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                            AFRICAN MINERAL SALTS CICHLID
Chemwatch Material Safety Data Sheet
Feb-8-2008 CHEMWATCH 02-0958
NB293ECP Version No:1
CD 2007/4 Page 1 of 10



Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION


PRODUCT NAME
AFRICAN MINERAL SALTS CICHLID

STATEMENT OF HAZARDOUS NATURE
CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200.

SUPPLIER
Company: Mars Fishcare North America Inc
Address:
50 East Hamilton Street
Chalfont
PA, 18914
USA
Telephone: +1 215 822 8181
Fax: +1 215 822 1906


PRODUCT USE
Used according to manufacturer's directions. For product 470.


Section 2 - HAZARDS IDENTIFICATION


CANADIAN WHMIS SYMBOLS




EMERGENCY OVERVIEW

RISK
Harmful if swallowed.
Irritating to eyes.

POTENTIAL HEALTH EFFECTS

ACUTE HEALTH EFFECTS

SWALLOWED
Accidental ingestion of the material may be harmful; animal experiments indicate that
ingestion of less than 150 gram may be fatal or may produce serious damage to the health
of the individual.

EYE
There is evidence that material may produce eye irritation in some persons and produce
eye damage 24 hours or more after instillation. Severe inflammation may be expected with
pain. There may be damage to the cornea. Unless treatment is prompt and adequate there
may be permanent loss of vision. Conjunctivitis can occur following repeated exposure.

continued...
AFRICAN MINERAL SALTS CICHLID
Chemwatch Material Safety Data Sheet
Feb-8-2008 CHEMWATCH 02-0958
NB293ECP Version No:1
CD 2007/4 Page 2 of 10
Section 2 - HAZARDS IDENTIFICATION

SKIN
Skin contact is not thought to produce harmful health effects (as classified using animal
models). Systemic harm, however, has been identified following exposure of animals by at
least one other route and the material may still produce health damage following entry
through wounds, lesions or abrasions. Good hygiene practice requires that exposure be
kept to a minimum and that suitable gloves be used in an occupational setting.
Open cuts, abraded or irritated skin should not be exposed to this material.

INHALED
The material is not thought to produce either adverse health effects or irritation of the
respiratory tract following inhalation (as classified using animal models). Nevertheless,
adverse effects have been produced following exposure of animals by at least one other
route and good hygiene practice requires that exposure be kept to a minimum and that
suitable control measures be used in an occupational setting.
Persons with impaired respiratory function, airway diseases and conditions such as
emphysema or chronic bronchitis, may incur further disability if excessive concentrations
of particulate are inhaled.

CHRONIC HEALTH EFFECTS
Long-term exposure to the product is not thought to produce chronic effects adverse to
the health (as classified using animal models); nevertheless exposure by all routes
should be minimized as a matter of course.
Long term exposure to high dust concentrations may cause changes in lung function i.e.
pneumoconiosis; caused by particles less than 0.5 micron penetrating and remaining in the
lung. Prime symptom is breathlessness; lung shadows show on X-ray.


Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS

NAME CAS RN %
calcium chloride 10043-52-4 30-40
nonhazardous ingredients >60


Section 4 - FIRST AID MEASURES


SWALLOWED
路 IF SWALLOWED, REFER FOR MEDICAL ATTENTION, WHERE POSSIBLE, WITHOUT DELAY.
路 Where Medical attention is not immediately available or where the patient is more than
15 minutes from a hospital or unless instructed otherwise:
路 For advice, contact a Poisons Information Center or a doctor.
路 Urgent hospital treatment is likely to be needed.
路 If conscious, give water to drink.
路 INDUCE vomiting with fingers down the back of the throat, ONLY IF CONSCIOUS. Lean
patient forward or place on left side (head-down position, if possible) to maintain open
airway and prevent aspiration.
NOTE: Wear a protective glove when inducing vomiting by mechanical means.
路 In the mean time, qualified first-aid personnel should treat the patient following
observation and employing supportive measures as indicated by the patient's condition.
路 If the services of a medical officer or medical doctor are readily available, the
patient should be placed in his/her care and a copy of the MSDS should be provided.
Further action will be the responsibility of the medical specialist.
路 If medical attention is not available on the worksite or surroundings send the patient
to a hospital together with a copy of the MSDS.

EYE
If this product comes in contact with the eyes:

continued...
AFRICAN MINERAL SALTS CICHLID
Chemwatch Material Safety Data Sheet
Feb-8-2008 CHEMWATCH 02-0958
NB293ECP Version No:1
CD 2007/4 Page 3 of 10
Section 4 - FIRST AID MEASURES

路 Wash out immediately with fresh running water.
路 Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and
moving the eyelids by occasionally lifting the upper and lower lids.
路 If pain persists or recurs seek medical attention.
路 Removal of contact lenses after an eye injury should only be undertaken by skilled
personnel.

SKIN
If skin or hair contact occurs:
路 Flush skin and hair with running water (and soap if available).
路 Seek medical attention in event of irritation.

INHALED
路 If fumes or combustion products are inhaled remove from contaminated area.
路 Other measures are usually unnecessary.

NOTES TO PHYSICIAN
Treat symptomatically.


Section 5 - FIRE FIGHTING MEASURES

Flash Point (掳 Not Applicable
F):
Lower Explosive Limit (%): Not Applicable
Upper Explosive Limit (%): Not Applicable
Autoignition Temp (掳 Not Applicable
F):

EXTINGUISHING MEDIA
路 There is no restriction on the type of extinguisher which may be used.
Use extinguishing media suitable for surrounding area.

FIRE FIGHTING
路 Alert Emergency Responders and tell them location and nature of hazard.
路 Wear breathing apparatus plus protective gloves for fire only.
路 Prevent, by any means available, spillage from entering drains or water course.
路 Use fire fighting procedures suitable for surrounding area.
路 Do not approach containers suspected to be hot.
路 Cool fire exposed containers with water spray from a protected location.
路 If safe to do so, remove containers from path of fire.
路 Equipment should be thoroughly decontaminated after use.

GENERAL FIRE HAZARDS/HAZARDOUS COMBUSTIBLE PRODUCTS
路 Non combustible.
路 Not considered to be a significant fire risk, however containers may burn.
Decomposition may produce toxic fumes of: hydrogen chloride.

FIRE INCOMPATIBILITY
None known.

PERSONAL PROTECTION
Glasses:
Chemical goggles.
Gloves:
Respirator:
Particulate




continued...
AFRICAN MINERAL SALTS CICHLID
Chemwatch Material Safety Data Sheet
Feb-8-2008 CHEMWATCH 02-0958
NB293ECP Version No:1
CD 2007/4 Page 4 of 10


Section 6 - ACCIDENTAL RELEASE MEASURES


MINOR SPILLS
路 Remove all ignition sources.
路 Clean up all spills immediately.
路 Avoid contact with skin and eyes.
路 Control personal contact by using protective equipment.
路 Use dry clean up procedures and avoid generating dust.
路 Place in a suitable labelled container for waste disposal.

MAJOR SPILLS
Moderate hazard.
路 CAUTION: Advise personnel in area.
路 Alert Emergency Responders and tell them location and nature of hazard.
路 Control personal contact by wearing protective clothing.
路 Prevent, by any means available, spillage from entering drains or water courses.
路 Recover product wherever possible.
路 IF DRY: Use dry clean up procedures and avoid generating dust. Collect residues and
place in sealed plastic bags or other containers for disposal. IF WET: Vacuum/shovel up
and place in labelled containers for disposal.
路 ALWAYS: Wash area down with large amounts of water and prevent runoff into drains.
路 If contamination of drains or waterways occurs, advise emergency services.



Section 7 - HANDLING AND STORAGE


PROCEDURE FOR HANDLING
路 DO NOT USE brass or copper containers / stirrers.
路 Avoid all personal contact, including inhalation.
路 Wear protective clothing when risk of exposure occurs.
路 Use in a well-ventilated area.
路 Prevent concentration in hollows and sumps.
路 DO NOT enter confined spaces until atmosphere has been checked.
路 DO NOT allow material to contact humans, exposed food or food utensils.
路 Avoid contact with incompatible materials.
路 When handling, DO NOT eat, drink or smoke.
路 Keep containers securely sealed when not in use.
路 Avoid physical damage to containers.
路 Always wash hands with soap and water after handling.
路 Work clothes should be laundered separately.
路 Launder contaminated clothing before re-use.
路 Use good occupational work practice.
路 Observe manufacturer's storing and handling recommendations.
路 Atmosphere should be regularly checked against established exposure standards to ensure
safe working conditions are maintained.

RECOMMENDED STORAGE METHODS
DO NOT use aluminum or galvanized containers.
路 Polyethylene or polypropylene container.
路 Check all containers are clearly labelled and free from leaks.


STORAGE REQUIREMENTS
路 Store in original containers.
路 Keep containers securely sealed.

continued...
AFRICAN MINERAL SALTS CICHLID
Chemwatch Material Safety Data Sheet
Feb-8-2008 CHEMWATCH 02-0958
NB293ECP Version No:1
CD 2007/4 Page 5 of 10
Section 7 - HANDLING AND STORAGE

路 Store in a cool, dry, well-ventilated area.
路 Store away from incompatible materials and foodstuff containers.
路 Protect containers against physical damage and check regularly for leaks.
路 Observe manufacturer's storing and handling recommendations.



Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION


EXPOSURE CONTROLS
Source Material TWA mg/m鲁 STEL mg/m鲁
__________________ __________________ _______ _______
Canada - Ontario Occupational calcium chloride (Calcium 5
Exposure Limits chloride)
Canada - Alberta Occupational calcium chloride (Coal dust 2
Exposure Limits (Respirable particulate))
Canada - Alberta Occupational calcium chloride (Cotton, dust, 0.2
Exposure Limits raw)
Canada - Saskatchewan calcium chloride (Particulates, 10 20
Occupational Health and Safety NOC++)
Regulations - Contamination
Limits
Canada - Saskatchewan calcium chloride (Respirable 3 6
Occupational Health and Safety size+)
Regulations - Contamination
Limits
US - Michigan Exposure Limits calcium chloride (Particulates 5
for Air Contaminants not otherwise regulated,
Respirable dust)



MATERIAL DATA
Not available. Refer to individual constituents.

INGREDIENT DATA
CALCIUM CHLORIDE:

PERSONAL PROTECTION

EYE
路 Safety glasses with side shields.
路 Chemical goggles.
路 Contact lenses pose a special hazard; soft lenses may absorb irritants and all lenses
concentrate them. DO NOT wear contact lenses.

HANDS/FEET
Experience indicates that the following polymers are suitable as glove materials for
protection against undissolved, dry solids, where abrasive particles are not present.
路 polychloroprene
路 nitrile rubber
路 butyl rubber
路 fluorocaoutchouc
路 polyvinyl chloride
Gloves should be examined for wear and/ or degradation constantly.



continued...
AFRICAN MINERAL SALTS CICHLID
Chemwatch Material Safety Data Sheet
Feb-8-2008 CHEMWATCH 02-0958
NB293ECP Version No:1
CD 2007/4 Page 6 of 10
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

OTHER
路 Overalls.
路 P.V.C. apron.
路 Barrier cream.
路 Skin cleansing cream.
路 Eye wash unit.

路 Respirators may be necessary when engineering and administrative controls do not
adequately prevent
路 exposures.
路 The decision to use respiratory protection should be based on professional judgment
that takes into account toxicity information, exposure measurement data, and frequency
and likelihood of the worker鈥檚 exposure.
路 Published occupational exposure limits, where they exist, will assist in determining
the adequacy of the selected respiratory . These may be government mandated or vendor
recommended.
路 Certified respirators will be useful for protecting workers from inhalation of
particulates when properly selected and fit tested as part of a complete respiratory
protection program.
路 Use approved positive flow mask if significant quantities of dust becomes airborne.
路 Try to avoid creating dust conditions.

RESPIRATOR
Protection Factor Half- Face Respirator Full- Face Respirator Powered Air Respirator
10 x PEL P1 - PAPR- P1
Air- line* - -
50 x PEL Air- line** P2 PAPR- P2
100 x PEL - P3 -
Air- line* -
100+ x PEL - Air- line** PAPR- P3

* - Negative pressure demand ** - Continuous flow
Explanation of Respirator Codes:
Class 1 low to medium absorption capacity filters.
Class 2 medium absorption capacity filters.
Class 3 high absorption capacity filters.
PAPR Powered Air Purifying Respirator (positive pressure) cartridge.
Type A for use against certain organic gases and vapors.
Type AX for use against low boiling point organic compounds (less than 65ºC).
Type B for use against certain inorganic gases and other acid gases and vapors.
Type E for use against sulfur dioxide and other acid gases and vapors.
Type K for use against ammonia and organic ammonia derivatives
Class P1 intended for use against mechanically generated particulates of sizes most
commonly encountered in industry, e.g. asbestos, silica.
Class P2 intended for use against both mechanically and thermally generated particulates,
e.g. metal fume.
Class P3 intended for use against all particulates containing highly toxic materials,
e.g. beryllium.

The local concentration of material, quantity and conditions of use determine the type of
personal protective equipment required.
Use appropriate NIOSH-certified respirator based on informed professional
judgement. In conditions where no reasonable estimate of exposure can be
made, assume the exposure is in a concentration IDLH and use NIOSH-certified
full face pressure demand SCBA with a minimum service life of 30 minutes, or
a combination full facepiece pressure demand SAR with auxiliary self-contained
air supply. Respirators provided only for escape from IDLH atmospheres shall be
NIOSH-certified for escape from the atmosphere in which they will be used.

continued...
AFRICAN MINERAL SALTS CICHLID
Chemwatch Material Safety Data Sheet
Feb-8-2008 CHEMWATCH 02-0958
NB293ECP Version No:1
CD 2007/4 Page 7 of 10
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

ENGINEERING CONTROLS
路 Local exhaust ventilation is required where solids are handled as powders or crystals;
even when particulates are relatively large, a certain proportion will be powdered by
mutual friction.
路 If in spite of local exhaust an adverse concentration of the substance in air could
occur, respiratory protection should be considered.
Such protection might consist of:
(a): particle dust respirators, if necessary, combined with an absorption cartridge;
(b): filter respirators with absorption cartridge or canister of the right type;
(c): fresh-air hoods or masks



Section 9 - PHYSICAL AND CHEMICAL PROPERTIES


PHYSICAL PROPERTIES
Mixes with water.

Molecular Weight: Not Applicable Boiling Range (掳 Not Applicable
F):
Melting Range (掳 Not Available
F): Specific Gravity (water= 1): Not Available
Solubility in water (g/L): Miscible pH (as supplied): Not Applicable
pH (1% solution): 8.0 (0.5g sol) Vapour Pressure (mmHG): Not Applicable
Volatile Component (%vol): Not Available Evaporation Rate: Not Applicable
Relative Vapor Density (air=1): Not Flash Point (掳 Not Applicable
F):
Applicable
Lower Explosive Limit (%): Not Applicable Upper Explosive Limit (%): Not Applicable
Autoignition Temp (掳 Not Applicable
F): Decomposition Temp (掳 Not Available
F):
State: Divided Solid Viscosity: Not Applicable



APPEARANCE
White powder with no odour; soluble in water.



Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION


CONDITIONS CONTRIBUTING TO INSTABILITY
路 Presence of incompatible materials.
路 Product is considered stable.
路 Hazardous polymerization will not occur.

STORAGE INCOMPATIBILITY
路 In presence of moisture, the material is corrosive to aluminium, zinc and tin producing
highly flammable hydrogen gas.



Section 11 - TOXICOLOGICAL INFORMATION


African Mineral Salts Cichlid

TOXICITY AND IRRITATION
Not available. Refer to individual constituents.

continued...
AFRICAN MINERAL SALTS CICHLID
Chemwatch Material Safety Data Sheet
Feb-8-2008 CHEMWATCH 02-0958
NB293ECP Version No:1
CD 2007/4 Page 8 of 10
Section 11 - TOXICOLOGICAL INFORMATION

CALCIUM CHLORIDE:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of
Chemical Substances.
TOXICITY IRRITATION
Oral (rat) LD50: 1000 mg/kg Skin (unknown): moderate*
Eye (unknown): severe* [ICI]



Section 12 - ECOLOGICAL INFORMATION

DO NOT discharge into sewer or waterways.
Refer to data for ingredients, which follows:

CALCIUM CHLORIDE:
Fish LC50 (96hr.) (mg/l): 8.4 (24hr)


Section 13 - DISPOSAL CONSIDERATIONS


Disposal Instructions
All waste must be handled in accordance with local, state and federal
regulations.
Legislation addressing waste disposal requirements may differ by country, state and/ or
territory. Each user must refer to laws operating in their area. In some areas, certain
wastes must be tracked.
A Hierarchy of Controls seems to be common - the user should investigate:
路 Reduction,
路 Reuse
路 Recycling
路 Disposal (if all else fails)
This material may be recycled if unused, or if it has not been contaminated so as to make
it unsuitable for its intended use. Shelf life considerations should also be applied in
making decisions of this type. Note that properties of a material may change in use, and
recycling or reuse may not always be appropriate.
DO NOT allow wash water from cleaning equipment to enter drains. Collect all wash water
for treatment before disposal.
路 Recycle wherever possible or consult manufacturer for recycling options.
路 Consult Waste Management Authority for disposal.
路 Bury residue in an authorized landfill.
路 Recycle containers where possible, or dispose of in an authorized landfill.


Section 14 - TRANSPORTATION INFORMATION

NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS:UN, IATA,
IMDG



Section 15 - REGULATORY INFORMATION




continued...
AFRICAN MINERAL SALTS CICHLID
Chemwatch Material Safety Data Sheet
Feb-8-2008 CHEMWATCH 02-0958
NB293ECP Version No:1
CD 2007/4 Page 9 of 10
Section 15 - REGULATORY INFORMATION




REGULATIONS

US EPCRA Section 313 Chemical List
Ingredient CAS % de minimus
concentration

US CERCLA List of Hazardous Substances and Reportable Quantities
Ingredient CAS RQ
African Mineral Salts Cichlid (CAS: None):
No regulations applicable

calcium chloride (CAS: 10043-52-4) is found on the following regulatory lists;
Canada - Alberta Occupational Exposure Limits
Canada - Ontario Occupational Exposure Limits
Canada - Saskatchewan Occupational Health and Safety Regulations - Contamination Limits
Canada Domestic Substances List (DSL)
Canada Environmental Quality Guidelines (EQGs) Water: Community
CODEX General Standard for Food Additives (GSFA) - Additives Permitted for Use in Food in General, Unless Otherwise Specified, in Accordance with GMP
International Council of Chemical Associations (ICCA) - High Production Volume List
OECD Representative List of High Production Volume (HPV) Chemicals
United Nations Convention Against Illicit Traffic in Narcotic Drugs and Psychotropic Substances - Table II
US - Michigan Exposure Limits for Air Contaminants
US DOE Temporary Emergency Exposure Limits (TEELs)
US EPA High Production Volume Chemicals Additional List
US EPA High Production Volume Program Chemical List
US OSHA Permissible Exposure Levels (PELs) - Table Z3
US Toxic Substances Control Act (TSCA) - Inventory
WHO Guidelines for Drinking-water Quality - Chemicals for which guideline values have not been established




Section 16 - OTHER INFORMATION



Reasonable care has been taken in the preparation of this information, but the
author makes no warranty of merchantability or any other warranty, expressed or
implied, with respect to this information. The author makes no representations
and assumes no liability for any direct, incidental or consequential damages
resulting from its use. CHEMTREC: (800) 424- 9300

Issue Date: Feb-8-2008
Print Date: Feb-8-2008

Classification of the preparation and its individual components has drawn on official and
authoritative sources as well as independent review by the Chemwatch Classification
committee using available literature references.
A list of reference resources used to assist the committee may be found at:
www.chemwatch.net/references.

The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk
Assessment. Many factors determine whether the reported Hazards are Risks in the
workplace or other settings. Risks may be determined by reference to Exposures Scenarios.
Scale of use, frequency of use and current or available engineering controls must be
considered.


continued...
AFRICAN MINERAL SALTS CICHLID
Chemwatch Material Safety Data Sheet
Feb-8-2008 CHEMWATCH 02-0958
NB293ECP Version No:1
CD 2007/4 Page 10 of 10
Section 16 - OTHER INFORMATION

For detailed advice on Personal Protective Equipment, refer to the following U.S.
Regulations and Standards:
OSHA Standards - 29 CFR:
1910.132 - Personal Protective Equipment - General requirements
1910.133 - Eye and face protection
1910.134 - Respiratory Protection
1910.136 - Occupational foot protection
1910.138 - Hand Protection

Eye and face protection - ANSI Z87.1
Foot protection - ANSI Z41
Respirators must be NIOSH approved.

For detailed advice on Personal Protective Equipment, refer to the following Canadian
Standards:
CAN/CSA-Z195 - Protective Footwear
Z195.1 - Guideline on Selection, Use, and Care of Protective Footwear
CAN/CSA-Z94.3 - Industrial Eye and Face Protectors
Z94.3.1 - Protective Eyewear User's Guide
CSA-Z94.4 - Selection, Use, and Care of Respirators
CAN/CSA-Z180.1 - Compressed Breathing Air and Systems.

This document is copyright. Apart from any fair dealing for the purposes of
private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from
CHEMWATCH. TEL (+61 3) 9572 4700.

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