ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM SAUDI ARABIA
OF
www.astra-agri.com.sa
MATERIAL SAFETY DATA SHEET
庐
SNAP 230SC
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
1. PRODUCT IDENTIFICATION
SNAP 230SC
Product Name:
Chemical Class: Pyrethroid Insecticide
Active Ingredients: Permethrin+ Tetramethrin+ Piperonyl Butoxide
SNAP 230SC is used for the control of a wide spectrum of
Use:
Public Health Insect Pests. Mainly Flying
insects such as Mosquitoes and flies.
Producer: Astra Industrial Complex Co., Ltd. "ASTRACHEM"
P.O. Box 30447, Al-Khobar 31952
Kingdom of Saudi Arabia -Emergency Tel.# (+966) 3 8121 406
2. COMPOSITION / INFORMATION ON INGREDIENTS
Contents
Substance Chemical Name (IUPAC) Chemical structure (g / Liter )
3-phenoxybenzyl (1RS,3RS;1RS,3SR)-3-(2,2- 99.0 -121.0
Permethrin Cl CH3
dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate
CO2 CH2 O
C CH
CAS No. 7696-12-0 Roth: 3-phenoxybenzyl (1RS)-cis-trans-3-(2,2- Cl
dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate
CH3
cyclohex-1-ene-1,2-dicarboximidomethyl 9.0 -11.0
Tetramethrin O
(1RS,3RS;1RS,3SR)-2,2-dimethyl-3-(2-methylprop-
CH3
1-enyl)cyclopropanecarboxylate CH3
CAS No. 52645-53-1
Alt: cyclohex-1-ene-1,2-dicarboximidomethyl (卤)-cis- CO2 CH2N
C CH
trans-chrysanthemate CH3
Roth: cyclohex-1-ene-1,2-dicarboximidomethyl
O
CH3
(1RS)-cis-trans-2,2-dimethyl-3-(2-methylprop-1-
enyl)cyclopropanecarboxylate
3,4,5,6-tetrahydrophthalimidomethyl (卤)-cis-trans-
chrysanthemate
99.0 -121.0
5-[2-(2-butoxyethoxy)ethoxymethyl]-6-propyl-1,3-
Piperonyl Butoxide CH3(CH2)3OCH 2CH 2OCH2CH2OCH 2 O
benzodioxole; 2-(2-butoxyethoxy)ethyl 6-
CAS No. 51-03-6 propylpiperonyl ether
O
CH 3(CH 2)2
Organic solvents 652.66
Formulation aid 50.02
SNAP 230SC / PESTICIDE
MSDS: 1
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM SAUDI ARABIA
OF
www.astra-agri.com.sa
3. HAZARD IDENTIFICATION
ACUTE EFFECTS
Physical hazards:
None
Health hazards:
Inhalation: Vapour or spray mist may be harmful if inhaled
Eye: Mild irritating to the eyes
Skin: Prolonged or repeated skin contact may cause
irritation or sensitization
Ingestion: May be harmful if swallowed.
4. FIRST AID MEASURES
First Aid:
Swallowed:
Provided the patient is conscious, wash out mouth with water.
Do not induce vomiting. Vomiting should only be induced under
the direction of a physician. If spontaneous vomiting occurs,
have victim lean forward with head down to avoid breathing in of
vomitus. Immediately transport victim to an emergency facility.
Eye:
Irrigate for 15 minutes with copious quantities of water with
eyelids held open. If irritation persists, seek medical attention
immediately.
Skin:
Remove contaminated clothing. Flush skin with running water
for a minimum of 20 minutes. If swelling, redness, blistering or
irritation occurs seek medical attention immediately.
Inhalation:
Remove victim to fresh air. If not breathing, give artificial
respiration preferably mouth-to-mouth. If breathing is labored,
give oxygen. Obtain immediate medical attention.
Advice to doctor:
This product contains materials that may cause severe
pneumonitis if aspirated. If ingestion has occurred less than 2
hours earlier, carry out careful gastric lavage; use endotracheal
SNAP 230SC / PESTICIDE
MSDS: 2
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM SAUDI ARABIA
OF
www.astra-agri.com.sa
cuff if available, to prevent aspiration. Observe patient for
respiratory difficulty from aspiration pneumonitis. Give artificial
resuscitation and appropriate chemotherapy if respiration is
depressed. Symptomatic treatment and supportive therapy as
indicated.
5. FIRE FIGHTING MEASURES
Extinguishing Media:
For small fires, use foam, carbon dioxide or dry powder
extinguishant. For large fires, use foam or water-fog; avoid use
of water jet. Contain run-off water with for example, temporary
earth barriers.
Fire and Explosion Hazards:
Flash Point 43掳C
Combustible liquid; Keep fire exposed containers cool by
spraying with water.
Fire Fighting Instructions:
Evacuate area and fight fire upwind from a safe distance to
avoid hazardous vapors and decomposition products. Fire
exposed containers can build up pressure and should be kept
cool with water spray if possible. Explosive vapor could form
from ruptured containers. Dike and collect water used to fight
fire to prevent environmental damage due to run off. Foam or
dry chemical fire extinguishing systems are preferred to prevent
environmental damage from excessive water run off.
Fire Fighting Equipment:
Self-contained breathing apparatus with full face-piece.
6. ACCIDENTAL RELEASE MEASURES
Contain spill and absorb with sand or proprietary absorbent
(vermiculite). Prevent from entering drains, waterway or sewers.
Collect in sealed open top containers for disposal. Generously
cover the contaminated areas with common, household
detergent brush and small amounts of water, work the detergent
into the remaining spilled material forming slurry. Collect slurry
in sealed open top container for disposal. This material is water
pollutant and should be prevented from drainage systems and
bodies of water.
SNAP 230SC / PESTICIDE
MSDS: 3
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM SAUDI ARABIA
OF
www.astra-agri.com.sa
Disposal:
Triple rinse containers, add rinsate to the spray tank, then offer
container for recycling/reconditioning, or puncture top, sides and
bottom and dispose of in landfill in accordance with local
regulations. On-site disposal of concentrate is not acceptable.
Waste disposal should be carried out by industrial incineration or
burial at a site approved by local authorities.
7. HANDLING AND STORAGE
Keep out of Reach of Children:
Use only in a well-ventilated area. Do not reuse empty
containers. Keep the container closed when not in use. Keep
away from food, feed and drinking water. Store in a well
ventilated dry place, away from heat and other sources of
ignition. Keep from freezing.
8. EXPOSURE CONTROLS / PERSONNEL PROTECTION
Exposure Standards:
For hydrocarbon solvent: 8 h, TWA, 150 mg/m3
Engineering Controls:
Natural ventilation only required when handling the concentrate.
A local exhaust should be used in confined areas to keep the
level of solvent within acceptable limits.
Personnel Protection:
Eye Protection: Safety glasses or goggles
Clothing: Long sleeved shirt and long pants, shoes
plus socks
Gloves: Chemical resistant gloves
Respirator: All pesticide handlers must wear a
respiratory protection device when working
SNAP 230SC / PESTICIDE
MSDS: 4
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM SAUDI ARABIA
OF
www.astra-agri.com.sa
User Safety Recommendations:
Wash hands before eating, drinking, chewing gum, using
tobacco or using the toilet. Remove clothing immediately if
pesticide gets inside. Then wash thoroughly and put on clean
clothing.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Clear, light yellow liquid free of visible
impurities.
Odour: Slightly aromatic
Boiling Point: Not available
Melting point: Not applicable
Vapor pressure: Not available
Density: 0.938-0.950 g / ml
> 40 掳C
Flash point:
Acididy as H2 SO4: < 0.5 g/Kg
Solubility in water: Emulsifiable
Water Contents: < 2 gm / Kg
10. STABILITY AND REACTIVITY
Stability:
Stable at room temperature.
Incompatibility:
Strong oxidizing agents. Acids and alkaline materials
Hazardous polymerization:
Will not occur.
Conditions to avoid:
Keep away from heat. Keep away from sources of ignition: No
smoking.
Hazardous Decomposition Products:
Thermal decomposition products are toxic and may include
hydrocarbons ammonia, organic and acid halides, oxides of
carbon, nitrogen and sulphur.
11. TOXICOLOGICAL INFORMATION
LD50 Oral rat: >5,000 mg/Kg
SNAP 230SC / PESTICIDE
MSDS: 5
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM SAUDI ARABIA
OF
www.astra-agri.com.sa
12. ECOLOGICAL INFORMATION
Keep out of water supplies ground water or open water. This
product is very toxic to aquatic organisms
Do not apply this product or allow it to drift to blooming crops or
weeds if bees are visiting the treatment area.
13. DISPOSAL CONSIDERATION
Disposal Method:
Do not contaminate ponds, waterways or ditches with chemical
or used containers. Dispose of in facility permitted for
hazardous waste.
Container disposal:
Empty container retains product residue. Triple rinse empty
containers, return rinse water to dilution mixture, and dispose of
dilution mixture as a hazardous waste if it cannot be disposed of
by use according to label instructions. Do not reuse container.
Offer if for recycling or reconditioning, or puncture and dispose
of in properly permitted landfill.
14. TRANSPORT INFORMATION
Proper Shipping Name: Insecticide, Liquid; Toxic, Flammable
UN Number 3082
Class 6.1
Packing Group III
Marine Pollutant
15. REGULATORY INFORMATION.
Public Health Pest Control Product
16. OTHER INFORMATION
Buyer assumes all responsibility for safety and use not in
accordance with the product label instructions.
SNAP 230SC / PESTICIDE
MSDS: 6
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