ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM SAUDI ARABIA
OF
www.astra-agri.com.sa
MATERIAL SAFETY DATA SHEET
庐
PERMENE PLUS
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
1. PRODUCT IDENTIFICATION
Product Name: PERMENE PLUS
Chemical Class: Pyrethroid Insecticide
Use: PERMENE PLUS is a public health insecticide, effective for the control of
a broad range of flying and crawling insects pests.
Producer: Astra Industrial Complex Co., Ltd.
P.O. Box 30447, Al-Khobar 31952
Kingdom of Saudi Arabia
Emergency Tel.# (+966) 3 8121 406
2. COMPOSITION / INFORMATION ON INGREDIENTS
Contents
Chemical structure (g / L)
Substance
9.0 -11.0
S-bioallethrin CH3
CH3
H
CAS No. 28434-00-6 CO2 CH2CH=CH2
Chemical Name (IUPAC): (S)-3-allyl-2-methyl-4- CH3
H
oxocyclopent-2-enyl (1R,3R)-2,2-dimethyl-3- C CH
(2-methylprop-1-enyl)cyclopropanecarboxylate CH3 O
CH3
90.0-100.0
Permethrin (Sis: trans ration 25:75) Cl CH3
CAS No. 7696-12-0 CO2 CH2 O
C CH
Cl
Chemical Name (IUPAC): 3-phenoxybenzyl
CH3
(1RS,3RS;1RS,3SR)-3-(2,2-dichlorovinyl)-2,2-
dimethylcyclopropanecarboxylate
99.0 -121.0
Piperonyl Butoxide
CAS No. 51-03-6
CH3(CH2)3OCH2CH2OCH2CH2OCH2
Chemical Name (IUPAC): 5-[2-(2- O
butoxyethoxy)ethoxymethyl]-6-propyl-1,3-
O
benzodioxole; 2-(2-butoxyethoxy)ethyl 6- CH3(CH2)2
propylpiperonyl ether
PERMENE PLUS庐 /
MSDS: Public Health Insecticide 1/6
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM SAUDI ARABIA
OF
www.astra-agri.com.sa
3. HAZARD IDENTIFICATION
ACUTE EFFECTS
Physical hazards:
Moderately combustible liquid
Health hazards: Irritating to eyes and skin
Inhalation: Vapour or spray mist may be harmful if inhaled
Eye: Mild irritating to the eyes
Skin: Prolonged or repeated skin contact may cause
irritation or sensitization
Ingestion: May be harmful if swallowed.
4. FIRST AID MEASURES
First Aid:
Swallowed:
Provided the patient is conscious, wash out mouth with water
and give 1 or 2 glasses of water to drink. Do not induce
vomiting. Immediately transport victim to an emergency facility
Eye:
Irrigate for 20 minutes with copious quantities of water with
eyelids held open. If irritation persists, repeat flushing. Seek
medical attention immediately.
Skin:
Remove contaminated clothing. Flush skin with running water
for a minimum of 20 minutes. If swelling, redness, blistering or
irritation occurs seek medical attention immediately.
Inhalation:
Remove victim to fresh air. If not breathing, give artificial
respiration preferably mouth-to-mouth. If breathing is labored,
give oxygen. Obtain immediate medical attention.
Advice to doctor:
This product contains materials that may cause severe
pneumonitis if aspirated. If ingestion has occurred less than 2
hours earlier, carry out careful gastric lavage; use endotracheal
cuff if available, to prevent aspiration. Observe patient for
respiratory difficulty from aspiration pneumonitis. Give artificial
resuscitation and appropriate chemotherapy if respiration is
depressed. Symptomatic treatment and supportive therapy as
indicated.
PERMENE PLUS庐 /
MSDS: Public Health Insecticide 2/6
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM SAUDI ARABIA
OF
www.astra-agri.com.sa
5. FIRE FIGHTING MEASURES
Fire and Explosion Hazards:
Flash Point: 42.5oC
Flammable
Keep fire exposed containers cool by spraying with water.
Extinguishing Media:
For small fires, use foam, carbon dioxide or dry powder
extinguishant. For large fires, use foam or water-fog; avoid use
of water jet. Contain run-off water with for example, temporary
earth barriers.
Protective Equipment:
A self contained breathing apparatus and suitable protective
clothing should be worn in fire conditions.
Unusual fire and explosion hazards:
Combustible liquid
6. ACCIDENTAL RELEASE MEASURES
Contain spill and absorb with sand or proprietary absorbent
(vermiculute). Prevent from entering drains, waterway or sewers.
Collect in sealed open top containers for disposal. Generously
cover the contaminated areas with common, household
detergent brush and small amounts of water, work the detergent
into the remaining spilled material forming slurry. Collect slurry in
sealed open top container for disposal.
Disposal:
Triple rinse containers, add rinsate to the spray tank, then offer
container for recycling/reconditioning, or puncture top, sides and
bottom and dispose of in landfill in accordance with local
regulations. On-site disposal of concentrate is not acceptable.
Wastes disposal by industrial incineration or burial at a site
approved by local authorities.
PERMENE PLUS庐 /
MSDS: Public Health Insecticide 3/6
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM SAUDI ARABIA
OF
www.astra-agri.com.sa
7. HANDLING AND STORAGE
Keep in original containers, tightly closed and locked up. Keep
out of the reach of children and away from food.
Avoid breathing vapors or spray mist. Use normal good industrial
hygiene and housekeeping practices.
Ideal storage temperature is 10-27掳C. Do not expose sealed
containers to temperature above 40掳C.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Standards:
For organic solvent.8 h, TWA, 150 mg/m3
Engineering Controls:
Natural ventilation only required when handling the concentrate.
A local exhaust should be used in confined areas to keep the
level of solvent within acceptable limits.
Personnel Protection:
Facial skin contact may cause temporary facial numbness.
Sensitive workers should use protective clothing. Avoid contact
with eyes and skin. Do not inhale spray mist. When preparing
spray wear cotton overalls buttoned to the neck and wrist and
washable hat, elbow-length PVC gloves and face shield or
goggles. After use and before eating, drinking or smoking wash
hands, arms and face thoroughly with soap and water. After
each day鈥檚 use, wash gloves, face shield or goggles and
contaminated clothing.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance Clear light yellow liquid free of visible impurities.
Odour Slightly Aromatic
Density 0.944 卤 0.006 g/ml
Flash point >40掳C
Acidity as H2SO4: <0.5 g/Kg
Water Content < 2.0 g/Kg
Solubility in H2O Emulsifiable
PERMENE PLUS庐 /
MSDS: Public Health Insecticide 4/6
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM SAUDI ARABIA
OF
www.astra-agri.com.sa
10. STABILITY AND REACTIVITY
Stability:
Stable at room temperature.
Incompatibility:
Strong Oxidiz Agents. Acids and alkaline materials
Hazardous polymerization:
Will not occur.
Conditions to avoid:
Keep away from heat. Keep away from sources of ignition 鈥? No
smoking.
Hazardous Decomposition Products:
Thermal decomposition products are toxic and may include
hydrocarbons ammonia, organic and acid halides, oxide of
carbon, nitrogen and Sulphur.
11. TOXICOLOGICAL INFORMATION
Formulation:
LD50 Oral rat >10,000 mg/Kg
Additional information:
May cause skin irritation. In humans may cause tingling or
numbness in exposed area (paraesthesia). The effect may result
from splash, aerosol or transfer to the face from contaminated
gloves and hands. This effect is transient, lasting up to 24 hours.
There is no evidence of any long term or cumulative effects
following repeated contamination Repeated and/or prolonged
contact may cause skin sensitization.
Inhalation
Additional Information High concentrations of this product
are irritating to the respiratory tract.
LC50 Inhalation rat: 6,850 mg / m3 (3 h)
General Information:
Slight skin and eye irritant (rabbits) May be weak skin sensitizer.
PERMENE PLUS庐 /
MSDS: Public Health Insecticide 5/6
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM SAUDI ARABIA
OF
www.astra-agri.com.sa
12. ECOLOGICAL INFORMATION
Keep out of water supplies ground water or open water. This
product is toxic to fish and wildlife.
Toxic to bees. Do not apply this product or allow it to drift to
blooming crops or weeds if bees are visiting the treatment area.
13. DISPOSAL CONSIDERATION
Disposal Method:
Do not contaminate ponds, waterways or ditches with chemical
or used containers. Dispose of in facility permitted for
hazardous waste.
Container Disposal:
Empty container retains product residue. Triple rinse or
equivalent, empty container, return rinse water to dilution
mixture, and dispose of dilution mixture as a hazardous waste if
it cannot be disposed of by use according to label instructions.
Do not reuse container. Offer if for recycling or reconditioning, or
puncture and dispose of in properly permitted landfill.
14. TRANSPORT INFORMATION
Proper Shipping Name PYRETHROID PESTICIDE, LIQUID,
TOXIC, FLAMMABLE, (Permethrin)
UN number UN3351
Class 6.1
Packing Group III
Marine Pollutant Yes
15. REGULATORY INFORMATION.
Public Health Pest Control Product
16. OTHER INFORMATION
Buyer assumes all responsibility for safety and use not in
accordance with the product label instructions.
PERMENE PLUS庐 /
MSDS: Public Health Insecticide 6/6
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