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MSDS Material Safety Data Sheet
CAS

121-75-5

File Name: astra-agri_com_sa---msds_mallet_570ec.asp
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa




MATERIAL SAFETY DATA SHEET

MALLET 570EC
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA

1. PRODUCT IDENTIFICATION

: MALLET 570 EC
Product Name
: Organophosphate Pesticide
Chemical Class

USE: MALLET 570EC Mallet 570 EC is use as a non-systemic insecticide and
acaricide with contact, stomach and respiratory action. It is used
to control a wide range of pests including: aphids, mites, grass-
hoppers, flies, scale; thrips, leaf miners loppers, pear psylla,
mealy bugs, bollworms, lice, ticks, ants, spiders and many others.
It is used in pome, soft and stone fruits, cotton, vegetables,
potatoes and rice.

Producer: Astra Industrial Complex Co. Ltd.
P.O. Box 30447, Al-Khobar 31952
Saudi Arabia
Emergency Tel.# (+966) 3 8121 406

2. COMPOSITION / INFORMATION ON INGREDIENTS

Proportions
Substance (% w/w) Chemical structure
Malathion Tech 58.35
(570 g / L) S
CAS No. 121-75-5
IUPAC Name: diethyl
(CH3O)2PS CHCH2CO2CH2CH3
(dimethoxythiophosphorylthio) succinate;
S-1,2-bis(ethoxycarbonyl)ethyl O,O- CO2CH2CH3
dimethyl phosphorodithioate


6.59
Formulation Aids
35.06
Organic solvents




3. HAZARD IDENTIFICATION
MALLET 570EC / PESTICIDE
MSDS: 1/6
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa




Acute Effects
Swallowed:
The concentrate is slightly toxic and considered harmful if swallowed.
Eye:
Moderately irritating to eye. Permanent eye injury is not expected.
Skin:
Slightly irritating to skin.
Inhalation:
Slightly toxic. Inhalation of excessive amount of spray may cause
cholinesterase inhibition.
Chronic effects:
Prolonged or repeated exposure may show adverse effects on the liver and
kidneys.
Other Health Hazard Information
Cholinesterase Inhibitor

4. FIRST AID MEASURES
First Aid:
Swallowed:
If poisoning occurs, contact a doctor. Do not give fluids or induce vomiting if
person is unconscious or having convulsions. If swallowed, give one
atropine tablet (0.6 mg) every 5 minutes until dryness of the mouth occurs.
Get affected person to a doctor or hospital promptly.
Eye:
Irrigate for 15 minutes with copious quantities of water with eyelids held
open. Seek medical advice.
Skin:
Remove contaminated clothing at once, was skin thoroughly with soap and
water. Obtain medical attention immediately.
Inhalation:
Remove to fresh air. Get to a doctor or hospital promptly.


First Aid Facilities:
Obtain an emergency supply of Atropine tablets (0.6 mg).


MALLET 570EC / PESTICIDE
MSDS: 2/6
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa




Advice to doctor:
A cholinesterase inhibitors. Atropine treatment may be required or treat with
up to 10 mg of IV diazepam 鈥? curare therapy is contraindicated. Treat
hydrocarbon pneumonitis secondary to pulmonary oedema. Do not give
adrenergic amines, aminophylline, succinylcholine, phenothiazines or
reserpine alkaloids or oils.

5. FIRE FIGHTING MEASURES
Toxic gases containing oxides of sulphur and phosphorous may be evolved if
involved in fires or exposed to extreme heat. Breathable air apparatus may be
required in confined area. Stay upwind.
Extinguishing Media:
Water fog, dry chemical, foam or carbon dioxide.
Special fire fighting procedures:
Fire fighters should use self contained breathing apparatus. Prevent runoff of fire
water. Avoid exposure to smoke.

6. ACCIDENTAL RELEASE MEASURES
Contain spill and absorb with sand or proprietary absorbent (vermiculite). Prevent
from entering drains, waterway or sewers. Collect in sealed open top containers
for disposal.
Disposal:
Triple rinse containers, add rinsate to the spray tank, then offer container for
recycling/reconditioning, or puncture top, sides and bottom and dispose of in
landfill in accordance with local regulations. On-site disposal of concentrate is not
acceptable.

7. HANDLING AND STORAGE
Keep out of reach of children, do not store with food, feed or other material to be
used or consumed by humans or animals. Do not contaminate water supplies,
lakes, streams, or ponds. Store in a secure, dry, well-ventilated area, segregated
from oxidizers and incompatible materials. Protect from moisture.




MALLET 570EC / PESTICIDE
MSDS: 3/6
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa




8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Standards:
Exposure standard for Malathion (maldison): 10 mg/m3 (TWA).
Engineering Controls:
Natural ventilation only required when handling the concentrate. A local exhaust
should be used in confined areas to keep the level of solvent within acceptable
limits.
Personnel Protection:
The concentrate is harmful; skin absorption is the most common route of
exposure. May be irritated the eyes and skin. Repeated minor exposure may have
cumulative effects. Avoid contact with the skin and eyes and avoid breathing the
vapor. Do not inhale the spray mist. When opening the container of concentrate
and preparing the spray, wear cotton overalls buttoned to the neck and wrist,
washable hat and elbow-length PVC gloves. When using in an enclosed area
wear face shield. If product spilled on skin wash affected area thoroughly with
soap and water. After use and before eating drinking or smoking, wash hands,
arms, face thoroughly with soap and water. After each day鈥檚 use, wash gloves,
face shield and contaminated clothing. Do not eat or smoke while spraying.

9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : Clear, light yellow liquid free of visible impurities.
Odour : Slightly aromatic
Boiling Point : 158-182 C for solvent
Melting point : <0 C
Density : 1.0698 Kg/L
Flash point : 45.5 C
Solubility in H2O : Emulsifiable
Other Properties:
Concentrate forms an emulsion with water.

10. STABILITY AND REACTIVITY
Stability : Stable
Conditions to avoid : Contact with iron and strong alkalis and storage above
50 C
Polymerization : Will not occur



MALLET 570EC / PESTICIDE
MSDS: 4/6
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa




Condition to avoid : None currently known
Incompatibility : Iron, strong alkalis and strong oxidizers
Hazardous : Thermal decomposition may produce isomalathion
Combustion : Hydrogen sulfide, sulfur, oxides of carbon and
phosphorus.

11. TOXICOLOGICAL INFORMATION
Technical Malathion:
Acute oral LD50 for rates : 1,375 鈥? 2,800 mg/Kg
Mice : 775 鈥? 3,321 mg/Kg
Cattle : 500 mg/Kg
Acute dermal LD50 for rabbits : 4,100 mg/Kg
Toxic to fish : Toxic to fish
LC50 for bluegill sunfish : 0.1mg/L
Toxicity to Bees : Toxic to bees
Toxicity to birds : Not acutely toxic to birds

12. ECOLOGICAL INFORMATION
Toxic to fish.
Dangerous to bees.
Do not spray and plants in flower while bees are foraging.
Do not contaminate dams, rivers or streams with pesticide or used container.
Do not use container for any other purpose.
Triple rinse containers with water and add rinsate to the spray solution. Puncture
top, bottom and sides of empty container, then crush and bury in an approved
landfill, or bury under at least 500 mm of soil in a non 鈥揷rop, non-pasture area
way from water sources or homes.
Malathion is rapidly biodegraded in soil and sewage treatment plants.

13. DISPOSAL CONSIDERATION
Pesticide wastes are toxic. Do not reuse product containers. Dispose of product
containers, waste containers and residues according to local health and
environmental regulations.




MALLET 570EC / PESTICIDE
MSDS: 5/6
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa




14. TRANSPORT INFORMATION

Proper Shipping Name: Organophosphorus pesticide, liquid, toxic,
flammable, flash point 鈮?23掳C (Malathion)
UN. No: UN 3017
Class: 6.1
Classification Code: TF2
Packing group: III
Subsidiary Risks: 6.1 + 3
Special provisions: 61
Limited quantities: LQ19
Packaging: Packing instructions P001, IBC03, R001
Special packing provisions
Mixed Packaging Provisions MP15
Instructions T7
UN Portable tanks Special Provisions TP2 TP28
Tank Code L4BH
ADR Tank Special Provision TU15 TE1 TE15 TE19
Vehicle for tank carriage FL
Transport Category 2
Special provision Packages
carriage Bulk
Loading, unloading & CV13 CV28
Handling
Operation S2 S9
Hazard Identification 63


15. REGULATORY INFORMATION
SARA, Title III section 313
Malathion (CAS: 121-75-5)
Section 311/312
Acute Health Hazard
Chronic Health Hazard

16. OTHER INFORMATION
Buyer assumes all responsibility for safety and use not in accordance with the
product label instructions.




MALLET 570EC / PESTICIDE
MSDS: 6/6

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