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MSDS Material Safety Data Sheet
CAS

126801-58-9
1310-73-2
151-21-3

File Name: bayercropscience_com_tr---sunrice.asp
Bayer Environmental Science
SAFETY DATA SHEET according to EC Directive 2001/58/EC

SUNRICE 60 WG 21541 10X10X0,01KG TR 1/8
Version 1 / F Revision Date: 30.01.2004
102000000698 Print Date: 26.11.2004


1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE
COMPANY/UNDERTAKING

Product information
Trade name SUNRICE 60 WG 21541 10X10X0,01KG TR
Product code (UVP) 05940478
Product code AE F095404 00 WG60 A2
Specification 21541
Usage herbicide
Company Bayer Environmental Science
16, rue Jean-Marie Leclair
69009 Lyon
France

Emergency telephone number +33(0)4.72.85.25.25
Telefax +33(0)4.72.85.27.99
Num茅ro INRS +33(0)1.45.42.59.59

2. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical nature
Water dispersible granules (WG)
ethoxysulfuron 60 %-w/w
Hazardous components
Chemical Name CAS-No. / Symbol(s) R-phrase(s) Concentration [%]
EINECS-No.
Ethoxysulfuron 126801-58-9 N R50/53 60,00

Perfluorinated Phosphinic- Xn, N R22, R51/53 >= 0,10
/Phosphonic acids
Sodium hydroxide 1310-73-2 C R35 >= 5,00
215-185-5
Sodium lauryl sulfate 151-21-3 Xn R20/22, >= 5,00
205-788-1 R37/38, R41


3. HAZARDS IDENTIFICATION

Risk advice to man and the environment
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Dust may form explosive mixtures with air.


4. FIRST AID MEASURES
Inhalation
Move the patient to fresh air and keep at rest. If symptoms persist, call a physician.
Skin contact
Take off contaminated clothing and shoes immediately. Wash off with soap and water. If
symptoms persist, call a physician.
Bayer Environmental Science
SAFETY DATA SHEET according to EC Directive 2001/58/EC

SUNRICE 60 WG 21541 10X10X0,01KG TR 2/8
Version 1 / F Revision Date: 30.01.2004
102000000698 Print Date: 26.11.2004

Eye contact
Rinse with plenty of water. If eye irritation persists, consult a specialist.
Ingestion
Do not induce vomiting. Rinse mouth thoroughly with water. Give small amounts of water to
drink. If symptoms persist, call a physician.
Notes to physician
Symptoms
To date no symptoms are known.
Treatment
Initial treatment should be symptomatic and supportive.
In the event of a mouthful or more being ingested, the following measures should be
considered:
If ingested, irrigate the stomach using activated charcoal in addition.
Elimination by dialysis (forced alkaline diuresis).


5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
water spray
foam
Extinguishing media which must not be used for safety reasons
dry powder
carbon dioxide (CO2)
high volume water jet
Specific hazards during fire fighting
In the event of fire the following can be released:
carbon dioxide (CO2)
carbon monoxide (CO)
nitrogen oxides (NOx)
Sulphur oxides
phosphorus oxides (eg phosphorus pentoxide)
hydrogen fluoride
hydrogen cyanide (hydrocyanic acid)
Special protective equipment for fire-fighters
In the event of fire, wear self-contained breathing apparatus.
Wear full protective suit.
Further information
Avoid generation of dust clouds
Collect contaminated fire extinguishing water separately. This must not be discharged into
drains.


6. ACCIDENTAL RELEASE MEASURES
Personal precautions
Use personal protective equipment.
Evacuate personnel to safe areas.
Environmental precautions
Do not flush into surface water or sanitary sewer system.
Bayer Environmental Science
SAFETY DATA SHEET according to EC Directive 2001/58/EC

SUNRICE 60 WG 21541 10X10X0,01KG TR 3/8
Version 1 / F Revision Date: 30.01.2004
102000000698 Print Date: 26.11.2004

Methods for cleaning up
Avoid dust formation and electrical charging (sparking) because dust explosion might occur.
Contain and collect spillage with an electrically protected vacuum cleaner or by wet-brushing
and place in container for disposal according to local regulations (see section 13).
Additional advice
Information regarding safe handling, see section 7.
Information regarding personal protective equipment, see section 8.
Information regarding waste disposal, see section 13.


7. HANDLING AND STORAGE
Handling
Advice on safe handling
Avoid dust formation.
Advice on protection against fire and explosion
During processing, dust may form explosive mixture in air.
Avoid deposition of dust
Advice on protection against fire and explosion
The product neither sensitive to impacts nor to rub effects and therefore not explosive.

Storage
Requirements for storage areas and containers
Keep containers tightly closed in a dry, cool and well-ventilated place.
Further information on storage conditions
The storage temperature should lie between 0 掳C and 30 掳C, maximum up to 50 掳C.
Protect against atmospheric moisture and water
Advice on common storage
Keep away from food, drink and animal feedingstuffs.
Storage stability
Storage period > 36 Months
Storage temperature 20 - 30 掳C


8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Components with workplace control parameters
Components CAS-No. Control parameters Update Basis
Sodium hydroxide 1310-73-2 2 mg/m3 (VME) 1999 INRS (FR)

Engineering measures
See chapter 7; no measures exceeding those mentioned are necessary.

Personal protective equipment
Respiratory protection Short term: filter apparatus, Filter P2

Hand protection PVC disposable gloves
nitrile rubber
Bayer Environmental Science
SAFETY DATA SHEET according to EC Directive 2001/58/EC

SUNRICE 60 WG 21541 10X10X0,01KG TR 4/8
Version 1 / F Revision Date: 30.01.2004
102000000698 Print Date: 26.11.2004

Eye protection Safety glasses / face shield

Skin and body protection Light protective clothing, thick material

Hygiene measures
When using, do not eat, drink or smoke.
Wash hands and face before breaks and immediately after handling the product.
Protective measures
Avoid contact with eyes.
Avoid contact with skin.


9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance
Form fine granules
Colour brown
Odour slightly acidic
Safety data
pH 7,9
Determined as a 1% suspension in distilled water.

Flammability (solid, gas) The product is not flammable.
92/69/EEC, A.10

Ignition temperature 430 掳C

Autoignition temperature 388 掳C
92/69/EEC, A.16
A exotherm reaction occurs at approx. 200 掳C.

Lower explosion limit 500 g/m3

Dust explosion class St1

Bulk density 610 - 680 g/l

Water solubility at 20 掳C
dispersible

Partition coefficient (n- POW: 391
octanol/water) log Pow: 2,59
The value mentioned relates to the active ingredient.

Impact Sensitivity Not impact-sensitive

Combustion number CN5 Complete combustion with flames

Explosivity 92/69/EEC, A.14 / OECD 113
Not explosive

Dust content almost dustfree
Bayer Environmental Science
SAFETY DATA SHEET according to EC Directive 2001/58/EC

SUNRICE 60 WG 21541 10X10X0,01KG TR 5/8
Version 1 / F Revision Date: 30.01.2004
102000000698 Print Date: 26.11.2004

Other information On the basis of the chemical structure of the substance it may be
assumed that the substance has no oxidising properties. The
substance has no functional groups that could have an oxidising
effect.

Other information Product is hygroscopic.



10. STABILITY AND REACTIVITY
Hazardous reactions Stable under recommended storage conditions.



11. TOXICOLOGICAL INFORMATION
Acute oral toxicity LD50 (rat) 2.811 mg/kg
Test conducted with a similar formulation.

Acute inhalation toxicity LC50 (rat) > 3,26 mg/l
Exposure time: 4 h
Test conducted with a similar formulation.
Highest attainable concentration.
Not relevant because of low dust formation.

Acute dermal toxicity LD50 (rat) > 2.000 mg/kg
Test conducted with a similar formulation.

Skin irritation No skin irritation (rabbit)
Test conducted with a similar formulation.

Eye irritation No eye irritation (rabbit)
Test conducted with a similar formulation.

Sensitization non-sensitizing (guinea pig)
OECD Test Guideline 406, Buehler test
Test conducted with a similar formulation.

Assessment mutagenicity
Tests on bacterial or mammalian cell cultures did not show mutagenic effects.
Assessment carcinogenicity
Did not show carcinogenic effects in animal experiments.
Assessment toxicity to reproduction
No indications of reprotoxic effects were observed in reproduction studies in animals.
Assessment teratogenicity
Did not show teratogenic effects in animal experiments., Ingestion of excessive amounts by
pregnant animals resulted in maternal and foetal toxicity.


12. ECOLOGICAL INFORMATION

Ecotoxicity effects
Bayer Environmental Science
SAFETY DATA SHEET according to EC Directive 2001/58/EC

SUNRICE 60 WG 21541 10X10X0,01KG TR 6/8
Version 1 / F Revision Date: 30.01.2004
102000000698 Print Date: 26.11.2004

Toxicity to fish LC50 (Rainbow trout (Oncorhynchus mykiss)) 72,4 mg/l
Exposure time: 96 h
Test conducted with a similar formulation.

Toxicity to daphnia EC50 (Water flea (Daphnia magna)) 115 mg/l
Exposure time: 48 h
Test conducted with a similar formulation.

Toxicity to algae EC50 (Scenedesmus subspicatus) 0,33 mg/l
Exposure time: 72 h
Test conducted with a similar formulation.



13. DISPOSAL CONSIDERATIONS
Product
Do not dispose of waste into sewer.
Dispose of by incineration in an authorised special waste incineration plant. Comply with local
legislation.
Contaminated packaging
Clean container with water.
Puncture container to avoid re-use.
Must be incinerated in a suitable incineration plant holding a permit delivered by the competent
authorities.


14. TRANSPORT INFORMATION

ADR/RID/ADNR
UN-No 3077
Labels 9
Packaging group III
Hazard no. 90
Description of the goods UN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
SOLID, N.O.S.
(ETHOXYSULFURON MIXTURE)

IMDG
UN-No 3077
Class 9
Packaging group III
Marine pollutant Marine pollutant
Description of the goods ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID,
N.O.S.
(ETHOXYSULFURON MIXTURE )

IATA
UN-No 3077
Class 9
Packaging group III
Description of the goods ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID,
N.O.S.
(ETHOXYSULFURON MIXTURE )
Bayer Environmental Science
SAFETY DATA SHEET according to EC Directive 2001/58/EC

SUNRICE 60 WG 21541 10X10X0,01KG TR 7/8
Version 1 / F Revision Date: 30.01.2004
102000000698 Print Date: 26.11.2004



15. REGULATORY INFORMATION
The product is classified and labelled in accordance with the EC Directive on dangerous
preparations 1999/45/EC as amended.

Symbol(s)
N Dangerous for the environment
R-phrase(s)
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
S-phrase(s)
S35 This material and its container must be disposed of in a safe way.
S57 Use appropriate containment to avoid environmental contamination.
Exceptional labelling of special preparations
Restricted to professional users.
To avoid risks to man and the environment, comply with the instructions for use.
Further information
WHO-classification: III (Slightly hazardous)


National legislation
Risk classification according not applicable
to BetrSichV (Germany)
Legislation on the control of Rubrique n掳1155: D茅p么ts de produits agropharmaceutiques.
major-accident hazards
involving dangerous
substances
Occupational health precautions
Work limitations for youth should be observed: - 94/33/EC und 2001/581/EC


16. OTHER INFORMATION

Further information
Text of R phrases mentioned in Section 2:
R20/22 Harmful by inhalation and if swallowed.
R22 Harmful if swallowed.
R35 Causes severe burns.
R37/38 Irritating to respiratory system and skin.
R41 Risk of serious damage to eyes.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
The advice on classification in section 15 of this Safety Data Sheet is based on European Directive
on Preparations (1999/45/EC and its subsequent adaptations). The legislation on pesticide
preparations should be applied by EU Member States not later than 30 July 2004.
This information is based on our present state of knowledge. It should not therefore be construed as
guaranteeing specific properties of the products described or their suitability for a particular
application.
The information given in this Data Sheet has been included in accordance with the guidelines
established by EC Directive 1991/55/EC as amended. This data sheet complements the user's
Bayer Environmental Science
SAFETY DATA SHEET according to EC Directive 2001/58/EC

SUNRICE 60 WG 21541 10X10X0,01KG TR 8/8
Version 1 / F Revision Date: 30.01.2004
102000000698 Print Date: 26.11.2004

instructions, but does not replace them. The information it contains is based on the knowledge
available about the product concerned at the time it was compiled. Users are further reminded of the
possible risks of using a product for purposes other than those for which it was intended. The
required information complies with current EEC legislation. Addressees are requested to observe
any additional national requirements.

Changes since the last version will be highlighted in the margin. This version replaces all previous
versions.

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