Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
ROVRAL 50 WP 19775 10X0,5KG DEUR 1/6
Version 1 / F Revision Date: 06.07.2004
102000002241 Print Date: 26.11.2004
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE
COMPANY/UNDERTAKING
Product information
Trade name ROVRAL 50 WP 19775 10X0,5KG DEUR
Product code (UVP) 05933315
Product code AE F062470 00 WP50 A3
Product code (EXP) 01671H
Specification 19775
Usage fungicide
Company Bayer CropScience SA
16, rue Jean-Marie Leclair
69009 Lyon
France
Emergency telephone number +33(0)4.72.85.25.25
Telefax +33(0)4.72.85.27.99
Num茅ro INRS +33(0)1.45.42.59.59
2. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical nature
Wettable powder (WP)
Iprodione 50% WP
Hazardous components
Chemical Name CAS-No. / Symbol(s) R-phrase(s) Concentration [%]
EINECS-No.
Iprodione 36734-19-7 Xn, N R40, R50/53 50,00
253-178-9
3. HAZARDS IDENTIFICATION
Risk advice to man and the environment
Limited evidence of a carcinogenic effect.
Very toxic to aquatic organisms.
May cause long-term adverse effects in the aquatic environment.
4. FIRST AID MEASURES
General advice
If you feel unwell, seek medical advice (show the label where possible).
Skin contact
After contact with skin, wash immediately with plenty of water.
Eye contact
In case of contact with the eyes rinse thoroughly with plenty of water or with an eye-cleaning
solution.
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
ROVRAL 50 WP 19775 10X0,5KG DEUR 2/6
Version 1 / F Revision Date: 06.07.2004
102000002241 Print Date: 26.11.2004
Ingestion
If swallowed, seek medical advice immediately and show this container or label.
Notes to physician
Risks
Medical supervision for minimum 48 hours.
Treatment
There is no antidote.
Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
foam
dry powder
carbon dioxide (CO2)
Specific hazards during fire fighting
The product itself does not burn.
In the event of fire the following can be released:
carbon monoxide (CO)
carbon dioxide (CO2)
hydrogen chloride (HCl)
nitrogen oxides (NOx)
Special protective equipment for fire-fighters
Use breathing apparatus.
Further information
Contain the spread of the fire-fighting media.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions
Use personal protective equipment.
Methods for cleaning up
Sweep up or vacuum up spillage and collect in suitable container for disposal.
Pick up and fill the product into a tightly closed container.
When picked up, treat material as prescribed in Ch. 13. "Disposal considerations".
7. HANDLING AND STORAGE
Handling
Advice on safe handling
Smoking, eating and drinking should be prohibited in the application area.
Advice on protection against fire and explosion
Dust explosivity : sensitive
Storage
Requirements for storage areas and containers
Keep out of the reach of children.
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
ROVRAL 50 WP 19775 10X0,5KG DEUR 3/6
Version 1 / F Revision Date: 06.07.2004
102000002241 Print Date: 26.11.2004
Advice on common storage
Keep away from food, drink and animal feedingstuffs.
Suitable materials
Rigid material with protection against moisture
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering measures
Provide appropriate exhaust ventilation at places where dust is formed.
Personal protective equipment
Respiratory protection Particle filter half mask, filter FFP2 (Standard EN149)
Hand protection Plastic-coated gloves
Eye protection Safety glasses with side-shields
Skin and body protection Light protective clothing
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Form wettable powder
Colour light grey
Safety data
pH 5-6
Determined as a 1% emulsion in distilled water.
Density 0,35 g/l
Tapped
Water solubility dispersible
10. STABILITY AND REACTIVITY
Hazardous reactions No hazardous reactions when stored and handled according to
prescribed instructions.
Stable under normal conditions.
11. TOXICOLOGICAL INFORMATION
Acute oral toxicity LD50 (rat) > 2.000 mg/kg
Acute inhalation toxicity LC50 (rat) >> 5 mg/l
Exposure time: 4 h
Highest attainable concentration.
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
ROVRAL 50 WP 19775 10X0,5KG DEUR 4/6
Version 1 / F Revision Date: 06.07.2004
102000002241 Print Date: 26.11.2004
Acute dermal toxicity LD50 (rat) > 2.000 mg/kg
Skin irritation non-irritant (rabbit)
Eye irritation non-irritant (rabbit)
Sensitization Non-sensitizing (guinea pig)
12. ECOLOGICAL INFORMATION
Ecotoxicity effects
Toxicity to fish LC50 (Rainbow trout (Oncorhynchus mykiss)) 24,6 mg/l
Exposure time: 96 h
Toxicity to daphnia EC50 (Water flea (Daphnia magna)) 0,72 mg/l
Exposure time: 48 h
Toxicity to algae IC50 (Scenedesmus subspicatus) 7,4 mg/l
Exposure time: 72 h
13. DISPOSAL CONSIDERATIONS
Product
Must be incinerated in a suitable incineration plant holding a permit delivered by the competent
authorities.
Contaminated packaging
Packaging that cannot be cleaned should be disposed of as product waste.
Waste key for the unused product
020108 agrochemical waste containing dangerous substances
14. TRANSPORT INFORMATION
ADR/RID/ADNR
UN-No 3077
Labels 9
Packaging group III
Hazard no. 90
Description of the goods UN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
SOLID, N.O.S.
(IPRODIONE MIXTURE)
IMDG
UN-No 3077
Class 9
Packaging group III
EmS F-A , S-F
Marine pollutant Marine pollutant
Description of the goods ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID,
N.O.S.
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
ROVRAL 50 WP 19775 10X0,5KG DEUR 5/6
Version 1 / F Revision Date: 06.07.2004
102000002241 Print Date: 26.11.2004
(IPRODIONE MIXTURE )
IATA
UN-No 3077
Class 9
Packaging group III
Description of the goods ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID,
N.O.S.
(IPRODIONE MIXTURE )
15. REGULATORY INFORMATION
Classification and labelling in accordance with the EC Directive on dangerous preparations
1999/45/EC as amended.
Hazardous components which must be listed on the label:
鈥? Iprodione
Symbol(s)
Xn Harmful
N Dangerous for the environment
R-phrase(s)
R40 Limited evidence of a carcinogenic effect.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
S-phrase(s)
S35 This material and its container must be disposed of in a safe way.
S36/37 Wear suitable protective clothing and gloves.
S57 Use appropriate containment to avoid environmental contamination.
Classement FRANCE (d茅cision de la Commission des Toxiques)
Classification:
Not classified
Further information
WHO-classification: III (Slightly hazardous)
Legislation on the control of Rubrique n掳1155: D茅p么ts de produits agropharmaceutiques.
major-accident hazards
involving dangerous
substances
Occupational health precautions
- Art. R. 231-56 脿 R. 231-56-11: R猫gles particuli猫res de pr茅vention du risque canc茅rog猫ne,
mutag猫ne ou toxique pour la reproduction.
16. OTHER INFORMATION
Further information
Text of R phrases mentioned in Section 2:
R40 Limited evidence of a carcinogenic effect.
R50 Very toxic to aquatic organisms.
R53 May cause long-term adverse effects in the aquatic environment.
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
ROVRAL 50 WP 19775 10X0,5KG DEUR 6/6
Version 1 / F Revision Date: 06.07.2004
102000002241 Print Date: 26.11.2004
The advice on classification in section 15 of this Safety Data Sheet is based on European Directive
on Preparations (1999/45/EC and its subsequent adaptations). The legislation on pesticide
preparations should be applied by EU Member States not later than 30 July 2004.
The information provided in this safety data sheet has been provided according the requirements
from the French modified decree "arr锚t茅 du 5 janvier 1993". This sheet complements the technical
sheet but does not replace it. The information contained in this sheet is based on knowledge of the
product at the date of publication and is given in good faith. Users are further reminded of the
possible risks of using a product for purposes other than those for which it was intended. The user is
fully responsible for taking all the necessary precautions whilst using the product.The aim of the
statutory regulations indicated is to help the user to fulfil his obligations regarding the use of
hazardous products. This list should not be considered as exhaustive. It does not exonerate the user
from fulfilling other existing legal obligations in addition to those mentioned, relating to the use and
storage of the product. This remains solely the responsibility of the user.
Changes since the last version will be highlighted in the margin. This version replaces all previous
versions.
|