ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM SAUDI ARABIA
OF
www.astra-agri.com.sa
MATERIAL SAFETY DATA SHEET
KLASH SUPER
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
1. PRODUCT IDENTIFICATION
KLASH super
Product Name:
Chemical Class: Pyrethroid Insecticide
Use: KLASH SUPER 170ULV is used as an Insecticide for the control of
insect pests in Public health programs.
Producer: Astra Industrial Complex Co., Ltd.
P.O. Box 30447, Al-Khobar 31952
Kingdom of Saudi Arabia
Emergency Tel.# (+966) 3 8121 406
2. COMPOSITION / INFORMATION ON INGREDIENTS
Proportions
Substance (% w/w) Chemical structure
S-bioallethrin CH3
CH3
CAS No. 28434-00-6 H
CO2 CH2CH=CH2
Chemical Name (S)-3-allyl-2-methyl-4- CH3
0.56 H
oxocyclopent-2-enyl (1R,3R)-2,2-dimethyl-3- C CH
CH3
(2-methylprop-1- O
CH3
enyl)cyclopropanecarboxylate (IUPAC)
Deltamethrin Br
CAS No. 7696-12-0 CN
C CH CH3 CO2
C O
Br
1.60
Chemical Name: (S)-伪-cyano-3-phenoxybenzyl HH
H
(1R,3R)-3-(2,2-dibromovinyl)-2,2- CH3
dimethylcyclopropanecarboxylate (IUPAC)
Piperonyl Butoxide CH3(CH2)3OCH2CH2OCH2CH2OCH2 O
CAS No. 51-03-6
Chemical Name: 5-[2-(2- O
CH3(CH2)2
16.45
butoxyethoxy)ethoxymethyl]-6-propyl-1,3-
benzodioxole; 2-(2-butoxyethoxy)ethyl 6-
propylpiperonyl ether (IUPAC)
81.39
Organic solvents
KLASH SUPER 170ULV /
MSDS: Public Health Insecticide 1/6
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM SAUDI ARABIA
OF
www.astra-agri.com.sa
3. HAZARD IDENTIFICATION
ACUTE EFFECTS
Physical hazards:
None
Health hazards:
Inhalation: Vapour or spray mist may be harmful if inhaled
Eye: Mild irritating to the eyes
Skin: Prolonged or repeated skin contact may cause
irritation or sensitization
Ingestion: May be harmful if swallowed.
4. FIRST AID MEASURES
First Aid:
Swallowed:
Provided the patient is conscious, wash out mouth with water.
Do not induce vomiting should only be induced under the
direction of a physician. If spontaneous vomiting occurs, have
victim lean forward with head down to avoid breathing in of
vomits. Immediately transport victim to an emergency facility
Eye:
Irrigate for 20 minutes with copious quantities of water with
eyelids held open. If irritation persists, repeat flushing. Seek
medical attention immediately.
Skin:
Remove contaminated clothing. Flush skin with running water
for a minimum of 20 minutes. If swelling, redness, blistering or
irritation occurs seek medical attention immediately.
Inhalation:
Remove victim to fresh air. If not breathing, give artificial
respiration preferably mouth-to-mouth. If breathing is labored,
give oxygen. Obtain immediate medical attention.
Advice to doctor:
This product contains materials that may cause severe
pneumonitis if aspirated. If ingestion has occurred less than 2
hours earlier, carry out careful gastric lavage; use endotracheal
cuff if available, to prevent aspiration. Observe patient for
respiratory difficulty from aspiration pneumonitis. Give artificial
resuscitation and appropriate chemotherapy if respiration is
depressed. Symptomatic treatment and supportive therapy as
indicated.
KLASH SUPER 170ULV /
MSDS: Public Health Insecticide 2/6
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM SAUDI ARABIA
OF
www.astra-agri.com.sa
5. FIRE FIGHTING MEASURES
Fire and Explosion Hazards:
Flash Point: 46oC
Combustible liquid. Keep fire exposed containers cool by
spraying with water.
Extinguishing Media:
For small fires, use foam, carbon dioxide or dry powder
extinguishant. For large fires, use foam or water-fog; avoid use
of water jet. Contain run-off water with for example, temporary
earth barriers.
Fire Fighting Instructions:
Evacuate area and fight fire upwind from a safe distance to
avoid hazardous vapors and decomposition products. Fire
exposed containers can build up pressure and should be kept
cool with water spray if possible. Explosive vapor could form
from ruptured containers. Dike and collect water used to fight fire
to prevent environmental damage due to run off. Foam or dry
chemical fire extinguishing systems is preferred to prevent
environmental damage from excessive water run off.
Fire Fighting Equipment:
A self-contained breathing apparatus with full face-piece
6. ACCIDENTAL RELEASE MEASURES
Contain spill and absorb with sand or proprietary absorbent
(vermiculite). Prevent from entering drains, waterway or sewers.
Collect in sealed open top containers for disposal. Generously
cover the contaminated areas with common, household
detergent brush in a small amounts of water, work the detergent
into the remaining spilled material forming slurry. Collect slurry in
sealed open top container for disposal. This material is water
pollutant and should be prevented from drainage systems and
bodies of water.
Disposal:
Triple rinse containers, add rinsate to the spray tank, then offer
container for recycling/reconditioning, or puncture top, sides and
bottom and dispose of in landfill in accordance with local
regulations. On-site disposal of concentrate is not acceptable.
Wastes disposal should be carried out by industrial incineration
or burial at a site approved by local authorities.
KLASH SUPER 170ULV /
MSDS: Public Health Insecticide 3/6
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM SAUDI ARABIA
OF
www.astra-agri.com.sa
7. HANDLING AND STORAGE
Keep out of Reach of Children.
Use only in a well-ventilated area. Do not reuse empty
containers. Keep the container closed when not in use. Keep
away from food, feed and drinking water. Store in a well-
ventilated, dry place away from heat and other sources of
ignition. Keep away from freezing.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering Controls:
Natural ventilation only required when handling the concentrate.
A local exhaust should be used in confined areas to keep the
level of solvent within acceptable limits.
Personnel Protection:
Eye Protection Safety glasses or goggles
Clothing Long sleeved shirt and long pants,
shoes plus socks.
Gloves Chemical resistant gloves
Respirator All pesticide handlers must wear a
respiratory protection device when
working.
User Safety Recommendations:
Wash hands before eating, drinking, chewing gum, using
tobacco or using the toilet. Remove clothing if pesticide gets
inside. Then wash throughly and put on clean clothing.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance Clear, yellow liquid free of visible impurities.
Odour Aromatic
Density 0.9415 Kg/L
Flash point 46掳C
Solubility in water Not soluble
KLASH SUPER 170ULV /
MSDS: Public Health Insecticide 4/6
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM SAUDI ARABIA
OF
www.astra-agri.com.sa
10. STABILITY AND REACTIVITY
Stability:
Stable at room temperature.
Incompatibility:
Strong oxidizing agents. Acids and alkaline materials
Hazardous polymerization:
Will not occur.
Conditions to avoid:
Keep away from heat. Keep away from sources of ignition 鈥? No
smoking.
Hazardous Decomposition Products:
Thermal decomposition products are toxic and may include
hydrocarbons ammonia, organic and acid halides, Oxides of
carbon, nitrogen and Sulphur.
11. TOXICOLOGICAL INFORMATION
Klash Super 170ULV:
LD50 Oral rat 7,273 mg/Kg
Active Ingredient:
LD50 Oral rat (Deltamethrin) 135 mg/Kg
LD50 Oral rat (S-bioallethrin) 784 mg/Kg
LD50 Oral rat (PBO) 7, 500 mg/Kg
12. ECOLOGICAL INFORMATION
Keep out of water supplies ground water or open water. This
very toxic to aquatic organisms..
Do not applay this product or allow it to drift to blooming crops or
weeds if bees are visiting the treatment area.
13. DISPOSAL CONSIDERATION
Disposal Method:
Do not contaminate ponds, waterways or ditches with chemical
or used containers. Dispose of in facility permitted for
hazardous waste.
KLASH SUPER 170ULV /
MSDS: Public Health Insecticide 5/6
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM SAUDI ARABIA
OF
www.astra-agri.com.sa
Container Disposal:
Empty container retains product residue. Triple rinse empty
container, return rinse water to dilution mixture, and dispose of
dilution mixture as a hazardous waste if it cannot be disposed of
by use according to label instructions. Do not reuse container.
Offer if for recycling or reconditioning, or puncture and dispose
of in properly permitted landfill.
14. TRANSPORT INFORMATION
Proper Shipping Name Insecticide, Liquid, Toxic, Flammable
UN number 3082
Class 6.1
Packing Group III
Marine Pollutant
15. REGULATORY INFORMATION.
Public Health Pest Control Product
16. OTHER INFORMATION
Buyer assumes all responsibility for safety and use not in
accordance with the product label instructions.
KLASH SUPER 170ULV /
MSDS: Public Health Insecticide 6/6
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