PRODUCT #: 333417 NAME: LIGROIN
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Thursday, March 20, 1903 2:51PM
Sigma Chemical Co. Aldrich Chemical Co., Inc. Fluka Chemical Corp.
P.O. Box 14508 1001 West St. Paul 1001 West St. Paul
St. Louis, MO 63178 Milwaukee, WI 53233 Milwaukee, WI 53233
Phone: 314-771-5765 Phone: 414-273-3850 Phone: 414-273-3850
SECTION 1. - - - - - - - - - CHEMICAL IDENTIFICATION- - - - - - - - - -
CATALOG #: 333417
NAME: LIGROIN
SECTION 2. - - - - - COMPOSITION/INFORMATION ON INGREDIENTS - - - - - -
CAS #: 8032-32-4
EC NO: 232-453-7
SYNONYMS
BENZINE (LIGHT PETROLEUM DISTILLATE) * BENZOLINE * CANADOL * LIGROIN *
PAINTERS NAPHTHA * PETROLEUM ETHER * PETROLEUM SPIRIT (DOT) *
REFINED SOLVENT NAPHTHA * SKELLYSOLVE F * SKELLYSOLVE G * UN1271 (DOT)
* VARNISH MARKER'S NAPHTHA * VM AND P NAPHTHA * VM & P NAPHTHA
(ACGIH) *
SECTION 3. - - - - - - - - - - HAZARDS IDENTIFICATION - - - - - - - - -
LABEL PRECAUTIONARY STATEMENTS
FLAMMABLE (USA)
HIGHLY FLAMMABLE (EU)
TOXIC
TOXIC BY INHALATION AND IF SWALLOWED.
IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN.
TARGET ORGAN(S):
CENTRAL NERVOUS SYSTEM
KEEP AWAY FROM SOURCES OF IGNITION - NO SMOKING.
KEEP CONTAINER TIGHTLY CLOSED IN A COOL WELL-VENTILATED PLACE.
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF
WATER AND SEEK MEDICAL ADVICE.
WEAR SUITABLE PROTECTIVE CLOTHING.
SECTION 4. - - - - - - - - - - FIRST-AID MEASURES- - - - - - - - - - -
IN CASE OF CONTACT, IMMEDIATELY WASH SKIN WITH SOAP AND COPIOUS
AMOUNTS OF WATER.
CONTAMINATION OF THE EYES SHOULD BE TREATED BY IMMEDIATE AND PROLONGED
IRRIGATION WITH COPIOUS AMOUNTS OF WATER.
ASSURE ADEQUATE FLUSHING OF THE EYES BY SEPARATING THE EYELIDS
WITH FINGERS.
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS.
CALL A PHYSICIAN.
REMOVE AND WASH CONTAMINATED CLOTHING PROMPTLY.
SECTION 5. - - - - - - - - - FIRE FIGHTING MEASURES - - - - - - - - - -
EXTINGUISHING MEDIA
CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE FOAM.
WATER MAY BE EFFECTIVE FOR COOLING, BUT MAY NOT EFFECT EXTINGUISHMENT.
SPECIAL FIREFIGHTING PROCEDURES
WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO
PREVENT CONTACT WITH SKIN AND EYES.
USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS.
FLAMMABLE LIQUID.
UNUSUAL FIRE AND EXPLOSIONS HAZARDS
VAPOR MAY TRAVEL CONSIDERABLE DISTANCE TO SOURCE OF IGNITION AND
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PRODUCT #: 333417 NAME: LIGROIN
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Thursday, March 20, 1903 2:51PM
FLASH BACK.
CONTAINER EXPLOSION MAY OCCUR UNDER FIRE CONDITIONS.
FORMS EXPLOSIVE MIXTURES IN AIR.
SECTION 6. - - - - - - - - ACCIDENTAL RELEASE MEASURES- - - - - - - - -
EVACUATE AREA.
SHUT OFF ALL SOURCES OF IGNITION.
WEAR SELF-CONTAINED BREATHING APPARATUS, RUBBER BOOTS AND HEAVY
RUBBER GLOVES.
COVER WITH AN ACTIVATED CARBON ADSORBENT, TAKE UP AND PLACE IN CLOSED
CONTAINERS. TRANSPORT OUTDOORS.
VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE.
SECTION 7. - - - - - - - - - - HANDLING AND STORAGE- - - - - - - - - - -
REFER TO SECTION 8.
SECTION 8. - - - - - - EXPOSURE CONTROLS/PERSONAL PROTECTION- - - - - -
WEAR APPROPRIATE NIOSH/MSHA-APPROVED RESPIRATOR, CHEMICAL-RESISTANT
GLOVES, SAFETY GOGGLES, OTHER PROTECTIVE CLOTHING.
SAFETY SHOWER AND EYE BATH.
MECHANICAL EXHAUST REQUIRED.
DO NOT BREATHE VAPOR.
AVOID CONTACT WITH EYES, SKIN AND CLOTHING.
AVOID PROLONGED OR REPEATED EXPOSURE.
WASH THOROUGHLY AFTER HANDLING.
KEEP TIGHTLY CLOSED.
KEEP AWAY FROM HEAT, SPARKS, AND OPEN FLAME.
STORE IN A COOL DRY PLACE.
SECTION 9. - - - - - - - PHYSICAL AND CHEMICAL PROPERTIES - - - - - - -
APPEARANCE AND ODOR
COLORLESS LIQUID
PHYSICAL PROPERTIES
BOILING POINT: 60 C TO 80 C
FLASHPOINT -16 F
- 8C
SPECIFIC GRAVITY: 0.656
VAPOR DENSITY: >1
SECTION 10. - - - - - - - - -STABILITY AND REACTIVITY - - - - - - - - -
INCOMPATIBILITIES
OXIDIZING AGENTS
HAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCTS
TOXIC FUMES OF:
CARBON MONOXIDE, CARBON DIOXIDE
SECTION 11. - - - - - - - - - TOXICOLOGICAL INFORMATION - - - - - - - -
ACUTE EFFECTS
HARMFUL IF INHALED OR SWALLOWED.
VAPOR OR MIST IS IRRITATING TO THE EYES, MUCOUS MEMBRANES AND UPPER
RESPIRATORY TRACT.
CAUSES SKIN IRRITATION.
SYMPTOMS OF EXPOSURE MAY INCLUDE BURNING SENSATION, COUGHING,
WHEEZING, LARYNGITIS, SHORTNESS OF BREATH, HEADACHE, NAUSEA AND
VOMITING.
TARGET ORGAN(S):
CENTRAL NERVOUS SYSTEM
RTECS #: OI6180000
LIGROINE
IRRITATION DATA
EYE-HMN 880 PPM/15M TXAPA9 32,263,1975
TOXICITY DATA
IHL-RAT LC50:3400 PPM/4H TXAPA9 32,263,1975
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PRODUCT #: 333417 NAME: LIGROIN
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Thursday, March 20, 1903 2:51PM
IVN-MUS LD50:40 MG/KG PCJOAU 7,765,1973
ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES
(RTECS) DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN RTECS FOR
COMPLETE INFORMATION.
SECTION 12. - - - - - - - - - ECOLOGICAL INFORMATION - - - - - - - - - -
DATA NOT YET AVAILABLE.
SECTION 13. - - - - - - - - - DISPOSAL CONSIDERATIONS - - - - - - - - -
BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND
SCRUBBER BUT EXERT EXTRA CARE IN IGNITING AS THIS MATERIAL IS HIGHLY
FLAMMABLE.
OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.
SECTION 14. - - - - - - - - - - TRANSPORT INFORMATION - - - - - - - - -
CONTACT ALDRICH CHEMICAL COMPANY FOR TRANSPORTATION INFORMATION.
SECTION 15. - - - - - - - - - REGULATORY INFORMATION - - - - - - - - - -
EUROPEAN INFORMATION
HIGHLY FLAMMABLE
TOXIC
R 45
MAY CAUSE CANCER.
R
HARMFUL: MAY CAUSE LUNG DAMAGE IF SWALLOWED.
S 53
AVOID EXPOSURE - OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
S 45
IN CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE
IMMEDIATELY (SHOW THE LABEL WHERE POSSIBLE).
REVIEWS, STANDARDS, AND REGULATIONS
OEL=MAK
ACGIH TLV-ANIMAL CARCINOGEN DTLVS* TLV/BEI,1996
ACGIH TLV-TWA 1370 MG/M3 (300 PPM) DTLVS* TLV/BEI,1996
EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION
FEREAC 54,7740,1989
NIOSH REL TO VM & P NAPHTHA-AIR:10H TWA 350 MG/M3;CL 1800 MG/M3/15M
NIOSH* DHHS #92-100,1992
NOHS 1974: HZD M0630; NIS 21; TNF 1437; NOS 22; TNE 10998
NOHS 1974: HZD M2829; NIS 459; TNF 182022; NOS 231; TNE 2414497
NOHS 1974: HZD T0180; NIS 16; TNF 1133; NOS 12; TNE 3524
NOES 1983: HZD M0630; NIS 1; TNF 5; NOS 2; TNE 1674; TFE 109
NOES 1983: HZD T0180; NIS 337; TNF 93614; NOS 196; TNE 1319179; TFE
164513
EPA TSCA SECTION 8(B) CHEMICAL INVENTORY
EPA TSCA SECTION 8(D) UNPUBLISHED HEALTH/SAFETY STUDIES
EPA TSCA TEST SUBMISSION (TSCATS) DATA BASE, APRIL 1997
NIOSH ANALYTICAL METHOD, 1994: NAPHTHAS, 1550
SECTION 16. - - - - - - - - - - OTHER INFORMATION- - - - - - - - - - - -
THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT BUT DOES NOT PURPORT TO
BE ALL INCLUSIVE AND SHALL BE USED ONLY AS A GUIDE. SIGMA, ALDRICH,
FLUKA SHALL NOT BE HELD LIABLE FOR ANY DAMAGE RESULTING FROM HANDLING
OR FROM CONTACT WITH THE ABOVE PRODUCT. SEE REVERSE SIDE OF INVOICE OR
PACKING SLIP FOR ADDITIONAL TERMS AND CONDITIONS OF SALE.
COPYRIGHT 1997 SIGMA CHEMICAL CO., ALDRICH CHEMICAL CO., INC.,
FLUKA CHEMIE AG
LICENSE GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY
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