ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa
MATERIAL SAFETY DATA SHEET
DECIBAN庐 25EC
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
1. PRODUCT IDENTIFICATION
庐
Product Name: DECIBAN 25EC
Pyrethroid Insecticide
Chemical Class:
Use: Deciban 25EC is an insecticide based on the synthetic-pyrethroid
Deltamethrin. It is used as a contact and stomach-poison
insecticide for the control of sucking, chewing and boring
insects in a number of crops
Producer: Astra Industrial Complex Co., Ltd.
P.O. Box 30447, Al-Khobar 31952
Kingdom of Saudi Arabia
Emergency Tel # (+966) 3 8121 406
2. COMPOSITION / INFORMATION ON INGREDIENTS
Proportions
Substance (% w/w) Chemical structure
Deltamethrin technical 98% Br
2.86
CAS No. 52918-63-5 CN
C CH
(25 卤 4 g/L) CH3 CO2
C O
Chemical Name: (S)-伪-cyano-3- Br H H
H
phenoxybenzyl (1R,3R)-3-(2,2-dibromovinyl)-
2,2-dimethylcyclopropanecarboxylate CH3
(IUPAC)
6.73
Blend of anionic and nonionic emulsifiers
90.41
Organic solvents
MSDS: DECIBAN庐 25EC / INSECTICIDE 1/6
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa
3. HAZARD IDENTIFICATION
Signs of Poisoning:
Symptoms of acute exposure include severe headaches,
fatigue, nausea and anorexia. Severe cases of direct contact
cause blurred vision, tightness in chest and convulsions.
Primary Routes of Entry:
Skin contact and absorption and vapor mist inhalation.
Effects of single over exposures:
Ingestion:
Accidental or deliberate ingestion could cause neurological
signs and symptoms such as ataxia and convulsions.
Skin Absorption:
May be cause irritation and facial skin sensations.
Inhalation:
May be cause irritation to the respiratory system.
Eyes:
May be cause eye irritation.
4. FIRST AID MEASURES
Emergency and First aid Procedures
Ingestion:
Call a physician or poison control center. Do not induce
vomiting. Do not give anything by mouth to an unconscious
person.
Skin:
Wash affected area with plenty of soap and water. Remove
contaminated clothing. Launder contaminated clothing
separately. Get medical attention.
Inhalation:
Remove victim to fresh air. If not breathing administer artificial
respiration. Avoid unprotected mouth to mouth resuscitation.
GET MEDICAL ATTENTION.
Eye:
Hold eyelids open and flush with a steady stream of water forat
least 15 minutes. GET MEDICAL ATTENTION.
MSDS: DECIBAN庐 25EC / INSECTICIDE 2/6
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa
Note to Physician:
There is no specific antidote. Treat symptomatically. If
convulsions occur, diazepam (10 or 20 mg for an adult) should
be given slowly, intravenously or rectally and repeated if
necessary.
5. FIRE FIGHTING MEASURES
Fire and Explosion:
43.6 掳C
Flash point
COMBUSTIBLE
Flammable limits in air:
Not determined.
Auto ignition Temperature:
Not determined.
Extinguishing Media:
Use carbon dioxide or dry chemical for small fires and water fog
or foam (alcohol, polymer or ordinary) for large fires. Cool
containers from maximum distance.
Unusual fire and explosion hazards:
Noxious fumes may be emitted under fire conditions.
Special fire fighting procedures:
Fire fighters should use self contained breathing apparatus and
full turnout gear. Prevent runoff of fire water. Avoid exposure to
smoke. (Keep upwind).
6. ACCIDENTAL RELEASE MEASURES
Steps to be taken if material is released or spilled:
Dike the area using absorbent materials such as sand or clay.
Recover and contain as much product as possible using
absorbent. Clean spill area using a solution of water and
detergent. Collect and contain wash water and all contaminated
absorbent for disposal. If spilled on the ground, the affected area
should be excavated to a depth of 1-2 inches. Prevent the
spilled product or washing from reaching public sewers or
waterways. Wear appropriate protective equipment during the
cleanup. Ensure that tools and equipment are adequately
decontaminated.
MSDS: DECIBAN庐 25EC / INSECTICIDE 3/6
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa
Waste disposal method:
Dispose of in accordance with local regulations.
Container disposal:
Dispose of in an approved facility according to local regulations.
7. HANDLING AND STORAGE
Store the product in a well-ventilated, secure area out of reach
of children and domestic animals. Do not use or store near heat
or open flame. Do not store food or feed in storage area.
Prevent eating, drinking or smoking in areas where there is a
potential exposure to the product. Wash hands before eating,
drinking or smoking after using the product.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Protective equipment should be used during the following procedures:
鈥? Manufacture, formulation or application of this product.
鈥? Repair and maintenance of contaminated equipment
鈥? Clear up of leaks and spills.
鈥? Any other activity that may result in hazardous exposures.
Respiratory Protection:
Use MSHA/NIOSH approved respirator for organic vapors. Use
positive pressure contained breathing apparatus where
emergency conditions or where exposure limits are exceeded.
Ventilation:
Exhaust appropriate for removal of vapors.
Protective clothing:
Chemical resistant gloves, coveralls, apron and foot coverings.
Eye Protection:
Safety goggles or face shield.
User safety recommendations:
Safety showers and eye wash should be easily accessible.
MSDS: DECIBAN庐 25EC / INSECTICIDE 4/6
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa
Personnel Protection:
May irritate the eyes and skin. Avoid contact with eyes and skin.
DO NOT inhale spray mist. When preparing spray and using the
prepared spray, wear cotton overalls buttoned to the neck and
wrist and washable hat, elbow-length PVC gloves and face
shied. After use and before eating drinking or smoking, wash
hands, arms and face thoroughly with soap and water. After
each day鈥檚 use, wash gloves, face shield and contaminated
clothing.
9. PHYSICAL AND CHEMICAL PROPERTIES
Assay "Deltamethrin" 25 卤 4 g/L
Appearance Clear Yellow Liquid free of visible
impurities
Odour Aromatic
Density (Kg/L) 0.893 卤 0.006
Acidity (g/Kg) as H2SO4 <0.5
Water Contents (g/Kg) <0.5
Flammability Flammable
>37oC
Flash Point
Explosivity Not Explosive
Corrosivity Corrosive to Iron
10. STABILITY AND REACTIVITY
Stability: Stable under normal conditions.
Condition to avoid: Excessive heat.
Materials to avoid: Strong oxidizers, acids, and alkalis.
Hazardous polymerization: will not occur
Emulsion Stability
Initial Emulsification Complete
Emulsion Stability (2 h) 1.0 ml Cream + 0.25 ml oil
Re-emulsification (24 h) Complete
Emulsion Stability (24.5 h) 1.0 ml Cream + 0.25 ml oil
Heat Stability (2 weeks @ 54oC) Passed
Cold Stability Passed
MSDS: DECIBAN庐 25EC / INSECTICIDE 5/6
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa
TOXICOLOGICAL INFORMATION
11.
Toxicology Data:
Acute Oral LD50 (rat) 431 mg/kg
2.69 mg/m3
Acute Inhalation LC50 (4 h rat)
Eye Irritation (rabbit) May cause irreversible eye
damage
Dermal Irritation (rabbit) Irritating to skin, may cause
facial skin sensations
Carcinogenicity, Teratogenicity Mutagenicity:
Deltamethrin is not carcinogenic. It did not show any mutagenic
or chromosome damaging activity. It is also not teratogenic to
mice and rabbits.
12. ECOLOGICAL INFORMATION
Keep out of water supplies ground water or open water. This
product is toxic to bees, fish and other aquatic life.
13. DISPOSAL CONSIDERATION
Pesticide wastes are toxic. Do not reuse product containers.
Dispose of product containers, waste containers and residues
according to local health and environmental regulations.
14. TRANSPORT INFORMATION
Proper Shipping Name Environmentally hazardous
substances, Pyrethyroid Pesticide,
Liquid, toxic
(Deltamethrin)
UN Number UN No 3351
Class 6.1
Packing Group III
Marine Pollutant Yes
REGULATORY INFORMATION.
15.
Pest Control Product
16. OTHER INFORMATION
Buyer assumes all responsibility for safety and use not in
accordance with the product label instructions.
MSDS: DECIBAN庐 25EC / INSECTICIDE 6/6
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