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File Name: aquariumpharm_com---buffer_max_marine_092107.asp
                                        BUFFER MAX MARINE
Chemwatch Material Safety Data Sheet (REVIEW)
Sep-21-2007 CHEMWATCH 6632-78
NB293ECP Version No:1
CD 2007/3 Page 1 of 12



Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION


PRODUCT NAME
BUFFER MAX MARINE

STATEMENT OF HAZARDOUS NATURE
CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200.

SUPPLIER
Company: Mars Fishcare North America Inc Company: Mars Fishcare North America Inc
Address: Address:
PO Box 218 50 East Hamilton Street
Chalfont Chalfont
PA, 18914- 0218 PA, 18914
USA USA
Telephone: +1 215 822 8181 Telephone: +1 215 822 8181
Emergency Tel: +1800 222 1222 (US Only) Fax: +1 215 822 1906


PRODUCT USE
Used according to manufacturer' s directions. For product 360.

SYNONYMS

"Formula ID# RM000265"


Section 2 - HAZARDS IDENTIFICATION


CANADIAN WHMIS SYMBOLS




EMERGENCY OVERVIEW

RISK
Harmful by inhalation.
Irritating to eyes, respiratory system and skin.

POTENTIAL HEALTH EFFECTS

ACUTE HEALTH EFFECTS

SWALLOWED
The material is not thought to produce adverse health effects following ingestion (as
classified using animal models). Nevertheless, adverse systemic effects have been
produced following exposure of animals by at least one other route and good hygiene
practice requires that exposure be kept to a minimum.


continued...
BUFFER MAX MARINE
Chemwatch Material Safety Data Sheet (REVIEW)
Sep-21-2007 CHEMWATCH 6632-78
NB293ECP Version No:1
CD 2007/3 Page 2 of 12
Section 2 - HAZARDS IDENTIFICATION

EYE
There is evidence that material may produce eye irritation in some persons and produce
eye damage 24 hours or more after instillation. Severe inflammation may be expected with
pain. There may be damage to the cornea. Unless treatment is prompt and adequate there
may be permanent loss of vision. Conjunctivitis can occur following repeated exposure.
Alkaline salts may be intensely irritating to the eyes and precautions should be taken to
ensure direct eye contact is avoided.

SKIN
The material may cause mild but significant inflammation of the skin either following
direct contact or after a delay of some time. Repeated exposure can cause contact
dermatitis which is characterized by redness, swelling and blistering.
Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may
produce systemic injury with harmful effects. Examine the skin prior to the use of the
material and ensure that any external damage is suitably protected.

INHALED
Inhalation of dusts, generated by the material, during the course of normal
handling, may be harmful.
The material can cause respiratory irritation in some persons. The body's response to
such irritation can cause further lung damage.

CHRONIC HEALTH EFFECTS
Long-term exposure to respiratory irritants may result in disease of the airways
involving difficult breathing and related systemic problems.
Limited evidence suggests that repeated or long-term occupational exposure may produce
cumulative health effects involving organs or biochemical systems.
Long term exposure to high dust concentrations may cause changes in lung function i.e.
pneumoconiosis; caused by particles less than 0.5 micron penetrating and remaining in the
lung. Prime symptom is breathlessness; lung shadows show on X-ray.


Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS

NAME CAS RN %
sodium salt, proprietary 40-50
sodium carbonate 497-19-8 30-40
other non hazardous ingredients, proprietary 10-20


Section 4 - FIRST AID MEASURES


SWALLOWED
路 Immediately give a glass of water.
路 First aid is not generally required. If in doubt, contact a Poisons Information Center
or a doctor.

EYE
If this product comes in contact with the eyes:
路 Wash out immediately with fresh running water.
路 Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and
moving the eyelids by occasionally lifting the upper and lower lids.
路 If pain persists or recurs seek medical attention.
路 Removal of contact lenses after an eye injury should only be undertaken by skilled
personnel.



continued...
BUFFER MAX MARINE
Chemwatch Material Safety Data Sheet (REVIEW)
Sep-21-2007 CHEMWATCH 6632-78
NB293ECP Version No:1
CD 2007/3 Page 3 of 12
Section 4 - FIRST AID MEASURES

SKIN
If skin contact occurs:
路 Immediately remove all contaminated clothing, including footwear
路 Flush skin and hair with running water (and soap if available).
路 Seek medical attention in event of irritation.

INHALED
路 If fumes or combustion products are inhaled remove from contaminated area.
路 Lay patient down. Keep warm and rested.
路 Prostheses such as false teeth, which may block airway, should be removed, where
possible, prior to initiating first aid procedures.
路 Apply artificial respiration if not breathing, preferably with a demand valve
resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary.
路 Transport to hospital, or doctor, without delay.

NOTES TO PHYSICIAN
For acute or short-term repeated exposures to highly alkaline materials:
路 Respiratory stress is uncommon but present occasionally because of soft tissue edema.
路 Unless endotracheal intubation can be accomplished under direct vision,
cricothyroidotomy or tracheotomy may be necessary.
路 Oxygen is given as indicated.
路 The presence of shock suggests perforation and mandates an intravenous line and fluid
administration.
路 Damage due to alkaline corrosives occurs by liquefaction necrosis whereby the
saponification of fats and solubilization of proteins allow deep penetration into the
tissue.
Alkalis continue to cause damage after exposure.

INGESTION:
路 Milk and water are the preferred diluents
No more than 2 glasses of water should be given to an adult.
路 Neutralizing agents should never be given since exothermic heat reaction may compound
injury.
* Catharsis and emesis are absolutely contra-indicated.
* Activated charcoal does not absorb alkali.
* Gastric lavage should not be used.

Supportive care involves the following:
路 Withhold oral feedings initially.
路 If endoscopy confirms transmucosal injury start steroids only within the first 48
hours.
路 Carefully evaluate the amount of tissue necrosis before assessing the need for surgical
intervention.
路 Patients should be instructed to seek medical attention whenever they develop
difficulty in swallowing (dysphagia).

SKIN AND EYE:
路 Injury should be irrigated for 20-30 minutes.
路 Eye injuries require saline. [Ellenhorn & Barceloux: Medical Toxicology].


Section 5 - FIRE FIGHTING MEASURES

Flash Point (掳 Not Applicable
F):
Lower Explosive Limit (%): Not Applicable
Upper Explosive Limit (%): Not Applicable
Autoignition Temp (掳 Not Applicable
F):


continued...
BUFFER MAX MARINE
Chemwatch Material Safety Data Sheet (REVIEW)
Sep-21-2007 CHEMWATCH 6632-78
NB293ECP Version No:1
CD 2007/3 Page 4 of 12
Section 5 - FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA
路 There is no restriction on the type of extinguisher which may be used.
Use extinguishing media suitable for surrounding area.

FIRE FIGHTING
路 Alert Emergency Responders and tell them location and nature of hazard.
路 Wear breathing apparatus plus protective gloves for fire only.
路 Prevent, by any means available, spillage from entering drains or water course.
路 Use fire fighting procedures suitable for surrounding area.
路 Do not approach containers suspected to be hot.
路 Cool fire exposed containers with water spray from a protected location.
路 If safe to do so, remove containers from path of fire.
路 Equipment should be thoroughly decontaminated after use.

GENERAL FIRE HAZARDS/HAZARDOUS COMBUSTIBLE PRODUCTS
路 Solid which exhibits difficult combustion or is difficult to ignite.
路 Avoid generating dust, particularly clouds of dust in a confined or unventilated space
as dusts may form an explosive mixture with air, and any source of ignition, i.e. flame
or spark, will cause fire or explosion. Dust clouds generated by the fine grinding of the
solid are a particular hazard; accumulations of fine dust may burn rapidly and fiercely
if ignited.
路 Dry dust can be charged electrostatically by turbulence, pneumatic transport, pouring,
in exhaust ducts and during transport.
路 Build-up of electrostatic charge may be prevented by bonding and grounding.
路 Powder handling equipment such as dust collectors, dryers and mills may require
additional protection measures such as explosion venting.
Combustion products include: carbon monoxide (CO), carbon dioxide (CO2), other
pyrolysis products typical of burning organic material.
May emit poisonous fumes.
May emit corrosive fumes.

FIRE INCOMPATIBILITY
Avoid contamination with oxidizing agents i.e. nitrates, oxidizing acids,
chlorine bleaches, pool chlorine etc. as ignition may result.

PERSONAL PROTECTION
Glasses:
Chemical goggles.
Gloves:
Respirator:
Particulate


Section 6 - ACCIDENTAL RELEASE MEASURES


MINOR SPILLS
路 Remove all ignition sources.
路 Clean up all spills immediately.
路 Avoid contact with skin and eyes.
路 Control personal contact by using protective equipment.
路 Use dry clean up procedures and avoid generating dust.
路 Place in a suitable labelled container for waste disposal.

MAJOR SPILLS
Moderate hazard.
路 CAUTION: Advise personnel in area.
路 Alert Emergency Responders and tell them location and nature of hazard.
路 Control personal contact by wearing protective clothing.
continued...
BUFFER MAX MARINE
Chemwatch Material Safety Data Sheet (REVIEW)
Sep-21-2007 CHEMWATCH 6632-78
NB293ECP Version No:1
CD 2007/3 Page 5 of 12
Section 6 - ACCIDENTAL RELEASE MEASURES

路 Prevent, by any means available, spillage from entering drains or water courses.
路 Recover product wherever possible.
路 IF DRY: Use dry clean up procedures and avoid generating dust. Collect residues and
place in sealed plastic bags or other containers for disposal. IF WET: Vacuum/shovel up
and place in labelled containers for disposal.
路 ALWAYS: Wash area down with large amounts of water and prevent runoff into drains.
路 If contamination of drains or waterways occurs, advise emergency services.



Section 7 - HANDLING AND STORAGE


PROCEDURE FOR HANDLING
路 Avoid all personal contact, including inhalation.
路 Wear protective clothing when risk of exposure occurs.
路 Use in a well-ventilated area.
路 Prevent concentration in hollows and sumps.
路 DO NOT enter confined spaces until atmosphere has been checked.
路 DO NOT allow material to contact humans, exposed food or food utensils.
路 Avoid contact with incompatible materials.
路 When handling, DO NOT eat, drink or smoke.
路 Keep containers securely sealed when not in use.
路 Avoid physical damage to containers.
路 Always wash hands with soap and water after handling.
路 Work clothes should be laundered separately.
路 Launder contaminated clothing before re-use.
路 Use good occupational work practice.
路 Observe manufacturer's storing and handling recommendations.
路 Atmosphere should be regularly checked against established exposure standards to ensure
safe working conditions are maintained.
Empty containers may contain residual dust which has the potential to accumulate
following settling. Such dusts may explode in the presence of an appropriate ignition
source.
路 Do NOT cut, drill, grind or weld such containers
路 In addition ensure such activity is not performed near full, partially empty or empty
containers without appropriate workplace safety authorisation or permit.

RECOMMENDED STORAGE METHODS
DO NOT use aluminum or galvanized containers.
路 Polyethylene or polypropylene container.
路 Check all containers are clearly labelled and free from leaks.


STORAGE REQUIREMENTS
路 Store in original containers.
路 Keep containers securely sealed.
路 Store in a cool, dry, well-ventilated area.
路 Store away from incompatible materials and foodstuff containers.
路 Protect containers against physical damage and check regularly for leaks.
路 Observe manufacturer's storing and handling recommendations.




continued...
BUFFER MAX MARINE
Chemwatch Material Safety Data Sheet (REVIEW)
Sep-21-2007 CHEMWATCH 6632-78
NB293ECP Version No:1
CD 2007/3 Page 6 of 12


Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION


EXPOSURE CONTROLS
Source Material TWA mg/m鲁 STEL mg/m鲁
_________ _________ _____ _____
Canada - Saskatchewan sodium carbonate 10 20
Occupational Health (Particulates, NOC++)
and Safety Regulations
- Contamination Limits
Canada - Saskatchewan sodium carbonate 3 6
Occupational Health (Respirable size+)
and Safety Regulations
- Contamination Limits



MATERIAL DATA
It is the goal of the ACGIH (and other Agencies) to recommend TLVs (or their equivalent)
for all substances for which there is evidence of health effects at airborne
concentrations encountered in the workplace.
At this time no TLV has been established, even though this material may produce adverse
health effects (as evidenced in animal experiments or clinical experience). Airborne
concentrations must be maintained as low as is practically possible and occupational
exposure must be kept to a minimum.
NOTE: The ACGIH occupational exposure standard for Particles Not Otherwise Specified
(P.N.O.S) does NOT apply.
Sensory irritants are chemicals that produce temporary and undesirable side-effects on
the eyes, nose or throat. Historically occupational exposure standards for these
irritants have been based on observation of workers' responses to various airborne
concentrations. Present day expectations require that nearly every individual should be
protected against even minor sensory irritation and exposure standards are established
using uncertainty factors or safety factors of 5 to 10 or more. On occasion animal no
-observable-effect-levels (NOEL) are used to determine these limits where human results
are unavailable. An additional approach, typically used by the TLV committee (USA) in
determining respiratory standards for this group of chemicals, has been to assign ceiling
values (TLV C) to rapidly acting irritants and to assign short-term exposure limits (TLV
STELs) when the weight of evidence from irritation, bioaccumulation and other endpoints
combine to warrant such a limit. In contrast the MAK Commission (Germany) uses a five
-category system based on intensive odour, local irritation, and elimination half-life.
However this system is being replaced to be consistent with the European Union (EU)
Scientific Committee for Occupational Exposure Limits (SCOEL); this is more closely
allied to that of the USA.
OSHA (USA) concluded that exposure to sensory irritants can:
路 cause inflammation
路 cause increased susceptibility to other irritants and infectious agents
路 lead to permanent injury or dysfunction
路 permit greater absorption of hazardous substances and
路 acclimate the worker to the irritant warning properties of these substances thus
increasing the risk of overexposure.

INGREDIENT DATA
SODIUM CARBONATE:
It is the goal of the ACGIH (and other Agencies) to recommend TLVs (or their equivalent)
for all substances for which there is evidence of health effects at airborne
concentrations encountered in the workplace.
At this time no TLV has been established, even though this material may produce adverse
health effects (as evidenced in animal experiments or clinical experience). Airborne
concentrations must be maintained as low as is practically possible and occupational
continued...
BUFFER MAX MARINE
Chemwatch Material Safety Data Sheet (REVIEW)
Sep-21-2007 CHEMWATCH 6632-78
NB293ECP Version No:1
CD 2007/3 Page 7 of 12
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

exposure must be kept to a minimum.
NOTE: The ACGIH occupational exposure standard for Particles Not Otherwise Specified
(P.N.O.S) does NOT apply.
Sensory irritants are chemicals that produce temporary and undesirable side-effects on
the eyes, nose or throat. Historically occupational exposure standards for these
irritants have been based on observation of workers' responses to various airborne
concentrations. Present day expectations require that nearly every individual should be
protected against even minor sensory irritation and exposure standards are established
using uncertainty factors or safety factors of 5 to 10 or more. On occasion animal no
-observable-effect-levels (NOEL) are used to determine these limits where human results
are unavailable. An additional approach, typically used by the TLV committee (USA) in
determining respiratory standards for this group of chemicals, has been to assign ceiling
values (TLV C) to rapidly acting irritants and to assign short-term exposure limits (TLV
STELs) when the weight of evidence from irritation, bioaccumulation and other endpoints
combine to warrant such a limit. In contrast the MAK Commission (Germany) uses a five
-category system based on intensive odour, local irritation, and elimination half-life.
However this system is being replaced to be consistent with the European Union (EU)
Scientific Committee for Occupational Exposure Limits (SCOEL); this is more closely
allied to that of the USA.
OSHA (USA) concluded that exposure to sensory irritants can:
路 cause inflammation
路 cause increased susceptibility to other irritants and infectious agents
路 lead to permanent injury or dysfunction
路 permit greater absorption of hazardous substances and
路 acclimate the worker to the irritant warning properties of these substances thus
increasing the risk of overexposure.
OEL STEL: (Russia) 5 mg/m3

PERSONAL PROTECTION

EYE
路 Safety glasses with side shields.
路 Chemical goggles.
路 Contact lenses pose a special hazard; soft lenses may absorb irritants and all lenses
concentrate them. DO NOT wear contact lenses.

HANDS/FEET
Suitability and durability of glove type is dependent on usage. Factors such as:
路 frequency and duration of contact,
路 chemical resistance of glove material,
路 glove thickness and
路 dexterity,
are important in the selection of gloves.
Experience indicates that the following polymers are suitable as glove materials for
protection against undissolved, dry solids, where abrasive particles are not present.
路 polychloroprene
路 nitrile rubber
路 butyl rubber
路 fluorocaoutchouc
路 polyvinyl chloride
Gloves should be examined for wear and/ or degradation constantly.

OTHER
路 Overalls.
路 P.V.C. apron.
路 Barrier cream.
路 Skin cleansing cream.
路 Eye wash unit.

continued...
BUFFER MAX MARINE
Chemwatch Material Safety Data Sheet (REVIEW)
Sep-21-2007 CHEMWATCH 6632-78
NB293ECP Version No:1
CD 2007/3 Page 8 of 12
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

RESPIRATOR
Protection Factor Half- Face Respirator Full- Face Respirator Powered Air Respirator
10 x PEL P1 - PAPR- P1
Air- line* - -
50 x PEL Air- line** P2 PAPR- P2
100 x PEL - P3 -
Air- line* -
100+ x PEL - Air- line** PAPR- P3

* - Negative pressure demand ** - Continuous flow
Explanation of Respirator Codes:
Class 1 low to medium absorption capacity filters.
Class 2 medium absorption capacity filters.
Class 3 high absorption capacity filters.
PAPR Powered Air Purifying Respirator (positive pressure) cartridge.
Type A for use against certain organic gases and vapors.
Type AX for use against low boiling point organic compounds (less than 65ºC).
Type B for use against certain inorganic gases and other acid gases and vapors.
Type E for use against sulfur dioxide and other acid gases and vapors.
Type K for use against ammonia and organic ammonia derivatives
Class P1 intended for use against mechanically generated particulates of sizes most
commonly encountered in industry, e.g. asbestos, silica.
Class P2 intended for use against both mechanically and thermally generated particulates,
e.g. metal fume.
Class P3 intended for use against all particulates containing highly toxic materials,
e.g. beryllium.

The local concentration of material, quantity and conditions of use determine the type of
personal protective equipment required.
Use appropriate NIOSH-certified respirator based on informed professional
judgement. In conditions where no reasonable estimate of exposure can be
made, assume the exposure is in a concentration IDLH and use NIOSH-certified
full face pressure demand SCBA with a minimum service life of 30 minutes, or
a combination full facepiece pressure demand SAR with auxiliary self-contained
air supply. Respirators provided only for escape from IDLH atmospheres shall be
NIOSH-certified for escape from the atmosphere in which they will be used.

ENGINEERING CONTROLS
Local exhaust ventilation usually required. If risk of overexposure exists, wear an
approved respirator. Correct fit is essential to obtain adequate protection an approved
self contained breathing apparatus (SCBA) may be required in some situations. Provide
adequate ventilation in warehouse or closed storage area.



Section 9 - PHYSICAL AND CHEMICAL PROPERTIES


PHYSICAL PROPERTIES
Mixes with water.
Alkaline.

Molecular Weight: Not Applicable Boiling Range (掳 Not Ap plicable
F):
Melting Range (掳 Not Available
F): Specific Gravity (water= 1): Not Available
Solubility in water (g/L): Miscible pH (as supplied): Not Applicable
pH (1% solution): 9.48 (0.5g in DI) Vapor Pressure (mmHg): 0Not Applicable
Volatile Component (%vol): Not Applicable Evaporation Rate: Not Applicable
Relative Vapor Density (air=1): Not Applicable Flash Point (掳 Not Applicable
F):
Lower Explosive Limit (%): Not Applicable Upper Explosive Limit (%): Not Applicable
continued...
BUFFER MAX MARINE
Chemwatch Material Safety Data Sheet (REVIEW)
Sep-21-2007 CHEMWATCH 6632-78
NB293ECP Version No:1
CD 2007/3 Page 9 of 12
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Autoignition Temp (掳 Not Applicable
F): Decomposition Temp (掳 Not Available
F):
State: Divided Solid Viscosity: Not Applicable


APPEARANCE
White powder; soluble in water.



Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION


CONDITIONS CONTRIBUTING TO INSTABILITY
路 Presence of incompatible materials.
路 Product is considered stable.
路 Hazardous polymerization will not occur.

STORAGE INCOMPATIBILITY
Metals and their oxides or salts may react violently with chlorine trifluoride. Chlorine
trifluoride is a hypergolic oxidizer. It ignites on contact (without external source of
heat or ignition) with recognized fuels - contact with these materials, following an
ambient or slightly elevated temperature, is often violent and may produce ignition. The
state of subdivision may affect the results.
In presence of moisture, the material is corrosive to aluminium, zinc and tin producing
highly flammable hydrogen gas.
Avoid strong acids.
Avoid contact with copper, aluminium and their alloys.



Section 11 - TOXICOLOGICAL INFORMATION


Buffer Max Marine

TOXICITY AND IRRITATION
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of
Chemical Substances.
Asthma-like symptoms may continue for months or even years after exposure to the material
ceases. This may be due to a non-allergenic condition known as reactive airways
dysfunction syndrome (RADS) which can occur following exposure to high levels of highly
irritating compound. Key criteria for the diagnosis of RADS include the absence of
preceding respiratory disease, in a non-atopic individual, with abrupt onset of
persistent asthma-like symptoms within minutes to hours of a documented exposure to the
irritant. A reversible airflow pattern, on spirometry, with the presence of moderate to
severe bronchial hyperreactivity on methacholine challenge testing and the lack of
minimal lymphocytic inflammation, without eosinophilia, have also been included in the
criteria for diagnosis of RADS. RADS (or asthma) following an irritating inhalation is an
infrequent disorder with rates related to the concentration of and duration of exposure
to the irritating substance. Industrial bronchitis, on the other hand, is a disorder that
occurs as result of exposure due to high concentrations of irritating substance (often
particulate in nature) and is completely reversible after exposure ceases. The disorder
is characterised by dyspnea, cough and mucus production.
The material may cause skin irritation after prolonged or repeated exposure and may
produce on contact skin redness, swelling, the production of vesicles, scaling and
thickening of the skin.

SODIUM CARBONATE:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of
continued...
BUFFER MAX MARINE
Chemwatch Material Safety Data Sheet (REVIEW)
Sep-21-2007 CHEMWATCH 6632-78
NB293ECP Version No:1
CD 2007/3 Page 10 of 12
Section 11 - TOXICOLOGICAL INFORMATION

Chemical Substances.
TOXICITY IRRITATION
Oral (rat) LD50: 4090 mg/kg Skin (rabbit): 500 mg/24h Mild
Inhalation (rat) LC50: 2300 mg/m鲁/2h Eye (rabbit): 100 mg/24h Moderate
Eye (rabbit): 100 mg/30s Mild
Eye (rabbit): 50 mg SEVERE
The material may cause skin irritation after prolonged or repeated exposure and may
produce on contact skin redness, swelling, the production of vesicles, scaling and
thickening of the skin.
Asthma-like symptoms may continue for months or even years after exposure to the material
ceases. This may be due to a non-allergenic condition known as reactive airways
dysfunction syndrome (RADS) which can occur following exposure to high levels of highly
irritating compound. Key criteria for the diagnosis of RADS include the absence of
preceding respiratory disease, in a non-atopic individual, with abrupt onset of
persistent asthma-like symptoms within minutes to hours of a documented exposure to the
irritant. A reversible airflow pattern, on spirometry, with the presence of moderate to
severe bronchial hyperreactivity on methacholine challenge testing and the lack of
minimal lymphocytic inflammation, without eosinophilia, have also been included in the
criteria for diagnosis of RADS. RADS (or asthma) following an irritating inhalation is an
infrequent disorder with rates related to the concentration of and duration of exposure
to the irritating substance. Industrial bronchitis, on the other hand, is a disorder that
occurs as result of exposure due to high concentrations of irritating substance (often
particulate in nature) and is completely reversible after exposure ceases. The disorder
is characterised by dyspnea, cough and mucus production.



Section 12 - ECOLOGICAL INFORMATION

DO NOT discharge into sewer or waterways.
Refer to data for ingredients, which follows:

SODIUM CARBONATE:
DO NOT discharge into sewer or waterways.


Section 13 - DISPOSAL CONSIDERATIONS


Disposal Instructions
All waste must be handled in accordance with local, state and federal
regulations.
Legislation addressing waste disposal requirements may differ by country, state and/ or
territory. Each user must refer to laws operating in their area. In some areas, certain
wastes must be tracked.
A Hierarchy of Controls seems to be common - the user should investigate:
路 Reduction,
路 Reuse
路 Recycling
路 Disposal (if all else fails)
This material may be recycled if unused, or if it has not been contaminated so as to make
it unsuitable for its intended use. Shelf life considerations should also be applied in
making decisions of this type. Note that properties of a material may change in use, and
recycling or reuse may not always be appropriate.
DO NOT allow wash water from cleaning equipment to enter drains. Collect all wash water
for treatment before disposal.
路 Recycle wherever possible.
路 Consult manufacturer for recycling options or consult Waste Management Authority for

continued...
BUFFER MAX MARINE
Chemwatch Material Safety Data Sheet (REVIEW)
Sep-21-2007 CHEMWATCH 6632-78
NB293ECP Version No:1
CD 2007/3 Page 11 of 12
Section 13 - DISPOSAL CONSIDERATIONS

disposal if no suitable treatment or disposal facility can be identified.
路 Dispose of by: Burial in a licensed land-fill or Incineration in a licensed apparatus
(after admixture with suitable combustible material)
路 Decontaminate empty containers. Observe all label safeguards until containers are
cleaned and destroyed.


Section 14 - TRANSPORTATION INFORMATION

NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS:UN, IATA,
IMDG



Section 15 - REGULATORY INFORMATION




REGULATIONS
Buffer Max Marine (CAS: None):
No regulations applicable

sodium carbonate (CAS: 497-19-8) is found on the following regulatory lists;
Canada - Alberta Occupational Exposure Limits
Canada - Saskatchewan Occupational Health and Safety Regulations - Contamination Limits
Canada Domestic Substances List (DSL)
Canada Ingredient Disclosure List (SOR/88-64)
CODEX General Standard for Food Additives (GSFA) - Additives Permitted for Use in Food in General, Unless Otherwise Specified, in Accordance with GMP
International Council of Chemical Associations (ICCA) - High Production Volume List
OECD Representative List of High Production Volume (HPV) Chemicals
US - Michigan Exposure Limits for Air Contaminants
US Cosmetic Ingredient Review (CIR) Cosmetic ingredients found safe as used
US DOE Temporary Emergency Exposure Limits (TEELs)
US EPA High Production Volume Chemicals Additional List
US Food Additive Database
US Toxic Substances Control Act (TSCA) - Inventory




Section 16 - OTHER INFORMATION


LIMITED EVIDENCE
Cumulative effects may result following exposure*.
* (limited evidence).


Reasonable care has been taken in the preparation of this information, but the
author makes no warranty of merchantability or any other warranty, expressed or
implied, with respect to this information. The author makes no representations
and assumes no liability for any direct, incidental or consequential damages
resulting from its use. CHEMTREC: (800) 424- 9300

Issue Date: Sep-21-2007
Print Date: Sep-21-2007



continued...
BUFFER MAX MARINE
Chemwatch Material Safety Data Sheet (REVIEW)
Sep-21-2007 CHEMWATCH 6632-78
NB293ECP Version No:1
CD 2007/3 Page 12 of 12
Section 16 - OTHER INFORMATION

Classification of the preparation and its individual components has drawn on official and
authoritative sources as well as independent review by the Chemwatch Classification
committee using available literature references.
A list of reference resources used to assist the committee may be found at:
www.chemwatch.net/references.

The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk
Assessment. Many factors determine whether the reported Hazards are Risks in the
workplace or other settings. Risks may be determined by reference to Exposures Scenarios.
Scale of use, frequency of use and current or available engineering controls must be
considered.

This document is copyright. Apart from any fair dealing for the purposes of
private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from
CHEMWATCH. TEL (+61 3) 9572 4700.

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