PRODUCT #: C6763 NAME: CALCIUM CARBONATE
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Wednesday, March 12, 1903 4:06PM
Sigma Chemical Co. Aldrich Chemical Co., Inc. Fluka Chemical Corp.
P.O. Box 14508 1001 West St. Paul 1001 West St. Paul
St. Louis, MO 63178 Milwaukee, WI 53233 Milwaukee, WI 53233
Phone: 314-771-5765 Phone: 414-273-3850 Phone: 414-273-3850
SECTION 1. - - - - - - - - - CHEMICAL IDENTIFICATION- - - - - - - - - -
CATALOG #: C6763
NAME: CALCIUM CARBONATE
SECTION 2. - - - - - COMPOSITION/INFORMATION ON INGREDIENTS - - - - - -
CAS #: 471-34-1
MF: CCAO3
EC NO: 207-439-9
SYNONYMS
AEROMATT * AKADAMA * ALBACAR * ALBACAR 5970 * ALBAFIL * ALBAGLOS *
ALBAGLOS SF * ALLIED WHITING * ATOMIT * ATOMITE * AX 363 * BF 200 *
BRILLIANT 15 * BRILLIANT 1500 * BRITOMYA M * BRITOMYA S * CALCENE CO *
CALCENE NC * CALCENE TM * CALCICOLL * CALCIDAR 40 * CALCILIT 8 *
CALCILIT 100 * CALCIUM CARBONATE (1:1) * CALCIUM MONOCARBONATE *
CALIBRITE * CAL-LIGHT SA * CALMOS * CALMOTE * CALOFIL A 4 * CALOFIL B
1 * CALOFIL E 2 * CALOFORT S * CALOFORT U * CALOFOR U 50 * CALOPAKE F
* CALOPAKE FS * CALOPAKE H * CALOPAKE HIGH OPACITY * CALOPAKE PC *
CALSEEDS * CALTEC * CAMEL-CARB * CAMEL-TEX * CAMEL-WITE * CARBITAL 90
* CARBIUM * CARBIUM MM * CARBOREX 2 * CARUSIS P * CCC G-WHITE * CCC
NO.AA OOLITIC * CCR * CCW * CHEMCARB * CLEFNON * C.I. PIGMENT WHITE
18 * CRYSTIC PREFIL S * DACOTE * DOMAR * DURAMITE * DURCAL 10 *
DURCAL 40 * DURCAL C 640305 * DURCAL 2NH * EGRI M 5 * ESKALON 100 *
ESKALON 200 * ESKALON 400 * ESKALON 800 * ESKALON 1500 * FILTEX WHITE
BASE * FINNCARB 6002 * GAROLITE SA * GILDER'S WHITING * HAKUENKA CC *
HAKUENKA CCR * HAKUENKA DD * HAKUENKA O * HAKUENKA PX * HAKUENKA PZ *
HAKUENKA R 06 * HAKUENKA T-DD * HOMOCAL D * HYDROCARB 60 * HYDROCARB
65 * K 250 * KOTAMITE * KREDAFIL 150 EXTRA * KREDAFIL RM 5 * KS 500 *
KS 1300 * KS 1500 * KS 1800 * KS 2100 * KULU 40 * LEVIGATED CHALK *
MARBLEWHITE 325 * MARFIL * MC-T * MICROCARB * MICROMIC CR 16 *
MICROMYA * MICROWHITE 25 * MONOCALCIUM CARBONATE * MSK-C * MSK-G *
MSK-K * MSK-P * MSK-PO * MSK-V * MULTIFLEX MM * MULTIFLEX SC * N 34 *
N 43 * NCC 45 * NCC-P * NEOANTICID * NEOLITE F * NEOLITE SP * NEOLITE
TPS * NON-FER-AL * NS * NS (CARBONATE) * NS 100 * NS 100 (CARBONATE) *
NS 200 * NS 200 (FILLER) * NS 400 * NS 2500 * NZ * OA-A 1102 * OMYA *
OMYA BLH * OMYA BLP 2 * OMYA BLP 3 * OMYA BLR 3 * OMYA BLRZ * OMYA
BBSH * OMYACARB F * OMYA D 40 * OMYA EXH 1 * OMYALENE G 200 *
OMYALITE 90 * OMYALITE BL * OS-CAL * PIGMENT WHITE 18 * P-LITE 500 *
P-LITE 700 * POLCARB * PREPARED CHALK * PS 100 * PS 100 (CARBONATE) *
PURECAL * PURECALO * PURECAL SC * PURECAL T * PURECAL U * PZ * PZ
(CARBONATE) * QUEENSGATE WHITING * RED BALL * R JUTAN * ROYAL WHITE
LIGHT * RX 2557 * RX 2558 * RX 2559 * SHIPRON A * SILVER W * SL 700 *
SMITHKO KALKARB WHITING * SNOWCAL * SNOWCAL 70 * SNOWCAL 6ML *
SNOWCAL 7ML * SNOWFLAKE WHITE * SNOW TOP * SOCAL * SOCAL D * SOCAL E
2 * SOCAL N 2 * SOCAL N 2S1 * SOCAL P 2 * SOCAL U 1 * SOCAL U 3 *
SOCAL U 1S2 * SOFTON 1000 * SOFTON 1200 * SOFTON 1500 * SOFTON 1800 *
SOFTON 2200 * SOFTON H * SS 30 * SS 30 (CARBONATE) * SS 50 * SS 50
(CARBONATE) * SSB 100 * STANWHITE 500 * STURCAL D * STURCAL H *
STURCAL L * STURCAL LS * STURCAL M * STURCAL X * SUNLIGHT 700 *
SUNLIGHT 800 * SUPER 1500 * SUPER 1700 * SUPER 2000 * SUPERCOAT *
SUPERMITE * SUPER MULTIFEX * SUPER-PFLEX * SUPER 3S * SUPER 5S *
Page 1
PRODUCT #: C6763 NAME: CALCIUM CARBONATE
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Wednesday, March 12, 1903 4:06PM
SUPER SSS * SURFEX MM * SURFIL S * SUSPENSO * SYLACAUGA 88B * T 130-
2500 * TAMA PEARL TP 121 * TAMA PEARL TP 262 * TANCAL 100 * TANCAL
200 * TANCAL PC * TM 1 * TM 1 (FILLER) * TONASO * TOYOFINE TF-X * TP
121 * TP 121 (FILLER) * TP 222 * TP 121 H * TP 222HS * ULTRA-PFLEX *
UNIBUR 70 * VEVETONE * VICRON * VICRON 31-6 * VICRON 41-8 * VICRON 15-
15 * VICRON 25-11 * VIENNA WHITE * VIGOT 15 * WHICA BA * WHITCARB W *
WHITE-POWDER * WHITING * WHITON 450 * WHITON 1500 * WHITON B * WHITON
H * WHITON P 10 * WHITON P 30 * WHITON P 50 * WHITON S * WHITON SB *
WHITON SO * WHITON SS * WHITON SSB * WINNOFIL S * WITCARB * WITCARB P
* WITCARB R * WITCARB RC * WITCARB REGULAR * YORK WHITE * ZG 301 *
SECTION 3. - - - - - - - - - - HAZARDS IDENTIFICATION - - - - - - - - -
LABEL PRECAUTIONARY STATEMENTS
IRRITANT
IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN.
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF
WATER AND SEEK MEDICAL ADVICE.
WEAR SUITABLE PROTECTIVE CLOTHING.
SECTION 4. - - - - - - - - - - FIRST-AID MEASURES- - - - - - - - - - -
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH COPIOUS AMOUNTS OF
WATER FOR AT LEAST 15 MINUTES.
IN CASE OF CONTACT, IMMEDIATELY WASH SKIN WITH SOAP AND COPIOUS
AMOUNTS OF WATER.
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS.
CALL A PHYSICIAN.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
SECTION 5. - - - - - - - - - FIRE FIGHTING MEASURES - - - - - - - - - -
EXTINGUISHING MEDIA
WATER SPRAY.
CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE FOAM.
SPECIAL FIREFIGHTING PROCEDURES
WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO
PREVENT CONTACT WITH SKIN AND EYES.
UNUSUAL FIRE AND EXPLOSIONS HAZARDS
EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
SECTION 6. - - - - - - - - ACCIDENTAL RELEASE MEASURES- - - - - - - - -
WEAR RESPIRATOR, CHEMICAL SAFETY GOGGLES, RUBBER BOOTS AND HEAVY
RUBBER GLOVES.
SWEEP UP, PLACE IN A BAG AND HOLD FOR WASTE DISPOSAL.
AVOID RAISING DUST.
VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE.
SECTION 7. - - - - - - - - - - HANDLING AND STORAGE- - - - - - - - - - -
REFER TO SECTION 8.
SECTION 8. - - - - - - EXPOSURE CONTROLS/PERSONAL PROTECTION- - - - - -
CHEMICAL SAFETY GOGGLES.
COMPATIBLE CHEMICAL-RESISTANT GLOVES.
NIOSH/MSHA-APPROVED RESPIRATOR.
SAFETY SHOWER AND EYE BATH.
MECHANICAL EXHAUST REQUIRED.
DO NOT BREATHE DUST.
AVOID CONTACT WITH EYES, SKIN AND CLOTHING.
WASH THOROUGHLY AFTER HANDLING.
IRRITANT.
KEEP TIGHTLY CLOSED.
STORE IN A COOL DRY PLACE.
SECTION 9. - - - - - - - PHYSICAL AND CHEMICAL PROPERTIES - - - - - - -
Page 2
PRODUCT #: C6763 NAME: CALCIUM CARBONATE
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Wednesday, March 12, 1903 4:06PM
APPEARANCE AND ODOR
WHITE POWDER
PHYSICAL PROPERTIES
SPECIFIC GRAVITY: 2.930
SECTION 10. - - - - - - - - -STABILITY AND REACTIVITY - - - - - - - - -
INCOMPATIBILITIES
STRONG OXIDIZING AGENTS
ACIDS
MAGNESIUM
ALUMINUM
HAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCTS
CARBON MONOXIDE, CARBON DIOXIDE
SECTION 11. - - - - - - - - - TOXICOLOGICAL INFORMATION - - - - - - - -
ACUTE EFFECTS
MAY BE HARMFUL BY INHALATION, INGESTION, OR SKIN ABSORPTION.
CAUSES EYE AND SKIN IRRITATION.
MATERIAL IS IRRITATING TO MUCOUS MEMBRANES AND UPPER
RESPIRATORY TRACT.
TO THE BEST OF OUR KNOWLEDGE, THE CHEMICAL, PHYSICAL, AND
TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED.
RTECS #: FF9335000
CARBONIC ACID, CALCIUM SALT (1:1)
IRRITATION DATA
SKN-RBT 500 MG/24H MOD 28ZPAK -,267,1972
EYE-RBT 750 UG/24H SEV 28ZPAK -,267,1972
TOXICITY DATA
ORL-RAT LD50:6450 MG/KG 28ZPAK -,267,1972
ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES
(RTECS) DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN RTECS FOR
COMPLETE INFORMATION.
SECTION 12. - - - - - - - - - ECOLOGICAL INFORMATION - - - - - - - - - -
DATA NOT YET AVAILABLE.
SECTION 13. - - - - - - - - - DISPOSAL CONSIDERATIONS - - - - - - - - -
BURY IN A LANDFILL SITE APPROVED FOR THE DISPOSAL OF CHEMICAL
AND HAZARDOUS WASTES.
OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.
SECTION 14. - - - - - - - - - - TRANSPORT INFORMATION - - - - - - - - -
CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION INFORMATION.
SECTION 15. - - - - - - - - - REGULATORY INFORMATION - - - - - - - - - -
EUROPEAN INFORMATION
IRRITANT
R 36/37/38
IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN.
S 26
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF
WATER AND SEEK MEDICAL ADVICE.
S 36
WEAR SUITABLE PROTECTIVE CLOTHING.
TLV AND SOURCE
FOR CALCIUM CARBONATE:
ACGIH TLV-TWA: 10 MG/M3.
OSHA PEL: 8H TWA 15 MG/M3 TOTAL PARTICULATE.
OSHA PEL: 8H TWA 5 MG/M3 RESPIRABLE FRACTION.
REVIEWS, STANDARDS, AND REGULATIONS
OEL=MAK
NOHS 1974: HZD M0841; NIS 17; TNF 1433; NOS 12; TNE 18263
NOHS 1974: HZD 15705; NIS 338; TNF 80902; NOS 189; TNE 1002651
Page 3
PRODUCT #: C6763 NAME: CALCIUM CARBONATE
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Wednesday, March 12, 1903 4:06PM
NOES 1983: HZD X6785; NIS 7; TNF 1255; NOS 16; TNE 20008; TFE 656
NOES 1983: HZD X9060; NIS 4; TNF 292; NOS 4; TNE 6239; TFE 2955
NOES 1983: HZD 15705; NIS 392; TNF 131230; NOS 237; TNE 2341639; TFE
392183
EPA TSCA SECTION 8(B) CHEMICAL INVENTORY
EPA TSCA SECTION 8(D) UNPUBLISHED HEALTH/SAFETY STUDIES
EPA TSCA TEST SUBMISSION (TSCATS) DATA BASE, APRIL 1997
NIOSH ANALYTICAL METHOD, 1994: CALCIUM AND COMPOUNDS, 7020
SECTION 16. - - - - - - - - - - OTHER INFORMATION- - - - - - - - - - - -
THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT BUT DOES NOT PURPORT TO
BE ALL INCLUSIVE AND SHALL BE USED ONLY AS A GUIDE. SIGMA, ALDRICH,
FLUKA SHALL NOT BE HELD LIABLE FOR ANY DAMAGE RESULTING FROM HANDLING
OR FROM CONTACT WITH THE ABOVE PRODUCT. SEE REVERSE SIDE OF INVOICE OR
PACKING SLIP FOR ADDITIONAL TERMS AND CONDITIONS OF SALE.
COPYRIGHT 1997 SIGMA CHEMICAL CO., ALDRICH CHEMICAL CO., INC.,
FLUKA CHEMIE AG
LICENSE GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY
Page 4
|