MATERIAL SAFETY DATA SHEET
1. CHEMICAL PRODUCT & COMPANY IDENTIFICATION
HAZARD RATINGS HMIS 庐 NFPA
Manufacturer/Supplier SI Group
P.O. Box 1046 Health 2* 1
, NY 12301 United States
Schenectady Flammability 1 1
Reactivity
Telephone Numbers - 24 Hour Emergency Assistance 0 0
PPE
1-(800)-424-9300 B
In USA -- CHEMTREC
NFPA Special Hazards
(703)-527-3887]
International [Call Collect]
Telephone Numbers - General Assistance
General 518-887-2400
Trade Name HRJ-13078
NAERG # 171
WHMIS Classifications D2A, D2B
CAS Number N/A
Chemical Name / Class LIQUID PHENOLIC RESOLE RESIN
Product Use Chemical intermediate
TSCA Status The material, or components, is either on the TSCA inventory list or is exempt from the requirement to be
listed.
Trade Secret This information is considered to represent confidential business information to SI Group
2. HAZARDS IDENTIFICATION
Emergency Overview
Hazard Statements
ANSI signal word for this material is: DANGER
Per SARA 312 regulations this material represents the following health hazard(s): acute chronic
Per SARA 312 regulations this material is classified as a mixture.
Not classified as dangerous in the meaning of transport regulations.
General Fire Hazards
This product is an aqueous mixture which will not burn. If evaporated to dryness, the solid residue may pose a slight fire hazard.
Vapors may be heavier than air and may travel along the ground to some distant source of ignition and flash back.
Appearance
Liquid
Emergency overview
Each person who could potentially be exposed to this material, via any route of entry, while performing their assignments, routine and
non-routine; from piping; and/or during an emergency situation, should review this MSDS in order to better understand the hazards
associated with the material. Accordingly, please note an * in a HMIS庐 field indicates this material may potentially involve certain chronic
health issues such as cancer -- HMIS庐 is a registered trade and service mark of the NPCA. To work safely with this material : keep
away from heat and ignition sources avoid contact with eyes, skin, or clothing avoid breathing material's vapors, dust, or fumes
keep container closed use with adequate ventilation -- do not enter any confined spaces without first verifying air quality wash
thoroughly after handling
Potential Health Effects
Health Dangers
per the NTP -- carcinogenicity reasonably anticipated per the IARC -- carcinogenic to humans per OSHA -- potential cancer hazard
Health Warnings
lung irritant may cause respiratory sensitization may cause skin sensitization
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Health Cautions
may cause nervous system effects may cause eye irritation may cause skin irritation may affect mucous membranes may
cause gastrointestinal disturbances
Environmental Concerns
Information for this material is not available. However, limited ingredient data, if available, is presented.
FORMALDEHYDE: Aquatic toxicity: trout LD = 50 ppm/24h; catfish TLM = 32 ppm/24h.
PHENOL: Aquatic toxicity: trout TLM = 7.5 ppm/48h; goldfish lethal dose = 1000 ppm/<1h; low bioconcentration.
3. COMPOSITION / INFORMATION ON INGREDIENTS
CAS Weight Trade OSHA Capable of
Number Range Secret Hazardous Release
Ingredient Name
PHENOLIC RESIN N/A 70 - 80 %
WATER 7732-18-5 5 - 15 %
PHENOL 108-95-2 4-8% *
FORMALDEHYDE 50-00-0 <3% *
4. FIRST AID MEASURES
Skin contact
Immediately take off all contaminated clothing. For skin contact, flush with large amounts of water. If any adverse effects persist, get medical
attention. The signs and symptoms that may result from an emergency or an unexpected acute overexposure include: irritation
Eye contact
For eye contact, rinse immediately with plenty of water. Seek medical advice. The signs and symptoms that may result from an
emergency or an unexpected acute overexposure include: irritation
Inhalation
Move person to non-contaminated air. If not breathing, give artificial respiration, preferably mouth-to-mouth. If breathing is difficult,
give oxygen. Seek medical attention. The signs and symptoms that may result from an emergency or an unexpected acute
overexposure include: irritation -- respiratory tract
Ingestion
If the material is swallowed, get immediate medical attention or advice. Never give anything by mouth to a victim who is unconscious or
is having convulsions. If patient has a good gag reflex, you can consider giving several ounces of water for dilution. The signs and
symptoms that may result from an emergency or an unexpected acute overexposure include: gastritis
Cardiovascular
The signs and symptoms that may result from an emergency or an unexpected acute overexposure include: arrhythmia
Central Nervous System
Monitor for shock; anticipate seizures and treat accordingly.
Medical Conditions Aggravated by Exposure to this Material
Provide general supportive measures and treat symptomatically. Please consider other resources such as a regional Poison Control
Center or web sites like the National Library of Medicine TOXNET @ http://toxnet.nlm.nih.gov. A specific antidote is not known.
5. FIRE FIGHTING MEASURES
Flammable Properties
Substance Name % LEL % UEL
NA NA
HRJ-13078
Sensitivity to Static Discharge
Material can accumulate static charges from material handling management. Bond and ground as appropriate. For additional recommendations,
consult an applicable guideline such as National Fire Protection Association [NFPA] 77, "Recommended Practices on Static Electricity".
Suitable extinguishing media
Dry chemical, foam, carbon dioxide, water fog.
Extinguishing media which must not be used for safety reasons
Do not use a solid water stream as it may scatter and spread fire.
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Protection of Firefighters/Specific Hazards Arising from the Chemical
Exclude air; treat like a gasoline or oil fire. Wear full protective clothing, including helmet, self-contained positive pressure or pressure demand
breathing apparatus, protective clothing and face mask.
6. ACCIDENTAL RELEASE, SPILL, LEAK PROCEDURES
Personal Precautions
Follow facility/company's emergency plans.
Environmental Precautions
Stop the flow of material, if this is without risk. Eliminate sources of ignition. Ventilate the contaminated area. Contain the spill and
prevent the material from obtaining access to any confined spaces, public sewers, or waterways.
Methods for Clean-Up
Ventilate the contaminated area. Eliminate ignition sources including sources of electrical, static or frictional sparks. Contain, absorb or,
for solids, vacuum or sweep up, material and place in container(s) applicable for ultimate transportation or disposal. Thoroughly clean
the release area with a suitable agent and collect any cleaning, rinsing media(s) for proper reclamation or disposal. Wear appropriate
personal protective equipment during cleanup activities.
Other Information
Wear appropriate protective equipment and clothing during clean-up. Determine appropriate course of action for the collected material.
Regulations vary. Consult local authorities before disposal.
Exposure Guidelines
All PPE use is to be determined by a qualified person.
7. HANDLING & STORAGE
Handling
Material should be protected from freezing. Air should be excluded, if at all possible, when closing containers. As with all chemicals, good
industrial hygiene practices should be followed when handling this material. When the container(s) is empty it may retain product residue including
vapors which could accumulate. Therefore, do not cut, drill, grind, or weld empty containers. Additionally, do not conduct such activity(ies) near
full, partially full, or empty product containers without appropriate workplace safety authorization(s) or permit(s).
Storage
Protect container from physical abuse. Keep the container tightly closed. Store in a cool, dry, well-ventilated storage area. Protect
from freezing. Keep separate from incompatibles. Bond and ground containers when transferring material. Empty product containers
may contain product residue. Do not reuse empty containers.
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8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
All PPE use is to be determined by a qualified person.
ACGIH - Threshold Limits Values - Ceilings (TLV-C)
FORMALDEHYDE 50-00-0 0.3 ppm Ceiling
ACGIH - Threshold Limits Values - Skin Notations
PHENOL 108-95-2 Skin - potential significant contribution to overall exposure
by the cutaneous route
ACGIH - Threshold Limits Values - Time Weighted Averages (TLV-TWA)
PHENOL 108-95-2 5 ppm TWA
AEL/REL [Acceptable/Recommended Exposure Limit]
FORMALDEHYDE 50-00-0 REL: TWA = 0.3 ppm; STEL = 0.6 ppm [Rohm & Haas]
Canada - Ontario - Occupational Exposure Limits - Skin Notations
PHENOL 108-95-2 Absorption through skin, eyes, or mucous membranes
Canada - Ontario - Occupational Exposure Limits - STEVs
FORMALDEHYDE 50-00-0 2 ppm STEV; 3 mg/m3 STEV
Canada - Ontario - Occupational Exposure Limits - TWAEVs
FORMALDEHYDE 50-00-0 1 ppm TWAEV; 1.5 mg/m3 TWAEV
PHENOL 108-95-2 5 ppm TWAEV; 19 mg/m3 TWAEV
U.S. - OSHA - Final PELs - Short Term Exposure Limits
FORMALDEHYDE 50-00-0 2 ppm STEL (see 29 CFR 1910.1048)
U.S. - OSHA - Final PELs - Skin Notations
PHENOL 108-95-2 prevent or reduce skin absorption
U.S. - OSHA - Final PELs - Time Weighted Averages (TWAs)
FORMALDEHYDE 50-00-0 0.75 ppm TWA
PHENOL 108-95-2 5 ppm TWA; 19 mg/m3 TWA
U.S. - OSHA - Specifically Regulated Chemicals
FORMALDEHYDE 50-00-0 0.5 ppm Action Level; 0.75 ppm TWA; 2 ppm STEL (Irritant
and potential cancer hazard - see 29 CFR 1910.1048)
Engineering Controls
Ventilation should be sufficient to effectively remove, and prevent buildup of, any vapors, dusts, or fumes that may be generated during
handling or thermal processing. In order to ensure appropriate electrical safety practices are followed, consult applicable standards.
These may include guidelines such as the National Fire Protection Association [NFPA] 70, "The National Electrical Code" and NFPA 499,
"Recommended Practice for the Classification of Combustible Dusts and of Hazardous (Classified) Locations for Electrical Installations in
Chemical Process Areas ". NOTE: since this material's vapors, dust or fumes can form explosive mixtures in air, ensure that any potential
areas where explosions may occur are designed to minimize potential damage. For recommendations to prevent such explosions and
associated damage, consult applicable guidelines such as NFPA 69, "Standard on Explosion Prevention Systems" and/or NFPA 68, "Guide
for Venting Deflagrations".
Personal Protective Equipment
Eye Protection
Wear safety glasses with side shields; chemical goggles (if splashing is possible). Wear a face shield if a splash hazard exists. Select & use eye
protection per a competent health & safety professional using: OSHA [29 CFR 1910.133] or Europe's [EN166].
Skin and body protection
Use appropriate hand protection. Wear impervious gloves for prolonged contact.
Respiratory Protection
Maintain material's vapors, fumes, or particulate levels below any levels of concern including, for solids, considering the material as a
particulate not otherwise classified [nuisance dust] @ 10 mg/m3. Select & use respirators per a competent health & safety professional
using: OSHA (29 CFR 1910.134); ANSI (Z88.2-1992); or Europe's [EN 149].
9. PHYSICAL & CHEMICAL PROPERTIES
Physical State Liquid
Flash Point > 201 掳F Tag Closed Cup
( > 94 掳C )
Evaporation Rate
Flammability Class Combustible IIIB
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Vapor Pressure N/A
Vapor Density >Air
Specific Gravity 1.2 g/cm3
Solubility in Water Soluble [>25%]
10. STABILITY & REACTIVITY
Stability
Stable under normal conditions [e.g., 70掳F (21掳C) & 14.7 psig (760 mmHg)].
Conditions to Avoid
Do not freeze. Exposing a liquid dispersion to air for extended periods may cause coalescence.
Incompatible Materials
This material may react with: strong oxidizing agents
WATER: On contact with acids, or bases, an exothermic reaction may occur emitting steam, heat and toxic fumes.
Hazardous Decomposition Products
Upon decomposition this product emits carbon monoxide, carbon dioxide, and/or low molecular weight hydrocarbons.
Possibility of Hazardous Reactions
Will not occur under normal conditions [e.g., 70掳F (21掳C) & 14.7 psig (760 mmHg)].
11. TOXICOLOGICAL INFORMATION
Overview
While OSHA 29 CFR 1910.1200 emphasizes the use of industrial -- human -- data for workplace hazard evaluations, relatively few materials have
such data available as toxicological information is primarily obtained from tests conducted on, or with, animals used as surrogates for humans.
Therefore, the effects and symptoms represented, and/or summarized, may not reflect actual workplace exposures. All materials used in a given
work area should be evaluated by a competent person who can then advise involved workers of health effects, or symptoms, if any, they may
experience from their assigned tasks.
Routes of Entry
inhalation ingestion eye contact skin contact
Target Organs
respiratory system central nervous system
Dermal LD50s
FORMALDEHYDE 50-00-0 Dermal LD50 [rabbit]: 270 mg/kg
PHENOLIC RESIN N/A Dermal LD50 [rat]: >2000 mg/kg
PHENOL 108-95-2 Dermal LD50 [rabbit]: 630 mg/kg
Oral LD50
FORMALDEHYDE 50-00-0 Oral LD50 [rat]: 100 mg/kg
PHENOLIC RESIN N/A Oral LD50 [rat]: >5000 mg/kg
PHENOL 108-95-2 Oral LD50 [rat]: 317 mg/kg
WATER 7732-18-5 Oral LD50 [rat]: >90 mL/kg
Inhalation LC50s
FORMALDEHYDE 50-00-0 Inhalation LC50 [rat]: 165 ppm
PHENOL 108-95-2 Inhalation LC50 [rat]: 82 ppm
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ACGIH - Threshold Limits Values - Carcinogens
FORMALDEHYDE 50-00-0 A2 - Suspected Human Carcinogen
PHENOL 108-95-2 A4 - Not Classifiable as a Human Carcinogen
IARC - Group 1 (Carcinogenic to Humans)
FORMALDEHYDE 50-00-0 Monograph 88 [2006], Monograph 62 [1995], Supplement 7
[1987]
IARC - Group 3 (Not Classifiable)
PHENOL 108-95-2 Monograph 71 [1999], Monograph 47 [1989]
NTP (National Toxicology Program) - Report on Carcinogens - Reasonably Anticipated to be Human
Carcinogens
FORMALDEHYDE 50-00-0 Reasonably Anticipated To Be A Carcinogen
U.S. - OSHA - Hazard Communication Carcinogens
FORMALDEHYDE 50-00-0 Present
12. ECOLOGICAL INFORMATION
Environmental Concerns
Information for this material is not available. However, limited ingredient data, if available, is presented.
FORMALDEHYDE: Aquatic toxicity: trout LD = 50 ppm/24h; catfish TLM = 32 ppm/24h.
PHENOL: Aquatic toxicity: trout TLM = 7.5 ppm/48h; goldfish lethal dose = 1000 ppm/<1h; low bioconcentration.
Persistence / degradability
Information for this material is not available. However, limited ingredient data, if available, is presented.
FORMALDEHYDE: Terrestrial Fate: biodegrades; low volatilization; leaches. Aquatic Fate: biodegradable [48 - 72 hours]; low volatilization.
Atmospheric Fate: photochemically degrades [half-life -- a few hours].
PHENOL: Terrestrial Fate: biodegrades; leaches; low volatilization. Aquatic Fate: biodegrades [BOD5 >50%]; slow volatilization [half-life: river
~107 days]. Atmospheric Fate: photochemically degrades [half-life ~15 hours].
Mobility
The product is soluble in water.
13. DISPOSAL CONSIDERATIONS
Disposal Instructions
Manage wastes to satisfy local, state & federal regulations. This material will not be a RCRA hazardous waste if disposed as shipped by SI Group.
U.S. - CERCLA/SARA - Hazardous Substances and their Reportable Quantities
FORMALDEHYDE 50-00-0 100 lb final RQ; 45.4 kg final RQ
PHENOL 108-95-2 1000 lb final RQ; 454 kg final RQ
U.S. - New York - Reporting of Releases Part 597 - List of Hazardous Substances
FORMALDEHYDE 50-00-0 100 lb RQ (air); 1 lb RQ (land/water)
PHENOL 108-95-2 1000 lb RQ (air); 1 lb RQ (land/water)
14. TRANSPORT INFORMATION
Comments
NOTE: This section's data are provided as a guide to the overall classification of the product. However, transportation classifications may
be subject to change as, for example, with changes in package size. Consult shipper requirements under IMO, ICAO (IATA), TDG and 49
CFR to assure regulatory compliance. Additionally, please contact the Transportation & Regulatory Affairs Specialist with SI Group @
(518)-370-4200 if there are questions regarding the cleaning of containers, or vessels. Remember that the reuse, treatment, or disposal,
of any related residuals or wastes must be in accordance with all federal, state, and local environmental regulations.
SURFACE TRANSPORTATION (HIGHWAY/RAIL)
BULK-- TANK TRUCK/TANK
CAR
Shipping Name Resin, coal tar or petroleum, not DOT hazardous
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SURFACE TRANSPORTATION (HIGHWAY/RAIL)
DRUM(s)/BAG(s)
Shipping Name Resin, coal tar or petroleum, not DOT hazardous
INTERMEDIATE BULK
CONTAINER
Shipping Name Resin, coal tar or petroleum, not DOT hazardous
PAIL(s)/CAN(s)
Shipping Name Resin, coal tar or petroleum, not DOT hazardous
IMDG CODE (WATER)
DRUM(s)/BAG(s)
Shipping Name Resin, coal tar or petroleum, non-dangerous
PAIL(s)/CAN(s)
Shipping Name Resin, coal tar or petroleum, non-dangerous
ICAO/IATA (AIR)
DRUM(s)/BAG(s)
Shipping Name Resin, coal tar or petroleum, not restricted
PAIL(s)/CAN(s)
Shipping Name Resin, coal tar or petroleum, not restricted
15. REGULATORY INFORMATION
U.S. - CAA (Clean Air Act) - 1990 Hazardous Air Pollutants
FORMALDEHYDE 50-00-0 Present
PHENOL 108-95-2 Present
U.S. - CAA (Clean Air Act) - Accidental Release Prevention - Toxic Substances
FORMALDEHYDE 50-00-0 15000 lbs threshold quantity (Solution)
U.S. - CAA (Clean Air Act) - HON Rule - Organic HAPs
FORMALDEHYDE 50-00-0 Present
PHENOL 108-95-2 Present
U.S. - CAA (Clean Air Act) - HON Rule - SOCMI Chemicals
FORMALDEHYDE 50-00-0 Group I
PHENOL 108-95-2 Group III
U.S. - CAA (Clean Air Act) - Volatile Organic Compounds (VOCs) in SOCMI
FORMALDEHYDE 50-00-0 Present
PHENOL 108-95-2 Present
OSHA Materials that May be Capable of Release (29 CFR 1910.1200(d)(5)(i)(iv))
Depending on the concentrations that may be released from this material, vapors may be heavier than air, may concentrate; and may travel along
the ground to some source of ignition including static electricity. The composite potential health hazards of the substance(s) marked as capable
of release include: potential cancer hazard eye burns skin burns toxic by inhalation harmful if absorbed thru skin harmful if
swallowed lung irritant has tested positive as a mutagen may cause reproductive system effects may affect the liver may affect the
kidneys may cause respiratory sensitization may cause skin sensitization may effect the nervous system may cause blood chemistry
changes may affect mucous membranes may cause allergic response may cause gastrointestinal disturbances may affect the heart
may affect the female's reproductive capabilities may effect the endocrine system may alter the body's biochemistry may affect muscular
response may affect the urinary tract
Superfund Amendments & Reauthorization Act of 1986
This material may be applicable to the SARA regulations. Thus, it may require you to file appropriate governmental reports if the total amount of
this material, or any of the listed constituents, in your possession ever exceeds the regulations' threshold values.
U.S. - CERCLA/SARA - Section 302 Extremely Hazardous Substances TPQs
FORMALDEHYDE 50-00-0 500 lb TPQ
PHENOL 108-95-2 500 lb lower threshold TPQ; 10000 lb upper threshold TPQ
U.S. - CERCLA/SARA - Section 313 - Emission Reporting
FORMALDEHYDE 50-00-0 0.1 % de minimis concentration
PHENOL 108-95-2 1.0 % de minimis concentration
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U.S. - California - 8 CCR Section 339 - Director's List of Hazardous Substances
FORMALDEHYDE 50-00-0 Present
PHENOL 108-95-2 Present
U.S. - California - Proposition 65 - Carcinogens List
FORMALDEHYDE 50-00-0 carcinogen, initial date 1/1/88 (gas)
U.S. - California - Proposition 65 - No Significant Risk Levels (NSRL)
FORMALDEHYDE 50-00-0 40 碌g/day NSRL
U.S. - New Jersey - Environmental Hazardous Substances List
FORMALDEHYDE 50-00-0 SN 0946 TPQ 500 lb
PHENOL 108-95-2 SN 1487 TPQ 500 lb
U.S. - New Jersey - Right to Know Hazardous Substance List
FORMALDEHYDE 50-00-0 sn 0946
PHENOL 108-95-2 sn 1487
U.S. - New Jersey - Special Health Hazards Substances List
FORMALDEHYDE 50-00-0 carcinogen; mutagen
PHENOL 108-95-2 mutagen
Canada - 2005 NPRI (National Pollutant Release Inventory)
FORMALDEHYDE 50-00-0 Part 1, Group 1 Substance; Part 5 Substance
PHENOL 108-95-2 Part 1, Group 1 Substance
Canada - WHMIS - Ingredient Disclosure List
FORMALDEHYDE 50-00-0 0.1 %
PHENOL 108-95-2 1%
WHMIS Ratings D2A, D2B
European Classifications
This substance is considered hazardous per The Safety Data Sheets Directive (91/155/EC) as amended
EU Risk Phrases
Irritating to eyes, respiratory system and skin.
R36/37/38
May cause sensitization by skin contact.
R43
Possible risk of irreversible effects.
R68
EU Safety Phrases
Avoid contact with skin and eyes.
S24/25
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S26
Wear suitable protective clothing, gloves and eye/face protection.
S36/37/39
In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
S45
EU Symbol(s)
Xn - Harmful
16. OTHER INFORMATION
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Disclaimer
The health and safety information is that available to SI Group as of the date published and SI Group makes no representation of the
information's completeness or accuracy. Any data provided is based on either: reference sources, testing performed on a representative
sample(s), or professional judgement. The physical data should not be construed as either representing specifications or a guaranteed
analysis. This material has been classified in accordance with the hazard criteria of the Controlled Products Regulation and the MSDS
contains information required by Controlled Products Regulation. SI Group provides its MSDS in several languages using English as the
primary language. While SI Group uses reasonable efforts to provide accurate translations, SI Group assumes no liability, or
responsibility, for errors, omissions or ambiguities in any translations. SI Group expects those persons who receive this MSDS to exercise
their independent professional judgement, or consult with a competent health/safety professional, to determine how to utilize this
material safely. This includes, but is not exclusive to, the material's appropriateness for a specific use, the type of personal protection
equipment necessary, and the use of engineering controls. In no event is SI Group liable for any damages whatsoever arising out of
your use of this material based upon information obtained from this MSDS including: direct, indirect, incidental, consequential or punitive
claims or damages.
Completed On 1/3/2008 Replaces Sheet Dated 12/4/2007
Completed By HGW
MSDS Sections Updated:
Accidental Release, Spill, Leak Procedures: Clean-Up Procedures
Disposal Considerations: U.S. EPA Waste Number Instructions
Ecological Information: Environmental Fate
Ecological Information: Persistence and Degradability
First Aid Measures: Notes to Physician
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