Material Safety Data Sheet
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Identification
Product Name: STABIL 9餂? LEAVENING AGENT
Reference Number: AST10057
Date: April 20, 2006
Use of the substance or preparation
Food Ingredient
Company/Undertaking Identification
ICL PERFORMANCE PRODUCTS LP
622 Emerson Road - Suite 500
St. Louis, Missouri 63141
Emergency telephone: In USA call CHEMTREC: 1 800 424 9300
In Canada call CANUTEC: 1 613 996 6666
General Information: 1 800 244 6169 (Worldwide)
2. COMPOSITION/INFORMATION ON INGREDIENTS
Composition
Substance CAS No. EINECS No. Risk Phrase
Sodium Aluminum Phosphate 7785-88-8 232-090-4 None
Monocalcium Phosphate Anhydrous 7758-23-8 231-837-1 None
Calcium Carbonate 471-34-1 207-439-9 None
Precipitated Amorphous Silica 7631-86-9 231-545-4 None
3. HAZARDS IDENTIFICATION
Classification of the substance/preparation
EC Classification None
Safety Phrase None
Human health effects
No significant hazards associated with this material.
EYE CONTACT: No more than slightly irritating based on toxicity studies with the components of
this material. The dry powder may cause foreign body irritation in some individuals.
ICL Performance Products LP Material Safety Data Sheet
Material: STABIL 9餂? LEAVENING AGENT Page 2 of 6
Reference No.: AST10057 April 20, 2006
SKIN CONTACT: No more than slightly toxic or slightly irritating based on toxicity studies with
the components of this material. Prolonged contact with the dry powder may cause drying or
chapping of the skin.
INHALATION: Inhalation of the dust may cause coughing and sneezing.
INGESTION: Not toxic if swallowed based on toxicity studies with the components of this
material. No significant adverse health effects are expected to develop if only small amounts
(less than a mouthful) are swallowed.
Refer to Section 11 for toxicological information.
Environmental effects
On the basis of available information, this material is not expected to produce any significant
adverse environmental effects when recommended use instructions are followed.
4. FIRST AID MEASURES
General
Likely Routes of Exposure: Inhalation and skin contact
Eye contact
Immediate first aid is not likely to be required. However, this material can be removed with water.
Remove material from eyes, skin and clothing. Wash heavily contaminated clothing before
reuse.
Skin contact
Immediate first aid is not likely to be required. However, this material can be removed with water.
Remove material from eyes, skin and clothing. Wash heavily contaminated clothing before
reuse.
Inhalation
Immediate first aid is not likely to be required. However, if symptoms occur, remove to fresh air.
Ingestion
Immediate first aid is not likely to be required. A physician or Poison Control Center can be
contacted for advice.
5. FIRE FIGHTING MEASURES
Extinguishing media
Not combustible.
No special requirements.
Unsuitable extinguishing media
Non-combustible.
No special requirements.
Exposure hazard
Not combustible.
Protective equipment
ICL Performance Products LP Material Safety Data Sheet
Material: STABIL 9餂? LEAVENING AGENT Page 3 of 6
Reference No.: AST10057 April 20, 2006
Not applicable.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions
Avoid unnecessary exposure and remove all material from eyes, skin and clothing.
Environmental precautions
Small quantities: Note methods for cleaning up in the next section.
Large quantities: Note methods for cleaning up in the next section.
Methods for cleaning up
In case of spill, sweep, scoop or vacuum and remove. Flush residual spill area with water.
Refer to Section 13 for disposal information and Sections 14 and 15 for reportable quantity
information.
7. HANDLING AND STORAGE
Handling
Product is stable under normal conditions of storage and handling. Handle in accordance with
good industrial hygiene and safety practices. These practices include avoiding unnecessary
exposure and removal of material from eyes, skin and clothing.
Engineering measures
Provide natural or mechanical ventilation to minimize exposure. The use of local mechanical
exhaust ventilation is preferred at sources of air contamination such as open process equipment.
Consult National Fire Protection Association (NFPA) Standard 91 for design of exhaust systems.
Storage
Emptied container retains product residue. Observe all labeled safeguards until container is
cleaned, reconditioned, or destroyed. The reuse of this material鈥檚 container for non-industrial
purposes is prohibited and any reuse must be in consideration of the data provided in this MSDS.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Limits
OSHA and ACGIH have not established specific exposure limits for this material. However,
OSHA and ACGIH have established limits for particulates not otherwise classified (PNOC) which
are the least stringent exposure limits applicable to dusts.
OSHA PEL ACGIH TLV
15 mg/m3 (total dust) 8-hr TWA 10 mg/m3 (inhalable) 8-hr TWA
5 mg/m3 (respirable) 8-hr TWA 3 mg/m3 (respirable) 8-hr TWA
Components referred to herein may be regulated by specific Canadian provincial legislation.
Please refer to exposure limits legislated for the province in which the substance will be used.
Respiratory protection
Avoid breathing dust. Use NIOSH/MSHA approved respiratory protection equipment (full face
piece recommended) when airborne exposure limits are exceeded. Consult the respirator
manufacturer to determine appropriate type equipment for a given application. Observe respirator
use limitations specified by NIOSH/MSHA or the manufacturer. Refer to U.S. OSHA regulations
29 CFR 1910.134 or European Standard EN 149.
ICL Performance Products LP Material Safety Data Sheet
Material: STABIL 9餂? LEAVENING AGENT Page 4 of 6
Reference No.: AST10057 April 20, 2006
Hand/Skin protection
Although this product does not present a significant skin concern, minimize skin contamination by
following good industrial practice. Wearing protective gloves is recommended. Wash hands and
contaminated skin thoroughly after handling.
Eye protection
This product does not cause significant eye irritation or eye toxicity requiring special protection.
Use good industrial practice to avoid eye contact. Refer to U.S. OSHA regulations 29 CFR
1910.133 or European Standard EN 166.
9. PHYSICAL AND CHEMICAL PROPERTIES
General information
Chemical Formula: Na3Al2H15(PO4)8 and Ca(H2PO4)2路H2O
Appearance: White powder
Odor: Odorless
Important health, safety and environmental information
Neutralizing Value: 88-98
NOTE: These physical data are typical values based on material tested but may vary from
sample to sample. Typical values should not be construed as a guaranteed analysis of any
specific lot or as specifications for the product.
10. STABILITY AND REACTIVITY
Product is stable under normal conditions of storage and handling.
Conditions to avoid
None known
Materials to avoid
None known
Hazardous decomposition
None known
11. TOXICOLOGICAL INFORMATION
Laboratory data
ICL Performance Products LP has not conducted toxicity studies with this material and no data
were found in a reasonably extensive search of the literature. However, data on the major
components are given below:
Sodium Aluminum Phosphate (SALP)
Single-dose (acute) animal studies indicate that SALP is practically nontoxic orally (rat). No
adverse effects were reported in dogs or rats repeatedly given SALP in their feed. In a similar
study, microconcretions of the kidney tubules were the only adverse effect reported in rats fed
SALP for 90 days. No adverse effects were reported in dogs fed SALP (acidic form) for 6
months. No adverse genetic changes were reported in standard tests using bacterial cells.
Monocalcium Phosphate Anhydrous
ICL Performance Products LP Material Safety Data Sheet
Material: STABIL 9餂? LEAVENING AGENT Page 5 of 6
Reference No.: AST10057 April 20, 2006
Single-dose (acute) animal studies on monocalcium phosphate monohydrate, a similar material,
indicate that it is practically nontoxic orally (rat) and after skin application (rabbit). It is slightly
irritating to rabbit eyes and nonirritating to rabbit skin.
No birth defects were reported in mice, rats, and rabbits given monocalcium monohydrate during
pregnancy. No adverse genetic changes were reported in standard tests with monocalcium
phosphate monohydrate using bacterial and yeast cells.
Data from ICL Performance Products LP studies and/or the available scientific literature on the
components of this material which have been identified as hazardous chemicals under the criteria
of the OSHA Hazard Communication Standard (29 CFR 1910.1200) are discussed below:
Calcium Carbonate
Inhalation of calcium carbonate dust may cause respiratory tract irritation, sneezing and
coughing. Calcium carbonate dusts may cause eye irritation and, following repeated or
prolonged contact, skin irritation.
Precipitated Amorphous Silica
Inhalation of precipitated amorphous silica can cause drying of mucous membranes of the eyes,
nose and throat (due to absorption of moisture and oils), which may result in irritation and
occasional nose bleeds. Repeated exposure to precipitate amorphous silica has not been
reported to have significant adverse health effects in workers; however, persons with breathing
problems or lung disease may be at an increased risk. Laboratory studies in animals exposed by
inhalation to precipitated amorphous silica report reversible lung effects.
12. ECOLOGICAL INFORMATION
Environmental toxicity
ICL Performance Products LP has not conducted environmental toxicity studies with this product.
Environmental Fate
ICL Performance Products LP has not conducted biodegradation studies with this product since
when dissolved / hydrolyzed in water it yields completely mineralized materials.
13. DISPOSAL CONSIDERATIONS
European waste catalog number
The data provided in this section is for information only. Please apply the appropriate
classification for your waste.
06 03 07 Waste from inorganic chemical processes, waste salts and their solutions, phosphates
and related solid salts
Disposal considerations
This material when discarded is not a hazardous waste as defined by the U.S. Resource
Conservation and Recovery Act (RCRA), 40 CFR 261. Dry material may be land filled or recycled
in accordance with local, state and federal regulations. Consult your attorney or appropriate
regulatory officials for information on such disposal.
14. TRANSPORT INFORMATION
The data provided in this section is for information only. Please apply the appropriate regulations
to properly classify your shipment for transportation.
Road/Rail, Sea and Air
IMDG/UN not regulated for transport
ICOA/IATA not regulated for transport
ICL Performance Products LP Material Safety Data Sheet
Material: STABIL 9餂? LEAVENING AGENT Page 6 of 6
Reference No.: AST10057 April 20, 2006
RID/ADR not regulated for transport
Canadian TDG not regulated for transport
US DOT not regulated for transport
15. REGULATORY INFORMATION
EC label
None
Chemical Inventory
USA TSCA Listed
Canada DSL Listed
WHMIS Classification: Not Controlled
SARA Hazard Notification
Hazard Categories Under Title III Rules (40 CFR 370): Not Applicable
Section 302 Extremely Hazardous Substances: Not Applicable
Section 313 Toxic Chemical(s): Not Applicable
CERCLA Reportable Quantity: Not Applicable
This product has been classified in accordance with the hazard criteria of the Canadian
Controlled Products Regulation and the MSDS contains all the information required by the
Canadian Controlled Products Regulation.
Refer to Section 11 for OSHA/HPA Hazardous Chemical(s) and Section 13 for RCRA
classification.
16. OTHER INFORMATION
Health Fire Reactivity Additional Information
Suggested NFPA Rating 0 0 0
Suggested HMIS Rating 0 0 0 E
E = Safety glasses, gloves, dust
respirator
Reason for revision: Revised section 1. Supersedes MSDS dated: November 1, 2005
Drafted in accordance with ECC Dir 2001/58/EC
STABIL 9庐 is a registered trademark of ICL Performance Products LP
Although the information and recommendations set forth herein (hereinafter 鈥淚nformation鈥?) are
presented in good faith and believed to be correct as of the date hereof, ICL Performance
Products LP makes no representations as to the completeness or accuracy thereof. Information
is supplied upon the condition that the persons receiving same will make their own determination
as to its suitability for their purposes prior to use. In no event will ICL Performance Products LP
be responsible for damages of any nature whatsoever resulting from the use of or reliance upon
information. NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED,
OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER
NATURE ARE MADE HEREUNDER WITH RESPECT TO INFORMATION OR THE PRODUCT
TO WHICH INFORMATION REFERS
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