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                                   ROCOL FOODGRADE 40 SPRAY
ChemWatch Material Safety Data Sheet CHEMWATCH 4919-6
Issue Date: Thu 18-Jul-2002 CD 2003/2 Page 1 of 9

IDENTIFICATION


STATEMENT OF HAZARDOUS NATURE

Not classified as hazardous according to Worksafe Australia criteria.

SUPPLIER

Company:
ITW Polymers and Fluids Pty Ltd
Address:
100 Hassall Street
Wetherill Park
NSW, 2164
AUS
Telephone: (+61 2) 9757 8800
Fax: (+61 2) 9757 3855

CHEMWATCH HAZARD RATINGS



Flammability:
Toxicity:
Body Contact:
Reactivity:
Chronic:

SCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4




PERSONAL PROTECTIVE EQUIPMENT FOR INDUSTRIAL/COMMERCIAL ENVIRONMENTS




Product Name: Rocol Foodgrade 40 Spray

CAS RN No(s): None
UN Number: 1950
Packing Group: None
Dangerous Goods Class: 2.1
Subsidiary Risk: None
Hazchem Code: 2Y
Poisons Schedule Number: None



continued...
ROCOL FOODGRADE 40 SPRAY
ChemWatch Material Safety Data Sheet CHEMWATCH 4919-6
Issue Date: Thu 18-Jul-2002 CD 2003/2 Page 2 of 9

IDENTIFICATION ...

USE
Food grade lubricant which meets AQIS requirements.

PHYSICAL DESCRIPTION/PROPERTIES

APPEARANCE
Clear colourless oily liquid with a very low odour; does not mix with water.
Supplied as an aerosol pack. Contents under PRESSURE. Contains highly flammable
hydrocarbon propellant.

Boiling Point (掳C): Not available.
Melting Point (掳C): Not available.
Vapour Pressure (kPa): Not available.
Specific Gravity: Not available.
Flash Point (掳C): -81 propellant
Lower Explosive Limit (%): Not available.
Upper Explosive Limit (%): Not available.
Solubility in Water (g/L): Immiscible

INGREDIENTS

NAME CAS RN %
paraffin oils 8012-95-1 30-59
(pharmaceutical grade)
alkanes, C9-12-iso- 90622-57-4 10-30
(food grade)
hydrocarbon propellant 68476-85-7. 30-60
NOTE: Manufacturer has supplied full ingredient
information to allow CHEMWATCH assessment.



HEALTH HAZARD


ACUTE HEALTH EFFECTS

SWALLOWED
The liquid is discomforting to the gastro-intestinal tract
Ingestion may result in nausea, abdominal irritation, pain and vomiting
Considered an unlikely route of entry in commercial/industrial environments


EYE
The mist is discomforting to the eyes
The material may produce moderate eye irritation leading to inflammation.
Repeated or prolonged exposure to irritants may produce conjunctivitis.


SKIN
The liquid may be discomforting to the skin
The material may cause skin irritation after prolonged or repeated exposure and
may produce on contact skin redness, swelling, the production of vesicles,
scaling and thickening of the skin.




continued...
ROCOL FOODGRADE 40 SPRAY
ChemWatch Material Safety Data Sheet CHEMWATCH 4919-6
Issue Date: Thu 18-Jul-2002 CD 2003/2 Page 3 of 9

HEALTH HAZARD ...

INHALED
The vapour/mist is discomforting to the upper respiratory tract
Inhalation hazard is increased at higher temperatures.
Acute effects from inhalation of high vapour concentrations may be chest and
nasal irritation with coughing, sneezing, headache and even nausea.
WARNING:Intentional misuse by concentrating/inhaling contents may be lethal.

CHRONIC HEALTH EFFECTS

Principal routes of exposure are by accidental skin and eye contact and by
inhalation of vapours especially at higher temperatures.
As with any chemical product, contact with unprotected bare skin; inhalation of
vapour, mist or dust in work place atmosphere; or ingestion in any form, should
be avoided by observing good occupational work practice.
WARNING: Aerosol containers may present pressure related hazards.

FIRST AID

SWALLOWED
If swallowed do NOT induce vomiting.
If vomiting occurs, lean patient forward or place on left side (head-down
position, if possible) to maintain open airway and prevent aspiration.
Observe the patient carefully.
Never give liquid to a person showing signs of being sleepy or with reduced
awareness; i.e. becoming unconscious.
Give water to rinse out mouth, then provide liquid slowly and as much as
casualty can comfortably drink.
Seek medical advice.



EYE
If this product comes in contact with the eyes:
Wash out immediately with fresh running water.
Ensure complete irrigation of the eye by keeping eyelids apart and away from eye
and moving the eyelids by occasionally lifting the upper and lower lids.
If pain persists or recurs seek medical attention.
Removal of contact lenses after an eye injury should only be undertaken by
skilled personnel.


SKIN
If solids or aerosol mists are deposited upon the skin:
Flush skin and hair with running water (and soap if available).
Remove any adhering solids with industrial skin cleansing cream.
DO NOT use solvents.
Seek medical attention in the event of irritation.


INHALED
If fumes or combustion products are inhaled remove from contaminated area.
Lay patient down. Keep warm and rested.
Prostheses such as false teeth, which may block airway, should be removed, where
possible, prior to initiating first aid procedures.
Apply artificial respiration if not breathing, preferably with a demand valve
resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if
necessary.


continued...
ROCOL FOODGRADE 40 SPRAY
ChemWatch Material Safety Data Sheet CHEMWATCH 4919-6
Issue Date: Thu 18-Jul-2002 CD 2003/2 Page 4 of 9

HEALTH HAZARD ...

Transport to hospital, or doctor.

ADVICE TO DOCTOR

Treat symptomatically.



PRECAUTIONS FOR USE


EXPOSURE STANDARDS

None assigned. Refer to individual constituents.




INGREDIENT DATA

PARAFFIN OILS:
PEL TWA: 5 mg/m鲁 [OSHA Z1]
oil mist, mineral
TLV TWA: 5 mg/m鲁; STEL: 10 mg/m鲁.
NOTICE OF INTENDED CHANGE.
TLV TWA 0.2 mg/m鲁 inhalable fraction highly refined A4
NOTE: This substance has been classified by the ACGIH as A4
NOT classifiable as causing cancer in humans.
ES TWA: 5 mg/m鲁 (oil mist, refined mineral)
Human exposure to oil mist alone has not been demonstrated to cause health
effects except at levels above 5 mg/m鲁 (this applies to particulates sampled by
a method that does not collect vapour). It is not advisable to apply this
standard to oils containing unknown concentrations and types of additive.

ALKANES, C9-12-ISO-:
CEL TWA: 300 ppm, 1750 mg/m鲁 (total hydrocarbons) [Manuf. EXX]

HYDROCARBON PROPELLANT:
hydrocarbon propellant, as liquified petroleum gas
TLV TWA: 1000 ppm, 1800 mg/m鲁
ES TWA: 1000 ppm, 1800 mg/m鲁
OES TWA: 1000 ppm, 1750 mg/m鲁; STEL: 1250 ppm, 2180 mg/m鲁

ENGINEERING CONTROLS

General exhaust is adequate under normal operating conditions. If risk of
overexposure exists, wear SAA approved respirator. Correct fit is essential to
obtain adequate protection. Provide adequate ventilation in warehouse or closed
storage areas. Air contaminants generated in the workplace possess varying
"escape" velocities which, in turn, determine the "capture velocities" of fresh
circulating air required to effectively remove the contaminant.

Type of Contaminant: Air Speed:
solvent, vapours, degreasing etc., 0.25-0.5 m/s (50-100 f/min)
evaporating from tank (in still air)
aerosols, fumes from pouring 0.5-1 m/s (100-200 f/min.)
operations, intermittent container
filling, low speed conveyer transfers,


continued...
ROCOL FOODGRADE 40 SPRAY
ChemWatch Material Safety Data Sheet CHEMWATCH 4919-6
Issue Date: Thu 18-Jul-2002 CD 2003/2 Page 5 of 9

PRECAUTIONS FOR USE ...

welding, spray drift, plating acid
fumes, pickling (released at low
velocity into zone of active
generation)
direct spray, spray painting in shallow 1-2.5 m/s (200-500 f/min)
booths, drum filling, conveyer loading,
crusher dusts, gas discharge (active
generation into zone of rapid air
motion)
grinding, abrasive blasting, tumbling, 2.5-10 m/s (500-2000 f/min.)
high speed wheel generated dusts
(released at high initial velocity into
zone of very high rapid air motion).

Within each range the appropriate value depends on:

Lower end of the range Upper end of the range
1: Room air currents minimal or 1: Disturbing room air currents
favourable to capture
2: Contaminants of low toxicity or of 2: Contaminants of high toxicity
nuisance value only
3: Intermittent, low production. 3: High production, heavy use
4: Large hood or large air mass in 4: Small hood - local control only
motion

Simple theory shows that air velocity falls rapidly with distance away from the
opening of a simple extraction pipe. Velocity generally decreases with the
square of distance from the extraction point (in simple cases). Therefore the
air speed at the extraction point should be adjusted, accordingly, after
reference to distance from the contaminating source. The air velocity at the
extraction fan, for example, should be a minimum of 1-2 m/s (200-400 f/min.) for
extraction of solvents generated in a tank 2 meters distant from the extraction
point. Other mechanical considerations, producing performance deficits within
the extraction apparatus, make it essential that theoretical air velocities are
multiplied by factors of 10 or more when extraction systems are installed or
used.

PERSONAL PROTECTION

EYE
Safety glasses with side shields; or as required, Chemical goggles. Contact
lenses pose a special hazard; soft lenses may absorb irritants and all lenses
concentrate them.



HANDS/FEET
No special equipment needed when handling small quantities.
OTHERWISE: Wear general protective gloves, eg. light weight rubber gloves. Or as
required: Wear chemical protective gloves, eg. PVC. Wear safety footwear.



OTHER
No special equipment needed when handling small quantities.
OTHERWISE:
Overalls.
Skin cleansing cream.


continued...
ROCOL FOODGRADE 40 SPRAY
ChemWatch Material Safety Data Sheet CHEMWATCH 4919-6
Issue Date: Thu 18-Jul-2002 CD 2003/2 Page 6 of 9

PRECAUTIONS FOR USE ...

Eyewash unit.
Do not spray on hot surfaces.



RESPIRATOR
Respiratory protection may be required when ANY "Worst Case" vapour-phase
concentration is exceeded (see Computer Prediction in "Exposure Standards").

Protection Factor Half-Face Respirator Full-Face Respirator
5 x ES Air-line* A-2
- A-PAPR-2
10 x ES - A-3
10+ x ES - Air-line**



* - Continuous Flow; ** - Continuous-flow or positive pressure demand
^ - Full-face

The local concentration of material, quantity and conditions of use determine
the type of personal protective equipment required. For further information
consult site specific CHEMWATCH data (if available), or your Occupational
Health and Safety Advisor.


SAFE HANDLING



STORAGE AND TRANSPORT

SUITABLE CONTAINER
Aerosol dispenser. Check that containers are clearly labelled.


STORAGE INCOMPATIBILITY
Avoid storage with oxidisers



STORAGE REQUIREMENTS
Store in original containers in approved flame-proof area.
DO NOT store in pits, depressions, basements or areas where vapours may be
trapped.
No smoking, naked lights, heat or ignition sources.
Keep containers securely sealed. Contents under pressure.
Store away from incompatible materials.
Store in a cool, dry, well ventilated area in an upright position.
Avoid storage at temperatures higher than 40 deg C.
Protect containers against physical damage and check regularly for leaks.
Observe manufacturer's storing and handling recommendations.

TRANSPORTATION
Class 2.1 - Flammable gases shall not be loaded in the same vehicle or packed in
the same freight container with:
Class 1 - Explosives;
Class 3 - Flammable liquids (where both flammable liquids and flammable gases
are in bulk);
Class 4.1 - Flammable solids;


continued...
ROCOL FOODGRADE 40 SPRAY
ChemWatch Material Safety Data Sheet CHEMWATCH 4919-6
Issue Date: Thu 18-Jul-2002 CD 2003/2 Page 7 of 9

SAFE HANDLING ...

Class 4.2 - Spontaneously combustible substances;
Class 4.3 - Dangerous when wet substances;
Class 5.1 - Oxidising agents;
Class 5.2 - Organic peroxides;
Class 7 - Radioactive substances.

SPILLS AND DISPOSAL

MINOR SPILLS
Clean up all spills immediately.
Avoid breathing vapours and contact with skin and eyes.
Wear protective clothing, impervious gloves and safety glasses.
Shut off all possible sources of ignition and increase ventilation.
Wipe up.
If safe, damaged cans should be placed in a container outdoors, away from all
ignition sources, until pressure has dissipated.
Undamaged cans should be gathered and stowed safely.



MAJOR SPILLS
Clear area of personnel and move upwind.
Alert Fire Brigade and tell them location and nature of hazard.
May be violently or explosively reactive.
Wear breathing apparatus plus protective gloves.
Prevent, by any means available, spillage from entering drains or water courses
No smoking, naked lights or ignition sources.
Increase ventilation.
Stop leak if safe to do so.
Water spray or fog may be used to disperse / absorb vapour.
Absorb or cover spill with sand, earth, inert materials or vermiculite.
If safe, damaged cans should be placed in a container outdoors, away from
ignition sources, until pressure has dissipated.
Undamaged cans should be gathered and stowed safely.
Collect residues and seal in labelled drums for disposal.

DISPOSAL
Consult State Land Waste Management Authority for disposal.
Discharge contents of damaged aerosol cans at an approved site.
Allow small quantities to evaporate.
DO NOT incinerate or puncture aerosol cans.
Bury residues and emptied aerosol cans at an approved site.

FIRE FIGHTERS' REPORT




EXTINGUISHING MEDIA
Water spray or fog.
Foam.
Dry chemical powder.
BCF (where regulations permit).
Carbon dioxide.




continued...
ROCOL FOODGRADE 40 SPRAY
ChemWatch Material Safety Data Sheet CHEMWATCH 4919-6
Issue Date: Thu 18-Jul-2002 CD 2003/2 Page 8 of 9

SAFE HANDLING ...

FIRE FIGHTING
Alert Fire Brigade and tell them location and nature of hazard.
May be violently or explosively reactive.
Wear breathing apparatus plus protective gloves.
Prevent, by any means available, spillage from entering drains or water course.
If safe, switch off electrical equipment until vapour fire hazard removed.
Use water delivered as a fine spray to control fire and cool adjacent area.
DO NOT approach containers suspected to be hot.
Cool fire exposed containers with water spray from a protected location.
If safe to do so, remove containers from path of fire.
Equipment should be thoroughly decontaminated after use.
When any large container (including road and rail tankers) is involved in a fire,
consider evacuation by 100 metres in all directions.



FIRE/EXPLOSION HAZARD
Liquid and vapour are highly flammable.
Severe fire hazard when exposed to heat or flame.
Vapour forms an explosive mixture with air.
Severe explosion hazard, in the form of vapour, when exposed to flame or spark.
Vapour may travel a considerable distance to source of ignition.
Heating may cause expansion or decomposition with violent container rupture.
Aerosol cans may explode on exposure to naked flames.
Rupturing containers may rocket and scatter burning materials.
Hazards may not be restricted to pressure effects.
May emit acrid, poisonous or corrosive fumes.
On combustion, may emit toxic fumes of carbon monoxide (CO).
Other combustion products include carbon dioxide (CO2)



FIRE INCOMPATIBILITY
Avoid contamination with strong oxidising agents as ignition may result

HAZCHEM
2Y



CONTACT POINT


COMPANY CONTACT
(+61 2) 9757 8800

AUSTRALIAN POISONS INFORMATION CENTRE
24 HOUR SERVICE: 13 11 26
POLICE, FIRE BRIGADE OR AMBULANCE: 000

NEW ZEALAND POISONS INFORMATION CENTRE
24 HOUR SERVICE: 0800 764 766
NZ EMERGENCY SERVICES: 111

End of Report

Issue Date: Thu 18-Jul-2002
Print Date: Tue 10-Jun-2003



continued...
ROCOL FOODGRADE 40 SPRAY
ChemWatch Material Safety Data Sheet CHEMWATCH 4919-6
Issue Date: Thu 18-Jul-2002 CD 2003/2 Page 9 of 9

CONTACT POINT ...

This document is copyright. Apart from any fair dealing for the purposes of
private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from
CHEMWATCH. TEL (+61 3) 9572 4700.

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