ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM SAUDI ARABIA
OF
www.astra-agri.com.sa
MATERIAL SAFETY DATA SHEET
庐
LAMDOC 50EC
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
1. PRODUCT IDENTIFICATION
LAMDOC庐 50EC
Product Name:
Chemical Class: Pyrethroid Insecticide
Use: Lamdoc 50EC is used for the control of a wide spectrum of insect
pests, e.g. aphids, beetles, thrips, Lepidoptera larvae,
Coleoptera larvae and adults, etc., in cereals,
ornamentals, potatoes, vegetables and other crops.
Producer: Astra Industrial Complex Co., Ltd.
P.O. Box 30447, Al-Khobar 31952
Kingdom of Saudi Arabia
Emergency Tel # (+966) 3 8121 406
2. COMPOSITION / INFORMATION ON INGREDIENTS
Proportions
Substance (% w/w) Chemical structure
Lambda-Cyhalothrin 90 Technical 6.16 (S) (Z)-(1R)-cis -
F3C
(50 卤 3 g/L)
CAS No. 91465-08-6 C CH CH3 C O2 CN
Chemical Name: A reaction product C O
Cl
HH
H
comprising equal quantities of (S)-伪-
cyano-3-phenoxybenzyl (Z)-(1R,3R)-3- CH3
(2-chloro-3,3,3-trifluoroprop-1-enyl)-2,2-
CH3 H
dimethylcyclopropanecarboxylate and H
Cl
(R)-伪-cyano-3-phenoxybenzyl (Z)-
CN
C O2
(1S,3S)-3-(2-chloro-3,3,3-trifluoroprop-1- C CH
C O
enyl)-2,2- CH3
F3C
H
dimethylcyclopropanecarboxylate
(IUPAC). (R) (Z)-(1S)-cis -
Blend of ionic and non ionic emulsifiers 6.66
87.18
Organic solvents
LAMDOC庐 50EC / Insecticide
MSDS: 1/7
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM SAUDI ARABIA
OF
www.astra-agri.com.sa
3. HAZARD IDENTIFICATION
Physical hazards:
None
Acute Hazard Symptoms:
Inhalation: Burning sensation. Convulsions. Cough. Laboured
breathing. Shortness of breath. Score throat.
Eye: Redness. Pain
Skin: Redness. Pain
Ingestion: Abdominal pain. Cough
Prevention:
Exposure: Prevent dispersion of dust! Strict Hygiene!
Inhalation: local exhaust, or breathing protection.
Eye: Safety spectacles.
Skin: Protective clothing.
Ingestion: Do not eat, drink, or smoke during work. Wash
hands before eating.
4. FIRST AID MEASURES
First Aid:
Exposure: In all cases consult a doctor!
Ingestion:
Do not induce vomiting. Provided the patient is conscious, wash
out mouth with water. Vomiting should only be induced under
the direction of a physician. If spontaneous vomiting occurs,
have victim lean forward with head down to avoid breathing in of
vomitus. Immediately transport victim to an emergency facility.
Eye:
First rinse with plenty of water for several minutes (remove
contact lenses if easily possible), then take to a doctor.
Skin:
Remove contaminated clothes. Rinse and then wash skin with
water and soap.
LAMDOC庐 50EC / Insecticide
MSDS: 2/7
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM SAUDI ARABIA
OF
www.astra-agri.com.sa
Inhalation:
Remove victim to fresh air, rest. If not breathing, give artificial
respiration preferably mouth-to-mouth. If breathing is labored,
give oxygen. Obtain immediate medical attention.
Advice to doctor:
This product contains materials that may cause pneumonitis if
aspirated. If ingestion has occurred less than 2 hours earlier,
carry out careful gastric lavage; use endotracheal cuff if
available, to prevent aspiration. Observe patient for respiratory
difficulty from aspiration pneumonitis. Give artificial resuscitation
and appropriate chemotherapy if respiration is depressed.
Symptomatic treatment and supportive therapy as indicated.
5. FIRE FIGHTING MEASURES
Extinguishing Media:
For small fires, use alcohol-resistant foam, dry sand, carbon
dioxide or dry powder extinguishant. For large fires, use foam or
water-fog, avoid use of water jet. Contain run-off water with for
example, temporary earth barriers.
Fire and Explosion Hazards:
Flash point: 43.0掳C
Combustible Liquid. Keep fire exposed containers cool by
spraying with water.
Fire Fighting Instructions:
Evacuate area and fight fire upwind from a safe distance to
avoid hazardous vapors and decomposition products. Fire
exposed containers can build up pressure and should be kept
cool with water spray if possible. Explosive vapor could form
from ruptured containers. Dike and collect water used to fight
fire to prevent environment damage due to run off. Foam or dry
chemical fire extinguishing systems are preferred to prevent
environmental damage from excessive water run off.
Self-contained breathing apparatus with full face - piece.
LAMDOC庐 50EC / Insecticide
MSDS: 3/7
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM SAUDI ARABIA
OF
www.astra-agri.com.sa
6. ACCIDENTAL RELEASE MEASURES
Contain spill and absorb with sand or proprietary absorbent
(vermiculite). Prevent from entering drains, waterway or sewers.
Collect in sealed open top containers for disposal. Generously
cover the contaminated areas with common, household
detergent brush in a small amount of water, work the detergent
into the remaining spilled material forming slurry. Collect slurry
in sealed open top container for disposal. This material is water
pollutant and should be prevented from drainage systems and
bodies of water.
Disposal:
Triple rinse containers, add rinsate to the spray tank, then offer
container for recycling/reconditioning, or puncture top, sides and
bottom and dispose of in landfill in accordance with local
regulations. On-site disposal of concentrate is not acceptable.
Waste disposal should be carried out by industrial incineration or
burial at a site approved by local authorities.
7. HANDLING AND STORAGE
Keep out of reach of Children:
Use only in a well-ventilated area. Do not reuse empty
containers. Keep the container closed when not in use. Keep
away from food, feed and drinking water. Keep in a well -
ventilated, dry place away from heat and other sources of
ignition. Keep from freezing.
8. EXPOSURE CONTROLS / PERSONNEL PROTECTION
Engineering Controls:
Natural ventilation only required when handling the concentrate.
A local exhaust should be used in confined areas to keep the
level of solvent within acceptable limits.
Personnel Protection:
Eyes Protection: Safety glasses or goggles.
Clothing: Long sleeved shirt and long pants, shoes and
socks.
LAMDOC庐 50EC / Insecticide
MSDS: 4/7
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM SAUDI ARABIA
OF
www.astra-agri.com.sa
Gloves: Chemical resistant gloves.
Respirator: All pesticide handlers must wear a respiratory
protection device when working.
User Safety Recommendations:
Wash hands before eating, drinking, chewing gum, using
tobacco or using the toilet. Remove clothing immediately if
pesticide gets inside. Then wash throughly and put on clean
clothing.
9. PHYSICAL AND CHEMICAL PROPERTIES
Assay "Lambda-Cyhalothrin" 50 卤 3 g/L
Appearance Clear, yellow liquid free of visible impurities.
Odour: Slightly aromatic.
Boiling Point: Not available.
Melting Point: Not applicable
Density 0.900 卤 0.006 Kg/L
Acidity as H2SO4 <0.5 g/ Kg
Flash point >40掳C
Water content <2.0 g / Kg
Solubility in water Form emulsion.
10. STABILITY AND REACTIVITY
Stability: Stable under room temperature.
Incompatibility: Strong oxidizing agents. Acids and alkaline
materials.
Hazardous Polymerization: Will not occur
Condition to avoid Keep away from heat. Keep away from
sources of ignition, No smoking.
Hazardous Decomposition Products:
Thermal decomposition products are toxic and may include
hydrocarbons ammonia, organic and acid halides, oxide of
carbon, nitrogen and sulfur.
LAMDOC庐 50EC / Insecticide
MSDS: 5/7
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM SAUDI ARABIA
OF
www.astra-agri.com.sa
11. TOXICOLOGICAL INFORMATION
Formulation:
LD50 oral for rat the product > 1,700 mg/Kg
Technical:
LD50 oral for rat for technical grade material used in the product:
Lambda-Cyhalothrin: 79 mg/Kg.
12. ECOLOGICAL INFORMATION
Keep out of water supplies ground water or open water. This
product is very toxic to aquatic organisms.
Do not apply this product or allow it to drift to blooming crops or
weeds if bees are visiting the treatment area.
13. DISPOSAL CONSIDERATION
Disposal Methods:
Do not contaminate ponds, waterways or ditches with chemical
or used containers. Dispose of in facility permitted for
hazardous waste.
Container Disposal:
Empty container retains product residue. Triple rinse empty
containers, return rinse water to dilution mixture, and dispose of
dilution mixture as a hazardous waste if it cannot be disposed of
by use according to label instructions. Do not reuse container.
Offer if for recycling or reconditioning, or puncture and dispose
of in properly permitted landfill.
LAMDOC庐 50EC / Insecticide
MSDS: 6/7
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM SAUDI ARABIA
OF
www.astra-agri.com.sa
14. TRANSPORT INFORMATION
Proper Shipping Name: Insecticide, Liquid; Toxic, Flammable
15. REGULATORY INFORMATION.
Insecticide for Agricultural Use
16. OTHER INFORMATION
Buyer assumes all responsibility for safety and use not in
accordance with the product label instructions.
LAMDOC庐 50EC / Insecticide
MSDS: 7/7
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