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                                MATERIAL SAFETY DATA SHEET




1. CHEMICAL PRODUCT & COMPANY IDENTIFICATION
HAZARD RATINGS HMIS 庐 NFPA
Manufacturer/Supplier SI Group
P.O. Box 1046 Health 1 0
, NY 12301 United States
Schenectady Flammability 1 1
Reactivity
Telephone Numbers - 24 Hour Emergency Assistance 0 0
PPE
1-(800)-424-9300 B
In USA -- CHEMTREC
NFPA Special Hazards
(703)-527-3887]
International [Call Collect]

Telephone Numbers - General Assistance
General 518-887-2400
Trade Name HRJ-11112

NAERG # 171

WHMIS Classifications D2A, D2B
CAS Number N/A

Chemical Name / Class ROSIN MODIFIED RESIN EMULSION
Product Use Chemical intermediate

TSCA Status The material, or components, is either on the TSCA inventory list or is exempt from the requirement to be
listed.

Trade Secret This information is not considered to represent confidential business information to SI Group

2. HAZARDS IDENTIFICATION
Emergency Overview
Hazard Statements
ANSI signal word for this material is: CAUTION

Per SARA 312 regulations this material represents the following health hazard(s): acute chronic

Per SARA 312 regulations this material is classified as a mixture.

Not classified as dangerous in the meaning of transport regulations.
General Fire Hazards
This product is an aqueous mixture which will not burn. If evaporated to dryness, the solid residue may pose a slight fire hazard.
Vapors may be heavier than air and may travel along the ground to some distant source of ignition and flash back.
Appearance
Tan colored aqueous emulsion.
Emergency overview
Each person who could potentially be exposed to this material, via any route of entry, while performing their assignments, routine and
non-routine; from piping; and/or during an emergency situation, should review this MSDS in order to better understand the hazards
associated with the material. Accordingly, please note an * in a HMIS庐 field indicates this material may potentially involve certain chronic
health issues such as cancer -- HMIS庐 is a registered trade and service mark of the NPCA. To work safely with this material : keep
away from heat and ignition sources avoid contact with eyes, skin, or clothing avoid breathing material's vapors, dust, or fumes
keep container closed use with adequate ventilation -- do not enter any confined spaces without first verifying air quality wash
thoroughly after handling This material represents minimal risk.
Health Warnings
lung irritant may cause skin sensitization
Health Cautions
may cause eye irritation may cause skin irritation may affect mucous membranes may cause gastrointestinal disturbances



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N/AP=Not Applicable N/A=Not Available
Environmental Concerns
Information for this material is not available. However, limited ingredient data, if available, is presented.

3. COMPOSITION / INFORMATION ON INGREDIENTS
CAS Weight Trade OSHA Capable of
Number Range Secret Hazardous Release
Ingredient Name

WATER 7732-18-5 47 - 50 %
!
TERPENE PHENOLIC RESIN N/A 43 - 45 %
!
DIPROPYLENE GLYCOL METHYL ETHER 34590-94-8 4-5%



4. FIRST AID MEASURES
Skin contact
Immediately take off all contaminated clothing. For skin contact, flush with large amounts of water. If any adverse effects persist, get medical
attention. The signs and symptoms that may result from an emergency or an unexpected acute overexposure include: irritation
Eye contact
For eye contact, rinse immediately with plenty of water. Seek medical advice. The signs and symptoms that may result from an
emergency or an unexpected acute overexposure include: irritation
Inhalation
Move person to non-contaminated air. If not breathing, give artificial respiration, preferably mouth-to-mouth. If breathing is difficult,
give oxygen. Seek medical attention. The signs and symptoms that may result from an emergency or an unexpected acute
overexposure include: irritation -- respiratory tract
Ingestion
If the material is swallowed, get immediate medical attention or advice. Never give anything by mouth to a victim who is unconscious or
is having convulsions. If patient has a good gag reflex, you can consider giving several ounces of water for dilution. The signs and
symptoms that may result from an emergency or an unexpected acute overexposure include: gastritis
Cardiovascular
The signs and symptoms that may result from an emergency or an unexpected acute overexposure include: arrhythmia
Central Nervous System
Monitor for shock; anticipate seizures and treat accordingly.
Medical Conditions Aggravated by Exposure to this Material
Provide general supportive measures and treat symptomatically. Please consider other resources such as a regional Poison Control
Center or web sites like the National Library of Medicine TOXNET @ http://toxnet.nlm.nih.gov. A specific antidote is not known.


5. FIRE FIGHTING MEASURES
Flammable Properties
Substance Name % LEL % UEL
NA NA
HRJ-11112
Sensitivity to Static Discharge
Material can accumulate static charges from material handling management. Bond and ground as appropriate. For additional recommendations,
consult an applicable guideline such as National Fire Protection Association [NFPA] 77, "Recommended Practices on Static Electricity".
Suitable extinguishing media
Dry chemical, foam, carbon dioxide, water fog.
Extinguishing media which must not be used for safety reasons
Do not use a solid water stream as it may scatter and spread fire.
Protection of Firefighters/Specific Hazards Arising from the Chemical
Exclude air; treat like a gasoline or oil fire. Wear full protective clothing, including helmet, self-contained positive pressure or pressure demand
breathing apparatus, protective clothing and face mask.


6. ACCIDENTAL RELEASE, SPILL, LEAK PROCEDURES
Personal Precautions
Follow facility/company's emergency plans. Follow facility/company's emergency plans.



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Environmental Precautions
Stop the flow of material, if this is without risk. Eliminate sources of ignition. Ventilate the contaminated area. Contain the spill and
prevent the material from obtaining access to any confined spaces, public sewers, or waterways.
Methods for Clean-Up
Ventilate the contaminated area. Eliminate ignition sources including sources of electrical, static or frictional sparks. Contain, absorb or,
for solids, vacuum or sweep up, material and place in container(s) applicable for ultimate transportation or disposal. Thoroughly clean
the release area with a suitable agent and collect any cleaning, rinsing media(s) for proper reclamation or disposal. Wear appropriate
personal protective equipment during cleanup activities.
Other Information
Wear appropriate protective equipment and clothing during clean-up. Determine appropriate course of action for the collected material.
Regulations vary. Consult local authorities before disposal. Wear appropriate protective equipment and clothing during clean-up.
Determine appropriate course of action for the collected material. Regulations vary. Consult local authorities before disposal.

Exposure Guidelines
All PPE use is to be determined by a qualified person.


7. HANDLING & STORAGE
Handling
Air should be excluded, if at all possible, when closing containers. Material should be protected from freezing. As with all chemicals, good
industrial hygiene practices should be followed when handling this material. When the container(s) is empty it may retain product residue including
vapors which could accumulate. Therefore, do not cut, drill, grind, or weld empty containers. Additionally, do not conduct such activity(ies) near
full, partially full, or empty product containers without appropriate workplace safety authorization(s) or permit(s).
Storage
Protect container from physical abuse. Keep the container tightly closed. Store in a cool, dry, well-ventilated storage area. Protect
from freezing. Keep separate from incompatibles. Bond and ground containers when transferring material. Empty product containers
may contain product residue. Do not reuse empty containers.


8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
All PPE use is to be determined by a qualified person.
ACGIH - Threshold Limits Values - Short Term Exposure Limits (TLV-STEL)
DIPROPYLENE GLYCOL METHYL ETHER 34590-94-8 150 ppm STEL
ACGIH - Threshold Limits Values - Skin Notations
DIPROPYLENE GLYCOL METHYL ETHER 34590-94-8 Skin - potential significant contribution to overall exposure
by the cutaneous route
ACGIH - Threshold Limits Values - Time Weighted Averages (TLV-TWA)
DIPROPYLENE GLYCOL METHYL ETHER 34590-94-8 100 ppm TWA
Canada - Ontario - Occupational Exposure Limits - STEVs
DIPROPYLENE GLYCOL METHYL ETHER 34590-94-8 150 ppm STEV; 910 mg/m3 STEV
Canada - Ontario - Occupational Exposure Limits - TWAEVs
DIPROPYLENE GLYCOL METHYL ETHER 34590-94-8 100 ppm TWAEV; 605 mg/m3 TWAEV
U.S. - OSHA - Final PELs - Skin Notations
DIPROPYLENE GLYCOL METHYL ETHER 34590-94-8 prevent or reduce skin absorption
U.S. - OSHA - Final PELs - Time Weighted Averages (TWAs)
DIPROPYLENE GLYCOL METHYL ETHER 34590-94-8 100 ppm TWA; 600 mg/m3 TWA

Engineering Controls
Ventilation should be sufficient to effectively remove, and prevent buildup of, any vapors, dusts, or fumes that may be generated during
handling or thermal processing. In order to ensure appropriate electrical safety practices are followed, consult applicable standards.
These may include guidelines such as the National Fire Protection Association [NFPA] 70, "The National Electrical Code" and NFPA 499,
"Recommended Practice for the Classification of Combustible Dusts and of Hazardous (Classified) Locations for Electrical Installations in
Chemical Process Areas ". NOTE: since this material's vapors, dust or fumes can form explosive mixtures in air, ensure that any potential
areas where explosions may occur are designed to minimize potential damage. For recommendations to prevent such explosions and
associated damage, consult applicable guidelines such as NFPA 69, "Standard on Explosion Prevention Systems" and/or NFPA 68, "Guide
for Venting Deflagrations".

Personal Protective Equipment
Eye Protection
Wear safety glasses with side shields; chemical goggles (if splashing is possible). Wear a face shield if a splash hazard exists. Select & use eye
protection per a competent health & safety professional using: OSHA [29 CFR 1910.133] or Europe's [EN166].


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Skin and body protection
Use appropriate hand protection. Wear impervious gloves for prolonged contact.
Respiratory Protection
Maintain material's vapors, fumes, or particulate levels below any levels of concern including, for solids, considering the material as a
particulate not otherwise classified [nuisance dust] @ 10 mg/m3. Select & use respirators per a competent health & safety professional
using: OSHA (29 CFR 1910.134); ANSI (Z88.2-1992); or Europe's [EN 149].

9. PHYSICAL & CHEMICAL PROPERTIES
Physical State Liquid

pH Value 10 - 11
Flash Point > 201 掳F Tag Closed Cup
( > 94 掳C )
Evaporation Rate
Flammability Class Combustible IIIB
Vapor Pressure N/A
Vapor Density >Air

Specific Gravity 1.05 g/cm3
Solubility in Water Soluble [>25%]


10. STABILITY & REACTIVITY
Stability
Stable under normal conditions [e.g., 70掳F (21掳C) & 14.7 psig (760 mmHg)].
Conditions to Avoid
Do not freeze. Keep away from heat, sparks, or open flame. Exposing a liquid dispersion to air for extended periods may cause coalescence.
Incompatible Materials
This material may react with: strong oxidizing agents
Hazardous Decomposition Products
Upon decomposition this product emits carbon monoxide, carbon dioxide, and/or low molecular weight hydrocarbons.
Possibility of Hazardous Reactions
Will not occur under normal conditions [e.g., 70掳F (21掳C) & 14.7 psig (760 mmHg)].


11. TOXICOLOGICAL INFORMATION
Overview
While OSHA 29 CFR 1910.1200 emphasizes the use of industrial -- human -- data for workplace hazard evaluations, relatively few materials have
such data available as toxicological information is primarily obtained from tests conducted on, or with, animals used as surrogates for humans.
Therefore, the effects and symptoms represented, and/or summarized, may not reflect actual workplace exposures. All materials used in a given
work area should be evaluated by a competent person who can then advise involved workers of health effects, or symptoms, if any, they may
experience from their assigned tasks.
Routes of Entry
eye contact skin contact inhalation ingestion
Target Organs
respiratory system


Dermal LD50s
DIPROPYLENE GLYCOL METHYL ETHER 34590-94-8 Dermal LD50 [rabbit]: 10 mL/kg


Oral LD50
DIPROPYLENE GLYCOL METHYL ETHER 34590-94-8 Oral LD50 [rat]: 5.4 ml/kg
WATER 7732-18-5 Oral LD50 [rat]: >90 mL/kg




Trade Name | HRJ-11112 MSDS ANSI2
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N/AP=Not Applicable N/A=Not Available
12. ECOLOGICAL INFORMATION
Environmental Concerns
Information for this material is not available. However, limited ingredient data, if available, is presented.
Persistence / degradability
While the ecological properties of this material have not been fully evaluated, it is likely that this material biodegrades slowly.
Mobility
The product is soluble in water.


13. DISPOSAL CONSIDERATIONS
Disposal Instructions
Manage wastes to satisfy local, state & federal regulations. This material will not be a RCRA hazardous waste if disposed as shipped by SI Group.
U.S. - CERCLA/SARA - Hazardous Substances and their Reportable Quantities
DIPROPYLENE GLYCOL METHYL ETHER 34590-94-8 1 lb statutory RQ (no final RQ is being assigned to the
generic or broad class. Includes mono- and di- ethers of
ethylene glycol, diethylene glycol and triethylene glycol
R-(OCH2CH2)n-OR'' where n = 1, 2 or 3, R = alkyl or aryl
groups, R'' = R h or groups which when removed yield
glycol ethers with the structure R-(OCH2CH2)n-OH.
Polymers are excluded from glycol category); 0.454 k


14. TRANSPORT INFORMATION
Comments
NOTE: This section's data are provided as a guide to the overall classification of the product. However, transportation classifications may
be subject to change as, for example, with changes in package size. Consult shipper requirements under IMO, ICAO (IATA), TDG and 49
CFR to assure regulatory compliance. Additionally, please contact the Transportation & Regulatory Affairs Specialist with SI Group @
(518)-370-4200 if there are questions regarding the cleaning of containers, or vessels. Remember that the reuse, treatment, or disposal,
of any related residuals or wastes must be in accordance with all federal, state, and local environmental regulations.

SURFACE TRANSPORTATION (HIGHWAY/RAIL)
BULK-- TANK TRUCK/TANK
CAR
Shipping Name Resin, coal tar or petroleum, not DOT hazardous
DRUM(s)/BAG(s)
Shipping Name Resin, coal tar or petroleum, not DOT hazardous
INTERMEDIATE BULK
CONTAINER
Shipping Name Resin, coal tar or petroleum, not DOT hazardous
PAIL(s)/CAN(s)
Shipping Name Resin, coal tar or petroleum, not DOT hazardous

IMDG CODE (WATER)
DRUM(s)/BAG(s)
Shipping Name Resin, coal tar or petroleum, non-dangerous
PAIL(s)/CAN(s)
Shipping Name Resin, coal tar or petroleum, non-dangerous

ICAO/IATA (AIR)
DRUM(s)/BAG(s)
Shipping Name Resin, coal tar or petroleum, not restricted
PAIL(s)/CAN(s)
Shipping Name Resin, coal tar or petroleum, not restricted




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15. REGULATORY INFORMATION
U.S. - CAA (Clean Air Act) - 1990 Hazardous Air Pollutants
DIPROPYLENE GLYCOL METHYL ETHER 34590-94-8 Present (includes mono- and di- ethers of ethylene glycol,
diethylene glycol, and triethylene glycol, except Ethylene
glycol monobutyl ether [EGBE]. See 40 CFR 63.62 for
Redefinition of glycol ethers listed as hazardous air
pollutants and 40 CFR 63.63 for deletion of EGBE)
U.S. - CAA (Clean Air Act) - HON Rule - Organic HAPs
DIPROPYLENE GLYCOL METHYL ETHER 34590-94-8 Present (Includes mono- and di- ethers of ethylene glycol,
diethylene glycol, and triethylene glycol R-(OCH2CH2)n-OR
[Prime] where: n = 1,2, or 3, R = alkyl or aryl groups, and
R [Prime] = R, H, or groups which, when removed, yield
glycol ethers with the structure: R-(OCH2CH2)n-OH.
Polymers are excluded from the glycol category)
Superfund Amendments & Reauthorization Act of 1986
This material may be applicable to the SARA regulations. Thus, it may require you to file appropriate governmental reports if the total amount of
this material, or any of the listed constituents, in your possession ever exceeds the regulations' threshold values.

U.S. - CERCLA/SARA - Section 313 - Emission Reporting
DIPROPYLENE GLYCOL METHYL ETHER 34590-94-8 1.0 % de minimis concentration (applies to
R-(OCH2CH2)n-OR', where n = 1,2, or 3, R=alkyl C7 or
less, or R = phenyl or alkyl substituted phenyl, R' = H or
alkyl C7 or less, or OR' consisting of carboxylic acid ester,
sulfate, phosphate, nitrate, or sulfonate, Chemical Category
N230)


U.S. - California - 8 CCR Section 339 - Director's List of Hazardous Substances
DIPROPYLENE GLYCOL METHYL ETHER 34590-94-8 Present
U.S. - New Jersey - Environmental Hazardous Substances List
DIPROPYLENE GLYCOL METHYL ETHER 34590-94-8 SN 3138 TPQ 500 lb (Category code N230. except
surfactants)
U.S. - New Jersey - Right to Know Hazardous Substance List
DIPROPYLENE GLYCOL METHYL ETHER 34590-94-8 sn 0804


Canada - WHMIS - Ingredient Disclosure List
DIPROPYLENE GLYCOL METHYL ETHER 34590-94-8 1%
WHMIS Ratings D2A, D2B

European Classifications
This substance is considered hazardous per The Safety Data Sheets Directive (91/155/EC) as amended

EU Risk Phrases
Irritating to eyes, respiratory system and skin.
R36/37/38
May cause sensitization by skin contact.
R43
EU Safety Phrases
Do not breathe vapour.
S23
Avoid contact with skin and eyes.
S24/25
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S26
Wear suitable gloves.
S37
EU Symbol(s)




Xi - Irritant


16. OTHER INFORMATION

Trade Name | HRJ-11112 MSDS ANSI2
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Short # | Printed On | 1/23/2008
N/AP=Not Applicable N/A=Not Available
Disclaimer
The health and safety information is that available to SI Group as of the date published and SI Group makes no representation of the
information's completeness or accuracy. Any data provided is based on either: reference sources, testing performed on a representative
sample(s), or professional judgement. The physical data should not be construed as either representing specifications or a guaranteed
analysis. This material has been classified in accordance with the hazard criteria of the Controlled Products Regulation and the MSDS
contains information required by Controlled Products Regulation. SI Group provides its MSDS in several languages using English as the
primary language. While SI Group uses reasonable efforts to provide accurate translations, SI Group assumes no liability, or
responsibility, for errors, omissions or ambiguities in any translations. SI Group expects those persons who receive this MSDS to exercise
their independent professional judgement, or consult with a competent health/safety professional, to determine how to utilize this
material safely. This includes, but is not exclusive to, the material's appropriateness for a specific use, the type of personal protection
equipment necessary, and the use of engineering controls. In no event is SI Group liable for any damages whatsoever arising out of
your use of this material based upon information obtained from this MSDS including: direct, indirect, incidental, consequential or punitive
claims or damages.

Completed On 1/23/2008 Replaces Sheet Dated 12/11/2007
Completed By HGW
MSDS Sections Updated:
Physical & Chemical Properties: Physical & Chemical Properties




Trade Name | HRJ-11112 MSDS ANSI2
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Short # | Printed On | 1/23/2008
N/AP=Not Applicable N/A=Not Available

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