rapid polymerization may occur at very high temperatures.
5.5 Extinguishing Methods:
CO2, Halon, Dry Chemical
5.6 Firefighting Procedures:
When involved in a fire, this product will ignite readily and decompose to produce oxides of carbon and
nitrogen and hydrogen cyanide. Vapors of this product are heavier than air and may travel to a source
of ignition and flash back to a leaking or open container.
First responders should wear eye protection. Structural firefighters must wear SCBAs and full protective
equipment. Use a water spray or fog to reduce or direct vapors. Water may not be effective in actually
extinguishing a fire involving this product.



6. ACCIDENTAL RELEASE MEASURES
6.1 Spills:
Before cleaning any spill or leak, individuals involved in spill cleanup must wear appropriate Personal Protective Equipment.
For small spills (e.g., <1 gallon) wear appropriate personal protective equipment (e.g., goggles, gloves). Maximize ventilation (open
doors and windows) and secure all sources of ignition. Remove spilled material with absorbent material and place into appropriate
closed container(s) for disposal. Dispose of properly in accordance with local, state and federal regulations. Wash all affected areas
and outside of container with plenty of warm water and soap. Remove any contaminated clothing and wash thoroughly before
reuse.
For spills 鈮? 1 gallon, deny entry to all unprotected individuals. Dike and contain spill with inert material (e.g., sand or earth). Use ONLY
non-sparking tools for recovery and cleanup. Transfer liquid to containers for recovery or disposal and solid diking material to
separate containers for proper disposal. Remove contaminated clothing promptly and wash affected skin areas with soap and water.
Keep spills and cleaning runoffs out of municipal sewers and open bodies of water.
Page 3 of 6
MATERIAL SAFETY DATA SHEET MSDS-049

Prepared to OSHA, ACC, ANSI, WHMIS & 2001/58 EC Standards MSDS Revision: 1.0 MSDS Revision Date: 01/01/2005
7. HANDLING & STORAGE INFORMATION
7.1 Work & Hygiene Practices:
Avoid prolonged or repeated skin contact. Avoid breathing vapors of this product. Use eye protection when using this product. Use
in a well-ventilated location (e.g., local exhaust ventilation, fans). After use, wash hands and exposed skin with soap & water. Do not
eat, drink or smoke while handling product.
7.2 Storage & Handling:
Open containers slowly on a stable surface. Keep container closed tightly when not in use. Empty container may contain residual
amounts of this product; therefore, empty containers should be handled with care.
Store containers in a cool, dry location, away from direct sunlight, other light sources, or sources of intense heat. Ideal storage
temperatures: 5-10 掳C. Store away from incompatible materials (see Section 10, Stability and Reactivity).
7.3 Special Precautions:
Open containers slowly on a stable surface. Keep container tightly closed when not in use. Empty containers may contain residual
amounts of this product; therefore, empty containers should be handled with care.


8. EXPOSURE CONTROLS & PERSONAL PROTECTION
8.1 Ventilation & Engineering Controls:
Use in a well ventilated location (e.g., local exhaust ventilation, fans).
8.2 Respiratory Protection:
No special respiratory protection is required under typical circumstances of use or handling. If necessary, use only respiratory
protection authorized per U.S. OSHA's requirement in 29 CFR 搂1910.134, or applicable U.S. state regulations, or the appropriate
standards of Canada, its provinces, E.C. member states, or Australia.
8.3 Eye Protection:
Safety glasses with side shields should be used with this product. This product is irritating to the eyes.
8.4 Hand Protection:
Warning! This product will bond skin instantly. Therefore, the use of latex or rubber gloves is recommended. If necessary, refer to U.S.
OSHA 29 CFR 搂1910.138, the appropriate standards of Canada, of the E.C. member states.
8.5 Body Protection:
No apron required when handling small quantities.
When handling large quantities (e.g., 鈮? 1 gallon), eye wash stations and deluge showers should be available. Upon completion of
work activities involving large quantities of this product, wash any exposed areas thoroughly with soap and water.


9. PHYSICAL & CHEMICAL PROPERTIES
9.1 Density: 1.04 (estimated)
9.2 Boiling Point: > 300掳F (> 149掳C)
9.3 Melting Point: ND
9.4 Evaporation Rate: ND
9.5 Vapor Pressure: < 0.2 mm Hg
9.6 Molecular Weight: NA
9.7 Appearance & Color: Clear to slightly yellow liquid. Thixotropic gel with sharp, irritating acrylic odor.
9.8 Odor Threshold: ND
9.9 Solubility: Insoluble in water.
9.10 pH NA
9.11 Viscosity: 40 cPs
9.12 Other Information: Vapor density > 3 @ 20掳C (68掳F) (air = 1); Polymerizes in water.


10. STABILITY & REACTIVITY
10.1 Stability: Stable under ambient conditions when stored properly (see Section 7, Storage and Handling).
10.2 Hazardous Decomposition Products: If exposed to extremely high temperatures, the products of thermal decomposition may include
irritating vapors and carbon oxide gases and hydrogen cyanide (e.g., CO, CO2, HCN).
10.3 Hazardous Polymerization: May occur, if exposed to extremely high temperatures or exposed to moisture.
10.4 Conditions to Avoid: Exposure to or contact with extreme temperatures, strong light sources or incompatible materials.
10.5 Incompatible Substances: This product is incompatible with strong oxidizers (e.g., peroxides, superoxides), strong acids (e.g.,
hydrochloric or muriatic acids), or strong bases (e.g., lye, potassium hydroxide).
Page 4 of 6
MATERIAL SAFETY DATA SHEET MSDS-049
Prepared to OSHA, ACC, ANSI, WHMIS & 2001/58 EC Standards MSDS Revision: 1.0 MSDS Revision Date: 01/01/2005


11. TOXICOLOGICAL INFORMATION
11.1 Toxicity Data: This product has not been tested on animals to obtain toxicological data. There are toxicology data
for the components of this product, which are found in the scientific literature. These data have not
been presented in this document.
11.2 Acute Toxicity: See Section 3.5
11.3 Chronic Toxicity: See Section 3.6
11.4 Suspected Carcinogen: NE

11.5 Reproductive Toxicity: This product is not reported to cause reproductive toxicity in humans.
Mutagenicity: This product is not reported to produce mutagenic effects in humans.
Embryotoxicity: This product is not reported to produce embryotoxic effects in humans.
Teratogenicity: This product is not reported to cause teratogenic effects in humans.
Reproductive Toxicity: This product is not reported to cause reproductive effects in humans.
11.6 Irritancy of Product: See Section 3.3
11.7 Biological Exposure Indices: NE
11.8 Physician Recommendations: Treat Symptomatically.


12. ECOLOGICAL INFORMATION
12.1 Environmental Stability:
This product will slowly volatile from soil. Components of this product will slowly decompose into
organic compounds.
12.2 Effects on Plants & Animals: There are no specific data available for this product.
12.3 Effects on Aquatic Life: There are no specific data available for this product; however, very large releases of this product
may be harmful or fatal to overexposed aquatic life.


13. DISPOSAL CONSIDERATIONS
13.1 Waste Disposal:
Waste disposal must be in accordance with federal, state, and local regulations.
13.2 Special Considerations:
NA


14. TRANSPORTATION INFORMATION
The basic description (proper shipping name, hazard class & division, ID Number, packing group) is shown for each mode of transportation.
Additional descriptive information may be required by 49 CFR, IATA/ICAO, IMDG and the CTDGR.
14.1 49 CFR (GND):
NOT REGULATED
14.2 IATA (AIR):
AVIATION REGULATED LIQUID, N.O.S. (ETHYL CYANOACRYLATE), 9, UN3334
(500 ml max. per package)
14.3 IMDG (OCN):
NOT REGULATED
14.4 TDGR (Canadian GND):
NOT REGULATED
14.5 ADR/RID (EU):
NOT REGULATED
Page 5 of 6
MATERIAL SAFETY DATA SHEET MSDS-049
Prepared to OSHA, ACC, ANSI, WHMIS & 2001/58 EC Standards MSDS Revision: 1.0 MSDS Revision Date: 01/01/2005


15. REGULATORY INFORMATION
15.1 SARA Reporting Requirements:
NA
15.2 SARA Threshold Planning Quantity:
NA
15.3 TSCA Inventory Status:
The components of this product are listed on the TSCA Inventory.
15.4 CERCLA Reportable Quantity (RQ):
NA
15.5 Other Federal Requirements:
This product complies with the appropriate sections of the Food and Drug Administration's 21 CFR subchapter G (Cosmetics).
15.6 Other Canadian Regulations:
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of
the information required by the CPR. The components of this product are listed on the DSL/NDSL. None
of the components of this product are listed on the Priorities Substances List.
15.7 State Regulatory Information:
Ethyl Cyanoacrylate, Poly (Methylmethacrylate) and Calcium Oxide are covered under specific state criteria. No component of this
mixture is listed in the California Proposition 65 Lists.
15.8 67/548/EEC (European Union) Requirements:

The primary component of this product is listed in Annex I of EU Directive 67/548/EEC:
Ethyl Cyanoacrylate: Irritant (Xi). R: 36/37/38-43 - Irritating to eyes, respiratory system and skin. May
cause sensitization by skin contact. S: 24/25-26-46 - Avoid contact with skin and eyes. In case of
contact with eyes, rinse immediately with plenty of water and seek medical advice. If swallowed, seek
medical advice immediately and show this MSDS or container label.


16. OTHER INFORMATION
16.1 Other Information:
Do not store near eye drops. Eye irritant. If eye contact occurs, flush immediately with water and seek medical attention. Bonds skin
instantly. If skin bonds, do not pull - peel apart gently using acetone. Avoid contact with fabrics as heat may occur. Keep out of
reach of children.
16.2 Terms & Definitions:
See page 6 of this MSDS.
16.3 Disclaimer:
This Material Safety Data Sheet is offered pursuant to OSHA鈥檚 Hazard Communication Standard, 29 CFR 搂1910.1200. Other
government regulations must be reviewed for applicability to this product. To the best of ShipMate's & OPI Products鈥? knowledge, the
information contained herein is reliable and accurate as of this date; however, accuracy, suitability or completeness are not
guaranteed and no warranties of any type, either expressed or implied, are provided. The information contained herein relates only
to the specific product(s). If this product(s) is combined with other materials, all component properties must be considered. Data
may be changed from time to time. Be sure to consult the latest edition.
16.4 Prepared for:
OPI Products, Inc.
13034 Saticoy Street
No. Hollywood, CA 91605 USA
(818) 759-2400 phone
(818) 759-5770 fax
http://www.opi.com/
16.5 Prepared by:
ShipMate, Inc.
18436 Hawthorne Boulevard, Suite 201
Torrance, CA 90504
310-360-3700 phone
310-360-5700 fax
http://www.shipmate.com/
Page 6 of 6
MATERIAL SAFETY DATA SHEET MSDS-049
Prepared to OSHA, ACC, ANSI, WHMIS & 2001/58 EC Standards MSDS Revision: 1.0 MSDS Revision Date: 01/01/2005
DEFINITION OF TERMS
A large number of abbreviations and acronyms appear on a MSDS. Some of these that are commonly used include the following:

GENERAL INFORMATION: NATIONAL FIRE PROTECTION ASSOCIATION: NFPA

CAS No. Chemical Abstract Service Number FLAMMABILITY LIMITS IN AIR:

EXPOSURE LIMITS IN AIR: Autoignition Minimum temperature required to initiate combustion
Temperature in air with no other source of ignition
ACGIH American Conference on Governmental Industrial Hygienists
LEL Lower Explosive Limit - lowest percent of vapor in air, by
TLV Threshold Limit Value
volume, that will explode or ignite in the presence of
OSHA U.S. Occupational Safety and Health Administration
an ignition source
PEL Permissible Exposure Limit
UEL Upper Explosive Limit - highest percent of vapor in air,
IDLH Immediately Dangerous to Life and Health by volume, that will explode or ignite in the presence of
an ignition source
FIRST AID MEASURES:

HAZARD RATINGS:
CPR Cardiopulmonary resuscitation - method in which a person
whose heart has stopped receives manual chest
0 Minimal Hazard
compressions and breathing to circulate blood and provide
oxygen to the body. 1 Slight Hazard
2 Moderate Hazard
HAZARDOUS MATERIALS IDENTIFICATION
HMIS庐


FLAMMABILITY
3 Severe Hazard REACTIVITY
SYSTEM: HMIS
4 Extreme Hazard
ACD Acidic
HEALTH
HEALTH, FLAMMABILITY & REACTIVITY RATINGS:
ALK Alkaline
0 Minimal Hazard COR Corrosive
FLAMMABILITY
1 Slight Hazard W Use No Water
2 Moderate Hazard OX Oxidizer
REACTIVITY SPECIAL
HEALTH
3 Severe Hazard PRECAUTIONS
4 Extreme Hazard PERSONAL PROTECTION TOXICOLOGICAL INFORMATION:
NCCHL44T 漏 NPCA Printed by Labelmaster, A, American Labelmark Co., Chicago, IL 60646 (800) 621-5808



PERSONAL PROTECTION RATINGS:
LD50 Lethal Dose (solids & liquids) which kills 50% of the
exposed animals s
A G LC50 Lethal concentration (gases) which kills 50% of the
exposed animal
ppm Concentration expressed in parts of material per
B H
million parts
TDlo Lowest dose to cause a symptom
C I TCLo Lowest concentration to cause a symptom
TDlo, LDlo, & LDo or Lowest dose (or concentration) to cause lethal or
D J TC, TCo, LClo, & LCo toxic effects
IARC International Agency for Research on Cancer
NTP National Toxicology Program
E K RTECS Registry of Toxic Effects of Chemical Substances
BCF Bioconcentration Factor
Consult your supervisor or S.O.P. for
F X TLm Median threshold limit
special handling directions.
log KOW or log KOC Coefficient of Oil/Water Distribution

REGULATORY INFORMATION:
Face Shield &
Safety Glasses Splash Goggles Gloves
Eye Protection WHMIS Canadian Workplace Hazardous Material Information System
DOT U.S. Department of Transportation
TC Transport Canada
EPA U.S. Environmental Protection Agency
Boots Synthetic Apron Full Suit Dust Respirator
DSL Canadian Domestic Substance List
NDSL Canadian Non-Domestic Substance List
PSL Canadian Priority Substances List
Full Face
Dust & Vapor Airline Hood/Mask
Vapor Respirator Respirator
Respirator or SCBA TSCA U.S. Toxic Substance Control Act
EU European Union (European Union Directive 67/548/EEC)
Note: the dotted circle indicates that this respiratory protective
equipment is required for high concentrations or for large
EC INFORMATION:
volume spills or releases of product.

OTHER STANDARD ABBREVIATIONS:
NA Not Available
NR No Results
NE Not Established
C E F N O T+ Xi Xn
ND Not Determined
ML Maximum Limit Corrosive Explosive Flammable Harmful Oxidizing Toxic Irritant Harmful
SCBA Self-Contained Breathing Apparatus

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