Helena Chemical Company 22-SEP-2004 16:59:40
PH: 901-761-0050 Page 1 Of 4
CHEMTREC: 800-424-9300
Material Safety Data Sheet
Effective Date: 22-SEP-2004
Product: TURpH CAL
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I. IDENTIFICATION
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Chemical Name: Not applicable, formulated mixture.
Chemical Family: Inorganic Metal Salts
Formula: Not applicable, formulated mixture.
Synonyms: None
CAS Number: Not applicable, formulated mixture.
EPA Number: None required
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II. PHYSICAL DATA
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Boiling Point: 102 Degrees C.
Freezing Point: <35 Degrees F.
Spec Gravity: 1.38 gms/cc
Vapor Pressure: 570 mm/Hg
Vapor Density: Not determined
Solubility: Soluble
Volatiles: Not determined
Evaporation: Not determined
Melting Point: Not applicable
Appearance: Clear yellow liquid with no odor.
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III. INGREDIENTS
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Material CAS Number Percent TLV Hazard
--------------------------- ----------- ------- ------- ---------------
Proprietary blend of Plant 100.00 N/E Skin & eye
Nutrients derived from Calcium irritant; acidic.
Nitrate, Calcium Hydroxide,
Hydrogen Phosphate, Calcium
Carbonate, Calcium Citrate,
and Di- and Tri-carboxyllic
Acids.
TYPICAL COMPOSITION:
Total Nitrogen (N): 5.00%
Calcium (Ca): 8.00%
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IV. FIRE AND EXPLOSION HAZARD
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Flash Point: Non-combustible
Autoignition Temp: Not applicable
Flammable Limit: Not determined
Extinguishing Media: Use water fog, foam, dry chemical or carbon
dioxide extinguishing media.
Special Fire Fight Proc: Wear self-contained breathing apparatus and
Helena Chemical Company 22-SEP-2004 16:59:40
PH: 901-761-0050 Page 2 Of 4
CHEMTREC: 800-424-9300
Material Safety Data Sheet
Effective Date: 22-SEP-2004
Product: TURpH CAL
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full protective clothing. Contain fire fighting
waters to prevent contamination of water
supplies, lakes, streams or ponds.
Fire and Expl Hazard: Carbon monoxide or phosphorous oxide may be
evolved at extreme temperatures.
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V. HEALTH HAZARD
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Carcinogen Information: None currently known.
ACUTE EFFECTS OF OVER EXPOSURE
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Swallowing: No Acute Oral LD50 has been determined. Due to
the acidic nature of this material (pH=0.5),
ingestion may result in corrosive damage to the
esophagus and digestive tract. Digestive upset
and other stomach disorders may occur if
ingested.
Skin Absorption: No Acute Dermal LD50 has been determined.
Dermal effects, such as skin reddening, may
occur in sensitive persons.
Inhalation: No Acute Inhalation LC50 has been determined.
Lung congestion may occur if mists are
inhaled.
Skin contact: No Acute Dermal LD50 has been determined.
Dermal effects, such as skin reddening, may
occur in sensitive persons.
Eye Contact: Irritation of the eyes may occur with direct
eye contact with mists or liquids.
Chronic Effects: None currently known.
Other Hazard: None currently known.
EMERGENCY AND FIRST AID PROCEDURES
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Swallowing: Drink 1 to 2 glasses of water and induce
vomiting by touching back of throat with
finger. Call a physician or poison control
center.
Skin: Wash affected area with plenty of soap and
water. If irritation persists, seek medical
treatment.
Inhalation: Move to fresh air. If irritation develops, seek
medical attention.
Eyes: Flush eyes with water for at least 15 minutes,
holding eyelids open. Seek medical attention if
irritation develops or persists.
Notes to Physician: There is no specific antidote for this
Helena Chemical Company 22-SEP-2004 16:59:40
PH: 901-761-0050 Page 3 Of 4
CHEMTREC: 800-424-9300
Material Safety Data Sheet
Effective Date: 22-SEP-2004
Product: TURpH CAL
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material. Treatment should be directed toward
control of the symptoms and the clinical
condition of the patient.
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VI. REACTIVITY
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Stability: Stable
Conditions to Avoid: None currently known.
Polymerization: Will Not Occur
Conditions to Avoid: None currently known.
Incompatibility material: Neutralization reaction will occur if exposed to
alkaline materials.
Hazardous Combustion: At extreme temperatures, carbon monoxide, an
oxidation product, or phosphorous oxide may be
evolved.
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VII. SPILL OR LEAK PROCEDURES
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Spill or Leak Proc: If uncontaminated, collect and reuse as
labeled. If contaminated, absorb with inert
absorbent, such as clay or sand, and place in
plastic recovery drums for proper disposal.
Waste Disposal Method: This material must be disposed of according to
Federal, State or Local procedures under the
Resource Conservation and Recovery Act.
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VIII. SPECIAL PROTECTION INFORMATION
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Respiration: None needed under normal use conditions.
Ventilation: Local exhaust sufficient.
Gloves: Rubber or PVC gloves.
Eyes: Chemical workers' goggles.
Other: Emergency shower, eyewash station, impervious
apron and footwear.
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IX. SPECIAL PRECAUTIONS
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Special precaution: Keep out of reach of children. Do not store
with food, feed or other material to be used or
consumed by humans or animals. Do not
contaminate water supplies, lakes, streams or
ponds with this product. If applied with
another fertilizer or pesticide, follow label
instruction for proper use and application.
Other precaution: None currently known.
Helena Chemical Company 22-SEP-2004 16:59:40
PH: 901-761-0050 Page 4 Of 4
CHEMTREC: 800-424-9300
Material Safety Data Sheet
Effective Date: 22-SEP-2004
Product: TURpH CAL
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X. SHIPPING INFORMATION
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Shipping name: Not regulated by DOT.
Hazard Class: None
Identification No: None
Labels Required: None required
Placarding: None
Freight Class: Compound, Fertilizer (Manufactured Fertilizer),
Liquid, NOIBN (NMFC Item 68140, Sub 6, Class
70) "Non-DOT Regulated"
Chemical Name Equivalent R.Q.
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Not applicable Not applicable
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XI. GENERAL PRODUCT INFORMATION
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National Fire Protection Association Rating:
(Rating level: 4-Extreme, 3-High, 2-Moderate, 1-Slight, 0-Minimum
Health: 2 Fire: 1 Reactivity: 1
S.A.R.A. Title III Hazard Classification: (Yes/No)
Immediate (Acute) Health: Y Delayed (Chronic) Health: N
Sudden Release of pressure: N Fire: N
Reactive: N
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Mail inquiries to: 225 Schilling Blvd., Suite 300 Collierville, TN 38017
Helena Chemical Company believes that the data contained herein is factual.
This data is not to be taken as a warranty or representation of legal
responsibility. It is offered solely for your consideration, investigation
and verification.
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