Product Name: Flash Point Reference Material
鈥? FPRM14
Revision Date: April 25, 2007
Page 1 of 9
MSDS ref CII07-020
MATERIAL SAFETY DATA SHEET
SECTION 1 PRODUCT AND COMPANY IDENTIFICATION
PRODUCT
Product name: Flash Point Reference Material 鈥? FPRM14
Alternate description/ brand: FPRM14
Product description: Tetradecane; hydrocarbon liquid
Product code: 9727-A20
Intended use: Flash Point Reference standard
COMPANY IDENTIFICATION
Supplier: Cannon Instrument Company
2139 High Tech Road
State College, Pennsylvania 16803
Product Technical Information: (814) 353-8000
Product MSDS Information: (814) 353-8000
EMERGENCY TELEPHONE NUMBER:
24-Hour Transportation Emergency: (800) 255-3924 Domestic CHEM-TEL Inc.
24-Hour Health Emergency: +1 (813) 248-0585 Overseas CHEM-TEL Inc. (please call collect)
SECTION 2 COMPOSITION/INFORMATION ON INGREDIENTS
OSHA Hazardous Substance(s) or Complex Substance(s)
This product is hazardous as defined in 29 CFR1910.1200, based on the following:
OSHA HAZARD COMPONENT
Combustible Tetradecane
Irritant Tetradecane
Ingestion (aspiration hazard) Tetradecane
SECTION 3 HAZARD IDENTIFICATION
EFFECTS OF OVEREXPOSURE:
Acute effects
Eye: Irritant
Skin: Irritant; can be absorbed through the skin
Inhalation: High vapor/aerosol concentrations (attainable at elevated temperatures) are irritating
to the eyes and the respiratory tract, and may cause headaches, dizziness,
anaesthesia, drowsiness, unconsciousness, and other central nervous system effects.
This substance is unlikely to present a significant inhalation hazard if used for the
recommended purpose.
This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. The information
and recommendations contained herein is compiled from suppliers鈥? MSDS and are accurate and reliable to the best of Cannon Instrument Company鈥檚 knowledge and belief as of the
indicated revision date. No representation, warranty or guarantee, however, is made with regards to accuracy, reliability or completeness. Conditions of use of the material are under
the control of the user; therefore, it is the user's responsibility to determine the suitability and completeness of such information for any specific conditions/ use.
Product Name: Flash Point Reference Material
鈥? FPRM14
Revision Date: April 25, 2007
Page 2 of 9
MSDS ref CII07-020
Oral: Low toxicity. Small amounts of this product aspirated into the respiratory system
during ingestion or vomiting may cause severe pulmonary injury, possibly progressing
to death.
Prolonged/ repeated exposure effects
Chronic effects
None identified
Signs and symptoms of overexposure:
Irritation and/ or redness of eyes and skin
Medical conditions aggravated by exposure
None identified
NFPA HAZARD ID: Health: 0 Flammability: 1 Reactivity: 0
(National Fire Protection Association)
NOTE: This material should not be used for any other purpose than the intended use in Section 1
SECTION 4 FIRST AID MEASURES
INHALATION Using proper respiratory protection, immediately remove the affected victim from exposure.
Administer artificial respiration if breathing is stopped. Keep at rest. Call for prompt medical
attention.
SKIN CONTACT Flush with large amounts of water; use soap if available. Remove grossly contaminated
clothing, including shoes, and launder before reuse.
EYE CONTACT Flush eyes with large amounts of water until irritation subsides. If irritation persists, get
medical attention.
INGESTION If swallowed, DO NOT induce vomiting. Keep at rest. Get prompt medical attention.
NOTE TO PHYSICIAN: Ingested material, if aspirated into the lungs, may cause chemical pneumonitis.
SECTION 5 FIRE-FIGHTING MEASURES
EXTINGUISHING MEDIA
Appropriate extinguishing media: Carbon dioxide, foam, dry chemical and water fog. Water can be
used to cool fire exposed containers
FIRE FIGHTING
Fire fighting instructions: Use water spray to cool fire exposed surfaces and to protect personnel.
Isolate "fuel" supply from fire. Use foam, dry chemical, or water spray to extinguish fire. Avoid
spraying water directly into storage containers due to danger of boilover. This liquid is volatile and
This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. The information
and recommendations contained herein is compiled from suppliers鈥? MSDS and are accurate and reliable to the best of Cannon Instrument Company鈥檚 knowledge and belief as of the
indicated revision date. No representation, warranty or guarantee, however, is made with regards to accuracy, reliability or completeness. Conditions of use of the material are under
the control of the user; therefore, it is the user's responsibility to determine the suitability and completeness of such information for any specific conditions/ use.
Product Name: Flash Point Reference Material
鈥? FPRM14
Revision Date: April 25, 2007
Page 3 of 9
MSDS ref CII07-020
gives off invisible vapors. Either the liquid or vapor may settle in low areas or travel some distance
along the ground or surface to ignition sources where they may ignite or explode.
Unusual fire hazards: None identified
Hazardous combustion products: Thermal breakdown of this product during fire or very high heat
conditions may evolve the following hazardous decomposition products: Fumes, smoke, carbon
monoxide, sulfur oxides, aldehydes and other decomposition products
GENERAL HAZARD
Combustible Liquid can form combustible mixtures at temperatures at or above the flashpoint.
Static Discharge: Material can accumulate static charges which can cause an incendiary electrical
discharge. "Empty" containers retain product residue (liquid and/or vapor) and can be dangerous.
DO NOT pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame,
sparks, static electricity, or other sources of ignition; THEY MAY EXPLODE AND CAUSE INJURY
OR DEATH. Empty drums should be completely drained, properly bunged and promptly re-
turned to a drum reconditioner, or properly disposed of.
FLAMMABILITY PROPERTIES
Flash point 掳C (掳F) [method]: 210oF/ 99oC
Flammable limits (approx. Volume % in air) 鈥? LEL: 0.5 UEL: not available
Autoignition temperature 掳C (掳F): 200 掳C/ 392 掳F
SECTION 6 ACCIDENTAL RELEASE MEASURES
NOTIFICATION PROCEDURES: Report spills/releases to appropriate authorities as required.
CONTAINMENT/ CLEANUP
PROCEDURES IF MATERIAL IS RELEASED OR SPILLED:
LAND SPILL: Shut off source taking normal safety precautions. Take measures to minimize
the effects on ground water. Recover by pumping (use an explosion proof or hand pump) or
contain spilled material with sand or other suitable absorbent and remove mechanically into
containers. If necessary, dispose of adsorbed residues as required by regulations (see Section
13.)
WATER SPILL: Confine the spill immediately with booms. Notify relevant authorities. Remove
from the surface by skimming or with suitable absorbents
ENVIRONMENTAL PRECAUTIONS: Prevent material from entering sewers, water sources or low lying
areas; advise the relevant authorities if it has, or if it contaminates soil/vegetation.
Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations.
PERSONAL PROTECTIVE EQUIPMENT FOR SPILLS
Eyes: Use proper protection 鈥? safety glasses as a minimum
Skin: Washing at mealtime and end-of-shift is adequate
Inhalation: No respiratory protection should be needed for small spills. For large spills, use
self-contained breathing apparatus or air-purifying respiratory protection according to established
local/ site emergency response procedures.
This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. The information
and recommendations contained herein is compiled from suppliers鈥? MSDS and are accurate and reliable to the best of Cannon Instrument Company鈥檚 knowledge and belief as of the
indicated revision date. No representation, warranty or guarantee, however, is made with regards to accuracy, reliability or completeness. Conditions of use of the material are under
the control of the user; therefore, it is the user's responsibility to determine the suitability and completeness of such information for any specific conditions/ use.
Product Name: Flash Point Reference Material
鈥? FPRM14
Revision Date: April 25, 2007
Page 4 of 9
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Precautionary measures: Avoid eye contact. Use reasonable care
SECTION 7 HANDLING AND STORAGE
HANDLING
Keep container closed. Handle and open containers with care.
ELECTROSTATIC ACCUMULATION HAZARD
Yes, use proper bonding and/or grounding procedure. Additional information regarding safe
handling of products with static accumulation potential can be ordered by contacting the
American Petroleum Institute (API) for API Recommended Practice 2003, entitled "Protection
Against Ignitions Arising Out of Static, Lightning, and Stray Currents" (American Petroleum
Institute, 1220 L Street Northwest, Washington, DC 20005), or the National Fire Protection
Association (NFPA) for NFPA 77 entitled "Static Electricity" (National Fire Protection Association,
1 Batterymarch Park, P.O. Box 9101, Quincy, MA 02269-9101).
STORAGE:
Keep containers closed when not in use. Do not store in open or unlabelled containers. Store in
a cool, well ventilated place, away from strong oxidizing agents and combustible materials. Do
not store near heat, sparks, flame or strong oxidants.
SPECIAL PRECAUTIONS
Prevent small spills and leakages to optimize housekeeping, minimize fire risk and avoid slip
hazards.
EMPTY CONTAINER WARNING
Empty containers retain residue (liquid and/or vapor) and can be dangerous. DO NOT
PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE SUCH
CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES
OF IGNITION; THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. Do not attempt to
refill or clean container since residue is difficult to remove. Empty drums should be completely
drained, properly bunged and promptly returned to a drum reconditioner. All containers should
be disposed of in an environmentally safe manner and in accordance with governmental
regulations.
STORAGE
Use reasonable care and store away from oxidizing materials
SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION
EXPOSURE LIMIT VALUES
None established
ENGINEERING CONTROLS
The use of local exhaust ventilation is recommended to control process emissions near
the source. Laboratory samples should be handled in a lab hood. Provide mechanical
ventilation of confined spaces. See respiratory protection recommendations.
PERSONAL PROTECTION
Personal protective equipment selections vary based on potential exposure conditions such as
applications, handling practices, concentration and ventilation. Information on the selection of protective
equipment for use with this material, as provided below, is based upon intended, normal usage.
This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. The information
and recommendations contained herein is compiled from suppliers鈥? MSDS and are accurate and reliable to the best of Cannon Instrument Company鈥檚 knowledge and belief as of the
indicated revision date. No representation, warranty or guarantee, however, is made with regards to accuracy, reliability or completeness. Conditions of use of the material are under
the control of the user; therefore, it is the user's responsibility to determine the suitability and completeness of such information for any specific conditions/ use.
Product Name: Flash Point Reference Material
鈥? FPRM14
Revision Date: April 25, 2007
Page 5 of 9
MSDS ref CII07-020
Respiratory Protection:
Where concentrations in air may exceed the limits given in this Section and engineering, work
practice or other means of exposure reduction are not adequate, NIOSH approved respirators
may be necessary to prevent overexposure by inhalation.
Hand Protection:
Where contact may occur, wear long sleeves, and chemical resistant gloves, protective clothing
and footwear
Eye Protection:
Use proper protection 鈥? safety glasses as a minimum. For open systems where contact is likely,
wear safety glasses with side shields. Where contact may occur, wear safety glasses with side
shields.
Specific Hygiene Measures:
Washing at mealtime and end-of-shift is usually adequate
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Typical physical and chemical properties are given below. Consult the Cannon Instrument Company as indicated
in Section 1 for additional data.
GENERAL INFORMATION
Physical state: Liquid
Form: Liquid
Color: Clear colorless
Odor: Characteristic petroleum odor
Odor threshold: not available
IMPORTANT HEALTH, SAFETY AND ENVIRONMENTAL INFORMATION
Specific Gravity @ 60oF: 0.8
Bulk density g/cc: Not available
Density, kg/m3 (lbs./gal.): Not available
Flash point 掳C (掳F) [method]: 210oF/ 99oC
Flammable limits (approx. Volume % in air) 鈥? LEL: 0.5 UEL: not available
Autoignition temperature 掳C (掳F): 200 掳C/ 392 掳F
Ignition temperature (polymers) 掳C (掳F): not applicable
Boiling point/range 掳C (掳F): 488 oF (254 oC)
Vapor density @ 101 kPa (air =1): Greater than air
Vapor pressure @ 20掳C, kPa (mm Hg): 0.012 mmHg
Evaporation rate (n-butyl acetate =1): Not available
pH: not applicable
Log Pow (n-Octanol/water partition coefficient): Not available
Solubility in water (20 掳C): negligible
Viscosity: Not available
OTHER INFORMATION
Freezing point 掳C (掳F): Not available
This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. The information
and recommendations contained herein is compiled from suppliers鈥? MSDS and are accurate and reliable to the best of Cannon Instrument Company鈥檚 knowledge and belief as of the
indicated revision date. No representation, warranty or guarantee, however, is made with regards to accuracy, reliability or completeness. Conditions of use of the material are under
the control of the user; therefore, it is the user's responsibility to determine the suitability and completeness of such information for any specific conditions/ use.
Product Name: Flash Point Reference Material
鈥? FPRM14
Revision Date: April 25, 2007
Page 6 of 9
MSDS ref CII07-020
6掳C (43 oF)
Melting Point 掳C (掳F):
Pour point 掳C (掳F): Not available
Molecular weight: 198
Hygroscopic: no
Coefficient of thermal expansion: Not available
SECTION 10 STABILITY AND REACTIVITY
STABILITY: Stable
CONDITIONS TO AVOID: Extreme heat and high energy sources of ignition.
MATERIALS TO AVOID: Halogens, molten sulfur, strong oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS: Product does not decompose at ambient temperatures.
HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur
SECTION 11 TOXICOLOGICAL INFORMATION
No specific toxicology data on this products have been provided by the supplier(s)
SECTION 12 ECOLOGICAL INFORMATION
Environmental fate and distribution
No specific ecological data are available for this product. Please refer to Section 6 for
information regarding accidental releases and Section 15 for regulatory reporting information
Air: No specific data are available
Water: No specific data are available
Soil: No specific data are available
Degradation: No specific data are available
Environmental effects
Toxicity to water organisms: No specific data are available
Toxicity to soil organisms: No specific data are available
Bioaccumulation: No specific data are available
Fate and effects in water treatment plants
No specific data are available
SECTION 13 DISPOSAL CONSIDERATIONS
This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. The information
and recommendations contained herein is compiled from suppliers鈥? MSDS and are accurate and reliable to the best of Cannon Instrument Company鈥檚 knowledge and belief as of the
indicated revision date. No representation, warranty or guarantee, however, is made with regards to accuracy, reliability or completeness. Conditions of use of the material are under
the control of the user; therefore, it is the user's responsibility to determine the suitability and completeness of such information for any specific conditions/ use.
Product Name: Flash Point Reference Material
鈥? FPRM14
Revision Date: April 25, 2007
Page 7 of 9
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Please refer to Sections 5, 6 and 15 for disposal and regulatory information
WASTE DISPOSAL: Product is suitable for burning in an enclosed, controlled burner for fuel value.
Such burning may be limited pursuant to the Resource Conservation and Recovery Act. In
addition, the product is suitable for processing by an approved recycling facility or can be
disposed of at an appropriate government waste disposal facility. Use of these methods is
subject to user compliance with applicable laws and regulations and consideration of product
characteristics at time of disposal.
SECTION 14 TRANSPORT INFORMATION
Note: The information provided below may not apply to all shipping situations. Consult appropriate
Dangerous Goods Regulations for additional requirements and mode-specific, material-specific, or
quantity-specific shipping requirements.
United States Department of Transportation (US DOT):
UN/ID# Proper Shipping Name Class/Division Hazard Label(s) Packing Group
Not Regulated As A Hazardous Material Or Dangerous Good For This Mode of Transportation.
International Air Transport Association (IATA):
UN/ID# Proper Shipping Name Class/Division Hazard Label(s) Packing Group
Not Regulated As A Hazardous Material Or Dangerous Good For This Mode of Transportation.
SECTION 15 REGULATORY INFORMATION
OSHA HAZARD COMMUNICATION STANDARD: This material is classified as hazardous in accordance with
OSHA 29 CFR 1910.1200. See section 2
NATIONAL CHEMICAL INVENTORY LISTING:
This product, and/ or its constituents, is listed on the US EPA/ TSCA (Toxic Substances Control Act)
Inventory
COMMUNITY RTK:
Tetradecane (CAS# 669-59-4) 鈥? 100%
Clean Water Act/Oil Pollution Act:
No specific information provided by the supplier(s) of this product
Section 304 CERCLA HAZARDOUS SUBSTANCES:
This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. The information
and recommendations contained herein is compiled from suppliers鈥? MSDS and are accurate and reliable to the best of Cannon Instrument Company鈥檚 knowledge and belief as of the
indicated revision date. No representation, warranty or guarantee, however, is made with regards to accuracy, reliability or completeness. Conditions of use of the material are under
the control of the user; therefore, it is the user's responsibility to determine the suitability and completeness of such information for any specific conditions/ use.
Product Name: Flash Point Reference Material
鈥? FPRM14
Revision Date: April 25, 2007
Page 8 of 9
MSDS ref CII07-020
No specific information provided by the supplier(s) of this product
SARA (311/312) REPORTABLE HAZARD CATEGORIES:
Under the provisions of Title III, Sections 311/312 of the Superfund Amendments and
Reauthorization Act, this product is classified into the following hazard categories:
Irritant, fire hazard.
SARA (313) TOXIC RELEASE INVENTORY:
No specific information provided by the supplier(s) of this product
International chemical inventories and hazard classifications
This product and/ or its components are on the Canadian Domestic Substance List/ Non-Domestic
Substances List (DSL/ NDSL)
WHMIS Classifications (Canada):
D2B - Poisonous and infectious material - Other Effects 鈥? Toxic
Skin or eye irritation
This product and/ or its components are on EINECS (European Inventory of Existing Chemical
Substances) and/ or ELINCS (European Library of Notified Chemical Substances)
EU Hazard Classification, risk and safety phrases (Europe):
Xn
R36: Irritating to eyes
R38: Irritating to skin
R65: Harmful: may cause lung damage if swallowed
S2: Keep out of reach of children
S24: Avoid contact with the skin
S25: Avoid contact with the eyes
S26: In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice
S62: If swallowed, do not induce vomiting: seek medical advice immediately and show
this container or label
S36/37: Wear suitable protective clothing and gloves
SECTION 16 OTHER INFORMATION
THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS:
Revision Summary:
鈥? October 15, 2005 -- This MSDS has been fully reviewed and reformatted to conform to changes
in standard format
鈥? February 27, 2007: Added Canadian and European classification and labeling information,
based on current regulations and/or recommendations from suppliers (see Section 15)
This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. The information
and recommendations contained herein is compiled from suppliers鈥? MSDS and are accurate and reliable to the best of Cannon Instrument Company鈥檚 knowledge and belief as of the
indicated revision date. No representation, warranty or guarantee, however, is made with regards to accuracy, reliability or completeness. Conditions of use of the material are under
the control of the user; therefore, it is the user's responsibility to determine the suitability and completeness of such information for any specific conditions/ use.
Product Name: Flash Point Reference Material
鈥? FPRM14
Revision Date: April 25, 2007
Page 9 of 9
MSDS ref CII07-020
鈥? April 25, 2007: Updated and standardized format of Transport Information (see Section 14)
NOTES:
This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. The information
and recommendations contained herein is compiled from suppliers鈥? MSDS and are accurate and reliable to the best of Cannon Instrument Company鈥檚 knowledge and belief as of the
indicated revision date. No representation, warranty or guarantee, however, is made with regards to accuracy, reliability or completeness. Conditions of use of the material are under
the control of the user; therefore, it is the user's responsibility to determine the suitability and completeness of such information for any specific conditions/ use.
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