Nama produk: Product name: Methyl isobutyl carbinol
Nombor MSDS: MSDS number: 63
Nombor bahan: Material number: 80063
Tarikh diterbitkan: Published 02/02/2006(V1)
date:
RISALAH DATA KESELAMATAN BAHAN
MATERIAL SAFETY DATA SHEET
1. Pengenalan Produk dan Syarikat
1. Product and Company Identification
Produk: Product: Metil isobutil karbinol Methyl isobutyl carbinol
Nombor MSDS: MSDS number: 63
Nombor bahan: Material number: 80063
Celanese Pte Ltd
501 Orchard Road
Wheelock Place #11-01
Singapore 238880
Tel No: (65) 67331767
Nombor telefon kecemasan pengangkutan:
+ (65) 66639259 (Operations Room direct dial)
+ (65) 62656917 (Operations Room direct dial)
+ (65) 62650177(Switchboard, ask for Operations Room)
or fax request to
+(65) 62644190 (Facsimile to Operations Room)
+(65) 62664696 (Facsimile to Operations Room)
or email to
opsroom@semco.psa.com.sg
or Call CHEMTREC 703 527 3887 (USA), collect calls accepted
"+" = International Dialing Access Code
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Kecemasan pengangkutan:
Transportation emergency: 703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day
1 of 24
Nama produk: Product name: Methyl isobutyl carbinol
Nombor MSDS: MSDS number: 63
Nombor bahan: Material number: 80063
Tarikh diterbitkan: Published 02/02/2006(V1)
date:
Kegunaan produk:
Product Use:
Perantara bagi zat tambah minyak pelincir, terutama zink dialkil ditiofosfat; agen pembuih bagi mengapungkan
bijih, terutama tembaga.
Intermediate for lube oil additives, especially zinc dialkyl dithiophosphates; frothing agent for ore flotation, especially
copper.
2. Komposisi/ Maklumat tentang Ramuan
2. Composition / Information on Ingredients
Komponen No. CAS % Berat Status kawalselia
Component CAS Number Percent % OSHA:
OSHA hazard
category:
2-Pentanol, 4-metil- 108-11-2 99 Berbahaya
METHYL ISOBUTYL CARBINOL Hazardous
3. Pengenalan Bahaya
3. Hazards Identification
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2 of 24
Nama produk: Product name: Methyl isobutyl carbinol
Nombor MSDS: MSDS number: 63
Nombor bahan: Material number: 80063
Tarikh diterbitkan: Published 02/02/2006(V1)
date:
Gambaran Menyeluruh Kecemasan:
Emergency Overview:
AMARAN!
WARNING!
鈥? Cecair dan wap mudah menyala.
鈥? Flammable liquid and vapor.
鈥? Boleh menyebabkan kerengsaan trek pernafasan dan mata.
鈥? May cause respiratory tract and eye irritation.
鈥? Boleh menyebabkan kerengsaan kulit.
鈥? May cause skin irritation.
鈥? Jika terkena secara berpanjangan atau berulang kali boleh mengeringkan kulit dan menyebabkan
kerengsaan.
鈥? Prolonged or repeated contact may dry skin and cause irritation.
鈥? Bahan menimbulkan bahaya khas kerana terapung di atas air.
鈥? Material creates a special hazard because it floats on water.
Perihalan produk
Product Description
Rupa:
Appearance: Cecair jernih, tak berwarna, mudah bergerak.
Clear, colorless mobile liquid.
Bau: Slightly irritating, alcohol odor.
Odor:
Kesan kesihatan yang berpotensi berlaku
Potential health effects
Laluan pendedahan: Kulit, mata, dihidu, ditelan.
Routes of exposure: Skin, eyes, inhalation, ingestion.
Kesan serta merta
Immediate effects:
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Transportation emergency: 703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day
3 of 24
Nama produk: Product name: Methyl isobutyl carbinol
Nombor MSDS: MSDS number: 63
Nombor bahan: Material number: 80063
Tarikh diterbitkan: Published 02/02/2006(V1)
date:
Kulit: Boleh menyebabkan kerengsaan kulit.
Skin: May cause skin irritation.
Sentuhan berpanjangan atau berulang kali boleh mengeringkan kulit dan
menyebabkan kerengsaan.
Prolonged or repeated contact may dry skin and cause irritation.
Boleh memudaratkan jika terserap melalui kulit.
May be harmful if absorbed through skin.
Gejala pendedahan mungkin termasuk: Symptoms of exposure may include:
depresi sistem saraf pusat berserta sakit kepala, stupor, perilaku tak selaras
atau ganjil atau tidak sedar.
Central nervous system depression with headache, stupor, uncoordinated or strange
behavior or unconsciousness.
kulit mengering, merekah atau mengalami radang.
Drying, cracking or inflammation of skin.
Mata: Pendedahan kepada wap dan cecair: Exposure to vapors and liquid
Eyes:
menyebabkan kerengsaan mata.
Causes eye irritation.
Gejala pendedahan mungkin termasuk: Symptoms of exposure may include:
kerengsaan mata, rasa terbakar atau bisa mata, mata berair, dan/atau
perubahan penglihatan
Eye irritation, burning sensation, pain, watering, and/or change of vision.
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Kecemasan pengangkutan:
Transportation emergency: 703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day
4 of 24
Nama produk: Product name: Methyl isobutyl carbinol
Nombor MSDS: MSDS number: 63
Nombor bahan: Material number: 80063
Tarikh diterbitkan: Published 02/02/2006(V1)
date:
Dihidu: Menyebabkan menyebabkan kerengsaan trek pernafasan.
Inhalation: Causes respiratory tract irritation.
Memudaratkan jika dihidu.
Harmful if inhaled.
Gejala pendedahan mungkin termasuk: Symptoms of exposure may include:
depresi sistem saraf pusat berserta mual, pening, sakit kepala, stupor, perilaku
tak selaras atau ganjil atau tidak sedar.
Central nervous system depression with nausea, dizziness, headache, stupor,
uncoordinated or strange behavior or unconsciousness.
lelehan hidung, suara garau, batuk-batuk, sakit dada dan kesukaran bernafas.
Nasal discharge, hoarseness, coughing, chest pain and breathing difficulty.
Ditelan: Boleh memudaratkan jika ditelan.
Ingestion: May be harmful if swallowed.
Gejala pendedahan mungkin termasuk: Symptoms of exposure may include:
mual, muntah-muntah, hilang selera makan, kerengsaan gastrousus dan/atau
diarea.
Nausea, vomiting, loss of appetite, gastrointestinal irritation and/or diarrhea.
Depresi sistem saraf pusat disertai rasa mual, sakit kepala dan kelembapan
mental.
Central nervous system depression with nausea, headache and mental
sluggishness.
Mutagenik: Tidak menunjukkan potensi mutagenik dalam kebanyakan ujian in vitro.
Mutagenic: Does not show mutatgenic potential in most in vitro tests.
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Kecemasan pengangkutan:
Transportation emergency: 703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day
5 of 24
Nama produk: Product name: Methyl isobutyl carbinol
Nombor MSDS: MSDS number: 63
Nombor bahan: Material number: 80063
Tarikh diterbitkan: Published 02/02/2006(V1)
date:
Kesan pada organ sasaran: 鈥? Pendedahan terlampau (pendadahan berpanjangan atau berulang kali)
Target Organ Effects: boleh menyebabkan:
鈥? Overexposure (prolonged or repeated exposure) may cause:
Kerosakan ginjal
Kidney damage
Depresi sistem saraf pusat
Central nervous system depression
Kecederaan kepada mata
Injury to the eyes
Kerengsaan trek pernafasan
Irritation of the respiratory tract
Kerengsaan trek pencernaan
Irritation of the digestive tract
Pengeringan kulit
Drying of the skin
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Kecemasan pengangkutan:
Transportation emergency: 703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day
6 of 24
Nama produk: Product name: Methyl isobutyl carbinol
Nombor MSDS: MSDS number: 63
Nombor bahan: Material number: 80063
Tarikh diterbitkan: Published 02/02/2006(V1)
date:
Keadaan perubatan yang Pendedahan yang banyak kepada bahan kimia ini boleh memberikan kesan
umumnya diketahui bertambah buruk terhadap orang yang menghidap penyakit akut atau kronik pada organ-
buruk oleh pendedahan: organ berikut:
Medical Conditions which may be Significant exposure to this chemical may adversely affect people with acute or
Aggravated by Exposure: chronic disease of the:
Saluran pernafasan
Respiratory Tract
Kulit
Skin
Mata
Eyes
Buah pinggang
Kidneys
Sistem saraf pusat
Central nervous system
Saluran pencernaan
Digestive tract
Bagi mendapatkan maklumat
lanjut, lihat: Bahagian 4 - Langkah-Langkah Pertolongan Cemas
For further information, see: Bahagian 5 - Langkah-Langkah Memadam Kebakaran
Bahagian 6 - Langkah-Langkah Pembebasan Tidak Sengaja
Bahagian 8 - Kawalan Pendedahan / Perlindungan Diri
Bahagian 9 - Sifat-Sifat Fizikal dan Kimia
Bahagian 10 - Kestabilan dan Kereaktifan
Section 4 - First Aid Measures
Section 5 - Fire Fighting Measures
Section 6 - Accidental Release Measures
Section 8 - Exposure Controls/Personal Protection
Section 9 - Physical and Chemical Properties
Section 10 - Stability and Reactivity
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Kecemasan pengangkutan:
Transportation emergency: 703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day
7 of 24
Nama produk: Product name: Methyl isobutyl carbinol
Nombor MSDS: MSDS number: 63
Nombor bahan: Material number: 80063
Tarikh diterbitkan: Published 02/02/2006(V1)
date:
4. Langkah-Langkah Pertolongan Cemas
4. First Aid Measures
Kulit: Siram kulit serta merta dengan air yang banyak. Tanggalkan pakaian dan
Skin: kasut yang tercemar. Panggil doktor jika kerengsaan terjadi dan berterusan.
Basuh pakaian sebelum menggunakannya semula. Bersihkan kasut sebersih-
bersihnya sebelum menggunakannya semula.
Immediately flush skin with plenty of water. Remove contaminated clothing and
shoes. Call a physician if irritation develops and persists. Wash clothing before
reuse. Thoroughly clean shoes before reuse.
Mata: Serta merta siram mata dengan air yang banyak selama sekurang-kurangnya
Eyes: 15 minit. Jika mudah, tanggalkan kanta lekap yang dipakai. Dapatkan
perhatian perubatan dengan serta merta.
Immediately flush eyes with plenty of water for at least 15 minutes. If easy to do,
remove contact lenses, if worn. Get medical attention immediately.
Dihidu: Pindahkan ke tempat berudara bersih. Jika tidak bernafas, berikan bantuan
Inhalation: pernafasan. Jika sukar bernafas, berikan oksigen. Dapatkan perhatian
perubatan.
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical attention.
Ditelan: JANGAN dipaksa muntah. Dapatkan perhatian perubatan dengan serta merta.
Ingestion: Jika mangsa sedar sepenuhnya, berikan secawan air. Jangan berikan apa-apa
melalui mulut kepada orang yang tidak sedar.
DO NOT induce vomiting. Get medical attention immediately. If victim is fully
conscious, give a cupful of water. Never give anything by mouth to an unconscious
person.
5. Langkah-Langkah Memadam Kebakaran
5. Fire Fighting Measures
NFPA: Health: 2 Flammability: 2 Reactivity: 0
Sifat-sifat mudah menyala
Flammable properties
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Kecemasan pengangkutan:
Transportation emergency: 703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day
8 of 24
Nama produk: Product name: Methyl isobutyl carbinol
Nombor MSDS: MSDS number: 63
Nombor bahan: Material number: 80063
Tarikh diterbitkan: Published 02/02/2006(V1)
date:
Takat kilat (kaedah ujian): 42.4 C (108 F)
Flash point (test method):
Had mudah menyala, Dalam udara, % mengikut isipadu
Flammable limits in air, % by volume:
Atas: 5.5 %
Upper:
1%
Bawah:
Lower:
Suhu swapencucuhan: 360.3 C (680 F)
Autoignition temperature:
Hasil Pembakaran: Karbon Monoksida.
Products of combustion: Carbon Monoxide.
Media pemadam: Gunakan CO2 atau kimia kering bagi kebakaran kecil.
Extinguishing Media: Use CO2 or dry chemical for small fires.
Gunakan busa pembentuk selaput akueus bagi kebakaran besar.
Use aqueous film forming foam for large fires.
Petunjuk Memadam Kebakaran
Fire Fighting Instructions Semburan air patut digunakan bagi menyejukkan struktur dan wadah yang
terdedah kepada api.
Water spray should be used to cool fire-exposed structures and vessels.
Kakitangan hendaklah dipindahkan dan dipastikan berada di atas arah tiupan
angin ke api. Jika ada kemungkinan pendedahan kepada wap atau produk
pembakaran, pakai pakaian bomba yang lengkap serta alat pernafasan
swalengkap yang diluluskan NIOSH. Bahan kimia yang mengoksida mungkin
mencepatkan kadar pembakaran dalam keadaan kebakaran.
Keep personnel removed from and upwind of fire. If potential for exposure to vapors
or products of combustion exists, wear full fire fighting turnout gear and NIOSH
approved self-contained breathing apparatus. Oxidizing chemicals may accelerate
the burning rate in a fire situation.
Persoalan Alam Sekitar Semasa
Memadam Kebakaran Kelengkapan pakaian bunker dan peralatan memadam kebakaran yang lain
Fire Fighting Environmental hendaklah dibersihkan daripada pencemaran sebelum digunakan semula.
Concerns Thoroughly decontaminate bunker gear and other fire-fighting equipment before re-
use.
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Kecemasan pengangkutan:
Transportation emergency: 703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day
9 of 24
Nama produk: Product name: Methyl isobutyl carbinol
Nombor MSDS: MSDS number: 63
Nombor bahan: Material number: 80063
Tarikh diterbitkan: Published 02/02/2006(V1)
date:
6. Langkah-Langkah Pembebasan Tidak Sengaja
6. Accidental Release Measures
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Kecemasan pengangkutan:
Transportation emergency: 703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day
10 of 24
Nama produk: Product name: Methyl isobutyl carbinol
Nombor MSDS: MSDS number: 63
Nombor bahan: Material number: 80063
Tarikh diterbitkan: Published 02/02/2006(V1)
date:
Petunjuk Tumpahan atau
Kebocoran Hapuskan punca-punca pencucuhan.
Spill or Leak Instructions Eliminate ignition sources.
Lihat peralatan perlindungan diri di Bahagian 8. Tumpahan hendaklah
ditampung dengan benteng tanah atau bahan penyerap yang tidak mudah
menyala bagi mengurangkan kawasan yang tercemar.
See Section 8 for appropriate personal protective equipment. Contain spill with dikes
of soil or nonflammable absorbent to minimize contaminated area.
Jika ada potensi kebakaran, selimutkan tumpahan dengan busa pembentuk
selaput akueus jenis alkohol atau gunakan aliran kabut air untuk menyebarkan
wap.
If fire potential exists, blanket spill with alcohol type aqueous film-forming foam or use
water fog stream to disperse vapors.
Hindarkan pengaliran ke dalam pembetung dan parit yang membawa ke
saluran air. Jika dikehendaki, maklumkan pihak berkuasa negeri dan tempatan.
Letakkan bekas yang bocor di kawasan yang sempurna pengudaraannya.
Avoid run-off into storm sewers and ditches leading to waterways. If required, notify
state and local authorities. Place leaking containers in well-ventilated area.
Bersihkan tumpahan kecil dengan menggunakan bahan penyerap tidak mudah
menyala atau dengan menyiram sedikit-sedikit dengan air. Tampung
tumpahan besar dengan benteng atau bahan penyerap tidak mudah menyala.
Bersihkan dengan vakum atau menyapu.
Clean up small spills by using a nonflammable absorbent or flushing sparingly with
water. Contain larger spills with nonflammable diking or absorbent. Clean up by
vacuuming or sweeping.
Orang yang tidak perlu jangan dibiarkan dekat; pencilkan kawasan bahaya dan
jangan benarkan masuk. Pastikan berada di atas arah tiupan angin; jauhi
kawasan rendah.
Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind;
keep out of low areas.
Pencilkan sejauh 800 meter atau 0.5 batu di semua arah jika tangki, gerabak,
atau lori tangki terbabit dalam kebakaran.
Isolate for 800 meters or 0.5 miles in all directions if tank, rail car, or tank truck in
involved in fire.
Bahan ini menimbulkan bahaya khas kerana boleh terapung di permukaan air.
Material creates a special hazard because it floats on water.
Taksir situasi tumpahan, kerana tumpahan mungkin tidak menghasilkan
banyak bahan pencemar bawaan udara yang berbahaya dalam kebanyakan
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Transportation emergency: 703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day
11 of 24
Nama produk: Product name: Methyl isobutyl carbinol
Nombor MSDS: MSDS number: 63
Nombor bahan: Material number: 80063
Tarikh diterbitkan: Published 02/02/2006(V1)
date:
situasi tumpahan di luar. Mungkin wajar dalam hal-hal tertentu untuk
memantau keadaan sahaja hingga produk tumpah itu dihapuskan.
Assess the spill situation, as the spill may not evolve large amounts of hazardous
airborne contaminants in many outdoor spill situations. It may be advisable in some
cases to simply monitor the situation until spilled product is removed.
7. Penanganan dan Penyimpanan
7. Handling and Storage
Penanganan: Gunakan dengan pengudaraan memadai. Bekas hendaklah sentiasa ditutup
Handling: apabila tidak digunakan. Bekas hendaklah dibuka perlahan-lahan bagi
melepaskan lebihan tekanan. Jangan menghidu wapnya. Hindarkan daripada
terkena mata, kulit atau pakaian. Basuh tubuh bersih-bersih dengan sabun
dan air setelah menanganinya. Pakaian kotor hendaklah dibersihkan daripada
pencemaran sebelum digunakan semula. Pakaian daripada kulit hendaklah
dimusnahkan jika tercemar.
Use with adequate ventilation. Keep containers closed when not in use. Always
open containers slowly to allow any excess pressure to vent. Avoid breathing vapor.
Avoid contact with eyes, skin or clothing. Wash thoroughly with soap and water after
handling. Decontaminate soiled clothing thoroughly before re-use. Destroy
contaminated leather clothing.
Produ ini mungkin membangkitkan cas statik. Bumikan/ikat peralatan
peralatan apabila memindahkan bahan bagi mencegah penumpukan statik. Di
AS, peralatan elektrik dan litar dalam semua situasi penyimpanan dan
penanganan mesti mematuhi Kod Elektrik Nasion (Perkara 500 dan 501) bagi
lokasi berbahaya.
This product may generate a static charge. Ground/bond equipment when
transferring material to prevent static accumulation. Electrical equipment and circuits
in all storage and handling must conform to requirements of National Electric Code
(Article 500 and 501) for hazardous location.
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Kecemasan pengangkutan:
Transportation emergency: 703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day
12 of 24
Nama produk: Product name: Methyl isobutyl carbinol
Nombor MSDS: MSDS number: 63
Nombor bahan: Material number: 80063
Tarikh diterbitkan: Published 02/02/2006(V1)
date:
Penyimpanan: Semua bekas hendaklah sentiasa ditutup ketat apabila tidak digunakan.
Storage: Simpan secara terlindung daripada sinaran matahari langsung dan di lantai
yang tidak telus.
Keep all containers tightly closed when not in use. Store out of direct sunlight and on
an impermeable floor.
Janga simpan bersama bahan yang tidak serasi. Lihat Bahagian 10. Kestabilan
dan Kereaktifan.
Do not store with incompatible materials. See Section 10. Stability and Reactivity.
8. Kawalan Pendedahan / Perlindungan Diri
8. Exposure Controls / Personal Protection
Kawalan kejuruteraan Pengudaraan umum atau sebaran sering kali tidak mencukupi sebagai satu-
Engineering Controls: satunya cara mengawal pendedahan pekerja. Biasanya pendedahan setempat
lebih diutamakan.
General or dilution ventilation is frequently insufficient as the sole means of
controlling employee exposure. Local ventilation is usually preferred.
Tempat mandi keselamatan dan tempat membasuh mata harus disediakan di
Peralatan pelindung diri
tempat mudah didapatkan.
Protective Equipment
A safety shower and eyebath should be readily available.
Perlindungan kulit: Pakai pakaian dan sarung tangan tidak telus bagi menghindari sentuhan.
Skin Protection: Disarankan supaya menggunakan getah butil. Bahan pelindung yang lain
boleh digunakan, mengikut keadaan, sekiranya ada data yang memadai
tentang degradasi dan penelapan. Jika bahan kimia lain digunakan bersama
bahan kimia ini, pemilihan bahan harus berdasarkan perlindungan terhadap
semua bahan kimia yang hadir.
Wear impervious clothing and gloves to prevent contact. Butyl rubber is
recommended. Other protective material may be used, depending on the situation, if
adequate degradation and permeation data is available. If other chemicals are used
in conjunction with this chemical, material selection should be based on protection for
all chemicals present.
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Kecemasan pengangkutan:
Transportation emergency: 703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day
13 of 24
Nama produk: Product name: Methyl isobutyl carbinol
Nombor MSDS: MSDS number: 63
Nombor bahan: Material number: 80063
Tarikh diterbitkan: Published 02/02/2006(V1)
date:
Perlindungan mata/muka: Pakai gogal kimia jika ada kemungkinan munasabah akan terkena mata.
Eye/face protection: Wear chemical goggles when there is a reasonable chance of eye contact.
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Kecemasan pengangkutan:
Transportation emergency: 703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day
14 of 24
Nama produk: Product name: Methyl isobutyl carbinol
Nombor MSDS: MSDS number: 63
Nombor bahan: Material number: 80063
Tarikh diterbitkan: Published 02/02/2006(V1)
date:
Perlindungan pernafasan: Berdasarkan aras pencemaran dan had bekerja alat pernafasan, gunakan alat
Respiratory Protection: pernafasan yang diluluskan oleh NIOSH. Berikut adalah peralatan minimum
disarankan bagi aras pendedahan pekerjaan. Bagi menganggarkan
pendedahan pekerjaan lihat Bahagian 3, Bahagian 8 dan Bahagian 11.
Based on workplace contaminant level and working limits of the respirator, use a
respirator approved by NIOSH. The following is the minimum recommended
equipment for an occupational exposure level. To estimate an occupational
exposure level see Section 3, Section 8 and Section 11.
Bagi kadar kepekatan > 1 dan <10 kali aras pendedahan pekerjaan: Gunakan
alat pernafasan pemurni udara dengan pelindung muka penuh dan kartrij wap
organik atau alat pernafasan pemurni udara berpelindung muka penuh dengan
bejana wap organik atau alat pernafasan kuasa pemurni udara berpelindung
muka penuh yang dilengkapi kartrij wap organik. Elemen pemurni udara harus
dilengkapi penunjuk tamat hayat perkhidmatan, atau harus disahkan dengan
dokumentasi jika ada perubahan tidak mengikut jadual. Jika tidak, gunakan
bekalan udara.
For concentrations > 1 and < 10 times the occupational exposure level: Use air-
purifying respirator with full facepiece and organic vapor cartridge(s) or air-purifying
full facepiece respirator with an organic vapor canister or a full facepiece powered
air-purifying respirator fitted with organic vapor cartridge(s). The air purifying element
must have an end of service life indicator, or a documented change out schedule
must be established. Otherwise, use supplied air.
Bagi kadar kepekatan lebih daripada 10 kali aras pendedahan pekerjaan dan
kurang daripada 100 kali aras pendedahan pekerjaan atau IDLH, mana yang
lebih rendah: Gunakan alat pernafasan bekalan udara berpelindung muka
penuh Jenis C dikendalikan dalam cara permintaan tekanan atau aliran terus
menerus.
For concentrations more than 10 times the occupational exposure level and less than
the lower of either 100 times the occupational exposure level or the IDLH: Use Type
C full facepiece supplied-air respirator operated in positive-pressure or continuous-
flow mode.
Bagi kadar kepekatan > 100 kali aras pendedahan pekerjaan atau lebih tinggi
daripada aras IDLH atau kadar kepekatan tidak diketahui (misalnya dalam
kecemasan): Gunakan alat pernafasan swalengkap dengan pelindung muka
penuh dalam cara tekanan positif atau alat pernafasan bekalan udara tekanan
positif berpelindung muka penuh Jenis C dengan sistem lolos alat pernafasan
swalengkap tekanan positif bantu.
For concentrations > 100 times the occupational exposure level or greater than the
IDLH level or unknown concentrations (such as in emergencies): Use self-contained
breathing apparatus with full facepiece in positive-pressure mode or Type C
positive-pressure full facepiece supplied-air respirator with an auxiliary positive-
pressure self-contained breathing apparatus escape system.
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Kecemasan pengangkutan:
Transportation emergency: 703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day
15 of 24
Nama produk: Product name: Methyl isobutyl carbinol
Nombor MSDS: MSDS number: 63
Nombor bahan: Material number: 80063
Tarikh diterbitkan: Published 02/02/2006(V1)
date:
Untuk lolos: Gunakan alat pernafasan swalengkap dengan pelindung muka
penuh atau mana-mana alat pernafasan yang khusus diluluskan bagi
meloloskan diri.
For escape: Use self-contained breathing apparatus with full facepiece or any
respirator specifically approved for escape.
Garis panduan pendedahan
Exposure guidelines
Komponen No. CAS % Berat ACGIH ACGIH ACGIH OSHA OSHA OSHA Mexico Mexico Mexico
Component CAS Percent TWA STEL CEILING TWA STEL CEILING WEL (Had TWA STEL CEILING
Number % Pendedah
an Tempat
Kerja)
Celanese
Celanese
WEL
(Workplace
Exposure
Limit)
2-Pentanol, 4-metil- 108-11-2 99 25 ppm 40 ppm - 25 ppm - - - 25 ppm 40 ppm -
METHYL ISOBUTYL
CARBINOL
Komponen No. CAS % Berat 1990 NIOSH IDLH 1994 NIOSH IDLH
Component CAS Number Percent % (Recognized by OSHA)
2-Pentanol, 4-metil- 108-11-2 99 2000 PPM 400 ppm
METHYL ISOBUTYL CARBINOL
Comments:
Celanese telah menerapkan TLV庐 ACGIH.
Celanese has adopted the ACGIH TLVs
* Workplace Exposure Limit
9. Sifat-Sifat Fizikal dan Kimia
9. Physical and Chemical Properties
Rupa:
Appearance: Cecair jernih, tak berwarna, mudah bergerak.
Clear, colorless mobile liquid.
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16 of 24
Nama produk: Product name: Methyl isobutyl carbinol
Nombor MSDS: MSDS number: 63
Nombor bahan: Material number: 80063
Tarikh diterbitkan: Published 02/02/2006(V1)
date:
Bau: Slightly irritating, alcohol odor.
Odor:
Tekanan Wap: 4.7 mm Hg at 20 deg C
Vapor Pressure:
3.53
Ketumpatan wap (udara = 1 pada 20o C):
Vapor Density (Air=1 @ 20 C):
132 C (269.6 F)
Takat didih (760 mmHgA):
Boiling Point (760 mmHgA):
< -50 C (< -58 F)
Takat beku:
Freezing Point:
1.82 grams per 100 grams H2O
Keterlarutan dalam air pada 20o
C:
Solubility in Water @ 20 C:
0.808 at 20 deg C
Graviti tentu:
Specific Gravity:
102.2
Berat molekul:
Molecular Weight:
0.26
Kadar penyejatan (n-Butil asetat = 1):
Evaporation Rate (n-Butyl acetate = 1):
10. Kestabilan dan Kereaktifan
10. Stability and Reactivity
Kestabilan: Stabil.
Stability: Stable.
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Nama produk: Product name: Methyl isobutyl carbinol
Nombor MSDS: MSDS number: 63
Nombor bahan: Material number: 80063
Tarikh diterbitkan: Published 02/02/2006(V1)
date:
Keadaan yang harus dihindarkan: Produk ini higroskopik. Satu kaedah bagi mengeluarkan lembapan mesti
Conditions to Avoid: disediakan bagi mencegah pencemaran dan kemungkinan terbentuknya
polimer.
Avoid heat , flames, sparks, and other sources of ignition.
Bahan yang harus dihindarkan: Jauhkan dari asid sulfurik dan asid tak organik keras yang lain, aluminum atau
Incompatibility: plumbum (termasuk peralatan yang dibuat daripada logam tersebut), dan agen
pengoksidaan seperti peroksida, asid nitrik, asid perklorik atau kromium
trioksida.
Keep away from sulfuric and other strong inorganic acids, aluminum or lead
(including equipment made of these metals), and oxidizing agents such as peroxides,
nitric acid, perchloric acid or chromium trioxide.
Hasil Pembakaran atau Hasil penguraian terma boleh termasuk oksida karbon.
Penguraian Berbahaya: Thermal decomposition products may include oxides of carbon.
Hazardous combustion or
decomposition products:
Pempolimeran berbahaya: Pempolimeran berbahaya tidak akan terjadi.
Hazardous Polymerization: Hazardous polymerization will not occur.
11. Maklumat Toksikologi
11. Toxicological Information
Component Toxicological Information
Komponen 2-Pentanol, 4-metil-
Component METHYL ISOBUTYL CARBINOL
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Nama produk: Product name: Methyl isobutyl carbinol
Nombor MSDS: MSDS number: 63
Nombor bahan: Material number: 80063
Tarikh diterbitkan: Published 02/02/2006(V1)
date:
Acute Exposure: Excessive exposure leads to depression of the central nervous
system which is generally reversible and is shown by headache, dizziness,
drowsiness, loss of coordination and unconsciousness.
Oral LD50: 2.6g-kg (rats); Slightly toxic to animals. Nausea, vomiting,
gastrointestinal irritation and diarrhea may occur.
Inhalation LC50: >3776 ppm (rats; vapor; 4hrs.); Slightly toxic to animals. Vapors
are irritating to the respiratory tract.
Skin: Repeated or prolonged contact may cause drying of the skin dermatitis.
Moderately irritating to rabbit skin. Slightly toxic (dermal LD50, rabbit:2.9g/kg).
Eyes: Liquid causes moderate to severe irritation of rabbit eyes. Vapors are irritating
to the eyes.
Mutagenicity: Not mutagenic in bacterial, yeast and rat liver cell in vitro assays,
including the Ames Test.
Carcinogenicity: No information.
Reproductive/Developmental Effects: No information.
Other: Methyl isobutyl carbinol has potentiated the liver toxicity of halogenated
solvents (e.g., chloroform and carbon tetrachloride) in experimental animals at oral
doses of 570 mg/kg or higher.
Repeated Exposure: Male and female rates exposed for 6hr/day. 5 days/wk for 6
wks to 211. 825 or 3698 mg/m3 showed no overt signs of toxicity, effects on blood
parameters or compound-related effects based on gross and microscopic
examination of tissues. Increased kidney weight was observed in the males at the
high dose. Effects on urine parameters were noted at all dose levels except for the
low dose males. There are several other studies of limited quality and with limited
details. In a 90-day inhalation study, kidney effects were reported in rats at 0.425
mg/1, but not in monkeys or dogs. The effect in rats was reversible on cessation of
exposure. In mice exposed 12 times for 4 hours to vapor saturated air
(approximately 20 mg/1), an anesthetic effect was reported, but no mortality. In
rabbits exposed dermally 5 times over a period of 15-21 days at 2.5 g/kg, no
systemic effects were observed.
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Kecemasan pengangkutan:
Transportation emergency: 703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day
19 of 24
Nama produk: Product name: Methyl isobutyl carbinol
Nombor MSDS: MSDS number: 63
Nombor bahan: Material number: 80063
Tarikh diterbitkan: Published 02/02/2006(V1)
date:
12. Maklumat Ekologi
12. Ecological Information
Component Ecological Information
Komponen 2-Pentanol, 4-metil-
Component METHYL ISOBUTYL CARBINOL
Ecotoxicity: Methyl isobutyl carbinol exhibits low acute toxicity to aquatic species.
The 96-hour LC50 for fish (Pimephales promelas) was greater than 92.4 ppm. There
was no mortality at this level. The 24-hour LC50 value for fish (Carassius auratus) is
360 ppm. The 24-hour LC50 value for shrimp (Artemia salina) is 370 ppm. The 48-
hour LC50 value for the clawed toad (Xenopus laevis) is 656 ppm. The 3-hour
EC50 for inhibition of bacteria was greater than 100 ppm in the Activated Sludge
Respiration Inhibition Test.
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Kecemasan pengangkutan:
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20 of 24
Nama produk: Product name: Methyl isobutyl carbinol
Nombor MSDS: MSDS number: 63
Nombor bahan: Material number: 80063
Tarikh diterbitkan: Published 02/02/2006(V1)
date:
13. Pertimbangan Pelupusan
13. Disposal Considerations
Lupuskan bahan tumpah sejajar dengan peraturan negeri dan tempatan bagi bahan buangan berbahaya.
Kaedah yang disarankan adalah penunuan atau pengolahan biologi di kemudahan pelupusan yang
diizinkan oleh pihak berkuasa negeri atau Persekutuan. Harap ingat bahawa maklumat ini adalah bagi
bahan sebagaimana dibuat; pemprosesan, penggunaan, atau pencemaran mungkin menjadikan maklumat
ini tidak wajar, tidak tepat atau tidak lengkap.
Dispose of spilled material in accordance with state and local regulations for hazardous waste. Recommended
methods are incineration or biological treatment at a federally or state-permitted disposal facility. Note that this
information applies to the material as manufactured; processing, use, or contamination may make this information
inappropriate, inaccurate, or incomplete.
Harap ingat bahawa maklumat penanganan dan pelupusan ini juga mungkin terpakai bagi bekas kosong,
pelapik dan bahan bilasannya. Peraturan atau sekatan peringkat negeri atau tempatan adalah kompleks
dan mungkin berbeza dengan peraturan persekutuan. Maklumat ini dimaksudkan sebagai bantuan bagi
penanganan dan pelupusan yang wajar; tanggung jawab muktamad bagi penanganan dan pelupusan
terletak di tangan pemilik bahan buangan berkenaan. Lihat Bahagian 9 Sifat-Sifat Fizikal dan Kimia.
Note that this handling and disposal information may also apply to empty containers, liners and rinsate. State or
local regulations or restrictions are complex and may differ from federal regulations. This information is intended as
an aid to proper handling and disposal; the final responsibility for handling and disposal is with the owner of the
waste. See Section 9 - Physical and Chemical Properties.
Kod Bahan Buangan Berbahaya EPA:
EPA Hazardous Waste Code(s):
D001
14. Maklumat Pengangkutan
14. Transport Information
US Department of Transportation:
UN/NA Number: UN 2053
Shipping name: METHYL ISOBUTYL CARBINOL
Hazard class: 3
Packing Group: PG III
Emergency Response Guide: 129
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Kecemasan pengangkutan:
Transportation emergency: 703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day
21 of 24
Nama produk: Product name: Methyl isobutyl carbinol
Nombor MSDS: MSDS number: 63
Nombor bahan: Material number: 80063
Tarikh diterbitkan: Published 02/02/2006(V1)
date:
ICAO/IATA:
IATA UN Number: UN 2053
Proper Shipping Name: METHYL ISOBUTYL CARBINOL
Hazard Classification: 3
Packing group: III
Label: (Flammable Liquid)
IMDG:
International Marine UN Number: UN 2053
Proper Shipping Name: METHYL ISOBUTYL CARBINOL
Hazard Class: 3
Packing Group: III
Takat kilat (kaedah ujian): 42.4 C (108 F)
Flash point (test method):
Transport Canada
Trade Information
Schedule B Code (export): 2905.19.0020
15. Maklumat Kawalselia
15. Regulatory Information
Hazard labeling:
In accordance with EC Directives
R phrases
R 10 Mudah menyala.
R 10 Flammable.
R 37 Merengsa sistem pernafasan.
R 37 Irritating to respiratory system.
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Transportation emergency: 703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day
22 of 24
Nama produk: Product name: Methyl isobutyl carbinol
Nombor MSDS: MSDS number: 63
Nombor bahan: Material number: 80063
Tarikh diterbitkan: Published 02/02/2006(V1)
date:
Keselamatan Safety
S 24/25 Hindarkan daripada terkena kulit dan mata.
S 24/25 Avoid contact with skin and eyes.
INTERNATIONAL REGULATIONS
Inventori kimia
International chemical inventories:
Disenaraikan dalam inventori kimia negara-negara berikut atau layak dikecualikan:
Listed on the chemical inventories of the following countries or qualifies for an exemption:
AUSTRALIA,CHINA,CANADA,EUROPE,KOREA,PHILIPPINES, JAPAN
16. Maklumat Lain
16. Other Information
Disiapkan oleh: Jabatan Penyeliaan Produk
Prepared by: Celanese Ltd.
Product Stewardship Department
Celanese Ltd.
Pentarafan bahaya Maklumat ini dimaksudkan untuk digunakan hanya oleh mereka yang terlatih
Hazard ratings dalam sistem NFPA dan/atau HMIS.
This information is intended solely for the use of individuals trained in the NFPA and/or HMIS
systems.
NFPA: Health: 2 Flammability: 2 Reactivity: 0
HMIS: Health: 2 Flammability: 2 Reactivity: 0
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Transportation emergency: 703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day
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Nama produk: Product name: Methyl isobutyl carbinol
Nombor MSDS: MSDS number: 63
Nombor bahan: Material number: 80063
Tarikh diterbitkan: Published 02/02/2006(V1)
date:
The following sections have been revised since the last issue of this MSDS.
Maklumat berikut telah disemak
sejak versi terakhir MSDS ini:
The following has been revised
since the last issue of this MSDS:
1. Pengenalan Produk dan Syarikat
Maklumat yang terkandung di sini adalah tepat sejauh pengetahuan kami. Kami tidak menyatakan atau menjamin
bahawa mana-mana bahaya yang disenaraikan di sini adalah satu-satunya yang wujud. Celanese Ltd. tidak memberi
jaminan dalam apa jua bentuk, secara nyata atau tersirat, tentang penggunaan bahan ini yang selamat dalam proses
anda atau secara bergabung dengan zat lain. Kesan-kesannya boleh diburukkan oleh bahan lain dan/atau bahan ini
pula boleh memburukkan atau menambah kesan-kesan bahan lain. Bahan ini boleh dibebaskan daripada bahan gas,
cecair, atau pepejal yang dibuat secara langsung atau tidak langsung daripadanya. Pengguna memikul tanggungjawab
tunggal untuk menentukan kesesuaian bahan-bahan bagi apa jua kegunaan dan cara penggunaan yang dirancangkan.
Pengguna mesti memenuhi semua piawai keselamatan dan kesihatan yang berkenaan. Lembaran data keselamatan
bahan disediakan di Internet oleh Celanese, Ltd. sebagai satu perkhidmatan untuk pelanggannya. Memiliki MSDS
Internet tidak menandakan bahawa pemilik MSDS itu adalah pembeli atau pengguna produk yang berkenaan.
Note: For industrial use only. The information contained herein is accurate to the best of our knowledge. We do not
suggest or guarantee that any hazards listed herein are the only ones which exist. Celanese Ltd. makes no warranty of
any kind, express or implied, concerning the safe use of this material in your process or in combination with other
substances. Effects can be aggravated by other materials and/or this material may aggravate or add to the effects of
other materials. This material may be released from gas, liquid, or solid materials made directly or indirectly from it. User
has the sole responsibility to determine the suitability of the materials for any use and the manner of use contemplated.
User must meet all applicable safety and health standards. Material safety data sheets are provided on the Internet by
Celanese, Ltd. as a service to its customers. Possession of an Internet MSDS does not indicate that the possessor of the
MSDS was a purchaser or user of the subject product.
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