Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
SPORGON 20898 10X1KG TR 1/7
Version 3 / D Revision Date: 08.03.2004
102000000859 Print Date: 26.11.2004
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE
COMPANY/UNDERTAKING
Product information
Trade name SPORGON 20898 10X1KG TR
Product code (UVP) 05935229
Product code AE B080109 00 WP50 A1
Specification 20898
Usage fungicide
Company Bayer CropScience AG
Alfred-Nobel-Stra脽e 50
40789 Monheim
Germany
Telephone +49(0)69-305-5748
Telefax +49(0)69-305-80950
Responsible Department Material and Transport Safety Management
+49(0)69-305-82369/12588
Emergency telephone number +49(0)2133-51-4233 (Sicherheitszentrale Dormagen, Bayer AG)
2. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical nature
Wettable powder (WP)
50% Prochloraz manganese chloride complex (equivalent to 46,1% Prochloraz)
Hazardous components
Chemical Name CAS-No. / Symbol(s) R-phrase(s) Concentration [%]
EINECS-No.
Prochloraz Manganese 75747-77-2 Xn, N R22, R50/53 50,00
chloride complex 278-301-3
Alkylated naphthalene 68425-94-5 Xi R36/38 > 5,00 - < 25,00
sulfonate, formaldehyde
polymer, sodium salt
3. HAZARDS IDENTIFICATION
Risk advice to man and the environment
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
4. FIRST AID MEASURES
General advice
Remove contaminated clothing immediately and dispose of safely. Symptoms of poisoning may
not appear for several hours. Keep under medical supervision for at least 48 hours.
Inhalation
Move the patient to fresh air and keep at rest. In the event of symptoms obtain medical
treatment.
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
SPORGON 20898 10X1KG TR 2/7
Version 3 / D Revision Date: 08.03.2004
102000000859 Print Date: 26.11.2004
Skin contact
When in contact with the skin, clean with soap and water. If skin problems persist, seek medical
advice.
Eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
Ingestion
When swallowed accidentally, do not induce vomiting, get medical help. Ingest activated
charcoal. Rinse out mouth and give plenty of water to drink.
Notes to physician
Symptoms
gastro-intestinal irritation.
Risks
Chronic exposure damages the central nervous system and the liver.
Treatment
In the event of a mouthful or more being ingested, the following measures should be
considered:
Gastric lavage with charcoal, if necessary further treatment.
Monitoring of liver and central nervous system
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Specific hazards during fire fighting
In the event of fire the following can be released:
nitrous gases (NOx)
carbon monoxide (CO)
hydrogen chloride (HCl)
Under certain conditions of combustion traces of other toxic substances cannot be excluded
Special protective equipment for fire-fighters
In the event of fire, wear self-contained breathing apparatus.
Wear full protective suit.
Further information
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with
local regulations.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions
Wear personal protective equipment. Unprotected persons must be kept away.
Environmental precautions
Do not discharge into the drains/surface water/groundwater.
If the product contaminates rivers and lakes or drains inform respective authorities.
Methods for cleaning up
Take up mechanically and collect in suitable container for disposal.
Dispose of contaminated material as prescribed
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
SPORGON 20898 10X1KG TR 3/7
Version 3 / D Revision Date: 08.03.2004
102000000859 Print Date: 26.11.2004
Additional advice
Information regarding personal protective equipment, see section 8.
Information regarding waste disposal, see section 13.
7. HANDLING AND STORAGE
Handling
Advice on safe handling
Keep container tightly closed.
Use only in area provided with appropriate exhaust ventilation.
Advice on protection against fire and explosion
Keep away from sources of ignition - No smoking.
Dust may form explosive mixtures with air.
Storage
Requirements for storage areas and containers
Keep tightly closed in a dry, cool and well-ventilated place.
Further information on storage conditions
The storage temperature should lie between 0 掳C and 30 掳C, maximum up to 50 掳C.
Advice on common storage
Keep away from food, drink and animal feedingstuffs.
German storage class 11 Combustible Solids
Storage stability
Storage period 24 Months
Storage temperature < 30 掳C
Humidity requirements Keep in a dry place.
Other data Stable under recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Additional advice
Observe General Limit For Dust (6mg/m鲁)
Engineering measures
See chapter 7; no measures exceeding those mentioned are necessary.
Personal protective equipment
Respiratory protection Particle filter half mask, filter FFP2 (Standard EN149)
Hand protection protective gloves
Eye protection tightly fitting safety goggles
Skin and body protection dust impervious protective suit
Hygiene measures
Keep away from food, drink and animal feedingstuffs.
After worktime and during work intervals the affected skin areas must be thoroughly cleaned.
Remove soiled clothing immediately.
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
SPORGON 20898 10X1KG TR 4/7
Version 3 / D Revision Date: 08.03.2004
102000000859 Print Date: 26.11.2004
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Form powder, Finely ground
Colour white
Odour almost odourless
Safety data
pH 7,5 at 10 g/l ( 20 掳C)
Autoignition temperature The product is not self-ignitable.
Dust explosion class St1
Bulk density 270 kg/m3
Water solubility dispersible
Partition coefficient (n- log Pow: 4,38
octanol/water) The value mentioned relates to the active ingredient prochloraz.
Oxidizing properties no oxidising properties
Explosivity 92/69/EEC, A.14 / OECD 113
The product is not explosive.
10. STABILITY AND REACTIVITY
Thermal decomposition No decomposition if used as directed.
Hazardous reactions No hazardous reactions when stored and handled according to
prescribed instructions.
Dust may form explosive mixtures with air.
11. TOXICOLOGICAL INFORMATION
Acute oral toxicity LD50 (rat) 2.700 mg/kg
Acute inhalation toxicity LC50 (rat) > 2,66 mg/l
Exposure time: 4 h
Highest attainable concentration.
Acute dermal toxicity LD50 (rat) > 2.000 mg/kg
Skin irritation non-irritant (rabbit)
Eye irritation slight irritant effect - does not require labelling (rabbit)
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
SPORGON 20898 10X1KG TR 5/7
Version 3 / D Revision Date: 08.03.2004
102000000859 Print Date: 26.11.2004
Sensitization non-sensitizing (guinea pig)
OECD Test Guideline 406, Magnusson & Kligman test
The value mentioned relates to the active ingredient prochloraz-
manganese.
12. ECOLOGICAL INFORMATION
Elimination information (persistence and degradability)
Bioaccumulation Rainbow trout (Oncorhynchus mykiss)
Bioconcentration factor (BCF): 200
The value mentioned relates to the active ingredient prochloraz.
Ecotoxicity effects
Toxicity to fish LC50 (Rainbow trout (Oncorhynchus mykiss)) 2,4 mg/l
Exposure time: 96 h
Toxicity to daphnia EC50 (Water flea (Daphnia magna)) 4,3 mg/l
Exposure time: 48 h
Toxicity to algae IC50 (Selenastrum capricornutum) 0,1 mg/l
Exposure time: 72 h
The value mentioned relates to the active ingredient prochloraz.
13. DISPOSAL CONSIDERATIONS
Product
Must not be disposed of together with household garbage. Do not allow product to reach
sewage system.
Dispose of as hazardous waste.
Contaminated packaging
Do not use containers for other products.
Dispose of as unused product.
Waste key for the unused product
020108 agrochemical waste containing dangerous substances
14. TRANSPORT INFORMATION
ADR/RID/ADNR
UN-No 3077
Labels 9
Packaging group III
Hazard no. 90
Description of the goods UN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
SOLID, N.O.S.
(PROCHLORAZ MANGANESE CHLORIDE COMPLEX
MIXTURE)
IMDG
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
SPORGON 20898 10X1KG TR 6/7
Version 3 / D Revision Date: 08.03.2004
102000000859 Print Date: 26.11.2004
UN-No 3077
Class 9
Packaging group III
EmS F-A , S-F
Marine pollutant Marine pollutant
Description of the goods ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID,
N.O.S.
(PROCHLORAZ MANGANESE CHLORIDE COMPLEX
MIXTURE )
IATA
UN-No 3077
Class 9
Packaging group III
Description of the goods ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID,
N.O.S.
(PROCHLORAZ MANGANESE CHLORIDE COMPLEX
MIXTURE )
15. REGULATORY INFORMATION
The product is classified and labelled in accordance with the EC Directive on dangerous
preparations 1999/45/EC as amended.
Symbol(s)
N Dangerous for the environment
R-phrase(s)
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
S-phrase(s)
S35 This material and its container must be disposed of in a safe way.
S57 Use appropriate containment to avoid environmental contamination.
Exceptional labelling of special preparations
To avoid risks to man and the environment, comply with the instructions for use.
National legislation
Water contamination class WGK 3 highly water endangering
(Germany) Classification according to VwVwS, Annex 4
Legislation on the control of Subjected to the "Disasters and Major Accidents Act "
major-accident hazards Annex I, list of dangerous substances, No. 9a
involving dangerous
substances
16. OTHER INFORMATION
Further information
Text of R phrases mentioned in Section 2:
R22 Harmful if swallowed.
R36/38 Irritating to eyes and skin.
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
SPORGON 20898 10X1KG TR 7/7
Version 3 / D Revision Date: 08.03.2004
102000000859 Print Date: 26.11.2004
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
The information given in this Data Sheet has been included in accordance with the guidelines
established by EC Directive 1991/155/EC as amended. This data sheet complements the user's
instructions, but does not replace them. The information it contains is based on the knowledge
available about the product concerned at the time it was compiled. Users are further reminded of the
possible risks of using a product for purposes other than those for which it was intended. The
required information complies with current EEC legislation. Addressees are requested to observe
any additional national requirements.
The advice on classification in section 15 of this Safety Data Sheet is based on European Directive
on Preparations (1999/45/EC and its subsequent adaptations). The legislation on pesticide
preparations should be applied by EU Member States not later than 30 July 2004.
Changes since the last version will be highlighted in the margin. This version replaces all previous
versions.
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