LOCTITE CORPORATION 09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 01 of 06
Permatex(R) Battery Protector and Sealer
80370
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: Permatex(R) Battery Protector and Sealer
Item No.: 80370
Part No.: SA-9
Product Type: Aerosol Sealant and Protectant
2. COMPOSITION, INFORMATION ON INGREDIENTS
Ingredients CAS No. %
TOLUENE* 108-88-3 30-40
Grease mixture Proprietary 10-20
Residual oils (petroleum),
hydrotreated 64742-57-0 10-20
BUTANE 106-97-8 5-20
ISOBUTANE 75-28-5 5-20
PROPANE 74-98-6 5-20
2-BUTOXYETHANOL* 111-76-2 1-10
ETHANE, 1,1,1-TRICHLORO-* 71-55-6 1-10
Mineral oil 64742-52-5 1-10
* This component is listed as a SARA Section 313 Toxic Chemical.
Ingredients which have exposure limits
Exposure Limits (TWA) ACGIH OSHA OTHER
Ingredients (TLV) (PEL)
TOLUENE 50 ppm skin 100 ppm None
188 mg/M3 skin 375mg/M3
BUTANE 800 ppm TWA 800 ppm TWA None
1900mg/M3 1900mg/M3
PROPANE Asphyxiant 1000 ppm None
1800 mg/m3
2-BUTOXYETHANOL 25 ppm TWA skin 50 ppm TWA skin None
121mg/m3 skin 120mg/m3 skin
ETHANE, 1,1,1-TRICHLORO- 350 ppm TWA 350 ppm TWA None
1910 mg/m3 1900 mg/m3
Mineral oil 5 mg/m3 mist 5 mg/m3 mist 5 mg/m3 mist
Exposure Limits (STEL) ACGIH OSHA
Ingredients (TLV) (PEL)
TOLUENE None 150 ppm
560mg/M3
ETHANE, 1,1,1-TRICHLORO- 450 ppm 450 ppm
2460 mg/m3 2450 mg/m3
LOCTITE CORPORATION 09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 02 of 06
Product Name: Permatex(R) Battery Protector and Sealer
Item No.: 80370
2. COMPOSITION, INFORMATION ON INGREDIENTS (continued)
Mineral oil 10 mg/m3 mist None
3. HAZARDS IDENTIFICATION
Toxicity: Skin and eye irritant. May irritate respiratory
tract. Aspiration hazard if swallowed. May cause
dizziness or narcosis in high vapor concentrations
Will cause defatting of skin.
Long term exposure to high concentrations of vapor
may cause lung, liver, or kidney damage. The
solvents listed have been reported to affect the
central nervous system.
May cause cardiac abnormalities.
Overexposure to toluene may cause nasal and brain
damage. 2-Butoxyethanol may cause corneal injury
blood abnormalities, may be absorbed through the
skin with toxic effects, and may cause damage to
spleen and testes.
Primary Routes of Entry: Skin absorption, ingestion, inhalation
Signs and symptoms
of Exposure: Inhalation: Difficulty in breathing.
Skin: Redness.
Ingestion: Vomiting.
Existing Conditions
Aggravated by Exposure: Heart disease, respiratory disorders.
Toluene may also aggravate central nervous system
diseases and alcoholism.
Literature Referenced Carcinogen
Ingredients Target Organ and Other Health Effects NTP IARC OSHA
TOLUENE CAR CNS DEV IRR NO NO NO
Grease mixture No Data NO NO NO
Residual oils (petroleum),
hydrotreated No Data NO NO NO
BUTANE CAR CNS IRR NO NO NO
ISOBUTANE CAR CNS LUN NO NO NO
PROPANE CAR CNS IRR NO NO NO
2-BUTOXYETHANOL BLO CNS IRR NO NO NO
ETHANE, 1,1,1-TRICHLORO- CAR CNS IRR LIV NO N/A NO
Mineral oil IRR NO NO NO
-------------------------------------------------------------------------------
Abbreviations
N/A Not Applicable BLO Blood
CAR Cardiac CNS Central nervous system
DEV Developmental IRR Irritant
LOCTITE CORPORATION 09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 03 of 06
Product Name: Permatex(R) Battery Protector and Sealer
Item No.: 80370
3. HAZARDS IDENTIFICATION (continued)
LIV Liver LUN Lung
4. FIRST AID MEASURES
Ingestion: Do not induce vomiting. Keep individual calm.
Obtain medical attention. Gastric lavage.
Inhalation: Remove to fresh air. If symptoms persist, obtain
medical attention. Give oxygen.
Skin Contact: Wash with soap and water.
Eye Contact: Flush with water for at least 15 minutes. Obtain
medical attention.
Never administer adrenalin following overexposure.
5. FIRE FIGHTING MEASURES
Flash Point: -142掳F Method: Tag Closed Cup
Recommended
Extinguishing Agents: Carbon dioxide, water fog, dry chemical
Hazardous Products formed
by Fire or Thermal Decomp Carbon dioxide, water, halogen acids, phosgene.
Unusual Fire or
Explosion Hazards: Heated cans may rupture.
Explosive Limits:
(% by volume in air)Lower 1.8
(% by volume in air)Upper 9.5%
6. ACCIDENTAL RELEASE MEASURES
Steps to be taken in case
of spill or leak: Remove ignition sources. Maintain adequate
ventilation. Soak up liquid in an inert absorbent
and store in a closed container until disposal.
7. HANDLING AND STORAGE
Safe Storage: Store away from heat, spark or open flame.
Store below 120掳F.
(Contact Loctite Customer Service 1-800-243-4874 for shelf Life information)
Handling: Avoid prolonged breathing of vapor. Keep away
from eyes. Avoid prolonged skin contact.
Keep away from heat, sparks, or open flame.
Do not smoke while using. Wash hands after use.
When spraying more than one half can or more than
LOCTITE CORPORATION 09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 04 of 06
Product Name: Permatex(R) Battery Protector and Sealer
Item No.: 80370
7. HANDLING AND STORAGE (continued)
one can consecutively, use NIOSH/MSA approved
respirator.
8. EXPOSURE CONTROLS, PERSONAL PROTECTION
Eyes: Safety glasses or goggles.
Skin: Rubber or plastic gloves. Long sleeves and long
pants.
Ventilation: Provide adequate local ventilation to maintain
vapor concentration below TLV.
Use self contained breathing apparatus when vapor
concentration exceeds TLV.
See Section 2 for Exposure Limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Purple liquid
Odor: Solvent
Boiling Point: -40掳F to 232掳F
pH: Does not apply
Solubility in Water: Negligible
Specific Gravity 0.8
Volatile Organic Compound
(EPA Method 24) 61.3% ; 490 grams per liter (calculated)
Vapor Pressure: 57 psig at 70掳F
Vapor Density: 4.0
Evaporation Rate
(Ether = 1) Faster than butyl acetate
10. STABILITY AND REACTIVITY
Stability: Stable
Hazardous Polymerization: Will not occur
Incompatibility: Strong oxidizers; active metals, stromg alkalies,
reactive metals, zinc, sodium, potassium.
Hazardous Decomposition
Products (non-thermal): None
11. TOXICOLOGICAL INFORMATION
See Section 3.
12. ECOLOGICAL INFORMATION
No data available
LOCTITE CORPORATION 09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 05 of 06
Product Name: Permatex(R) Battery Protector and Sealer
Item No.: 80370
13. DISPOSAL CONSIDERATIONS
Recommended methods of
disposal: Do not puncture or incinerate cans. Give cans to
licensed disposal service equipped for safe
disposal of aerosol containers.
EPA Hazardous Waste
Number D001/F002 - Hazardous waste per 40CFR 261.21 and
261.31/1,1,1-Trichloroethane
14. TRANSPORT INFORMATION
DOT (49 CFR 172)
Domestic Ground Transport
Proper Shipping Name: Consumer Commodity
Hazard Class or
Division: ORM-D
Identification Number: None
Marine Pollutant: None
IATA
Proper Shipping Name: Aerosols, flammable, n.o.s. containing
substances in Division 6.1, Packing Group III
Class or Division: Division 2.1 Subsidiary Risk 6.1
UN or ID Number: UN 1950
15. REGULATORY INFORMATION
CA Proposition 65: WARNING: This product contains a chemcial known to
the State of California to cause birth
defects or other reproductive harm.
16. OTHER INFORMATION
Estimated NFPA(R) Code:
Health Hazard: 2
Fire Hazard: 4
Reactivity Hazard: 0
Specific Hazard: Does not apply
Estimated HMIS(R) Code:
Health Hazard: 2
Flammability Hazard: 4
Reactivity Hazards: 0
Personal Protection: See Section 8.
NFPA is a registered trademark of the National Fire Protection Assn.
HMIS is a registered trademark of the National Paint and Coatings Assn.
Prepared By: Stephen Repetto
Title: Research Chemist, Health and Safety
LOCTITE CORPORATION 09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 06 of 06
Product Name: Permatex(R) Battery Protector and Sealer
Item No.: 80370
16. OTHER INFORMATION (continued)
Company: Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067
(24hr.) Phone: (860) 571-5100
Revision Date: January 22, 1996 Revision: 0004
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