Material Safety Data Sheet
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: Py-Ran 庐
Reference Number: AST10050
Date: October 23, 2006
Chemical Name: Mixture of Phosphoric Acid, Calcium Salt and
Phosphoric Acid, Aluminum Salt
Synonyms: MCP; MAL;
Company Information:
ICL PERFORMANCE PRODUCTS LP
622 Emerson Road - Suite 500
St. Louis, Missouri 63141
Emergency telephone: In USA call CHEMTREC: 1 800 424 9300
In Canada call CANUTEC: 1 613 996 6666
General Information: +1 800 244 6169 (Worldwide)
2. COMPOSITION/INFORMATION ON INGREDIENTS
Component CAS No.
Monocalcium Phosphate Anhydrous 7758-23-8
Monoaluminum Phosphate Anhydrous 7784-30-7
Dicalcium Phosphate Anhydrous 7757-93-9
Amorphous Percipitated Silicon Dioxide 7631-86-9
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Appearance and Odor: White crystals with no odor
WARNING STATEMENTS
NO SIGNIFICANT HAZARDS ASSOCIATED WITH THIS MATERIAL
POTENTIAL HEALTH EFFECTS
Likely Routes of Exposure: Skin contact and inhalation
EYE CONTACT: No more than slightly irritating based on toxicity studies with a similar material.
The dry powder may cause foreign body irritation in some individuals.
SKIN CONTACT: No more than slightly toxic or slightly irritating based on toxicity studies with a
similar material. Prolonged contact with the dry powder may cause drying or chapping of the
skin.
ICL Performance Products LP Material Safety Data Sheet
Material: Py-Ran 庐 Page 2 of 4
Reference No.: AST10050 October 23, 2006
INHALATION: Inhalation of the dust may cause coughing and sneezing.
INGESTION: Not toxic if swallowed based on toxicity studies with a similar material. No
significant adverse health effects are expected to develop if only small amounts (less than a
mouthful) are swallowed.
Refer to Section 11 for toxicological information.
4. FIRST AID MEASURES
IF IN EYES OR ON SKIN, immediate first aid is not likely to be required. However, this material
can be removed with water. Remove material from eyes, skin and clothing. Wash heavily
contaminated clothing before reuse.
IF INHALED, immediate first aid is not likely to be required. However, if symptoms occur, remove
to fresh air.
IF SWALLOWED, immediate first aid is not likely to be required. A physician or Poison Control
Center can be contacted for advice.
5. FIRE FIGHTING MEASURES
FLASH POINT: Not combustible
HAZARDOUS PRODUCTS OF COMBUSTION: Not applicable
EXTINGUISHING MEDIA: Not applicable
UNUSUAL FIRE AND EXPLOSION HAZARDS: None known
6. ACCIDENTAL RELEASE MEASURES
In case of spill, sweep, scoop or vacuum and remove. Flush residual spill area with water.
Refer to Section 13 for disposal information and Sections 14 and 15 for reportable quantity
information.
7. HANDLING AND STORAGE
HANDLING
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICES.
THESE PRACTICES INCLUDE AVOIDING UNNECESSARY EXPOSURE AND REMOVAL OF
MATERIAL FROM EYES, SKIN AND CLOTHING.
STORAGE: Store in a cool, dry place to maintain product performance.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
EYE PROTECTION: This product does not cause significant eye irritation or eye toxicity requiring
special protection. Use good industrial practice to avoid eye contact.
SKIN PROTECTION: Although this product does not present a significant skin concern, minimize
skin contamination by following good industrial practice. Wearing protective gloves is
recommended. Wash hands and contaminated skin thoroughly after handling.
RESPIRATORY PROTECTION: Avoid breathing dust. Use NIOSH/MSHA approved respiratory
protection equipment when airborne exposure is excessive. Consult the respirator manufacturer
to determine appropriate type equipment for a given application. Observe respirator use
limitations specified by NIOSH/MSHA or the manufacturer. Respiratory protection programs
must comply with 29 C.F.R. 1910.134.
ICL Performance Products LP Material Safety Data Sheet
Material: Py-Ran 庐 Page 3 of 4
Reference No.: AST10050 October 23, 2006
VENTILATION: Provide natural or mechanical ventilation to control exposure levels below
airborne exposure limits (see below). The use of local mechanical exhaust ventilation is
preferred at sources of air contamination such as open process equipment.
AIRBORNE EXPOSURE LIMITS: OSHA and ACGIH have not established specific exposure
limits for this material. However, OSHA and ACGIH have established limits for particulates not
otherwise classified (PNOC) which are the least stringent exposure limits applicable to dusts.
OSHA PEL ACGIH TLV
15 mg/m3 (total dust) 8-hr TWA 10 mg/m3 (inhalable) 8-hr TWA
5 mg/m3 (respirable) 8-hr TWA 3 mg/m3 (respirable) 8-hr TWA
This product contains a trace amount (<2%) of amorphorus percipitated silicon dioxide.
CAS # 11296-00-8 (CAS # 7631-86-9 for TSCA purposes)
OSHA PEL-TWA ACGIH TLV-TWA
amorphous percipitated 20 mppcf 10 mg/m3, Inhalable particulate
silicon dioxide 3 mg/m3, Respirable particulate
Components referred to herein may be regulated by specific Canadian provincial legislation.
Please refer to exposure limits legislated for the province in which the substance will be used.
9. PHYSICAL AND CHEMICAL PROPERTIES
Chemical Formula: Ca(H2PO4)2
Appearance: White crystals
Solubility in Water: 8 gm/l @ 30 degrees C (86 degrees F)
Neutralizing Value 80 min.
NOTE: These physical data are typical values based on material tested but may vary from
sample to sample. Typical values should not be construed as a guaranteed analysis of any
specific lot or as specifications for the product.
10. STABILITY AND REACTIVITY
STABILITY: Product is stable under normal conditions of storage and handling.
MATERIALS TO AVOID: None known
HAZARDOUS DECOMPOSITION PRODUCTS: None known
HAZARDOUS POLYMERIZATION: Will not occur
11. TOXICOLOGICAL INFORMATION
ICL Performance Products LP has not conducted toxicity studies with this material and no data
was found in a reasonably extensive search of the literature. However, data on a similar material
are given below:
Oral - rat LD50: 7,100 mg/kg; practically nontoxic
Dermal - rabbit LD50: >7,940 mg/kg; practically nonirritating
Eye Irritation - rabbit: 9.3/110.0; slightly irritating
Skin Irritation - rabbit: 0.0/8.0; nonirritating
No adverse genetic changes were reported in standard tests using material and yeast cells. No
birth defects were reported in mice, rats or rabbits given this material during pregnancy.
12. ECOLOGICAL INFORMATION
ICL Performance Products LP has not conducted environmental toxicity or biodegradation
studies with this product.
ICL Performance Products LP Material Safety Data Sheet
Material: Py-Ran 庐 Page 4 of 4
Reference No.: AST10050 October 23, 2006
13. DISPOSAL CONSIDERATIONS
This material when discarded is not a hazardous waste as that term is defined by the Resource,
Conservation and Recovery Act (RCRA), 40 CFR 261. Dry material may be landfilled or recycled
in accordance with local, state and federal regulations. Consult your attorney or appropriate
regulatory officials for information on such disposal.
14. TRANSPORT INFORMATION
The data provided in this section is for information only. Please apply the appropriate regulations
to properly classify your shipment for transportation.
US DOT Not regulated for transport
Canadian TDG Not regulated for transport
15. REGULATORY INFORMATION
TSCA Inventory: Listed
DSL Inventory: Listed
WHMIS Classification: Not Controlled
SARA Hazard Notification
Hazard Categories Under Title III Rules (40 CFR 370): Not Applicable
Section 302 Extremely Hazardous Substances: Not Applicable
Section 313 Toxic Chemical(s): Not Applicable
CERCLA Reportable Quantity: Not applicable
This product has been classified in accordance with the hazard criteria of the Canadian
Controlled Products Regulation and the MSDS contains all the information required by the
Canadian Controlled Products Regulation.
Refer to Section 11 for OSHA/HPA Hazardous Chemical(s) and Section 13 for RCRA
classification.
16. OTHER INFORMATION
Health Fire Reactivity Additional Information
Suggested NFPA Rating 0 0 0
Suggested HMIS Rating 0 0 0 E
E = Safety glasses, gloves, dust
respirator
Reason for revision: Revised sections 2 & 8. Supersedes MSDS dated: September 1, 2006
Product Use: Food Ingredient
Py-Ran 庐 is a registered trademark of ICL Performance Products LP
Although the information and recommendations set forth herein (hereinafter 鈥淚nformation鈥?) are
presented in good faith and believed to be correct as of the date hereof, ICL Performance
Products LP makes no representations as to the completeness or accuracy thereof. Information
is supplied upon the condition that the persons receiving same will make their own determination
as to its suitability for their purposes prior to use. In no event will ICL Performance Products LP
be responsible for damages of any nature whatsoever resulting from the use of or reliance upon
information. NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED,
OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER
NATURE ARE MADE HEREUNDER WITH RESPECT TO INFORMATION OR THE PRODUCT
TO WHICH INFORMATION REFERS
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