ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa
MATERIAL SAFETY DATA SHEET
庐
TRANSACT 18EC
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
1. PRODUCT IDENTIFICATION
TRANSACT 18EC
Product Name:
Chemical Class: Avermectin (Acaricide / Insecticide)
Use: Transact 18EC is used as an acaricide / insecticide for the control of
Mites, Leafminers, Pear Psylla, Leafhoppers, Fire ants and
others on several agricultural crops.
Producer: Astra Industrial Complex Co., Ltd.
P.O. Box 30447, Al-Khobar 31952
Kingdom of Saudi Arabia
Emergency Tel # (+966) 3 8121 406
2. COMPOSITION / INFORMATION ON INGREDIENTS
Proportions
Substance (% w/w) Chemical structure
Abamectin 1.86
CAS No. 71751-41- 2
(18 卤 2.5 g/L)
Chemical Name: (10E,14E,16E,22Z)-
OCH3
(1R,4S,5'S,6S,6'R,8R,12S,13S,20R,21R,24S)-6'-[(S)-
HO
sec-butyl]-21,24-dihydroxy-5',11,13,22-tetramethyl-2-
OCH3
oxo-3,7,19-trioxatetracyclo[15.6.1.14,8.020,24]pentacosa-
O
O
CH3
10,14,16,22-tetraene-6-spiro-2'-(5',6'-dihydro-2'H- CH3
CH3 H
pyran)-12-yl 2,6-dideoxy-4-O-(2,6-dideoxy-3-O-methyl- O
O O CH3
CH3
伪-L-arabino-hexopyranosyl)-3-O-methyl-伪-L-arabino- O
H
hexopyranoside (i) mixture with (10E,14E,16E,22Z)- R
H
CH3
(1R,4S,5'S,6S,6'R,8R,12S,13S,20R,21R,24S)-21,24- O O
dihydroxy-6'-isopropyl-5',11,13,22-tetramethyl-2-oxo- H
OH
(i) R = -CH 2CH3 (avermectin B 1a)
3,7,19-trioxatetracyclo[15.6.1.14,8.020,24]pentacosa-
10,14,16,22-tetraene-6-spiro-2'-(5',6'-dihydro-2'H- O CH3
pyran)-12-yl 2,6-dideoxy-4-O-(2,6-dideoxy-3-O-methyl- (ii) R = -CH 3 (avermectin B 1b) H
OH
伪-L-arabino-hexopyranosyl)-3-O-methyl-伪-L-arabino-
hexopyranoside (ii) (4:1)
Blend of anionic and nonionic emulsifiers 10.37
Antioxidant 1.04
Organic solvents 86.67
TRANSACT 庐18EC - Acaricide / Insecticide
MSDS: 1/6
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa
3. HAZARD IDENTIFICATION
Signs of Poisoning:
As observed in laboratory animals include pupil dilation
vomiting, convulsions, tremor and coma.
Primary Routes of Entry:
Ingestion, skin and eye contact.
Effects of single overexposures;
Skin Absorption
May cause Sensitization
Inhalation
May cause irritation of eyes, nose and throat
Eyes
May cause moderate eye irritation
4. FIRST AID MEASURES
Emergency and First aid Procedures
Swallowing:
Do not induce vomiting. If the victim is fully conscious give large
quantity of water to drink. Call a physician or poison control
center.
Skin:
Wash affected area with plenty of soap and water. Remove
contaminated clothing. Launder contaminated clothing
separately. Get medical attention.
Inhalation:
Remove victim to fresh air. If not breathing administers artificial
respiration. Avoid unprotected mouth to mouth resuscitation.
GET MEDICAL ATTENTION.
Eye
Hold eyelids open and flush with a steady stream of water for at
least 15 minutes. GET MEDICAL ATTENTION.
TRANSACT 庐18EC - Acaricide / Insecticide
MSDS: 2/6
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa
5. FIRE FIGHTING MEASURES
Fire and Explosion:
Flash point >60掳C
Flammable limits in air:
Not determined.
Auto ignition Temperature:
Not determined.
Extinguishing Media:
Use carbon dioxide or dry chemical for small fires and water fog
or foam (alcohol, polymer or ordinary) for large fires.
Unusual fire and explosion hazards:
Noxious fumes may be emitted under fire conditions.
Special fire fighting procedures:
Fire fighters should use self-contained breathing apparatus and
full turnout gear. Prevent runoff of fire - water. Avoid exposure
to smoke.
6. ACCIDENTAL RELEASE MEASURES
Steps to be taken if material is released or spilled:
Dike the area using absorbent materials such as sand or clay.
Recover and contain as much product as possible using
absorbent. Clean spill area using a solution of water and
detergent. Collect and contain wash water and all contaminated
absorbent for disposal. If spilled on the ground, the affected area
should be excavated to a depth of 1-2 inches. Prevent the
spilled product or washing from reaching public sewers or
waterways. Wear appropriate protective equipment during the
cleanup. Ensure that tools and equipment are adequately
decontaminated.
Waste disposal method:
Dispose of in accordance with local regulations.
Container disposal:
Dispose of in an approved facility according to local regulations.
TRANSACT 庐18EC - Acaricide / Insecticide
MSDS: 3/6
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa
7. HANDLING AND STORAGE
Store the product in a well-ventilated, secure area out of reach
of children and domestic animals. Do not use or store near heat
or open flame. Do not store food or feed in storage area.
Prevent eating, drinking or smoking in areas where there is a
potential exposure to the product. Wash hands before eating,
drinking or smoking after using the product.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Protective equipment should be used during the following procedures:
Manufacture, formulation or application of this product.
鈥?
Repair and maintenance of contaminated equipment
鈥?
Clear up of leaks and spills.
鈥?
Any other activity that may result in hazardous exposures.
鈥?
Respiratory Protection:
Use NIOSH / MSHA approved respirator for organic vapors.
Use positive pressure contained breathing apparatus where
emergency conditions or where exposure limits are exceeded.
Ventilation:
Exhaust appropriate for removal of vapors.
Protective clothing:
Chemical resistant gloves, coveralls, apron and foot coverings.
Eye Protection:
Safety goggles or face shield.
User safety recommendations:
Safety showers and eye wash should be easily accessible.
9. PHYSICAL AND CHEMICAL PROPERTIES
Assay Abamectin 18 卤 2.7 g/L
Appearance Clear yellow Liquid free of visible impurities
Odour Mild
0.970 卤 0.006 Kg/L
Density
Flash Point >60掳C
Acidity as H2 SO4 < 5.0 g/Kg
Water contents <10.0 g/Kg
TRANSACT 庐18EC - Acaricide / Insecticide
MSDS: 4/6
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa
10. STABILITY AND REACTIVITY
Stability: Stable under normal conditions.
Condition to avoid: Excessive heat.
Materials to avoid: Strong oxidizers, acids, and alkalis.
Hazardous decomposition products:
Not known.
11. TOXICOLOGICAL INFORMATION
Toxicology Data (Abamectin tech.):
Acute Oral LD50 (rat) 10 mg/kg
Acute Dermal LD50 (rabbit) >2000 mg/Kg
Eye Irritation (rabbit) Mild irritant
Dermal sensitization Sensitizer for Guinea Pig
Mutagenicity
Non-mutagenic in the Ames test.
Reproductive effect
It may have potential to cause reproductive effect at high doses.
Carcinogenicity
Not carcinogenic in rats and mice.
Tetratogenicity
Not likely to cause teratogenic effects except at doses to the
mother
12. ECOLOGICAL INFORMATION
Non-toxic to birds
鈥?
Highly toxic to fish and aquatic invertebrates.
鈥?
Highly toxic to bees.
鈥?
13. DISPOSAL CONSIDERATION
Pesticide wastes are toxic. Do not reuse product containers.
Dispose of product containers, waste containers and residues
according to local health and environmental regulations.
TRANSACT 庐18EC - Acaricide / Insecticide
MSDS: 5/6
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa
14. TRANSPORT INFORMATION
UN. No: UN 2902
Proper Shipping name: Pesticide, liquid, toxic, N.O.S (Abamectin)
Class: 6.1
T6
Classification Code:
Packing group: III
6.1
Subsidiary Risks:
61
Special provisions:
LQ19
Limited quantities:
Packaging: Packing instructions P001 IBC03 LP01
R001
Special packing provisions
Mixed Packaging Provisions MP15
Instructions T7
UN Portable tanks: Special Provisions TP2 TP28
Tank Code L4BH
ADR Tank: Special Provision TU15 TE1 TE15 TE19
Vehicle for tank carriage AT
Transport Category 2
Special provision carriage: Packages -
Bulk -
Loading, unloading & Handling CV13 CV28
Operation S9
Hazard Identification 60
15. REGULATORY INFORMATION.
SARA Title III classification
Section 311/312
16. OTHER INFORMATION
Buyer assumes all responsibility for safety and use not in
accordance with the product label instructions.
TRANSACT 庐18EC - Acaricide / Insecticide
MSDS: 6/6
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