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MSDS Material Safety Data Sheet
CAS

002008-39-1

File Name: bingeiagung_com---dma6-msds.asp
                            MATERIAL SAFETY DATA SHEET
Emergency Phone: 800-992-5994
Dow AgroSciences LLC
Indianapolis, IN 46268

Effective Date: 1/23/01
Product Code: 22064
DMA* -6M HERBICIDE MSDS: 005987

INGESTION: Single dose oral toxicity is low. The oral LD50
1. PRODUCT AND COMPANY IDENTIFICATION:
for male rats is 1100 mg/kg and for female rats is 860
PRODUCT: DMA* -6M HERBICIDE mg/kg. Small amounts swallowed incidental to normal
handling operations are not likely to cause injury; however,
COMPANY IDENTIFICATION: swallowing larger amounts may cause injury.
Dow AgroSciences
9330 Zionsville Road INHALATION: Single exposure to vapors is not likely to be
Indianapolis, IN 46268-1189 hazardous.
2. COMPOSITION/INFORMATION ON INGREDIENTS:
SYSTEMIC (OTHER TARGET ORGAN) EFFECTS: In
70% animals, effects have been reported on the following
2,4-D Dimethylamine Salt: CAS #002008-39-1
organs: adrenal gland, bone marrow, eye, kidney, liver,
2,4-Dichlorophenoxyacetic
spleen, testes, and thyroid.
Acid, Dimethylamine Salt
Other Ingredients, Total 30%
CANCER INFORMATION: 2,4-Dichlorophenoxyacetic acid
did not cause cancer in laboratory animal studies.
This document is prepared pursuant to the OSHA Hazard
Communication Standard (29 CFR 1910.1200). In addition,
TERATOLOGY (BIRTH DEFECTS): For 2,4-D acid: Did
other substances not 鈥楬azardous鈥? per this OSHA Standard
not cause birth defects; other fetal effects occurred only at
may be listed. Where proprietary ingredient shows, the
doses toxic to the mother.
identity may be made available as provided in this
standard.
REPRODUCTIVE EFFECTS: Excessive dietary levels of
3. HAZARDOUS IDENTIFICATIONS: 2,4-D acid caused toxic effects (weight and viability
reduction) in rats on a reproduction study.
EMERGENCY OVERVIEW
4. FIRST AID:
Hazardous Chemical. Dark amber to black liquid with a
mild phenolic odor. May cause eye irritation with corneal
EYES: Immediate and continuous irrigation with flowing
injury. LD50 for skin absorption in rabbits is 2244 mg/kg;
water for at least 30 minutes is imperative. Prompt medical
oral LD50 for rats is 1090 mg/kg (males) and 863 mg/kg
consultation is essential.
(females). Corrosive. Avoid excessive heat.
EMERGENCY PHONE NUMBER: 800-992-5994
SKIN: Wash off in flowing water or shower.
POTENTIAL HEALTH EFFECTS: This section includes
possible adverse effects, which could occur if this material INGESTION: If swallowed, seek medical attention. Do not
induce vomiting unless directed to do so by medical
is not handled in the recommended manner.
personnel.
EYE: May cause severe irritation with corneal injury, which
INHALATION: Remove to fresh air if effects occur. Consult
may result in permanent impairment of vision, even
a physician.
blindness.

NOTE TO PHYSICIAN: If burn is present, treat as any
SKIN: Prolonged exposure may cause skin irritation.
thermal burn, after decontamination. No specific antidote.
Repeated exposure may cause skin burns. A single
Supportive care. Treatment based on judgment of the
prolonged exposure is not likely to result in the material
physician in response to reactions of the patient.
being absorbed through skin in harmful amounts. Repeated
skin exposure may result in absorption of harmful amounts.
The LD50 for skin absorption in rabbits is 2244 mg/kg.




*Trademark of Dow AgroSciences
1
MATERIAL SAFETY DATA SHEET
Emergency Phone: 800-992-5994
Dow AgroSciences LLC
Indianapolis, IN 46268

Effective Date: 1/23/01
Product Code: 22064
DMA* -6M HERBICIDE MSDS: 005987

5. FIRE FIGHTING MEASURES: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION:
These precautions are suggested for conditions where a
FLASH POINT: None (tested to 290掳C)
potential for exposure exists. Emergency conditions may
METHOD USED: TOC
require additional precautions.
FLAMMABLE LIMITS
EXPOSURE GUIDELINE(S): 2,4-D Dimethylamine Salt:
LFL: Not determined
None established. ACGIH TLV and OSHA PEL are 10
UFL: Not determined
mg/M3 for 2,4-D acid.
EXTINGUISHING MEDIA: Water fog, foam.
EXPOSURE CONTROLS: Provide general and/or local
FIRE & EXPLOSION HAZARDS: Noxious fumes produced exhaust ventilation to control airborne levels below the
exposure guidelines.
under fire conditions. Contain water from fire fighting to
prevent entry to surface and ground water.
RECOMMENDATIONS FOR MANUFACTURING,
COMMERICAL BLENDING, AND PACKAGING
FIRE-FIGHTING EQUIPMENT: Wear positive-pressure,
WORKERS:
self-contained breathing apparatus and full protective
clothing.
RESPIRATORY PROTECTION: Atmospheric levels should
6. ACCIDENTAL RELEASE MEASURES:
be maintained below the exposure guideline. When
ACTION TO TAKE FOR SPILLS/LEAKS: Absorb in respiratory protection is required for certain operations, use
material such as sawdust, sand or clay. Dike area in case a NIOSH approved air-purifying respirator for organic
of large spills; notify Dow AgroSciences at 800-992-5994. vapors.
Wear protective clothing and self-contained breathing
apparatus if vapors are present. SKIN PROTECTION: Use protective clothing impervious to
this material. Selection of specific items such as face
7. HANDLING AND STORAGE: shield, gloves, boots, apron, or full body suit will depend on
operation. Remove contaminated clothing immediately,
PRECAUTIONS TO BE TAKEN IN HANDLING AND
wash skin area with soap and water, and launder clothing
STORAGE:
before reuse.
HANDLING: Keep out of reach of children. Harmful if
EYE PROTECTION: Use chemical goggles. Eyewash
swallowed, inhaled, or absorbed through skin. Causes eye
fountain should be located in the immediate work area.
irritation. Avoid contact with eyes, skin and clothing. Users
should wash hands before eating, drinking, chewing gum,
APPLICATORS AND ALL OTHER HANDLERS: Refer to
using tobacco, or using the toilet.
the product label for personal protective clothing and
equipment.
STORAGE: Do not store below temperature of 45掳F (7掳C).
If frozen (crystallized), warm to 80掳-90掳F (27掳-32掳C) and re-
dissolve before using by rolling or shaking the container.
Store in safe manner in original container only. Store in
cool, dry place. Keep container tightly closed when not in
use. See product label for handling/storage precautions
relative to the end use of this product.




*Trademark of Dow AgroSciences
2
MATERIAL SAFETY DATA SHEET
Emergency Phone: 800-992-5994
Dow AgroSciences LLC
Indianapolis, IN 46268

Effective Date: 1/23/01
Product Code: 22064
DMA* -6M HERBICIDE MSDS: 005987

ECOTOXICOLOGY:
9. PHYSICAL AND CHEMICAL PROPERTIES:
Material is practically non-toxic to aquatic organisms on an
BOILING POINT: 212掳F (>100掳C) acute basis (LC50/EC50 >100 mg/L in most sensitive
VAPOR PRESSURE: 8.0 x 10-10 mmHg @ 25掳C species).
VAPOR DENSITY: Water vapor Acute LC50 for fathead minnow (Pimephales promelas) is
344 mg/L.
SOLUBILITY IN WATER: Infinite
Acute LC50 for bluegill (Lepomis macrochirus) is 524 mg/L.
SPECIFIC GRAVITY: 1.24 (68掳/68掳F) (20掳C)
Acute LC50 for rainbow trout (Oncorhynchus mykiss) is 250
APPEARANCE: Dark amber to black liquid
mg/L.
ODOR: Mild phenolic
Acute LC50 for water flea (Daphnia magna) is 184 mg/L.
10. STABILITY AND REACTIVITY: Acute EC50 for shell deposition inhibition in eastern oyster
(Crassostrea virginica) is 136 mg/L.
STABILITY: (CONDITIONS TO AVOID) Avoid excessive
Acute LC50 for pink shrimp (Penaeus duorarum) is 181
heat. Stable under normal storage conditions.
mg/L.
Acute LC50 for tidewater silverside (Menidia beryllina) is 469
INCOMPATIBILITY: (SPECIFIC MATERIALS TO AVOID)
mg/L.
Acids and oxidizing materials.
Material is practically non-toxic to birds on a dietary basis
(LC50 is >5000 ppm).
HAZARDOUS DECOMPOSITION PRODUCTS: Hydrogen Material is moderately toxic to birds on an acute basis (LD50
chloride and nitrogen oxides may be produced under fire is between 51 and 500 mg/kg).
conditions. Dietary LC50 for bobwhite (Colinus virginianus) is >5620
ppm.
HAZARDOUS POLYMERIZATION: Not known to occur. Dietary LC50 for mallard (Anas platyrhynchos) is >5620
ppm.
11. TOXICOLOGICAL INFORMATION:
Growth inhibition EC50 for duckweed (Lemna sp.) is 0.58
MUTAGENICITY (EFFECTS OF GENETIC MATERIAL): mg/L.
In-vitro mutagenicity studies were negative. For 2,4-D acid: Growth inhibition EC50 for marine diatom (Skeletonema
animal mutagenicity studies were predominantly negative. costatum) is 36.60 mg/L.
Growth inhibition EC50 for blue-green alga (Anabaena flos-
12. ECOLOGICAL INFORMATION: aquae) is 153 mg/L.
Growth inhibition EC50 for green alga (Selenastrum
ENVIRONMENTAL FATE:
capricornutum) is 66.5 mg/L.
Growth inhibition EC50 for diatom (Navicula sp.) is 5.28
MOVEMENT & PARTITIONING:
mg/L.
Bioconcentration potential is low (BCF <100 or Log Pow
<3). Potential for mobility in soil is high (Koc between 50- 13. DISPOSAL CONSIDERATIONS:
150).
Bioconcentration factor (BCF) in fish is between 0.1-0.47. DISPOSAL METHOD: Wastes are toxic. Improper disposal
Soil organic carbon/water partition coefficient (Koc) is 72- of excess waste, spray mixture, or rinsate is a violation of
136. Federal law and may contaminate groundwater. If these
wastes cannot be disposed by use according to label
DEGRADATION AND PERSISTENCE: instructions, contact your state pesticide or environmental
5-Day biochemical oxygen demand (BOD5) is 0.72. control agency, or the hazardous waste representative at
10-Day biochemical oxygen demand (BOD10) is 0.72. the nearest EPA regional office for guidance.
20-Day biochemical oxygen demand (BOD20) is 0.72.
Chemical oxygen demand (COD) is 0.72.
Under aerobic soil conditions the half-life is 4-23 days.
Under aerobic aquatic conditions the half-life is 0.5-11
days.

*Trademark of Dow AgroSciences
3
MATERIAL SAFETY DATA SHEET
Emergency Phone: 800-992-5994
Dow AgroSciences LLC
Indianapolis, IN 46268

Effective Date: 1/23/01
Product Code: 22064
DMA* -6M HERBICIDE MSDS: 005987

NATIONAL FIRE PROTECTION ASSOCIATION (NFPA)
14. TRANSPORT INFORMATION:
RATINGS:
For DOT regulatory information, if required, consult
transportation regulations, product-shipping papers, or Category Rating
contact your Dow AgroSciences representative. Health 3
Flammability 1
15. REGULATORY INFORMATION:
Reactivity 1
NOTICE: The information herein is presented in good faith
COMPREHENSIVE ENVIRONMENTAL RESPONSE
and believed to be accurate as of the effective date shown
COMPENSATION AND LIABILITY ACT (CERCLA, or
above. However, no warranty, express or implied, is given.
Regulatory requirements are subject to change and may SUPERFUND): This product contains the following
differ from one location to another; it is the buyer鈥檚 substance(s) listed as "Hazardous Substances" under
responsibility to ensure that its activities comply with CERCLA, which may require reporting of releases:
federal, state or provincial, and local laws. The following
specific information is made for the purpose of complying Chemical Name CAS Number RQ % in Product
with numerous federal, state or provincial, and local laws 2,4-Dichlorophenol 000120-83-2 100 0.1%
and regulations.
16. OTHER INFORMATION:
U.S. REGULATIONS
MSDS STATUS: Revised Sections: 2,3,7,8,10,12, & 13
Reference: DR-0008-3556
SARA 313 INFORMATION: To the best of our knowledge, Replaces MSDS Dated: 2/19/99
this product contains no chemical subject to SARA Title III
Section 313 supplier notification requirements.

SARA HAZARD CATEGORY: This product has been
reviewed according to the EPA "Hazard Categories"
promulgated under Sections 311 and 312 of the Superfund
Amendment and Reauthorization Act of 1986 (SARA Title
III) and is considered, under applicable definitions, to meet
the following categories:

An immediate health hazard
A delayed health hazard

TOXIC SUBSTANCES CONTROL ACT (TSCA): All
ingredients are on the TSCA inventory or are not required
to be listed on the TSCA inventory.

OSHA HAZARD COMMUNICATION STANDARD: This
product is a "Hazardous Chemical" as defined by the OSHA
Hazard Communication Standard, 29 CFR 1910.1200.


The Information Here in is Given in Good Faith, But No
Warranty, Express or Implied, Is Made. Consult Dow
AgroSciences for Further Information.



*Trademark of Dow AgroSciences
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