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MSDS Material Safety Data Sheet
CAS

106-97-8
74-98-6
141-78-6
123-86-4

File Name: henryscheinbrand_com---900-2482.asp
GP-04-Adh盲siv_L枚ser Spray-03-05_engl.
EC Safety Data Sheet 91/155/EWG
1. Commercial product name and supplier
Commercial product name: Adhesive Spray Remover, Solvent Spray Remover 9002482
Producer: Henry Schein Inc, Melville, 11747 NY, USA
Henry Schein UK Holdings Ltd
Gillingham ME8 0SB
Tel.: ++44 (0)1634/ 878750

TOX emergency number: Landesberatungsstelle f眉r Vergiftungserscheinungen und Embryonal-
Toxikologie Pulsstra脽e 3-7, D-14059 Berlin
Chemtrec + 1 703 527 3887 Tel. ++49 (0)30 19240;
Telefax: ++49 (0)30 32680721

2. Composition/information on ingredients
Hazardous components:
CAS-No. EINECS-No. EG-Ind.-No. Label R-Phrases %
n-Butane/ F+



iso-Butane 106-97-8 203-448-7 601-004-00-0 F+ 12 15-30
Hochentz眉ndlich




F+



Propane 74-98-6 200-827-9 601-003-00-5 F+ 12 15-30
Hochentz眉ndlich




F Xi



Ethylacetate 141-78-6 205-500-4 607-022-00-5 F, Xi 11-36-66-67 20-
30
Leichtentz眉ndlich Reizend




F



Butylacetate 123-86-4 204-658-1 607-025-00-1 F 11-66-67 20-30
Leichtentz眉ndlich




3. Hazard identification
F+ Xi


R 12 Extremely flammable. R 36 Irritating to eyes. R 37 Irritating to respiratory system.
R 67 Vapors may cause drowsiness and dizziness.
Hochentz眉ndlich Reizend




Specific hazards:
Pressurised container. Protect from sunlight and do not expose to temperatures exceeding 50掳C. Do not
pierce or burn even after use. Do not spray on a naked flame or incandescent material.

4. First aid measures
General information:
Remove affected person from the danger area and lay down.
On contact with eyes:
On contact with the eyes, rinse immediately with plenty of water. If irritation of the eyes occurs, seek
ophthalmological advice.
On contact with skin:
On contact with the skin, wash off immediately with soap and water. Remove contaminated, saturated
clothing immediately.
If swallowed:
After Ingestion call a physician immediately and show packaging or label.
On Inhalation:
Provide with fresh air. In case of inhalation, affected person should be moved into fresh air and kept still
and warm.


Stand: 2005-08 Seite 1 von 5
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GP-04-Adh盲siv_L枚ser Spray-03-05_engl.


EC Safety Data Sheet 91/155/EWG
5. Fire-fighting measures
Suitable extinguishing media:
Foam, powder, carbon dioxide, water fog
extinguishing media to avoid:
Do not use direct water stream
further information:
Cool containers in the vicinity of the blaze using a water spray. Risk of explosion if heated under
confinement. Violent eruption of containers may occur under fire conditions.

6. Accidental release measures
Personal precautions:
Avoid skin contact with leaking liquid (danger of frostbite).
Environmental precautions:
Keep away from sources of ignition. No smoking - Explosion hazards! Do not allow to enter
drains/surface waters/groundwater.
Methods for cleaning up / taking up:
Suitable material for picking up: Universal binder. Treat recovered material as prescribed in: Disposal
considerations.
Additional information:
none

7. Handling and storage
Hints for safe handling:
Avoid the following: Skin and eye contact and inhalation of substance. Do not pierce or burn even after
use.
Hints for protection against fire and explosion
Product is extremely flammable. Protect from sunlight and do not expose to temperatures exceeding
50掳C.
Storage:
Do not expose to direct sunshine. Store in cool, dry well ventilated area away from sources of ignition
and heat. Do not smoke.
Further information on storage conditions:
See 75/324/EEC
Storage class:
2B

8. Exposure limitation and personal protective equipment
Constituents with occupational exposure limits rsp. biological occupational exposure limits requiring
monitoring:
n-Butane CAS-No.: 106-97-8
Propane CAS-No. : 74-98-6
Ethylacetate CAS-No.: 141-78-6
Butylacetate CAS-No. : 123-86-4




Stand: 2005-08 Seite 2 von 5
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GP-04-Adh盲siv_L枚ser Spray-03-05_engl.
EC Safety Data Sheet 91/155/EWG
Exposure limit type:
2350 mg/m3 (n-Butane)
MAK: 1000ppm
2350 mg/m3 (Propane)
MAK: 1000ppm
400ml/m3 1400mg/m3 (Ethylacetate)
MAK:
3
950mg/m3 (Butylacetate)
MAK: 200ml/m
Personal protection equipment
Respiratory protection:
Respiratory protection necessary at exposure limit excess. Filtering device (full mask or mouthpiece)
with filter A2.
Hand protection:
Hand protection is necessary. Suitable materials is Butyl (butyl rubber) 0,5mm. Breakthrough time
(maximal wear duration at permanent contact:): 60min.
Eye protection:
Eye glasses with side protection.
Protective clothing:
Labor smock.
General health and safety measures:
Usual hygienic measures are necessary. When using, do not drink, eat or smoke.

9. Physical and chemical properties
Appearance: liquified gas
Colour: colourless
Odour: practically odourless
Change in physical state:
Boiling point: -0,5掳C (Butane)
Ignition temperature: 240掳C (Butane)
Flashpoint: approx. -41掳C (Butane)
Explosion limits: Lower: 1,5 Vol.% Upper: 11,0 Vol.% (Butane)
Vapourpressure: 3,5 bar at 20掳C;
Solubility in water: practically not
pH-Value: not applicable

10. Stability and reactivity
Conditions to avoid:
When heated:
Do not expose to temperatures exceeding 50掳C, danger of bursting.
Materials to avoid:
Oxidizing agent.
Hazardous decomposition products:
No hazardous decomposition products if stored and handled as prescribed.
Further information:
Extremely flammable product. Avoid ignition sources such as flames or spark producing equipment.




Stand: 2005-08 Seite 3 von 5
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GP-04-Adh盲siv_L枚ser Spray-03-05_engl.
EC Safety Data Sheet 91/155/EWG
11. Toxicological information
Acute toxicity:
LD50 oral 5600 mg/kg (rat, Ethylacetate)
LC50/4h inhal. 1600ml/l (rat, Ethylacetate)
LD50 oral 13100 mg/kg (rat, Butylacetate)
After eye contact:
irritant.
After skin contact:
irritant.
After inhalation:
irritant.
Sensitization:
Not sensitizing.

12. Ecological information
Information about elimination (persistence and degradation)
Abbiotic degradation in air.
Aquatic toxicity:
EC0 (Pseudomonas putida) 2900mg/l/16h (Ethylacetate)
EC50 (Pseudomonas putida) 959mg/l/18h (Butylacetate)
Bacteria toxicity:
EC50 (Daphnia magna) 717mg/l/48h (Ethylacetate)
IC50 (Scenedesmu subspicatus 675mg/l/72h (Butylacetate)
Further ecological information:
Will not pollute the effluent provided it is processed correctly. Do not allow to enter drains/surface
waters/groundwater.
German 鈥濿assergef盲hrdungsklasse鈥? WGK 1.

13. Disposal considerations
Disposal / Waste (product):
Incineration on land.
Packages:
150104 (metallic packaging)




Stand: 2005-08 Seite 4 von 5
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GP-04-Adh盲siv_L枚ser Spray-03-05_engl.
EC Safety Data Sheet 91/155/EWG
14. Transport information
Transport at land (GGVS/GGVE)
GGVS/E Class: 2
Cipher: 5F
Kemler-No: -
UN-No: 1950
Name of substance: Aerosols, flammable
Packing group: -
Transport at sea (IMDG/GGVSee):
IMDG/GGVSee-Class: 2
IMDG-Code page: 2102
UN-No: 1950
EMS-Nummer: 2-13
MFAG: 620
Air transport (ICAO-TI and IATA-DGR):
ICAO/IATA-Class: 2.1
UN/ID-No: 1950
Packing group: -
Name of substance: Aerosols, flammable

15. Regulatory information
This product requires classification according to the criteria of the EC and the 鈥濭efahrstoffverordnung鈥?
Labelling
F+ Xi


F+ Extremely flammable, Xi Irritant
Reizend
Hochentz眉ndlich




Risk phrases:
R 12 Extremely flammable
R 36 Irritating to eyes.
R 37 Irritating to respiratory system.
R 67 Vapors may cause drowsiness and dizziness.
Safety phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition 鈥? No smoking.
S 24/25 Avoid contact with skin and eyes.
S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
Pressurised container. Protect from sunlight and do not expose to temperatures exceeding 50掳C. Do not
pierce or burn even after use. Do not spray on a naked flame or incandescent material. Keep out of the
reach of children. During shipment, storage, installation and use, this material Should not be exposed to
flame or ignition sources.

16. Other information
The above mentioned date correspond to our present state of knowledge and experience. The safety data
sheet serves as description of the products in regard to necessary safety measures. The indications have
not the meaning of guarantees on properties.




Stand: 2005-08 Seite 5 von 5
Rev. 01 AM

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