PRODUCT #: 62493 NAME: LITHIUM DIISOPROPYLAMIDE
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Thursday, March 20, 1903 2:50PM
Sigma Chemical Co. Aldrich Chemical Co., Inc. Fluka Chemical Corp.
P.O. Box 14508 1001 West St. Paul 1001 West St. Paul
St. Louis, MO 63178 Milwaukee, WI 53233 Milwaukee, WI 53233
Phone: 314-771-5765 Phone: 414-273-3850 Phone: 414-273-3850
SECTION 1. - - - - - - - - - CHEMICAL IDENTIFICATION- - - - - - - - - -
CATALOG #: 62493
NAME: LITHIUM DIISOPROPYLAMIDE
SECTION 2. - - - - - COMPOSITION/INFORMATION ON INGREDIENTS - - - - - -
CAS #: 4111-54-0
MF: C6H14LIN
EC NO: 223-893-0
SECTION 3. - - - - - - - - - - HAZARDS IDENTIFICATION - - - - - - - - -
LABEL PRECAUTIONARY STATEMENTS
FLAMMABLE (USA)
HIGHLY FLAMMABLE (EU)
CORROSIVE
SPONTANEOUSLY FLAMMABLE IN AIR.
CAUSES BURNS.
KEEP AWAY FROM SOURCES OF IGNITION - NO SMOKING.
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING.
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF
WATER AND SEEK MEDICAL ADVICE.
WEAR SUITABLE PROTECTIVE CLOTHING, GLOVES AND EYE/FACE
PROTECTION.
HANDLE AND STORE UNDER NITROGEN.
MOISTURE SENSITIVE
KEEP TIGHTLY CLOSED.
SECTION 4. - - - - - - - - - - FIRST-AID MEASURES- - - - - - - - - - -
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH COPIOUS
AMOUNTS OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED
CLOTHING AND SHOES.
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS.
CALL A PHYSICIAN.
DISCARD CONTAMINATED CLOTHING AND SHOES.
SECTION 5. - - - - - - - - - FIRE FIGHTING MEASURES - - - - - - - - - -
EXTINGUISHING MEDIA
DRY CHEMICAL POWDER.
DO NOT USE WATER.
SPECIAL FIREFIGHTING PROCEDURES
WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO
PREVENT CONTACT WITH SKIN AND EYES.
PYROPHORIC.
UNUSUAL FIRE AND EXPLOSIONS HAZARDS
CATCHES FIRE IF EXPOSED TO AIR.
EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
REACTS WITH WATER TO LIBERATE FLAMMABLE AND/OR EXPLOSIVE GAS.
SECTION 6. - - - - - - - - ACCIDENTAL RELEASE MEASURES- - - - - - - - -
EVACUATE AREA.
WEAR SELF-CONTAINED BREATHING APPARATUS, RUBBER BOOTS AND HEAVY
RUBBER GLOVES.
COVER WITH DRY-LIME, SAND, OR SODA ASH. PLACE IN COVERED CONTAINERS
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PRODUCT #: 62493 NAME: LITHIUM DIISOPROPYLAMIDE
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Thursday, March 20, 1903 2:50PM
USING NON-SPARKING TOOLS AND TRANSPORT OUTDOORS.
VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE.
SECTION 7. - - - - - - - - - - HANDLING AND STORAGE- - - - - - - - - - -
REFER TO SECTION 8.
SECTION 8. - - - - - - EXPOSURE CONTROLS/PERSONAL PROTECTION- - - - - -
WEAR APPROPRIATE NIOSH/MSHA-APPROVED RESPIRATOR, CHEMICAL-RESISTANT
GLOVES, SAFETY GOGGLES, OTHER PROTECTIVE CLOTHING.
SAFETY SHOWER AND EYE BATH.
USE ONLY IN A CHEMICAL FUME HOOD.
FACESHIELD (8-INCH MINIMUM).
USE NONSPARKING TOOLS.
AVOID CONTACT AND INHALATION.
AVOID PROLONGED OR REPEATED EXPOSURE.
WASH THOROUGHLY AFTER HANDLING.
CORROSIVE.
KEEP TIGHTLY CLOSED.
DO NOT EXPOSE TO AIR AND FIRE.
AIR SENSITIVE
MOISTURE SENSITIVE
CONTAINER SHOULD BE OPENED ONLY BY A TECHNICALLY QUALIFIED PERSON.
HANDLE AND STORE UNDER NITROGEN.
STORE IN A COOL DRY PLACE.
SECTION 9. - - - - - - - PHYSICAL AND CHEMICAL PROPERTIES - - - - - - -
APPEARANCE AND ODOR
WHITE TO OFF-WHITE POWDER
PHYSICAL PROPERTIES
VAPOR DENSITY: >1
SECTION 10. - - - - - - - - -STABILITY AND REACTIVITY - - - - - - - - -
INCOMPATIBILITIES
STRONG OXIDIZING AGENTS
MAY DECOMPOSE ON EXPOSURE TO AIR.
MAY DECOMPOSE ON EXPOSURE TO MOIST AIR OR WATER.
ACIDS
HAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCTS
CARBON MONOXIDE, CARBON DIOXIDE
NITROGEN OXIDES
SECTION 11. - - - - - - - - - TOXICOLOGICAL INFORMATION - - - - - - - -
ACUTE EFFECTS
HARMFUL IF SWALLOWED, INHALED, OR ABSORBED THROUGH SKIN.
MATERIAL IS EXTREMELY DESTRUCTIVE TO TISSUE OF THE MUCOUS MEMBRANES
AND UPPER RESPIRATORY TRACT, EYES AND SKIN.
INHALATION MAY RESULT IN SPASM, INFLAMMATION AND EDEMA OF THE
LARYNX AND BRONCHI, CHEMICAL PNEUMONITIS AND PULMONARY EDEMA.
SYMPTOMS OF EXPOSURE MAY INCLUDE BURNING SENSATION, COUGHING,
WHEEZING, LARYNGITIS, SHORTNESS OF BREATH, HEADACHE, NAUSEA AND
VOMITING.
SECTION 12. - - - - - - - - - ECOLOGICAL INFORMATION - - - - - - - - - -
DATA NOT YET AVAILABLE.
SECTION 13. - - - - - - - - - DISPOSAL CONSIDERATIONS - - - - - - - - -
UNDER AN INERT ATMOSPHERE, CAUTIOUSLY ADD THE MATERIAL TO DRY BUTANOL
IN AN APPROPRIATE SOLVENT. THE CHEMICAL REACTION MAY BE VIGOROUS
AND/OR EXOTHERMIC. PROVISIONS MUST BE MADE FOR THE VENTING OF LARGE
VOLUMES OF HIGHLY FLAMMABLE HYDROGEN AND/OR HYDROCARBON GASES.
NEUTRALIZE THE SOLUTION WITH AQUEOUS ACID. FILTER OFF ANY SOLID RES-
IDUES FOR DISPOSAL AS HAZARDOUS WASTE. BURN THE LIQUID PORTION IN A
CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER.
OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.
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PRODUCT #: 62493 NAME: LITHIUM DIISOPROPYLAMIDE
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Thursday, March 20, 1903 2:50PM
SECTION 14. - - - - - - - - - - TRANSPORT INFORMATION - - - - - - - - -
CONTACT FLUKA CHEMICAL COMPANY FOR TRANSPORTATION INFORMATION.
SECTION 15. - - - - - - - - - REGULATORY INFORMATION - - - - - - - - - -
EUROPEAN INFORMATION
HIGHLY FLAMMABLE
CORROSIVE
R 17
SPONTANEOUSLY FLAMMABLE IN AIR.
R 34
CAUSES BURNS.
HIGHLY FLAMMABLE
S 16
KEEP AWAY FROM SOURCES OF IGNITION - NO SMOKING.
S 27
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING.
S 26
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF
WATER AND SEEK MEDICAL ADVICE.
S 36/37/39
WEAR SUITABLE PROTECTIVE CLOTHING, GLOVES AND EYE/FACE
PROTECTION.
SECTION 16. - - - - - - - - - - OTHER INFORMATION- - - - - - - - - - - -
THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT BUT DOES NOT PURPORT TO
BE ALL INCLUSIVE AND SHALL BE USED ONLY AS A GUIDE. SIGMA, ALDRICH,
FLUKA SHALL NOT BE HELD LIABLE FOR ANY DAMAGE RESULTING FROM HANDLING
OR FROM CONTACT WITH THE ABOVE PRODUCT. SEE REVERSE SIDE OF INVOICE OR
PACKING SLIP FOR ADDITIONAL TERMS AND CONDITIONS OF SALE.
COPYRIGHT 1997 SIGMA CHEMICAL CO., ALDRICH CHEMICAL CO., INC.,
FLUKA CHEMIE AG
LICENSE GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY
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