ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa
MATERIAL SAFETY DATA SHEET
庐
DRAGOCOMBI 500EC
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
1. PRODUCT IDENTIFICATION
DRAGOCOMBI庐 500EC
Product Name:
Chemical Class: Organophosphorus insecticide
USE: DRAGOCOMBI 500EC is an Insecticide Emulsifiable Concentrate formulation based on two
organophosphorus active ingredients, Dimethoate and Chlorpyrifos. It is
uses as a systemic insecticide and acaricide with contact and stomach
action to control a wide range of pests including: aphids, mites, grass-
hoppers, white flies, scale; thrips, Leafminers and many others in cereals,
citrus, cotton, grapes, vegetables, potatoes and other crops.
Producer: Astra Industrial Complex Co., Ltd.
P.O. Box 30447, Al-Khobar 31952
Kingdom of Saudi Arabia
Emergency Tel.# (+966) 3 8121 406
2. COMPOSITION / INFORMATION ON INGREDIENTS
Substance Contents (g / L) Chemical structure
Diamethoate S
IUPAC Name. O,O-dimethyl S-methylcarbamoyl- 226.53 CH3NHCOCH2SP(OCH3)2
methyl phosphorodithioate; 2-
(pure 222)
dimethoxyphosphinothioylthio-N-methylacetamide
CAS No.60-51-5
Chlorpyrifos S
IUPAC Name: O, O-diethyl O-3,5,6-trichloro-2-pyridyl
OP(OCH2CH3)2
Cl N
283.69
phosphorothioate
(pure 278)
CAS No. 2921-88-2
Cl Cl
Organic solvents 60.00
Formulation aids 522.66
MSDS: DRAGOCOMBI 庐500EC / Insecticide 1/6
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa
3. HAZARD IDENTIFICATION.
ACUTE EFFECTS
Swallowed:
The concentrate is considered harmful if swallowed. It will induce
cholinesterase inhibition if swallowed in sufficient quantity.
Physical hazards:
None
Health hazards:
Inhalation:
Inhalation of solvent may cause headache, nausea, and intoxication.
Inhalation of spray mists may cause effects due to Dimethoate and
Chlorpyrifos, such as cholinesterase inhibition.
Eye:
Will produce mild irritation with the possibility of some injury.
Skin:
The product may cause skin and eye irritation. The active ingredient is
readily absorbed through the skin and eyes. Prolonged or repeated
exposure may cause defatting of skin, which could lead to secondary
dermatitis from the action of the solvent and surface-active agents.
4. FIRST AID MEASURES
First Aid:
Swallowed:
If poisoning occurs, contact a doctor or Poisons Information Center. Do not
give fluids or induce vomiting to a person who is unconscious of having
convulsions.
If swallowed give one atropine tablet every 5 minutes until dryness of the
mouth occurs. Get to a doctor or hospital quickly.
Eye:
Irrigate for 15 minutes with copious quantities of water with eyelids held
open. Seek medical advice.
MSDS: DRAGOCOMBI 庐500EC / Insecticide 2/6
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa
Skin:
Never give fluids by mouth to a person who is unconscious or having
convulsions. Remove contaminated clothing and launder before re-use.
Wash affected area thoroughly with soap and water. If poisoned by skin
absorption give one atropine tablet every 5 minutes until dryness of the
mouth occurs. Seek medical advice. Get to a doctor or hospital promptly.
Inhalation:
Remove to fresh air until recovered if poisoned by absorption through the
lungs give one atropine tablet every 5 minutes until dryness of the mouth
occurs. Get to a doctor or hospital promptly.
Advice to doctor:
Cholinesterase inhibitor. Atropine treatment may be necessary along with
1 g IV Pralidoxime for profound weakness or muscle twitching-curare
therapy is contraindicated. Do not give adrenergic amines, aminophylline,
succinylcholine, phenothiazines, or reserpine alkaloids or oils. Treat
pulmonary pneumonitis and bronchopneumonia secondary to pulmonary
oedema.
5. FIRE FIGHTING MEASURES
Extinguishing Media:
Alcohol鈥? foam, water fog, dry chemical, carbon dioxide
Fire and Explosion Hazards:
Flash point: 38.0 掳C
Fire Fighting Instructions:
Product will burn readily. Will emit toxic fumes of dimethyl sulfide, methyl
mercaptans, carbon monxide, carbon dioxide, phosphorous pentoxide and
nitrogen oxides if involved in fires or exposed to extreme heat. Breathable
air apparatus may have to be worn in confined spaces.
MSDS: DRAGOCOMBI 庐500EC / Insecticide 3/6
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa
6. ACCIDENTAL RELEASE MEASURES
Contain spill and absorb with sand or proprietary absorbent (vermiculute).
Prevent from entering drains, waterway or sewers. Collect in sealed open
top containers for disposal. Treatment with alkaline materials such as
dilute lime will decompose the active ingredient(s). At pH 9, 50% of
dimethoate will decompose in 12 days at average temperatures.
Disposal:
Triple rinse containers, add rinsate to the spray tank, then offer container
for recycling/reconditioning, or puncture top, sides and bottom and dispose
of in landfill in accordance with local regulations. On-site disposal of
concentrate is not acceptable.
Waste disposal by industrial incineration or burial at a site approved by
local authorities.
7. HANDLING AND STORAGE
Caution:
May be harmful if swallowed, inhaled or absorbed through the skin. Avoid
breathing spray mist. Avoid contact with skin, eyes or clothing.
Store in the closed, original container in a well ventilated are away from
children, animals, food, feedstuffs, seed and fertilizers. Classified as a
dangerous good for transport by road, rail, sea or air.
8. EXPOSURE CONTROLS / PERSONNAL PROTECTION.
Engineering Controls:
Natural ventilation only required when handling the concentrate. A local
exhaust should be used in confined areas to keep the level of solvent
within acceptable limits.
Personnel Protection:
Eye Protection: Safety glasses or goggles.
Clothing: Long sleeved shirt and long pants, shoes with socks.
Gloves: Chemical resistant gloves.
Respirator: All pesticide handlers must wear a respiratory protection
device when working.
MSDS: DRAGOCOMBI 庐500EC / Insecticide 4/6
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa
User Safety Recommendations:
Wash hands before eating, drinking, chewing gum, using tobacco or using
the toilet. Remove clothing immediately if pesticide gets inside. Then
wash throughly and put on clean clothing.
9. PHYSICAL AND CHEMICAL PROPERTIES.
278 卤 13.9 g / L
Assay: Chlorpyrifos
222 卤 11.1 g /L
Dimethoate
Appearance: Clear, light brown liquid.
Odour: Characteristic
Density: 1.080 - 1.100. Kg/L
Acidity as H2 SO4: 0.5% (w/w) max
38 掳C
Flash point:
Water content: <0.2% w/w
Solubility in water: Emulsifiable.
10. STABILITY AND REACTIVITY
Stability:
Stable under room temperature.
Incompatibility:
Strong oxidizing agents. Acids and alkaline materials.
Hazardous Polymerization:
Hazardous demposition only expected when material when material
involved in fires or subjected to extreme heat
Conditions to avoid:
Keep away from heat. Keep away from sources of ignition, No smoking.
11. TOXICOLOGICAL INFORMATION
Formulation:
Acute oral LD50 (rat): >600 mg/Kg
Technical:
Acute oral LD50 (rat) Chlorpyrifos: 150 mg/Kg
Acute oral LD50 (rat) Dimethoate: 387 mg/Kg.
MSDS: DRAGOCOMBI 庐500EC / Insecticide 5/6
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa
12. ECOLOGICAL INFORMATION.
Keep out of water supplies ground water or open water. This product is
toxic to bees, fish and wildlife including birds and waterfowl.
Do not apply this product or allow it to drift to blooming crops or weeds if
bees are visiting the treatment area.
13. DISPOSAL CONSIDERATION
Disposal Methods:
Pesticide wastes are toxic. Do not reuse product containers. Dispose of
product containers, waste containers and residues according to local
health and environmental regulations.
Container Disposal:
Empty container retains product residue. Triple rinse empty containers,
return rinse water to dilution mixture, and dispose of dilution mixture as a
hazardous waste if it cannot be disposed of by use according to label
instructions. Do not reuse container. Offer if for recycling or
reconditioning, or puncture and dispose of in properly permitted landfill.
14. TRANSPORT INFORMATION
Proper Shipping Name: Organophosphurus liquid pesticide
UN number UN3017
Class 6.1
Packing Group III
Marine Pollutant Yes
15. REGULATORY INFORMATION.
SARA title III classification:
Section 302/304
Section 311/212
16. OTHER INFORMATION.
Buyer assumes all responsibility for safety and use not in accordance with
the product label instructions.
MSDS: DRAGOCOMBI 庐500EC / Insecticide 6/6
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