PRODUCT #: I2387 NAME: INDIGO CARMINE
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Wednesday, March 12, 1903 1:39PM
Sigma Chemical Co. Aldrich Chemical Co., Inc. Fluka Chemical Corp.
P.O. Box 14508 1001 West St. Paul 1001 West St. Paul
St. Louis, MO 63178 Milwaukee, WI 53233 Milwaukee, WI 53233
Phone: 314-771-5765 Phone: 414-273-3850 Phone: 414-273-3850
SECTION 1. - - - - - - - - - CHEMICAL IDENTIFICATION- - - - - - - - - -
CATALOG #: I2387
NAME: INDIGO CARMINE
SECTION 2. - - - - - COMPOSITION/INFORMATION ON INGREDIENTS - - - - - -
CAS #: 860-22-0
MF: C16H8N2NA2O8S2
EC NO: 212-728-8
SYNONYMS
ACID BLUE W * ACID LEATHER BLUE IC * A.F. BLUE NO. 2 * AIREDALE BLUE
IN * AMACID BRILLIANT BLUE * ANILINE CARMINE POWDER * ATUL INDIGO
CARMINE * 1311 BLUE * 12070 BLUE * BUCACID INDIGOTINE B * CANACERT
INDIGO CARMINE * CARMINE BLUE (BIOLOGICAL STAIN) * C.I. 73015 * C.I.
75781 * C.I. ACID BLUE 74 * C.I. FOOD BLUE 1 * C.I. FOOD BLUE 1,
DISODIUM SALT * CILEFA BLUE R * C.I. NATURAL BLUE 2 * DISODIUM INDIGO-
5,5-DISULFONATE * DISODIUM SALT OF 1-INDIGOTIN-S,S'-DISULPHONIC ACID *
DOLKWAL INDIGO CARMINE * E 132 * EDICOL SUPRA BLUE X * FD&C BLUE 2 *
FD AND C BLUE NO. 2 * FOOD BLUE 2 * GRAPE BLUE A GEIGY * HD INDIGO
CARMINE * HD INDIGO CARMINE SUPRA * HEXACERT BLUE NO. 2 * HEXACOL
INDIGO CARMINE SUPRA * INDIGO CARMINE * INDIGO CARMINE A * INDIGO
CARMINE AC * INDIGO CARMINE (BIOLOGICAL STAIN) * INDIGO CARMINE BP *
INDIGO CARMINE CONC. FQ * INDIGO CARMINE DISODIUM SALT * INDIGO
CARMINE POWDER * INDIGO CARMINE X * INDIGO DISULFONATE (BIOLOGICAL
STAIN) * INDIGO EXTRACT * INDIGO-KARMIN (GERMAN) * INDIGOTIN I * 5,5'-
INDIGOTINDISULFONIC ACID * INDIGOTIN-5,5'-DISULFONIC ACID DISODIUM
SALT * INDIGOTINE * INDIGOTINE B * INDIGOTINE BLUE LZ * INDIGOTINE
CONC. POWDER * INDIGOTINE DISODIUM SALT * INDIGOTINE EXTRA PURE A *
INDIGOTINE I * INDIGOTINE LAKE * INDIGOTINE N * INDOCARMINE F *
INTENSE BLUE * L-BLAU 2 (GERMAN) * MAPLE INDIGO CARMINE * MITSUI
INDIGO CARMINE * MODR KYSELA 74 (CZECH) * MODR PIGMENT 63 (CZECH) *
MODR POTRAVINARSKA 1 (CZECH) * MURABBA * SACHSISCHBLAU * SAN-EI
INDIGO CARMINE * SCHULTZ NR. 1309 (GERMAN) * SODIUM
INDIGOTINDISULFONATE * SODIUM 5,5'-INDIGOTIDISULFONATE * SOLUBLE
INDIGO * SUMITOMO WOOL BLUE SBC * USACERT BLUE NO. 2 *
SECTION 3. - - - - - - - - - - HAZARDS IDENTIFICATION - - - - - - - - -
LABEL PRECAUTIONARY STATEMENTS
HARMFUL
HARMFUL IF SWALLOWED.
WEAR SUITABLE PROTECTIVE CLOTHING.
SECTION 4. - - - - - - - - - - FIRST-AID MEASURES- - - - - - - - - - -
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH COPIOUS AMOUNTS OF
WATER FOR AT LEAST 15 MINUTES.
IN CASE OF CONTACT, IMMEDIATELY WASH SKIN WITH SOAP AND COPIOUS
AMOUNTS OF WATER.
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS.
CALL A PHYSICIAN.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
SECTION 5. - - - - - - - - - FIRE FIGHTING MEASURES - - - - - - - - - -
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PRODUCT #: I2387 NAME: INDIGO CARMINE
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Wednesday, March 12, 1903 1:39PM
EXTINGUISHING MEDIA
WATER SPRAY.
CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE FOAM.
SPECIAL FIREFIGHTING PROCEDURES
WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO
PREVENT CONTACT WITH SKIN AND EYES.
UNUSUAL FIRE AND EXPLOSIONS HAZARDS
EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
SECTION 6. - - - - - - - - ACCIDENTAL RELEASE MEASURES- - - - - - - - -
WEAR RESPIRATOR, CHEMICAL SAFETY GOGGLES, RUBBER BOOTS AND HEAVY
RUBBER GLOVES.
SWEEP UP, PLACE IN A BAG AND HOLD FOR WASTE DISPOSAL.
AVOID RAISING DUST.
VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE.
SECTION 7. - - - - - - - - - - HANDLING AND STORAGE- - - - - - - - - - -
REFER TO SECTION 8.
SECTION 8. - - - - - - EXPOSURE CONTROLS/PERSONAL PROTECTION- - - - - -
CHEMICAL SAFETY GOGGLES.
COMPATIBLE CHEMICAL-RESISTANT GLOVES.
NIOSH/MSHA-APPROVED RESPIRATOR.
SAFETY SHOWER AND EYE BATH.
MECHANICAL EXHAUST REQUIRED.
AVOID INHALATION.
AVOID CONTACT WITH EYES, SKIN AND CLOTHING.
AVOID PROLONGED OR REPEATED EXPOSURE.
WASH THOROUGHLY AFTER HANDLING.
HARMFUL SOLID.
KEEP TIGHTLY CLOSED.
LIGHT SENSITIVE
STORE IN A COOL DRY PLACE.
SECTION 9. - - - - - - - PHYSICAL AND CHEMICAL PROPERTIES - - - - - - -
APPEARANCE AND ODOR
PURPLE POWDER
SECTION 10. - - - - - - - - -STABILITY AND REACTIVITY - - - - - - - - -
INCOMPATIBILITIES
STRONG OXIDIZING AGENTS
SENSITIVE TO LIGHT
HAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCTS
TOXIC FUMES OF:
CARBON MONOXIDE, CARBON DIOXIDE
NITROGEN OXIDES
SULFUR OXIDES
SECTION 11. - - - - - - - - - TOXICOLOGICAL INFORMATION - - - - - - - -
ACUTE EFFECTS
HARMFUL IF SWALLOWED.
MAY BE HARMFUL IF INHALED.
MAY BE HARMFUL IF ABSORBED THROUGH THE SKIN.
MAY CAUSE EYE IRRITATION.
MAY CAUSE SKIN IRRITATION.
TO THE BEST OF OUR KNOWLEDGE, THE CHEMICAL, PHYSICAL, AND
TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED.
RTECS #: DU3000000
(DELTA(SUP 2,2')-BIINDOLINE)-5,5'-DISULFONIC ACID, 3,3'-DIOXO-,
DISODIUM SALT
TOXICITY DATA
ORL-RAT LD50:2 GM/KG SCPHA4 47,39,1979
IVN-RAT LD50:93 MG/KG NIIRDN 6,83,1982
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PRODUCT #: I2387 NAME: INDIGO CARMINE
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Wednesday, March 12, 1903 1:39PM
ORL-MUS LD50:2500 MG/KG SCPHA4 47,39,1979
SCU-MUS LD50:405 MG/KG SCPHA4 47,39,1979
ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES
(RTECS) DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN RTECS FOR
COMPLETE INFORMATION.
SECTION 12. - - - - - - - - - ECOLOGICAL INFORMATION - - - - - - - - - -
DATA NOT YET AVAILABLE.
SECTION 13. - - - - - - - - - DISPOSAL CONSIDERATIONS - - - - - - - - -
DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE SOLVENT AND BURN IN A
CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER.
OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.
SECTION 14. - - - - - - - - - - TRANSPORT INFORMATION - - - - - - - - -
CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION INFORMATION.
SECTION 15. - - - - - - - - - REGULATORY INFORMATION - - - - - - - - - -
EUROPEAN INFORMATION
HARMFUL
R 22
HARMFUL IF SWALLOWED.
S 36
WEAR SUITABLE PROTECTIVE CLOTHING.
REVIEWS, STANDARDS, AND REGULATIONS
OEL=MAK
NOHS 1974: HZD 84752; NIS 5; TNF 314; NOS 6; TNE 1736
NOES 1983: HZD 84752; NIS 7; TNF 393; NOS 28; TNE 9691; TFE 3035
EPA GENETOX PROGRAM 1988, NEGATIVE: HISTIDINE REVERSION-AMES TEST
EPA GENETOX PROGRAM 1988, NEGATIVE: S CEREVISIAE GENE CONVERSION
EPA GENETOX PROGRAM 1988, INCONCLUSIVE: B SUBTILIS REC ASSAY
EPA TSCA SECTION 8(B) CHEMICAL INVENTORY
SECTION 16. - - - - - - - - - - OTHER INFORMATION- - - - - - - - - - - -
THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT BUT DOES NOT PURPORT TO
BE ALL INCLUSIVE AND SHALL BE USED ONLY AS A GUIDE. SIGMA, ALDRICH,
FLUKA SHALL NOT BE HELD LIABLE FOR ANY DAMAGE RESULTING FROM HANDLING
OR FROM CONTACT WITH THE ABOVE PRODUCT. SEE REVERSE SIDE OF INVOICE OR
PACKING SLIP FOR ADDITIONAL TERMS AND CONDITIONS OF SALE.
COPYRIGHT 1997 SIGMA CHEMICAL CO., ALDRICH CHEMICAL CO., INC.,
FLUKA CHEMIE AG
LICENSE GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY
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