The tests that comprise the Freshwater Master Test Kit have changed, so
this packet contains Material Safety Data Sheets that may not pertain to the
kit in your possession.
LIQUID NITRATE TEST SOLUTION #1
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-15
Issue Date: 21-Oct-2005 CD 2005/3 Page 1 of 16
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
LIQUID NITRATE TEST SOLUTION #1
STATEMENT OF HAZARDOUS NATURE
CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR
1910.1200.
SUPPLIER
Company: Aquarium Pharmaceuticals Incorporated Company: Aquarium Pharmaceuticals Incorporated
Address: Address:
50 East Hamilton Street PO Box 218
Chalfont Chalfont
PA, 18914 PA, 18914-0218
USA USA
Telephone: +1 215 822 8181 Telephone: +1 215 822 8181
Emergency Tel: +1800 222 1222 (US Only)
PRODUCT USE
Nitrate test solution for product LR1800, 34 and 401M.
SYNONYMS
"Solution ID# 3306"
Section 2 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
hydrochloric acid 7647-01-0 14 ap.
other ingredients, proprietary N/S
Section 3 - HAZARDS IDENTIFICATION
CANADIAN WHMIS SYMBOLS
EMERGENCY OVERVIEW
RISK
Harmful by inhalation.
Irritating to eyes, respiratory system and skin.
Cumulative effects may result following exposure*.
Eye contact may produce serious damage*.
continued...
LIQUID NITRATE TEST SOLUTION #1
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-15
Issue Date: 21-Oct-2005 CD 2005/3 Page 2 of 16
Section 3 - HAZARDS IDENTIFICATION
Exposure may produce irreversible effects*. *(limited evidence)
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
Ingestion of acidic corrosives may produce burns around and in the mouth. the
throat and esophagus. Immediate pain and difficulties in swallowing and speaking
may also be evident. Swelling of the epiglottis may make it difficult to breathe
which may result in suffocation. More severe exposure may result in vomiting
blood and thick mucus, shock, abnormally low blood pressure, fluctuating pulse,
shallow respiration and clammy skin, inflammation of stomach wall, and rupture
of esophageal tissue. Untreated shock may eventually result in kidney failure.
Severe cases may result in perforation of the stomach and abdominal cavity with
consequent infection, rigidity and fever. There may be severe narrowing of the
esophageal or pyloric sphincters; this may occur immediately or after a delay of
weeks to years. There may be coma and convulsions, followed by death due to
infection of the abdominal cavity, kidneys or lungs.
EYE
This material can cause eye irritation and damage in some persons.
If applied to the eyes, this material causes severe eye damage.
Direct eye contact with acid corrosives may produce pain, tears, sensitivity to
light and burns. Mild burns of the epithelia generally recover rapidly and
completely. Severe burns produce long-lasting and possibly irreversible damage.
The appearance of the burn may not be apparent for several weeks after the
initial contact. The cornea may ultimately become deeply opaque resulting in
blindness.
SKIN
Skin contact with acidic corrosives may result in pain and burns; these may be
deep with distinct edges and may heal slowly with the formation of scar tissue.
Entry into the blood-stream, through, for example, cuts, abrasions or lesions,
may produce systemic injury with harmful effects. Examine the skin prior to the
use of the material and ensure that any external damage is suitably protected.
INHALED
Inhalation of vapors or aerosols (mists, fumes), generated by the material
continued...
LIQUID NITRATE TEST SOLUTION #1
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-15
Issue Date: 21-Oct-2005 CD 2005/3 Page 3 of 16
Section 3 - HAZARDS IDENTIFICATION
during the course of normal handling, may be harmful.
There is some evidence to suggest that this material can cause, if inhaled once,
irreversible damage of organs.
Corrosive acids can cause irritation of the respiratory tract, with coughing,
choking and mucous membrane damage. There may be dizziness, headache, nausea and
weakness. Swelling of the lungs can occur, either immediately or after a delay;
symptoms of this include chest tightness, shortness of breath, frothy phlegm and
cyanosis. Lack of oxygen can cause death hours after onset.
CHRONIC HEALTH EFFECTS
Repeated or prolonged exposure to acids may result in the erosion of teeth,
swelling and or ulceration of mouth lining. Irritation of airways to lung, with
cough, and inflammation of lung tissue often occurs. Chronic exposure may
inflame the skin or conjunctiva. Substance accumulation, in the human body, may
occur and may cause some concern following repeated or long-term occupational
exposure. There has been some concern that this material can cause cancer or
mutations but there is not enough data to make an assessment.
Section 4 - FIRST AID MEASURES
SWALLOWED
- For advice, contact a Poisons Information Center or a doctor at once.
- Urgent hospital treatment is likely to be needed.
- If swallowed do NOT induce vomiting.
- If vomiting occurs, lean patient forward or place on left side (head-down
position, if possible) to maintain open airway and prevent aspiration.
- Observe the patient carefully.
- Never give liquid to a person showing signs of being sleepy or with reduced
awareness; i.e. becoming unconscious.
- Give water to rinse out mouth, then provide liquid slowly and as much as
casualty can comfortably drink.
- Transport to hospital or doctor without delay.
EYE
If this product comes in contact with the eyes:
- Immediately hold eyelids apart and flush the eye continuously with running
water.
- Ensure complete irrigation of the eye by keeping eyelids apart and away from
eye and moving the eyelids by occasionally lifting the upper and lower lids.
- Continue flushing until advised to stop by the Poisons Information Center or a
doctor, or for at least 15 minutes.
- Transport to hospital or doctor without delay.
- Removal of contact lenses after an eye injury should only be undertaken by
skilled personnel.
SKIN
If skin or hair contact occurs:
- Immediately flush body and clothes with large amounts of water, using safety
shower if available.
- Quickly remove all contaminated clothing, including footwear.
- Wash skin and hair with running water. Continue flushing with water until
advised to stop by the Poisons Information Center.
- Transport to hospital, or doctor.
continued...
LIQUID NITRATE TEST SOLUTION #1
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-15
Issue Date: 21-Oct-2005 CD 2005/3 Page 4 of 16
Section 4 - FIRST AID MEASURES
INHALED
- If fumes or combustion products are inhaled remove from contaminated area.
- Lay patient down. Keep warm and rested.
- Prostheses such as false teeth, which may block airway, should be removed,
where possible, prior to initiating first aid procedures.
- Apply artificial respiration if not breathing, preferably with a demand valve
resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if
necessary.
- Transport to hospital, or doctor, without delay.
NOTES TO PHYSICIAN
For acute or short term repeated exposures to strong acids:
- Airway problems may arise from laryngeal edema and inhalation exposure. Treat
with 100% oxygen initially.
- Respiratory distress may require cricothyroidotomy if endotracheal intubation
is contraindicated by excessive swelling
- Intravenous lines should be established immediately in all cases where there
is evidence of circulatory compromise.
- Strong acids produce a coagulation necrosis characterized by formation of a
coagulum (eschar) as a result of the dessicating action of the acid on proteins
in specific tissues.
INGESTION:
- Immediate dilution (milk or water) within 30 minutes post ingestion is
recommended.
- DO NOT attempt to neutralize the acid since exothermic reaction may extend the
corrosive injury.
- Be careful to avoid further vomit since re-exposure of the mucosa to the acid
is harmful. Limit fluids to one or two glasses in an adult.
- Charcoal has no place in acid management.
- Some authors suggest the use of lavage within 1 hour of ingestion.
SKIN:
- Skin lesions require copious saline irrigation. Treat chemical burns as
thermal burns with non-adherent gauze and wrapping.
- Deep second-degree burns may benefit from topical silver sulfadiazine.
EYE:
- Eye injuries require retraction of the eyelids to ensure thorough irrigation
of the conjuctival cul-de-sacs. Irrigation should last at least 20-30 minutes.
DO NOT use neutralizing agents or any other additives. Several liters of saline
are required.
- Cycloplegic drops, (1% cyclopentolate for short-term use or 5% homatropine for
longer term use) antibiotic drops, vasoconstrictive agents or artificial tears
may be indicated dependent on the severity of the injury.
- Steroid eye drops should only be administered with the approval of a
consulting ophthalmologist).
[Ellenhorn and Barceloux: Medical Toxicology].
Section 5 - FIRE FIGHTING MEASURES
Flash Point (掳F): Not Applicable
Lower Explosive Limit (%): Not Applicable
Upper Explosive Limit (%): Not Applicable
Autoignition Temp (掳F): Not Applicable
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LIQUID NITRATE TEST SOLUTION #1
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-15
Issue Date: 21-Oct-2005 CD 2005/3 Page 5 of 16
Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
- Water spray or fog.
- Foam.
- Dry chemical powder.
- BCF (where regulations permit).
- Carbon dioxide.
FIRE FIGHTING
- Alert Emergency Responders and tell them location and nature of hazard.
- Wear full body protective clothing with breathing apparatus.
- Prevent, by any means available, spillage from entering drains or water
course.
- Use fire fighting procedures suitable for surrounding area.
- DO NOT approach containers suspected to be hot.
- Cool fire exposed containers with water spray from a protected location.
- If safe to do so, remove containers from path of fire.
- Equipment should be thoroughly decontaminated after use.
When any large container (including road and rail tankers) is involved in a fire,
consider evacuation by 2625 feet in all directions.
GENERAL FIRE HAZARDS/HAZARDOUS COMBUSTIBLE PRODUCTS
- Non combustible.
- Not considered to be a significant fire risk.
- Acids may react with metals to produce hydrogen, a highly flammable and
explosive gas.
- Heating may cause expansion or decomposition leading to violent rupture of
rigid containers.
- May emit corrosive, poisonous fumes. May emit acrid smoke.
Decomposition may produce toxic fumes of, hydrogen chloride.
FIRE INCOMPATIBILITY
None known.
PERSONAL PROTECTION
Glasses:
Full face- shield.
Gloves:
PE/EVAL/PE Gloves.
Respirator:
Type B-P Filter of sufficient capacity
Section 6 - ACCIDENTAL RELEASE MEASURES
MINOR SPILLS
- Clean up all spills immediately.
- Avoid breathing vapors and contact with skin and eyes.
- Control personal contact by using protective equipment.
- Contain and absorb spill with sand, earth, inert material or vermiculite.
- Wipe up.
- Place in a suitable labeled container for waste disposal.
MAJOR SPILLS
- Clear area of personnel and move upwind.
- Alert Emergency Responders and tell them location and nature of hazard.
continued...
LIQUID NITRATE TEST SOLUTION #1
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-15
Issue Date: 21-Oct-2005 CD 2005/3 Page 6 of 16
Section 6 - ACCIDENTAL RELEASE MEASURES
- Wear full body protective clothing with breathing apparatus.
- Prevent, by any means available, spillage from entering drains or water
course.
- Consider evacuation.
- Stop leak if safe to do so.
- Contain spill with sand, earth or vermiculite.
- Collect recoverable product into labeled containers for recycling.
- Neutralize/decontaminate residue.
- Collect solid residues and seal in labeled drums for disposal.
- Wash area and prevent runoff into drains.
- After clean up operations, decontaminate and launder all protective clothing
and equipment before storing and re-using.
- If contamination of drains or waterways occurs, advise emergency services.
EMERGENCY EXPOSURE LIMITS
Material Revised IDLH Revised IDLH
Value (ppm) Value (mg/m3)
Hydrogen chloride 50
PROTECTIVE ACTIONS FOR SPILL
PROTECTIVE ACTION ZONE
half
evacuation
downwind
direction
distance
down wind distance
wind isolation
distance
direction
half
evacuation downwind
INITIAL direction distance
ISOLATION
ZONE
From IERG (Canada/Australia)
Isolation Distance 25 meters
Downwind Protection Distance 250 meters
FOOTNOTES
1 PROTECTIVE ACTION ZONE is defined as the area in which people are at risk
of harmful exposure. This zone assumes that random changes in wind direction
confines the vapour plume to an area within 30 degrees on either side of the
predominant wind direction, resulting in a crosswind protective action distance
equal to the downwind protective action distance.
2 PROTECTIVE ACTIONS should be initiated to the extent possible, beginning with
those closest to the spill and working away from the site in the downwind
direction. Within the protective action zone a level of vapour concentration
may exist resulting in nearly all unprotected persons becoming incapacitated
and unable to take protective action and/or incurring serious or irreversible
health effects.
3 INITIAL ISOLATION ZONE is determined as an area, including upwind of the
incident, within which a high probability of localised wind reversal may
expose nearly all persons without appropriate protection to life-threatening
concentrations of the material.
4 SMALL SPILLS involve a leaking package of 200 litres (55 US gallons) or less,
such as a drum (jerrican or box with inner containers). Larger packages leaking
continued...
LIQUID NITRATE TEST SOLUTION #1
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-15
Issue Date: 21-Oct-2005 CD 2005/3 Page 7 of 16
Section 6 - ACCIDENTAL RELEASE MEASURES
less than 200 litres and compressed gas leaking from a small cylinder are also
considered "small spills".
LARGE SPILLS involve many small leaking packages or a leaking package of
greater than 200 litres, such as a cargo tank, portable tank or a "one-tonne"
compressed gas cylinder.
5 Guide 154 is taken from the US DOT emergency response guide book.
6 IERG information is derived from CANUTEC - Transport Canada.
ACUTE EXPOSURE GUIDELINE LEVELS (AEGL) (in ppm)
AEGL Type 5 min 10 min 30 min 60 min 4 hr 8 hr
AEGL 1 1.8 1.8 1.8 1.8 1.8
AEGL 2 100 43 22 11 11
AEGL 3 620 210 100 26 26
AEGL 1: The airborne concentration of a substance above which it is predicted
that the general population, including susceptible individuals, could
experience notable discomfort, irritation, or certain asymptomatic nonsensory
effects. However, the effects are not disabling and are transient and
reversible upon cessation of exposure.
AEGL 2: The airborne concentration of a substance above which it is predicted
that the general population, including susceptible individuals, could
experience irreversible or other serious, long-lasting adverse health effects
or an impaired ability to escape.
AEGL 3: The airborne concentration of a substance above which it is predicted
that the general population, including susceptible individuals, could
experience life-threatening health effects or death.
EMERGENCY RESPONSE PLANNING GUIDELINES (ERPG)
The maximum airborne concentration below which it is believed that nearly all
individuals could be exposed for up to one hour WITHOUT experiencing or developing
life-threatening health effects is:
hydrochloric acid 150 ppm
irreversible or other serious effects or symptoms which could
impair an individual's ability to take protective action is:
hydrochloric acid 20 ppm
other than mild, transient adverse effects
without perceiving a clearly defined odour is:
hydrochloric acid 3 ppm
The threshold concentration below which most people.
will experience no appreciable risk of health effects:
hydrochloric acid 0.5 ppm
American Industrial Hygiene Association (AIHA)
Ingredients considered according exceed the following cutoffs
Very Toxic (T+) >= 0.1% Toxic (T) >= 3.0%
R50 >= 0.25% Corrosive (C) >= 5.0%
R51 >= 2.5%
else >= 10%
where percentage is percentage of ingredient found in the mixture
continued...
LIQUID NITRATE TEST SOLUTION #1
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-15
Issue Date: 21-Oct-2005 CD 2005/3 Page 8 of 16
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
- Avoid all personal contact, including inhalation.
- Wear protective clothing when risk of exposure occurs.
- Use in a well-ventilated area.
- WARNING: To avoid violent reaction, ALWAYS add material to water and NEVER
water to material.
- Avoid smoking, naked lights or ignition sources.
- Avoid contact with incompatible materials.
- When handling, DO NOT eat, drink or smoke.
- Keep containers securely sealed when not in use.
- Avoid physical damage to containers.
- Always wash hands with soap and water after handling.
- Work clothes should be laundered separately.
- Launder contaminated clothing before re-use.
- Use good occupational work practice.
- Observe manufacturer's storing and handling recommendations.
- Atmosphere should be regularly checked against established exposure standards
to ensure safe working conditions are maintained.
DO NOT allow clothing wet with material to stay in contact with skin.
RECOMMENDED STORAGE METHODS
DO NOT use aluminum or galvanized containers.
Check regularly for spills and leaks.
STORAGE REQUIREMENTS
- Store in original containers.
- Keep containers securely sealed.
- Store in a cool, dry, well-ventilated area.
- Store away from incompatible materials and foodstuff containers.
- Protect containers against physical damage and check regularly for leaks.
- Observe manufacturer's storing and handling recommendations.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
US OSHA Permissible Exposure Levels ( PELs)
Z Material TWA TWA STEL STEL Peak Peak Max Max Max
ppm mg/m鲁 ppm mg/m鲁 ppm mg/m鲁 excursion excursion excursion
ppm mg/m鲁 duration
(mins)
__ ______________ ____ ____ ____ ____ ____ ____ ________ ________ ________
Z1 Hydrogen 5 7
chloride
Source Material TWA TWA STEL STEL Peak Peak
ppm mg/m鲁 ppm mg/m鲁 ppm mg/m鲁
_________________________ ________________ _____ _____ _____ _____ _____ _____
continued...
LIQUID NITRATE TEST SOLUTION #1
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-15
Issue Date: 21-Oct-2005 CD 2005/3 Page 9 of 16
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
US California Permissible Hydrogen 5 7
Exposure Limits for chloride;
Chemical Contaminants muriatic acid
US Minnesota Permissible Hydrogen 5 7
Exposure Limits (PELs) chloride
US Vermont Permissible Hydrogen (C)5 (C)7
Exposure Limits Table chloride
Z-1-A Transitional Limits
for Air Contaminants
US Vermont Permissible Hydrogen 5 7
Exposure Limits Table chloride
Z-1-A Final Rule Limits
for Air Contaminants
US Tennessee Occupational Hydrogen 5 7
Exposure Limits - Limits chloride
For Air Contaminants
US Idaho - Limits for Air Hydrogen 5 7
Contaminants chloride
Canada Saskatchewan Hydrogen 7.50000
Occupational Health and chloride
Safety Regulations -
Contamination Limits
Canada Yukon Permissible Hydrogen 5 7 - -
Concentrations for chloride
Airborne Contaminant
Substances
US Washington Permissible Hydrogen 5.0
exposure limits of air chloride
contaminants
Canadian British Columbia Hydrogen 2
Occupational Exposure chloride
Limits (Revised 2003)
NIOSH Recommended Hydrogen 5
Exposure Limits for chloride
Hazardous Agents in the
Workplace
US California Permissible Hydrogen 5 7
Exposure Limits for chloride;
Chemical Contaminants muriatic acid
US Minnesota Permissible Hydrogen 5 7
Exposure Limits (PELs) chloride
US Vermont Permissible Hydrogen (C)5 (C)7
Exposure Limits Table chloride
Z-1-A Transitional Limits
for Air Contaminants
US Vermont Permissible Hydrogen 5 7
Exposure Limits Table chloride
Z-1-A Final Rule Limits
for Air Contaminants
US Tennessee Occupational Hydrogen 5 7
Exposure Limits - Limits chloride
For Air Contaminants
US Idaho - Limits for Air Hydrogen 5 7
Contaminants chloride
Canada Saskatchewan Hydrogen 7.50000
Occupational Health and chloride
continued...
LIQUID NITRATE TEST SOLUTION #1
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-15
Issue Date: 21-Oct-2005 CD 2005/3 Page 10 of 16
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Safety Regulations -
Contamination Limits
Canada Yukon Permissible Hydrogen 5 7 - -
Concentrations for chloride
Airborne Contaminant
Substances
US Washington Permissible Hydrogen 5.0
exposure limits of air chloride
contaminants
Canadian British Columbia Hydrogen 2
Occupational Exposure chloride
Limits (Revised 2003)
NIOSH Recommended Hydrogen 5
Exposure Limits for chloride
Hazardous Agents in the
Workplace
ODOUR SAFETY FACTOR (OSF)
OSF=1.3 (hydrochloric acid)
Exposed individuals are NOT reasonably expected to be warned, by smell, that the
Exposure Standard is being exceeded.
Odor Safety Factor (OSF) is determined to fall into either Class C, D or E.
The Odor Safety Factor (OSF) is defined as:
OSF= Exposure Standard (TWA) ppm/ Odor Threshold Value (OTV) ppm
Classification into classes follows:
Class OSF Description
A 550 Over 90% of exposed
individuals are aware by
smell that the Exposure
Standard (TLV-TWA for
example) is being
reached, even when
distracted by working
activities
B 26-550 Idem for 50-90% of
persons being distracted
C 1-26 Idem for less than 50% of
persons being distracted
D 0.18-1 0-50% of persons aware of
being tested perceive by
smell that the Exposure
Standard is being reached
E <0.18 Idem for less than 10% of
persons aware of being
tested
Amoore and Hautala * have determined that it is only at an OSF value of 26 that
50% of distracted persons can detect the substance at the Exposure Standard
value. In the case of alerted persons, an OSF of 26 means that 99% of them can
detect the odor at the Exposure Standard value. It is ONLY for substances
belonging to Class A and B that there is a reasonable chance of being warned in
time, that the Exposure Standard is being exceeded. * Journal Applied
Toxicology: Vol 3, 1983, p272
NOTE: The use of the OSF may be inappropriate for mixtures where substances mask
the odor of others.
continued...
LIQUID NITRATE TEST SOLUTION #1
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-15
Issue Date: 21-Oct-2005 CD 2005/3 Page 11 of 16
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
INGREDIENT DATA
HYDROCHLORIC ACID:
Odour Threshold Value: 0.262 ppm (detection), 10.06 ppm (recognition)
NOTE: Detector tubes for hydrochloric acid, measuring in excess of 1 ppm,
are available commercially.
Hydrogen chloride is a strong irritant to the eyes, mucous membranes and
skin. Chronic exposure produces a corrosive action on the teeth. Reports
of respiratory irritation following short-term exposure at 5 ppm have lead
to the recommended TLV-C. There is no indication that skin contact with
hydrogen chloride elicits systemic poisoning and a skin designation has
not been applied.
Exposure of humans to hydrogen chloride at 50 to 100 ppm for 1 hour is
reported to be barely tolerable; 35 ppm caused irritation of the throat on
short exposure and 10 ppm was the maximal concentration for prolonged
exposure. It has been stated that hydrogen chloride at concentrations of
5 ppm is immediately irritating.
-
Toxic effects of hydrochloric acid
-------------------------------------------------------------------------
Concentration Clinical effects
-------------------------------------------------------------------------
0.067 - 0.267 ppm Reported range of odour thresholds and
changes in respiratory pattern
5 ppm No organic damage
10 ppm Irritation; work undisturbed
10-50 ppm Work difficult but possible
35 ppm Short exposure irritation of the throat
50-100 ppm Exposure for 1 h barely tolerable
1000-2000 ppm Brief exposure dangerous; laryngospasm
1300-2000 ppm Lethal after a few minutes
-------------------------------------------------------------------------
PERSONAL PROTECTION
EYE
- Chemical goggles.
- Full face shield.
- Contact lenses pose a special hazard; soft contact lenses may absorb irritants
and all lenses concentrate them.
HANDS/FEET
Elbow length PVC gloves.
When handling corrosive liquids, wear trousers or overalls outside of boots, to
avoid spills entering boots.
OTHER
- Overalls.
- PVC Apron.
- PVC protective suit may be required if exposure severe.
- Eyewash unit.
- Ensure there is ready access to a safety shower.
RESPIRATOR
Selection of the Class and Type of respirator will depend upon the level of
breathing zone contaminant and the chemical nature of the contaminant.
Protection Factors (defined as the ratio of contaminant outside and inside the
continued...
LIQUID NITRATE TEST SOLUTION #1
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-15
Issue Date: 21-Oct-2005 CD 2005/3 Page 12 of 16
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
mask) may also be important.
Breathing Zone Maximum Protection Half-face Full-Face
Level ppm (volume) Factor Respirator Respirator
1000 10 B-1 P -
1000 50 - B-1 P
5000 50 Airline* -
5000 100 - B-2 P
10000 100 - B-3 P
100+ Airline* *
* - Continuous Flow ** - Continuous-flow or positive pressure demand.
The local concentration of material, quantity and
conditions of use determine the type of personal
protective equipment required.
Use appropriate NIOSH-certified respirator based on informed professional
judgement. In conditions where no reasonable estimate of exposure can be
made, assume the exposure is in a concentration IDLH and use NIOSH-certified
full face pressure demand SCBA with a minimum service life of 30 minutes, or
a combination full facepiece pressure demand SAR with auxiliary self-contained
air supply. Respirators provided only for escape from IDLH atmospheres shall be
NIOSH-certified for escape from the atmosphere in which they will be used.
ENGINEERING CONTROLS
Local exhaust ventilation usually required. If risk of overexposure exists, wear
an approved respirator. Correct fit is essential to obtain adequate protection
an approved self contained breathing apparatus (SCBA) may be required in some
situations. Provide adequate ventilation in warehouse or closed storage area.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL PROPERTIES
Liquid.
Mixes with water.
Corrosive.
Acid.
Molecular Weight: Not Applicable Boiling Range (掳C): Not Available
Melting Range (掳C): Not Available Specific Gravity (water=1): 1.155
Solubility in water (g/L): Miscible pH (as supplied): <1
pH (1% solution): Not Available Vapor Pressure (kPa): Not Available
Volatile Component (%vol): Not Available Evaporation Rate: Not Available
Relative Vapor Density (air=1): Not Available Flash Point (掳C): Not Applicable
Lower Explosive Limit (%): Not Applicable Upper Explosive Limit (%): Not Applicable
Autoignition Temp (掳C): Not Applicable Decomposition Temp (掳C): Not Available
State: Liquid
APPEARANCE
Yellow-orange highly acidic liquid with no odour; mixes with water.
continued...
LIQUID NITRATE TEST SOLUTION #1
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-15
Issue Date: 21-Oct-2005 CD 2005/3 Page 13 of 16
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
Contact with alkaline material liberates heat.
- Presence of incompatible materials.
- Product is considered stable.
- Hazardous polymerization will not occur.
STORAGE INCOMPATIBILITY
Segregate from alkalis, oxidizing agents and chemicals readily decomposed by
acids, i.e. cyanides, sulfides, carbonates.
Reacts with mild steel, galvanised steel / zinc producing hydrogen gas which may
form an explosive mixture with air.
Avoid strong bases.
Section 11 - TOXICOLOGICAL INFORMATION
Liquid Nitrate Test Solution #1
Not available. Refer to individual constituents.
unless otherwise specified data extracted from RTECS - Register of Toxic Effects
of Chemical Substances
HYDROCHLORIC ACID:
TOXICITY IRRITATION
Unreported (man) LDLo: 81 mg/kg Eye (rabbit): 5mg/30s - mild
Inhalation (human) LCLo: 1300 ppm/30 min
Inhalation (human) LCLo: 3000 ppm/5 min
Inhalation (rat) LC50: 3124 ppm/1h
Oral (rat) LD50: 900 mg/kg
The substance is classified by IARC as Group 3:
NOT classifiable as to its carcinogenicity to humans.
Evidence of carcinogenicity may be inadequate or limited in animal testing.
MATERIAL CARCINOGEN SENSITIZER SKIN MUTAGEN REPROTOXIN
______________________________ ____________ __________ __________ __________ __________
Liquid Nitrate Test Solution
#1
hydrochloric acid Listed
CARCINOGEN
ACGIH: hydrochloric acid: A4
Section 12 - ECOLOGICAL INFORMATION
Prevent, by any means available, spillage from entering drains or water
courses.
DO NOT discharge into sewer or waterways.
Refer to data for ingredients, which follows:
HYDROCHLORIC ACID:
Hazardous Air Pollutant: Yes
Fish LC50 (96hr.) (mg/l): 0.282
continued...
LIQUID NITRATE TEST SOLUTION #1
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-15
Issue Date: 21-Oct-2005 CD 2005/3 Page 14 of 16
Section 12 - ECOLOGICAL INFORMATION
Ecotoxicity
Fish LC100 (24 h): trout 10 mg/l
TLm (96 h): mosquito fish 282 ppm (fresh water)
LC50 : goldfish 178 mg/l
Shrimp LC50 (48 h): 100 - 330 ppm (salt water)
Starfish LC50 (48 h): 100 - 330 mg/l
Cockle LC50 (48 h): 330 - 1000 mg/l
[Hach]
Hydrogen chloride in water dissociates almost completely, releasing
hydrogen and chloride ions; the hydrogen ions are captured by water to
produce hydronium ions.
Hydrochloric acid infiltrates soil, the rate dependent on moisture
content. During soil transport, hydrochloric acid dissolves soil
components.
Drinking water standard:
chloride: 400 mg/l (UK max.)
250 mg/l (WHO guideline)
DO NOT discharge into sewer or waterways.
Section 13 - DISPOSAL CONSIDERATIONS
US EPA Waste Number & Descriptions
A. General Product Information
Corrosivity characteristic: use EPA hazardous waste number D002 (waste code C)
Disposal Instructions
All waste must be handled in accordance with local, state and federal
regulations.
- Recycle wherever possible.
- Consult manufacturer for recycling options or consult Waste Management
Authority for disposal if no suitable treatment or disposal facility can be
identified.
- Treat and neutralize at an approved treatment plant. Treatment should involve:
Neutralization with soda-ash or soda-lime followed by:
- Burial in a licensed land-fill or Incineration in a licensed apparatus (after
admixture with suitable combustible material).
- Decontaminate empty containers with 5% aqueous sodium hydroxide or soda ash,
followed by water. Observe all label safeguards until containers are cleaned and
destroyed.
Puncture containers to prevent re-use and bury at an authorized landfill.
Section 14 - TRANSPORTATION INFORMATION
Shipping Name: CORROSIVE LIQUID, ACIDIC,
INORGANIC, N.O.S.
Hazard Class: 8
SubRisk: None
UN/NA Number: 3264
Packing Group: II
Labels Required: corrosive
Additional Shipping Information:
continued...
LIQUID NITRATE TEST SOLUTION #1
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-15
Issue Date: 21-Oct-2005 CD 2005/3 Page 15 of 16
Section 14 - TRANSPORTATION INFORMATION
International Transport Regulations:
IMO: 8
Section 15 - REGULATORY INFORMATION
RISK
Harmful by inhalation.
Irritating to eyes, respiratory system and skin.
US Federal Regulations
A. General Product Information
In addition to Federal and State regulation, local regulations may
apply. Check with your local regulatory authorities.
B. Component Information
This material contains one or more of the following chemicals required
to be identified under SARA Section 302 (40 CFR 455 Appendix A)
SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4):
-------------------------------------------------------------------
hydrochloric acid (7647-01-0,14ap.% )
SARA 313: form R reporting required for 1.0% de minimus concentration
CERCLA: final RQ = 5000 pounds (2270 kg)
-------------------------------------------------------------------
Component TSCA
hydrochloric acid Y
State Regulations
A. General Product Information
B. Component Information
The following components appear on one or more of the following state
hazardous substance lists.
Component CAS No CA FL MA MN NJ PA
hydrochloric acid 7647-01-0 Y Y Y Y Y Y
Y=Yes this material appears on that state's hazardous substances list.
N=No this material does not appear on that state's hazardous substances list.
Other Regulations
A. Component Information
CANADA
The following component(s) are identified under the Canadian
Hazardous Products Act Ingredient Disclosure List:
continued...
LIQUID NITRATE TEST SOLUTION #1
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-15
Issue Date: 21-Oct-2005 CD 2005/3 Page 16 of 16
Section 15 - REGULATORY INFORMATION
Component CAS No % Min Conc.
hydrochloric acid 7647-01-0 14 ap. 1% item 845 (502)
All of this product's components are on the Canadian Domestic
.
REGULATIONS
hydrochloric acid (CAS: 7647-01-0) is found on the following regulatory lists
Canadian Domestic Substances List (DSL)
US Toxic Substances Control Act (TSCA)
US ACGIH Carcinogens Listing
US SARA Section 302 Extremely Hazardous Substances
Canada Prohibited Toxic Substances, Schedule 2, Concentration Limits (English)
Canada Prohibited Toxic Substances - Schedule 2: Concentration Limits (French)
US OSHA List of Highly Hazardous Chemicals, Toxics and Reactives
US EPA Hazardous Substances
US California Occupational Safety and Health Regulations (CAL/OSHA) - Hazardous
Substances List
US CERCLA List of Hazardous Substances and Reportable Quantities
US CWA (Clean Water Act) - List of Hazardous Substances
US CWA (Clean Water Act) - Reportable Quantities of Designated Hazardous
Substances
US Minnesota Hazardous Substance List
US Oregon Hazardous Materials
US EPA High Production Volume Chemicals Additional List
US EPCRA Section 313 Chemical List For Reporting Year 2004
US Food Additive Database
US EPA List of Regulated Toxic Substances and Threshold Quantities for
Accidental Release Prevention
Canada Yukon Permissible Concentrations for Airborne Contaminant Substances
US Connecticut Hazardous Air Pollutants
Canadian Ingredient Disclosure List (SOR/88-64)
US EPA High Production Volume Program Chemical List
Section 16 - OTHER INFORMATION
Reasonable care has been taken in the preparation of this information, but the
author makes no warranty of merchantability or any other warranty, expressed or
implied, with respect to this information. The author makes no representations
and assumes no liability for any direct, incidental or consequential damages
resulting from its use. For additional technical information please call our
toxicology department on +800 CHEMCALL.
Issue Date: 21-Oct-2005
Print Date: 21-Oct-2005
This document is copyright. Apart from any fair dealing for the purposes of
private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from
CHEMWATCH. TEL (+61 3) 9572 4700.
LIQUID NITRATE TEST SOLUTION #2
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-20
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 1 of 12
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
LIQUID NITRATE TEST SOLUTION #2
STATEMENT OF HAZARDOUS NATURE
CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR
1910.1200.
SUPPLIER
Company: Aquarium Pharmaceuticals Incorporated Company: Aquarium Pharmaceuticals Incorporated
Address: Address:
50 East Hamilton Street PO Box 218
Chalfont Chalfont
PA, 18914 PA, 18914-0218
USA USA
Telephone: +1 215 822 8181 Telephone: +1 215 822 8181
Emergency Tel: +1800 222 1222 (US Only)
PRODUCT USE
Nitrate test solution for product LR1800, 34 and 401M.
SYNONYMS
"Solution ID# 3307"
Section 2 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
polyethylene glycol 25322-68-3 98
sulfanilamide 63-74-1 <5
Section 3 - HAZARDS IDENTIFICATION
CANADIAN WHMIS SYMBOLS
EMERGENCY OVERVIEW
RISK
Exposure may produce irreversible effects*.
May affect fertility*.
May possibly be harmful to the fetus/ embryo*.
May produce discomfort of the eyes, respiratory tract and skin*. *(limited evidece)
continued...
LIQUID NITRATE TEST SOLUTION #2
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-20
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 2 of 12
Section 3 - HAZARDS IDENTIFICATION
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
The material has NOT been classified as "harmful by ingestion". This is because
of the lack of corroborating animal or human evidence. The material may still be
damaging to the health of the individual, following ingestion, especially where
pre-existing organ (e.g. liver, kidney) damage is evident. Present definitions
of harmful or toxic substances are generally based on doses producing mortality
(death) rather than those producing morbidity (disease, ill-health).
Gastrointestinal tract discomfort may produce nausea and vomiting. In an
occupational setting however, unintentional ingestion is not thought to be cause
for concern.
EYE
There is some evidence to suggest that this material can cause
eye irritation and damage in some persons.
Limited evidence or practical experience suggests, that the material may cause
eye irritation in a substantial number of individuals. Prolonged eye contact may
cause inflammation characterized by a temporary redness of the conjunctiva
(similar to windburn).
Eye drops with sulfonamides can cause local irritation, sensations of burning
and stinging, blurred vision and loss of depth perception. The conjunctiva and
cornea may become inflamed, and the cornea and lens may become clouded.
SKIN
There is some evidence to suggest that this material can cause inflammation of
the skin on contact in some persons.
Skin contact is not thought to have harmful health effects, however the material
may still produce health damage following entry
through wounds, lesions or abrasions.
There is some evidence to suggest that the material may cause mild but
significant inflammation of the skin either following direct contact or after a
delay of some time. Repeated exposure can cause contact dermatitis which is
characterized by redness, swelling and blistering.
Entry into the blood-stream, through, for example, cuts, abrasions or lesions,
may produce systemic injury with harmful effects. Examine the skin prior to the
use of the material and ensure that any external damage is suitably protected.
INHALED
There is some evidence to suggest that this material, if inhaled, can irritate
the throat and lungs of some persons.
Although inhalation is not thought to produce harmful effects, the material may
still produce health damage, especially where pre-existing organ (e.g. liver,
kidney) damage is evident. Present definitions of harmful or toxic substances
are generally confined to doses producing mortality (death) rather than those
producing morbidity (disease, ill-health).
There is some evidence to suggest that the material can cause respiratory
irritation in some persons. The body's response to such irritation can cause
further lung damage.
Not normally a hazard due to non-volatile nature of product.
CHRONIC HEALTH EFFECTS
There has been some concern that this material can cause cancer or mutations but
continued...
LIQUID NITRATE TEST SOLUTION #2
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-20
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 3 of 12
Section 3 - HAZARDS IDENTIFICATION
there is not enough data to make an assessment. There is some evidence to
provide a presumption that human exposure to the material may result in impaired
fertility on the basis of: some evidence in animal studies of impaired fertility
in the absence of toxic effects, or evidence of impaired fertility occurring at
around the same dose levels as other toxic effects but which is not a secondary
non-specific consequence of other toxic effects. Prolonged oral treatment with
sulfonamides has caused nausea, vomiting, diarrhea, abdominal pain, loss of
appetite, inflammation of the mouth cavity, impaired folic acid absorption,
exacerbation of porphyria, acidosis, liver damage with impaired blood clotting,
jaundice and inflammation of the pancreas. Effects on the kidney include blood
and crystals in the urine, painful and frequent urination or lack of urine with
nitrogen retention. Nervous system symptoms include headache, drowsiness,
trouble sleeping, dizziness, ringing in the ears, hearing loss, depression,
hallucinations, inco-ordination, paralysis of muscles, numbness in the
extremities, spinal cord damage and inflammation, convulsions and
unconsciousness. Effects on the blood includes a change in blood cell
distribution with loss of white blood cells and platelets, and anemia, which
Africans seem to be more prone to developing than Europeans. Cyanosis can occur
owing to complexes being formed by hemoglobin. Eye effects include inflamed
cornea and conjunctiva with eyelid swelling and in severe cases, fear of the
light. Allergies and cross-sensitivity is common, and can cause itches, wheals
and sometimes a severe red rash with blisters that is often fatal. This class of
drugs can scar the cornea and conjunctiva, swelling around the eyes, painful and
inflamed joints, reduced sperm counts, pneumonia, fever, chills, hair loss,
inflammation of vessels, lupus, reduced lung function, infertility,
hypothyroidism and goiter, and increased urinary output. More seriously, the
lungs may become permanently scarred and there may be irreversible damage to the
nervous system and muscles. Inflammation of the skin has occurred after the drug
is ingested and has traveled through the bloodstream. Skin effects often occur
when there has been exposure in conjunction with UV light. Clothed areas are
initially less likely to be affected but may be in later stages. Rarely there
may be persistence of inflammation on light contact even after the drug has been
removed.
Section 4 - FIRST AID MEASURES
SWALLOWED
- Immediately give a glass of water.
- First aid is not generally required. If in doubt, contact a Poisons
Information Center or a doctor.
EYE
If this product comes in contact with the eyes:
- Wash out immediately with fresh running water.
- Ensure complete irrigation of the eye by keeping eyelids apart and away from
eye and moving the eyelids by occasionally lifting the upper and lower lids.
- If pain persists or recurs seek medical attention.
- Removal of contact lenses after an eye injury should only be undertaken by
skilled personnel.
SKIN
If skin contact occurs:
- Immediately remove all contaminated clothing, including footwear
- Flush skin and hair with running water (and soap if available).
continued...
LIQUID NITRATE TEST SOLUTION #2
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-20
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 4 of 12
Section 4 - FIRST AID MEASURES
- Seek medical attention in event of irritation.
INHALED
- If fumes or combustion products are inhaled remove from contaminated area.
- Other measures are usually unnecessary.
NOTES TO PHYSICIAN
Treat symptomatically.
In cases of recent sulfonamide overdose the stomach should be emptied by
aspiration and lavage. If kidney function is adequate, a saline purgative, such
as sodium sulfate, 30 g in 250 ml water, may be given to promote peristalsis and
elimination of sulfonamide in the urine may be assisted by giving alkalis, such
as sodium bicarbonate and increasing fluid intake. Severe crystalluria may
require ureteric catheterization and irrigation with warm 2.5% sodium
bicarbonate solution. Treatment should be continued until it can be assumed that
the sulfonamide has been eliminated. The majority of sulfonamides are
metabolized to acetylated derivatives which retain the toxicity of the parent
compound and thus may indicate more active removal when adverse effects are very
severe. Active measures may include forced diuresis, peritoneal dialysis and
charcoal hemoperfusion.
[Martindale: The Extra Pharmacopoeia, 28th Ed.].
Section 5 - FIRE FIGHTING MEASURES
Flash Point (掳F): Not Applicable
Lower Explosive Limit (%): Not Applicable
Upper Explosive Limit (%): Not Applicable
Autoignition Temp (掳F): Not Applicable
EXTINGUISHING MEDIA
- Water spray or fog.
- Foam.
- Dry chemical powder.
- BCF (where regulations permit).
- Carbon dioxide.
FIRE FIGHTING
- Alert Emergency Responders and tell them location and nature of hazard.
- Wear full body protective clothing with breathing apparatus.
- Prevent, by any means available, spillage from entering drains or water
course.
- Use water delivered as a fine spray to control fire and cool adjacent area.
- Avoid spraying water onto liquid pools.
- Do not approach containers suspected to be hot.
- Cool fire exposed containers with water spray from a protected location.
- If safe to do so, remove containers from path of fire.
GENERAL FIRE HAZARDS/HAZARDOUS COMBUSTIBLE PRODUCTS
- Combustible.
- Slight fire hazard when exposed to heat or flame.
- Heating may cause expansion or decomposition leading to violent rupture of
containers.
- On combustion, may emit toxic fumes of carbon monoxide (CO).
- May emit acrid smoke.
- Mists containing combustible materials may be explosive.
continued...
LIQUID NITRATE TEST SOLUTION #2
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-20
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 5 of 12
Section 5 - FIRE FIGHTING MEASURES
Combustion products include, carbon dioxide (CO2), nitrogen oxides (NOx), sulfur
oxides (SOx), other pyrolysis products typical of burning organic material.
May emit poisonous fumes.
May emit corrosive fumes.
FIRE INCOMPATIBILITY
Avoid contamination with oxidizing agents i.e. nitrates, oxidizing acids,
chlorine bleaches, pool chlorine etc. as ignition may result.
Section 6 - ACCIDENTAL RELEASE MEASURES
MINOR SPILLS
- Remove all ignition sources.
- Clean up all spills immediately.
- Avoid breathing vapors and contact with skin and eyes.
- Control personal contact by using protective equipment.
- Contain and absorb spill with sand, earth, inert material or vermiculite.
- Wipe up.
- Place in a suitable labeled container for waste disposal.
MAJOR SPILLS
Moderate hazard.
- Clear area of personnel and move upwind.
- Alert Emergency Responders and tell them location and nature of hazard.
- Wear breathing apparatus plus protective gloves.
- Prevent, by any means available, spillage from entering drains or water
course.
- No smoking, naked lights or ignition sources. Increase ventilation.
- Stop leak if safe to do so.
- Contain spill with sand, earth or vermiculite.
- Collect recoverable product into labeled containers for recycling.
- Absorb remaining product with sand, earth or vermiculite.
- Collect solid residues and seal in labeled drums for disposal.
- Wash area and prevent runoff into drains.
- If contamination of drains or waterways occurs, advise emergency services.
ACUTE EXPOSURE GUIDELINE LEVELS (AEGL) (in ppm)
AEGL 1: The airborne concentration of a substance above which it is predicted
that the general population, including susceptible individuals, could
experience notable discomfort, irritation, or certain asymptomatic nonsensory
effects. However, the effects are not disabling and are transient and
reversible upon cessation of exposure.
AEGL 2: The airborne concentration of a substance above which it is predicted
that the general population, including susceptible individuals, could
experience irreversible or other serious, long-lasting adverse health effects
or an impaired ability to escape.
AEGL 3: The airborne concentration of a substance above which it is predicted
that the general population, including susceptible individuals, could
experience life-threatening health effects or death.
continued...
LIQUID NITRATE TEST SOLUTION #2
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-20
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 6 of 12
Section 6 - ACCIDENTAL RELEASE MEASURES
EMERGENCY RESPONSE PLANNING GUIDELINES (ERPG)
The maximum airborne concentration below which it is believed that nearly all
individuals could be exposed for up to one hour WITHOUT experiencing or developing
life-threatening health effects is:
polyethylene glycol 500 mg/m鲁
irreversible or other serious effects or symptoms which could
impair an individual's ability to take protective action is:
polyethylene glycol 50 mg/m鲁
other than mild, transient adverse effects
without perceiving a clearly defined odour is:
polyethylene glycol 30 mg/m鲁
The threshold concentration below which most people.
will experience no appreciable risk of health effects:
polyethylene glycol 10 mg/m鲁
American Industrial Hygiene Association (AIHA)
Ingredients considered according exceed the following cutoffs
Very Toxic (T+) >= 0.1% Toxic (T) >= 3.0%
R50 >= 0.25% Corrosive (C) >= 5.0%
R51 >= 2.5%
else >= 10%
where percentage is percentage of ingredient found in the mixture
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
DO NOT USE brass or copper containers / stirrers.
- Avoid all personal contact, including inhalation.
- Wear protective clothing when risk of exposure occurs.
- Use in a well-ventilated area.
- Prevent concentration in hollows and sumps.
- DO NOT enter confined spaces until atmosphere has been checked.
- Avoid smoking, naked lights or ignition sources.
- Avoid contact with incompatible materials.
- When handling, DO NOT eat, drink or smoke.
- Keep containers securely sealed when not in use.
- Avoid physical damage to containers.
- Always wash hands with soap and water after handling.
- Work clothes should be laundered separately.
- Use good occupational work practice.
- Observe manufacturer's storing and handling recommendations.
- Atmosphere should be regularly checked against established exposure standards
to ensure safe working conditions.
DO NOT allow clothing wet with material to stay in contact with skin.
RECOMMENDED STORAGE METHODS
- Metal can or drum
- Packing as recommended by manufacturer.
- Check all containers are clearly labeled and free from leaks.
continued...
LIQUID NITRATE TEST SOLUTION #2
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-20
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 7 of 12
Section 7 - HANDLING AND STORAGE
STORAGE REQUIREMENTS
- Store in original containers.
- Keep containers securely sealed.
- No smoking, naked lights or ignition sources.
- Store in a cool, dry, well-ventilated area.
- Store away from incompatible materials and foodstuff containers.
- Protect containers against physical damage and check regularly for leaks.
- Observe manufacturer's storing and handling recommendations.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
Source Material TWA TWA STEL STEL Peak Peak
ppm mg/m鲁 ppm mg/m鲁 ppm mg/m鲁
_________________________ ________________ _____ _____ _____ _____ _____ _____
US AIHA Workplace Polyethylene 10
Environmental Exposure Glycols
Levels (WEELs)
No data available: sulfanilamide as (CAS: 63-74-1)
Not available. Refer to individual constituents.
INGREDIENT DATA
POLYETHYLENE GLYCOL:
No exposure limits set by NOHSC or ACGIH.
For powdered forms:
Dusts not otherwise classified, as inspirable dust;
ES TWA: 10 mg/m鲁.
The polyethylene glycols are extremely low in oral toxicity, are not
significantly irritating to the eyes or skin, and are not absorbed
through the skin in toxic amounts. vapour pressures are extremely low and
inhalation exposure is limited to mists. Based on experimental data and
human experience, these substances do not present significant hazards to
health in the workplace.
SULFANILAMIDE:
Dusts not otherwise classified, as inspirable dust;
ES TWA: 10 mg/m鲁.
Particulate (insoluble or poorly soluble *) Not Otherwise Specified (P.N.O.C)
TLV TWA: 10 mg/m鲁 Inhalable particulate
TLV TWA: 3 mg/m鲁 Respirable particulate
OEL-Sweden, United Kingdom: 10 mg/m鲁 total dust, 5 mg/m鲁 respirable dust
These "dusts" have little adverse effect on the lungs and do not produce toxic
effects or organic disease. Although there is no dust which does not evoke some
cellular response at sufficiently high concentrations, the cellular response
caused by P.N.O.C.s has the following characteristics:
- the architecture of the air spaces remain intact,
- scar tissue (collagen) is not synthesised to any degree,
- tissue reaction is potentially reversible.
Extensive concentrations of P.N.O.C.s may:
continued...
LIQUID NITRATE TEST SOLUTION #2
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-20
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 8 of 12
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
- seriously reduce visibility,
- cause unpleasant deposits in the eyes, ears and nasal passages,
- contribute to skin or mucous membrane injury by chemical or mechanical action,
per se, or by the rigorous skin cleansing procedures necessary for their
removal. [ACGIH]
This limit does not apply:
- to brief exposures to higher concentrations
- nor does it apply to those substances that may cause physiological impairment
at lower concentrations but for which a TLV has as yet to be determined.
This exposure standard applies to particles which
- are insoluble or poorly soluble* in water or, preferably, in aqueous lung
fluid (if data is available) and
- have a low toxicity (i.e.. are not cytotoxic, genotoxic, or otherwise
chemically reactive with lung tissue, and do not emit ionizing radiation, cause
immune sensitization, or cause toxic effects other than by inflammation or by a
mechanism of lung overload)
* Notice of intended change.
PERSONAL PROTECTION
Glasses:
Chemical goggles.
Gloves:
PVC chemical resistant type.
Respirator:
EYE
- Safety glasses with side shields.
- Chemical goggles.
- Contact lenses pose a special hazard; soft lenses may absorb irritants and all
lenses concentrate them. DO NOT wear contact lenses.
HANDS/FEET
Wear chemical protective gloves, eg. PVC.
Wear safety footwear or safety gumboots, eg. Rubber.
OTHER
- Overalls.
- P.V.C. apron.
- Barrier cream.
- Skin cleansing cream.
- Eye wash unit.
The local concentration of material, quantity and
conditions of use determine the type of personal
protective equipment required.
Use appropriate NIOSH-certified respirator based on informed professional
judgement. In conditions where no reasonable estimate of exposure can be
made, assume the exposure is in a concentration IDLH and use NIOSH-certified
full face pressure demand SCBA with a minimum service life of 30 minutes, or
a combination full facepiece pressure demand SAR with auxiliary self-contained
air supply. Respirators provided only for escape from IDLH atmospheres shall be
NIOSH-certified for escape from the atmosphere in which they will be used.
continued...
LIQUID NITRATE TEST SOLUTION #2
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-20
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 9 of 12
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS
General exhaust is adequate under normal operating conditions. Local exhaust
ventilation may be required in special circumstances. If risk of overexposure
exists, wear an approved respirator An approved respirator (supplied air type)
may be required in special circumstances. Correct fit is essential to ensure
adequate protection. Provide adequate ventilation in warehouses and enclosed
storage areas.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL PROPERTIES
Liquid.
Mixes with water.
Molecular Weight: Not Applicable Boiling Range (掳C): Not Available
Melting Range (掳C): Not Available Specific Gravity (water=1): 1.127
Solubility in water (g/L): Miscible pH (as supplied): Not Available
pH (1% solution): Not Available Vapor Pressure (kPa): Not Available
Volatile Component (%vol): Not Available Evaporation Rate: Not Available
Relative Vapor Density (air=1): Not Available Flash Point (掳C): Not Applicable
Lower Explosive Limit (%): Not Applicable Upper Explosive Limit (%): Not Applicable
Autoignition Temp (掳C): Not Applicable Decomposition Temp (掳C): Not Available
State: Liquid
APPEARANCE
Translucent light gray liquid with no odor; mixes with water.
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
- Presence of incompatible materials.
- Product is considered stable.
- Hazardous polymerization will not occur.
STORAGE INCOMPATIBILITY
Avoid reaction with oxidizing agents.
Section 11 - TOXICOLOGICAL INFORMATION
Liquid Nitrate Test Solution #2
Not available. Refer to individual constituents.
unless otherwise specified data extracted from RTECS - Register of Toxic Effects
of Chemical Substances
POLYETHYLENE GLYCOL:
TOXICITY IRRITATION
Oral (rat) LD50: 33750 mg/kg Skin (rabbit): 500mg/24h - mild.
Eye (rabbit): 500mg/24h - mild.
for molecular weights (200-8000) *
continued...
LIQUID NITRATE TEST SOLUTION #2
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-20
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 10 of 12
Section 11 - TOXICOLOGICAL INFORMATION
Oral (rat) LD50: 31000->50000 mg/kg
Oral (mice) LD50: 38000->50000 mg/kg
Oral (g.pig) LD50: 17000->50000 mg/kg
Oral (rabbit) LD50: 14000->50000 mg/kg * AIHA WEEL Guides
Intraperitoneal (mice) LD50: 3100-12900 mg/kg
SULFANILAMIDE:
No significant acute toxicological data identified in literature search.
Section 12 - ECOLOGICAL INFORMATION
DO NOT discharge into sewer or waterways.
Refer to data for ingredients, which follows:
POLYETHYLENE GLYCOL:
BOD 5 if unstated: 0-0.02,1%
COD : 1.62-1.74,98%
Toxicity Fish: TLm(96)>10000mg/L
Section 13 - DISPOSAL CONSIDERATIONS
Disposal Instructions
All waste must be handled in accordance with local, state and federal
regulations.
Puncture containers to prevent re-use and bury at an authorized landfill.
Section 14 - TRANSPORTATION INFORMATION
DOT Information
Shipping Name: None
Hazard Class: None
SubRisk: None
UN/NA Number: None
Packing Group: None
Additional Shipping Information:
International Transport Regulations:
IMO: None
Section 15 - REGULATORY INFORMATION
RISK
US Federal Regulations
A. General Product Information
In addition to Federal and State regulation, local regulations may
apply. Check with your local regulatory authorities.
B. Component Information
This material contains one or more of the following chemicals required
continued...
LIQUID NITRATE TEST SOLUTION #2
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-20
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 11 of 12
Section 15 - REGULATORY INFORMATION
to be identified under SARA Section 302 (40 CFR 455 Appendix A)
SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4): None
-------------------------------------------------------------------
Component TSCA
polyethylene glycol Y
sulfanilamide Y
State Regulations
A. General Product Information
B. Component Information
The following components appear on one or more of the following state
hazardous substance lists.
Component CAS No CA FL MA MN NJ PA
polyethylene glycol 25322-68-3 N N N Y N N
sulfanilamide 63-74-1 N N N N N N
Y=Yes this material appears on that state's hazardous substances list.
N=No this material does not appear on that state's hazardous substances list.
Other Regulations
A. General Product Information
All components are listed in the European Inventory of New and
Existing Chemical Substances (EINECS)
B. Component Information
CANADA
The following component(s) are identified under the Canadian
Hazardous Products Act Ingredient Disclosure List:
All of this product's components are on the Canadian Domestic
.
REGULATIONS
polyethylene glycol (CAS: 25322-68-3) is found on the following regulatory lists
Canadian Domestic Substances List (DSL)
US Toxic Substances Control Act (TSCA)
US Minnesota Hazardous Substance List
US EPA High Production Volume Program Chemical List
US California OEHHA/ARB - Acute Reference Exposure Levels and Target Organs
(RELs) - Respiratory
US Food Additive Database
sulfanilamide (CAS: 63-74-1) is found on the following regulatory lists
Canadian Domestic Substances List (DSL)
US Toxic Substances Control Act (TSCA)
US DOE Temporary Emergency Exposure Limits (TEELs)
US California OEHHA/ARB - Acute Reference Exposure Levels and Target Organs
(RELs) - Respiratory
Section 16 - OTHER INFORMATION
Reasonable care has been taken in the preparation of this information, but the
author makes no warranty of merchantability or any other warranty, expressed or
implied, with respect to this information. The author makes no representations
continued...
LIQUID NITRATE TEST SOLUTION #2
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-20
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 12 of 12
Section 16 - OTHER INFORMATION
and assumes no liability for any direct, incidental or consequential damages
resulting from its use. For additional technical information please call our
toxicology department on +800 CHEMCALL.
Issue Date: Tue 4-Oct-2005
Print Date: Thu 6-Oct-2005
This document is copyright. Apart from any fair dealing for the purposes of
private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from
CHEMWATCH. TEL (+61 3) 9572 4700.
FRESHWATER PH INDICATOR SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-4
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 1 of 7
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
FRESHWATER PH INDICATOR SOLUTION
STATEMENT OF HAZARDOUS NATURE
Not considered a hazardous substance according to OSHA 29
CFR 1910.1200.
SUPPLIER
Company: Aquarium Pharmaceuticals Incorporated Company: Aquarium Pharmaceuticals Incorporated
Address: Address:
50 East Hamilton Street PO Box 218
Chalfont Chalfont
PA, 18914 PA, 18914-0218
USA USA
Telephone: +1 215 822 8181 Telephone: +1 215 822 8181
Emergency Tel: +1800 222 1222 (US Only)
PRODUCT USE
pH indicator solution for product 28.
SYNONYMS
"Solution ID# 3320"
Section 2 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
non hazardous ingredients 100
Section 3 - HAZARDS IDENTIFICATION
CANADIAN WHMIS SYMBOLS
None
EMERGENCY OVERVIEW
RISK
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
The material has NOT been classified as "harmful by ingestion". This is because
of the lack of corroborating animal or human evidence. The material may still be
damaging to the health of the individual, following ingestion, especially where
pre-existing organ (e.g. liver, kidney) damage is evident. Present definitions
of harmful or toxic substances are generally based on doses producing mortality
continued...
FRESHWATER PH INDICATOR SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-4
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 2 of 7
Section 3 - HAZARDS IDENTIFICATION
(death) rather than those producing morbidity (disease, ill-health).
Gastrointestinal tract discomfort may produce nausea and vomiting. In an
occupational setting however, unintentional ingestion is not thought to be cause
for concern.
EYE
Although the liquid is not thought to be an irritant, direct contact with the
eye may produce transient discomfort characterized by tearing or conjunctival
redness (as with windburn).
SKIN
The material is not thought to produce adverse health effects or skin irritation
following contact (as classified using animal models). Nevertheless, good
hygiene practice requires that exposure be kept to a minimum and that suitable
gloves be used in an occupational setting.
INHALED
The material is not thought to produce adverse health effects or irritation of
the respiratory tract (as classified using animal models). Nevertheless, good
hygiene practice requires that exposure be kept to a minimum and that suitable
control measures be used in an occupational setting.
CHRONIC HEALTH EFFECTS
Long-term exposure to the product is not thought to produce chronic effects
adverse to the health (as classified using animal models); nevertheless exposure
by all routes should be minimized as a matter of course.
Section 4 - FIRST AID MEASURES
SWALLOWED
- Immediately give a glass of water.
- First aid is not generally required. If in doubt, contact a Poisons
Information Center or a doctor.
EYE
If this product comes in contact with eyes:
- Wash out immediately with water.
- If irritation continues, seek medical attention.
- Removal of contact lenses after an eye injury should only be undertaken by
skilled personnel.
SKIN
If skin or hair contact occurs:
- Flush skin and hair with running water (and soap if available).
- Seek medical attention in event of irritation.
INHALED
- If fumes or combustion products are inhaled remove from contaminated area.
- Other measures are usually unnecessary.
NOTES TO PHYSICIAN
Treat symptomatically.
continued...
FRESHWATER PH INDICATOR SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-4
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 3 of 7
Section 5 - FIRE FIGHTING MEASURES
Flash Point (掳F): Not Applicable
Lower Explosive Limit (%): Not Applicable
Upper Explosive Limit (%): Not Applicable
Autoignition Temp (掳F): Not Applicable
EXTINGUISHING MEDIA
- There is no restriction on the type of extinguisher which may be used.
Use extinguishing media suitable for surrounding area.
FIRE FIGHTING
- Use water delivered as a fine spray to control fire and cool adjacent area.
- DO NOT approach containers suspected to be hot.
- Cool fire exposed containers with water spray from a protected location.
- If safe to do so, remove containers from path of fire.
- Equipment should be thoroughly decontaminated after use.
GENERAL FIRE HAZARDS/HAZARDOUS COMBUSTIBLE PRODUCTS
- Non combustible.
- Not considered to be a significant fire risk.
- Expansion or decomposition on heating may lead to violent rupture of
containers.
- Decomposes on heating and may produce toxic/ irritating fumes.
- May emit acrid smoke.
FIRE INCOMPATIBILITY
Avoid contamination with oxidizing agents i.e. nitrates, oxidizing acids,
chlorine bleaches, pool chlorine etc. as ignition may result.
Section 6 - ACCIDENTAL RELEASE MEASURES
MINOR SPILLS
- Clean up all spills immediately.
- Avoid breathing vapors and contact with skin and eyes.
- Control personal contact by using protective equipment.
- Contain and absorb spill with sand, earth, inert material or vermiculite.
- Wipe up.
- Place in a suitable labeled container for waste disposal.
MAJOR SPILLS
- Clear area of personnel and move upwind.
- Alert Emergency Responders and tell them location and nature of hazard.
- Control personal contact by using protective equipment.
- Prevent spillage from entering drains, sewers or water courses.
- Recover product wherever possible.
- Put residues in labeled containers for disposal.
- If contamination of drains or waterways occurs, advise emergency services.
ACUTE EXPOSURE GUIDELINE LEVELS (AEGL) (in ppm)
AEGL 1: The airborne concentration of a substance above which it is predicted
continued...
FRESHWATER PH INDICATOR SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-4
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 4 of 7
Section 6 - ACCIDENTAL RELEASE MEASURES
that the general population, including susceptible individuals, could
experience notable discomfort, irritation, or certain asymptomatic nonsensory
effects. However, the effects are not disabling and are transient and
reversible upon cessation of exposure.
AEGL 2: The airborne concentration of a substance above which it is predicted
that the general population, including susceptible individuals, could
experience irreversible or other serious, long-lasting adverse health effects
or an impaired ability to escape.
AEGL 3: The airborne concentration of a substance above which it is predicted
that the general population, including susceptible individuals, could
experience life-threatening health effects or death.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
- Limit all unnecessary personal contact.
- Wear protective clothing when risk of exposure occurs.
- Use in a well-ventilated area.
- When handling DO NOT eat, drink or smoke.
- Always wash hands with soap and water after handling.
- Avoid physical damage to containers.
- Use good occupational work practice.
- Observe manufacturer's storing and handling recommendations.
RECOMMENDED STORAGE METHODS
- Polyethylene or polypropylene container.
- Packing as recommended by manufacturer
- Check all containers are clearly labeled and free from leaks.
STORAGE REQUIREMENTS
- Store in original containers.
- Keep containers securely sealed.
- Store in a cool, dry, well-ventilated area.
- Store away from incompatible materials and foodstuff containers.
- Protect containers against physical damage and check regularly for leaks.
- Observe manufacturer's storing and handling recommendations.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
Not available. Refer to individual constituents.
PERSONAL PROTECTION
Glasses:
Chemical goggles.
Gloves:
When handling larger quantities:
General purpose rubber glove.
Respirator:
continued...
FRESHWATER PH INDICATOR SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-4
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 5 of 7
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EYE
- Safety glasses with side shields
- Chemical goggles.
- Contact lenses pose a special hazard; soft lenses may absorb irritants and all
lenses concentrate them.
HANDS/FEET
Wear general protective gloves, e.g.. light weight rubber gloves.
OTHER
No special equipment needed when handling small quantities.
OTHERWISE:
- Overalls.
- Barrier cream.
- Eyewash unit.
The local concentration of material, quantity and
conditions of use determine the type of personal
protective equipment required.
Use appropriate NIOSH-certified respirator based on informed professional
judgement. In conditions where no reasonable estimate of exposure can be
made, assume the exposure is in a concentration IDLH and use NIOSH-certified
full face pressure demand SCBA with a minimum service life of 30 minutes, or
a combination full facepiece pressure demand SAR with auxiliary self-contained
air supply. Respirators provided only for escape from IDLH atmospheres shall be
NIOSH-certified for escape from the atmosphere in which they will be used.
ENGINEERING CONTROLS
General exhaust is adequate under normal operating conditions. If risk of
overexposure exists, wear an approved respirator. Correct fit is essential to
obtain adequate protection. Provide adequate ventilation in warehouse or closed
storage areas.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL PROPERTIES
Liquid.
Mixes with water.
Molecular Weight: Not Applicable Boiling Range (掳C): Not Available
Melting Range (掳C): Not Available Specific Gravity (water=1): 0.997
Solubility in water (g/L): Miscible pH (as supplied): 4.5-5.8
pH (1% solution): Not Available Vapor Pressure (kPa): Not Available
Volatile Component (%vol): Not Available Evaporation Rate: Not Available
Relative Vapor Density (air=1): Not Available Flash Point (掳C): Not Applicable
Lower Explosive Limit (%): Not Applicable Upper Explosive Limit (%): Not Applicable
Autoignition Temp (掳C): Not Applicable Decomposition Temp (掳C): Not Available
State: Liquid
APPEARANCE
Orange brown odorless liquid; mixes with water.
continued...
FRESHWATER PH INDICATOR SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-4
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 6 of 7
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
- Presence of incompatible materials.
- Product is considered stable.
- Hazardous polymerization will not occur.
STORAGE INCOMPATIBILITY
Avoid contamination of water, foodstuffs, feed or seed.
Avoid reaction with oxidizing agents.
Section 11 - TOXICOLOGICAL INFORMATION
Freshwater pH Indicator Solution
Not available. Refer to individual constituents.
unless otherwise specified data extracted from RTECS - Register of Toxic Effects
of Chemical Substances
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Disposal Instructions
All waste must be handled in accordance with local, state and federal
regulations.
- Recycle wherever possible.
- Consult manufacturer for recycling options or consult Waste Management
Authority for disposal if no suitable treatment or disposal facility can be
identified.
- Dispose of by: Burial in a licensed land-fill or Incineration in a licensed
apparatus (after admixture with suitable combustible material)
- Decontaminate empty containers. Observe all label safeguards until containers
are cleaned and destroyed.
Section 14 - TRANSPORTATION INFORMATION
DOT Information
Shipping Name: None
Hazard Class: None
SubRisk: None
UN/NA Number: None
Packing Group: None
Additional Shipping Information:
International Transport Regulations:
IMO: None
continued...
FRESHWATER PH INDICATOR SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-4
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 7 of 7
Section 15 - REGULATORY INFORMATION
RISK
US Federal Regulations
A. General Product Information
In addition to Federal and State regulation, local regulations may
apply. Check with your local regulatory authorities.
B. Component Information
This material contains one or more of the following chemicals required
to be identified under SARA Section 302 (40 CFR 455 Appendix A)
SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4): None
-------------------------------------------------------------------
Component TSCA
State Regulations
A. General Product Information
B. Component Information
The following components appear on one or more of the following state
hazardous substance lists.
Component CAS No CA FL MA MN NJ PA
Y=Yes this material appears on that state's hazardous substances list.
N=No this material does not appear on that state's hazardous substances list.
Other Regulations
A. General Product Information
All components are listed in the European Inventory of New and
Existing Chemical Substances (EINECS)
B. Component Information
CANADA
All of this product's components are on the Canadian Domestic
.
Section 16 - OTHER INFORMATION
Reasonable care has been taken in the preparation of this information, but the
author makes no warranty of merchantability or any other warranty, expressed or
implied, with respect to this information. The author makes no representations
and assumes no liability for any direct, incidental or consequential damages
resulting from its use. For additional technical information please call our
toxicology department on +800 CHEMCALL.
Issue Date: Tue 4-Oct-2005
Print Date: Thu 6-Oct-2005
This document is copyright. Apart from any fair dealing for the purposes of
private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from
CHEMWATCH. TEL (+61 3) 9572 4700.
HIGH RANGE PH TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-6
Issue Date: Mon 3-Oct-2005 CD 2005/3 Page 1 of 8
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
HIGH RANGE PH TEST SOLUTION
STATEMENT OF HAZARDOUS NATURE
Not considered a hazardous substance according to OSHA 29
CFR 1910.1200.
SUPPLIER
Company: Aquarium Pharmaceuticals Incorporated Company: Aquarium Pharmaceuticals Incorporated
Address: Address:
50 East Hamilton Street PO Box 218
Chalfont Chalfont
PA, 18914 PA, 18914-0218
USA USA
Telephone: +1 215 822 8181 Telephone: +1 215 822 8181
Emergency Tel: +1800 222 1222 (US Only)
PRODUCT USE
pH test solution for product 27, 34 and 401M.
SYNONYMS
"Solution ID# 3339"
Section 2 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
m-cresol purple 2303-01-7 N/S^
Section 3 - HAZARDS IDENTIFICATION
CANADIAN WHMIS SYMBOLS
None
EMERGENCY OVERVIEW
RISK
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
The material has NOT been classified as "harmful by ingestion". This is because
of the lack of corroborating animal or human evidence. The material may still be
damaging to the health of the individual, following ingestion, especially where
pre-existing organ (e.g. liver, kidney) damage is evident. Present definitions
of harmful or toxic substances are generally based on doses producing mortality
continued...
HIGH RANGE PH TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-6
Issue Date: Mon 3-Oct-2005 CD 2005/3 Page 2 of 8
Section 3 - HAZARDS IDENTIFICATION
(death) rather than those producing morbidity (disease, ill-health).
Gastrointestinal tract discomfort may produce nausea and vomiting. In an
occupational setting however, unintentional ingestion is not thought to be cause
for concern.
EYE
Although the liquid is not thought to be an irritant, direct contact with the
eye may produce transient discomfort characterized by tearing or conjunctival
redness (as with windburn).
SKIN
The material is not thought to produce adverse health effects or skin irritation
following contact (as classified using animal models). Nevertheless, good
hygiene practice requires that exposure be kept to a minimum and that suitable
gloves be used in an occupational setting.
INHALED
The material is not thought to produce adverse health effects or irritation of
the respiratory tract (as classified using animal models). Nevertheless, good
hygiene practice requires that exposure be kept to a minimum and that suitable
control measures be used in an occupational setting.
CHRONIC HEALTH EFFECTS
Long-term exposure to the product is not thought to produce chronic effects
adverse to the health (as classified using animal models); nevertheless exposure
by all routes should be minimized as a matter of course.
Section 4 - FIRST AID MEASURES
SWALLOWED
- Immediately give a glass of water.
- First aid is not generally required. If in doubt, contact a Poisons
Information Center or a doctor.
EYE
If this product comes in contact with eyes:
- Wash out immediately with water.
- If irritation continues, seek medical attention.
- Removal of contact lenses after an eye injury should only be undertaken by
skilled personnel.
SKIN
If skin or hair contact occurs:
- Flush skin and hair with running water (and soap if available).
- Seek medical attention in event of irritation.
INHALED
- If fumes or combustion products are inhaled remove from contaminated area.
- Other measures are usually unnecessary.
NOTES TO PHYSICIAN
Treat symptomatically.
continued...
HIGH RANGE PH TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-6
Issue Date: Mon 3-Oct-2005 CD 2005/3 Page 3 of 8
Section 5 - FIRE FIGHTING MEASURES
Flash Point (掳F): Not Applicable
Lower Explosive Limit (%): Not Applicable
Upper Explosive Limit (%): Not Applicable
Autoignition Temp (掳F): Not Applicable
EXTINGUISHING MEDIA
- There is no restriction on the type of extinguisher which may be used.
Use extinguishing media suitable for surrounding area.
FIRE FIGHTING
- Use water delivered as a fine spray to control fire and cool adjacent area.
- DO NOT approach containers suspected to be hot.
- Cool fire exposed containers with water spray from a protected location.
- If safe to do so, remove containers from path of fire.
- Equipment should be thoroughly decontaminated after use.
GENERAL FIRE HAZARDS/HAZARDOUS COMBUSTIBLE PRODUCTS
- Non combustible.
- Not considered to be a significant fire risk.
- Expansion or decomposition on heating may lead to violent rupture of
containers.
- Decomposes on heating and may produce toxic/ irritating fumes.
- May emit acrid smoke.
FIRE INCOMPATIBILITY
None known.
Section 6 - ACCIDENTAL RELEASE MEASURES
MINOR SPILLS
- Clean up all spills immediately.
- Avoid breathing vapors and contact with skin and eyes.
- Control personal contact by using protective equipment.
- Contain and absorb spill with sand, earth, inert material or vermiculite.
- Wipe up.
- Place in a suitable labeled container for waste disposal.
MAJOR SPILLS
- Clear area of personnel and move upwind.
- Alert Emergency Responders and tell them location and nature of hazard.
- Control personal contact by using protective equipment.
- Prevent spillage from entering drains, sewers or water courses.
- Recover product wherever possible.
- Put residues in labeled containers for disposal.
- If contamination of drains or waterways occurs, advise emergency services.
ACUTE EXPOSURE GUIDELINE LEVELS (AEGL) (in ppm)
AEGL 1: The airborne concentration of a substance above which it is predicted
that the general population, including susceptible individuals, could
continued...
HIGH RANGE PH TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-6
Issue Date: Mon 3-Oct-2005 CD 2005/3 Page 4 of 8
Section 6 - ACCIDENTAL RELEASE MEASURES
experience notable discomfort, irritation, or certain asymptomatic nonsensory
effects. However, the effects are not disabling and are transient and
reversible upon cessation of exposure.
AEGL 2: The airborne concentration of a substance above which it is predicted
that the general population, including susceptible individuals, could
experience irreversible or other serious, long-lasting adverse health effects
or an impaired ability to escape.
AEGL 3: The airborne concentration of a substance above which it is predicted
that the general population, including susceptible individuals, could
experience life-threatening health effects or death.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
- Limit all unnecessary personal contact.
- Wear protective clothing when risk of exposure occurs.
- Use in a well-ventilated area.
- When handling DO NOT eat, drink or smoke.
- Always wash hands with soap and water after handling.
- Avoid physical damage to containers.
- Use good occupational work practice.
- Observe manufacturer's storing and handling recommendations.
RECOMMENDED STORAGE METHODS
- Polyethylene or polypropylene container.
- Packing as recommended by manufacturer
- Check all containers are clearly labeled and free from leaks.
STORAGE REQUIREMENTS
- Store in original containers.
- Keep containers securely sealed.
- Store in a cool, dry, well-ventilated area.
- Store away from incompatible materials and foodstuff containers.
- Protect containers against physical damage and check regularly for leaks.
- Observe manufacturer's storing and handling recommendations.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
Not available. Refer to individual constituents.
PERSONAL PROTECTION
Glasses:
Chemical goggles.
Gloves:
When handling larger quantities:
General purpose rubber glove.
Respirator:
continued...
HIGH RANGE PH TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-6
Issue Date: Mon 3-Oct-2005 CD 2005/3 Page 5 of 8
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EYE
- Safety glasses with side shields
- Chemical goggles.
- Contact lenses pose a special hazard; soft lenses may absorb irritants and all
lenses concentrate them.
HANDS/FEET
Wear general protective gloves, e.g.. light weight rubber gloves.
OTHER
No special equipment needed when handling small quantities.
OTHERWISE:
- Overalls.
- Barrier cream.
- Eyewash unit.
The local concentration of material, quantity and
conditions of use determine the type of personal
protective equipment required.
Use appropriate NIOSH-certified respirator based on informed professional
judgement. In conditions where no reasonable estimate of exposure can be
made, assume the exposure is in a concentration IDLH and use NIOSH-certified
full face pressure demand SCBA with a minimum service life of 30 minutes, or
a combination full facepiece pressure demand SAR with auxiliary self-contained
air supply. Respirators provided only for escape from IDLH atmospheres shall be
NIOSH-certified for escape from the atmosphere in which they will be used.
ENGINEERING CONTROLS
General exhaust is adequate under normal operating conditions. If risk of
overexposure exists, wear an approved respirator. Correct fit is essential to
obtain adequate protection. Provide adequate ventilation in warehouse or closed
storage areas.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL PROPERTIES
Liquid.
Mixes with water.
Molecular Weight: Not Applicable Boiling Range (掳C): Not Available
Melting Range (掳C): Not Available Specific Gravity (water=1): 0.997 approx.
Solubility in water (g/L): Miscible pH (as supplied): 7.6-8.4
pH (1% solution): Not Available Vapor Pressure (kPa): Not Available
Volatile Component (%vol): Not Available Evaporation Rate: Not Available
Relative Vapor Density (air=1): Not Available Flash Point (掳C): Not Applicable
Lower Explosive Limit (%): Not Applicable Upper Explosive Limit (%): Not Applicable
Autoignition Temp (掳C): Not Applicable Decomposition Temp (掳C): Not Available
State: Liquid
APPEARANCE
Purple red solution with a mild odor; mixes with water.
continued...
HIGH RANGE PH TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-6
Issue Date: Mon 3-Oct-2005 CD 2005/3 Page 6 of 8
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
- Presence of incompatible materials.
- Product is considered stable.
- Hazardous polymerization will not occur.
STORAGE INCOMPATIBILITY
Avoid contamination of water, foodstuffs, feed or seed. None known.
Section 11 - TOXICOLOGICAL INFORMATION
High Range pH Test Solution
Not available. Refer to individual constituents.
unless otherwise specified data extracted from RTECS - Register of Toxic Effects
of Chemical Substances
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Disposal Instructions
All waste must be handled in accordance with local, state and federal
regulations.
- Recycle wherever possible.
- Consult manufacturer for recycling options or consult Waste Management
Authority for disposal if no suitable treatment or disposal facility can be
identified.
- Dispose of by: Burial in a licensed land-fill or Incineration in a licensed
apparatus (after admixture with suitable combustible material)
- Decontaminate empty containers. Observe all label safeguards until containers
are cleaned and destroyed.
Section 14 - TRANSPORTATION INFORMATION
DOT Information
Shipping Name: None
Hazard Class: None
SubRisk: None
UN/NA Number: None
Packing Group: None
Additional Shipping Information:
International Transport Regulations:
IMO: None
continued...
HIGH RANGE PH TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-6
Issue Date: Mon 3-Oct-2005 CD 2005/3 Page 7 of 8
Section 15 - REGULATORY INFORMATION
RISK
US Federal Regulations
A. General Product Information
In addition to Federal and State regulation, local regulations may
apply. Check with your local regulatory authorities.
B. Component Information
This material contains one or more of the following chemicals required
to be identified under SARA Section 302 (40 CFR 455 Appendix A)
SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4): None
-------------------------------------------------------------------
Component TSCA
m-cresol purple Y
State Regulations
A. General Product Information
B. Component Information
The following components appear on one or more of the following state
hazardous substance lists.
Component CAS No CA FL MA MN NJ PA
m-cresol purple 2303-01-7 N N N N N N
Y=Yes this material appears on that state's hazardous substances list.
N=No this material does not appear on that state's hazardous substances list.
Other Regulations
A. General Product Information
All components are listed in the European Inventory of New and
Existing Chemical Substances (EINECS)
B. Component Information
CANADA
All of this product's components are on the Canadian Domestic
.
Section 16 - OTHER INFORMATION
Reasonable care has been taken in the preparation of this information, but the
author makes no warranty of merchantability or any other warranty, expressed or
implied, with respect to this information. The author makes no representations
and assumes no liability for any direct, incidental or consequential damages
resulting from its use. For additional technical information please call our
toxicology department on +800 CHEMCALL.
Issue Date: Mon 3-Oct-2005
Print Date: Thu 6-Oct-2005
This document is copyright. Apart from any fair dealing for the purposes of
private study, research, review or criticism, as permitted under the Copyright
continued...
HIGH RANGE PH TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-6
Issue Date: Mon 3-Oct-2005 CD 2005/3 Page 8 of 8
Section 16 - OTHER INFORMATION
Act, no part may be reproduced by any process without written permission from
CHEMWATCH. TEL (+61 3) 9572 4700.
FRESHWATER/SALTWATER NITRITE TEST SOLUTION
Chemwatch Material Safety Data Sheet
Jun-7-2007 CHEMWATCH 4650-16
NB293ECP Version No:5
CD 2007/2 Page 1 of 15
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
FRESHWATER/SALTWATER NITRITE TEST SOLUTION
STATEMENT OF HAZARDOUS NATURE
CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200.
SUPPLIER
Company: Aquarium Pharmaceuticals Inc Company: Aquarium Pharmaceuticals Inc
Address: Address:
PO Box 218 50 East Hamilton Street
Chalfont Chalfont
PA, 18914- 0218 PA, 18914
USA USA
Telephone: +1 215 822 8181 Telephone: +1 215 822 8181
Emergency Tel: +1800 222 1222 (US Only) Fax: +1 215 822 1906
PRODUCT USE
Nitrate test solution for products 26, 34 and 401M.
SYNONYMS
"Solution ID# 3317"
Section 2 - HAZARDS IDENTIFICATION
CANADIAN WHMIS SYMBOLS
None
EMERGENCY OVERVIEW
RISK
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
The material has NOT been classified by EC Directives or other classification systems as
"harmful by ingestion". This is because of the lack of corroborating animal or human
evidence. The material may still be damaging to the health of the individual, following
ingestion, especially where pre-existing organ (e.g liver, kidney) damage is evident.
Present definitions of harmful or toxic substances are generally based on doses producing
mortality rather than those producing morbidity (disease, ill-health). Gastrointestinal
tract discomfort may produce nausea and vomiting. In an occupational setting however,
ingestion of insignificant quantities is not thought to be cause for concern.
EYE
Although the liquid is not thought to be an irritant (as classified by EC Directives),
direct contact with the eye may produce transient discomfort characterised by tearing or
conjunctival redness (as with windburn).
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FRESHWATER/SALTWATER NITRITE TEST SOLUTION
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CD 2007/2 Page 2 of 15
Section 2 - HAZARDS IDENTIFICATION
SKIN
The material is not thought to produce adverse health effects or skin irritation
following contact (as classified by EC Directives using animal models). Nevertheless,
good hygiene practice requires that exposure be kept to a minimum and that suitable
gloves be used in an occupational setting.
INHALED
The material is not thought to produce adverse health effects or irritation of the
respiratory tract (as classified by EC Directives using animal models). Nevertheless,
good hygiene practice requires that exposure be kept to a minimum and that suitable
control measures be used in an occupational setting.
Not normally a hazard due to non-volatile nature of product.
Inhalation hazard is increased at higher temperatures.
CHRONIC HEALTH EFFECTS
Long-term exposure to the product is not thought to produce chronic effects adverse to
health (as classified by EC Directives using animal models); nevertheless exposure by all
routes should be minimised as a matter of course.
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
polyethylene glycol 25322-68-3 <95
hydrochloric acid 7647-01-0 0.97
Section 4 - FIRST AID MEASURES
SWALLOWED
路 Immediately give a glass of water.
路 First aid is not generally required. If in doubt, contact a Poisons Information Centre
or a doctor.
EYE
If this product comes in contact with eyes:
路 Wash out immediately with water.
路 If irritation continues, seek medical attention.
路 Removal of contact lenses after an eye injury should only be undertaken by skilled
personnel.
SKIN
If skin or hair contact occurs:
路 Flush skin and hair with running water (and soap if available).
路 Seek medical attention in event of irritation.
INHALED
路 If fumes or combustion products are inhaled remove from contaminated area.
路 Other measures are usually unnecessary.
NOTES TO PHYSICIAN
Treat symptomatically.
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FRESHWATER/SALTWATER NITRITE TEST SOLUTION
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CD 2007/2 Page 3 of 15
Section 5 - FIRE FIGHTING MEASURES
Flash Point (掳 Not Applicable
F):
Lower Explosive Limit (%): Not Applicable
Upper Explosive Limit (%): Not Applicable
Autoignition Temp (掳 Not Applicable
F):
EXTINGUISHING MEDIA
路 Water spray or fog.
路 Foam.
路 Dry chemical powder.
路 BCF (where regulations permit).
路 Carbon dioxide.
FIRE FIGHTING
路 Alert Fire Brigade and tell them location and nature of hazard.
路 Wear full body protective clothing with breathing apparatus.
路 Prevent, by any means available, spillage from entering drains or water course.
路 Use water delivered as a fine spray to control fire and cool adjacent area.
路 Avoid spraying water onto liquid pools.
路 DO NOT approach containers suspected to be hot.
路 Cool fire exposed containers with water spray from a protected location.
路 If safe to do so, remove containers from path of fire.
GENERAL FIRE HAZARDS/HAZARDOUS COMBUSTIBLE PRODUCTS
路 Combustible.
路 Slight fire hazard when exposed to heat or flame.
路 Heating may cause expansion or decomposition leading to violent rupture of containers.
路 On combustion, may emit toxic fumes of carbon monoxide (CO).
路 May emit acrid smoke.
路 Mists containing combustible materials may be explosive.
Combustion products include: carbon dioxide (CO2), hydrogen chloride, other pyrolysis
products typical of burning organic material, phosgene.
FIRE INCOMPATIBILITY
Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine
bleaches, pool chlorine etc. as ignition may result.
PERSONAL PROTECTION
Glasses:
Safety Glasses.
Chemical goggles.
Gloves:
When handling larger quantities:
General purpose rubber glove.
Respirator:
Type B- P Filter of sufficient capacity
Section 6 - ACCIDENTAL RELEASE MEASURES
MINOR SPILLS
路 Remove all ignition sources.
路 Clean up all spills immediately.
路 Avoid breathing vapours and contact with skin and eyes.
路 Control personal contact by using protective equipment.
路 Contain and absorb spill with sand, earth, inert material or vermiculite.
路 Wipe up.
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Jun-7-2007 CHEMWATCH 4650-16
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CD 2007/2 Page 4 of 15
Section 6 - ACCIDENTAL RELEASE MEASURES
路 Place in a suitable labelled container for waste disposal.
MAJOR SPILLS
Moderate hazard.
路 Clear area of personnel and move upwind.
路 Alert Fire Brigade and tell them location and nature of hazard.
路 Wear breathing apparatus plus protective gloves.
路 Prevent, by any means available, spillage from entering drains or water course.
路 No smoking, naked lights or ignition sources.
路 Increase ventilation.
路 Stop leak if safe to do so.
路 Contain spill with sand, earth or vermiculite.
路 Collect recoverable product into labelled containers for recycling.
路 Absorb remaining product with sand, earth or vermiculite.
路 Collect solid residues and seal in labelled drums for disposal.
路 Wash area and prevent runoff into drains.
路 If contamination of drains or waterways occurs, advise emergency services.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
DO NOT USE brass or copper containers / stirrers.
路 Avoid all personal contact, including inhalation.
路 Wear protective clothing when risk of exposure occurs.
路 Use in a well-ventilated area.
路 Prevent concentration in hollows and sumps.
路 DO NOT enter confined spaces until atmosphere has been checked.
路 Avoid smoking, naked lights or ignition sources.
路 Avoid contact with incompatible materials.
路 When handling, DO NOT eat, drink or smoke.
路 Keep containers securely sealed when not in use.
路 Avoid physical damage to containers.
路 Always wash hands with soap and water after handling.
路 Work clothes should be laundered separately.
路 Use good occupational work practice.
路 Observe manufacturer's storing and handling recommendations.
路 Atmosphere should be regularly checked against established exposure standards to
ensure safe working conditions.
RECOMMENDED STORAGE METHODS
路 Metal can or drum
路 Packaging as recommended by manufacturer.
路 Check all containers are clearly labelled and free from leaks.
STORAGE REQUIREMENTS
路 Store in original containers.
路 Keep containers securely sealed.
路 No smoking, naked lights or ignition sources.
路 Store in a cool, dry, well-ventilated area.
路 Store away from incompatible materials and foodstuff containers.
路 Protect containers against physical damage and check regularly for leaks.
路 Observe manufacturer's storing and handling recommendations.
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CD 2007/2 Page 5 of 15
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
US OSHA Permissible Exposure Levels ( PELs)
Z Materia TWA ppm TWA STEL STEL Peak Peak Max Max Max TWA
l mg/m鲁 ppm mg/m鲁 ppm mg/m鲁 excursi excursi excursi F/CC
on ppm on on
mg/m鲁 duratio
n
(mins)
__ _______ ____ ____ ____ ____ ____ ____ _______ _______ _______ ____
Z1 Hydroge 5 7
n
chlorid
e
Source Material TWA ppm TWA mg/m鲁 STEL ppm STEL mg/m鲁Peak ppm Peak mg/m鲁 TWA F/CC
_________ _________ _____ _____ _____ _____ _____ _____ _____
Canada - polyethyle 3 6
Saskatchew ne glycol
an (Respirabl
Occupation e size+)
al Health
and Safety
Regulation
s-
Contaminat
ion Limits
Canada - polyethyle 10 20
Saskatchew ne glycol
an (Particula
Occupation tes,
al Health NOC++)
and Safety
Regulation
s-
Contaminat
ion Limits
Canada - polyethyle 10
British ne glycol
Columbia (Particles
Occupation
al (Insoluble
Exposure or Poorly
Limits Soluble)
Not
Otherwise
Classified
(PNOC))
US - hydrochlor 5 7
Minnesota ic acid
Permissibl (Hydrogen
e Exposure chloride)
Limits
(PELs)
Canada - hydrochlor 2
Ontario ic acid
Occupation (Hydrogen
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Jun-7-2007 CHEMWATCH 4650-16
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CD 2007/2 Page 6 of 15
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Source Material TWA ppm TWA mg/m鲁 STEL ppm STEL mg/m鲁Peak ppm Peak mg/m鲁 TWA F/CC
_________ _________ _____ _____ _____ _____ _____ _____ _____
al chloride)
Exposure
Limits
Canada - hydrochlor 5 7, 5
Quebec ic acid
Occupation (Chlorure
al d'
Exposure hydrog猫ne)
Limits
(French)
US - hydrochlor (C)5 (C)7
Vermont ic acid
Permissibl (Hydrogen
e Exposure chloride)
Limits
Table Z-
1- A
Transition
al Limits
for Air
Contaminan
ts
US - hydrochlor 5 7
Vermont ic acid
Permissibl (Hydrogen
e Exposure chloride)
Limits
Table Z-
1- A Final
Rule
Limits for
Air
Contaminan
ts
US - hydrochlor 5 7
Tennessee ic acid
Occupation (Hydrogen
al chloride)
Exposure
Limits -
Limits For
Air
Contaminan
ts
US - hydrochlor 5 7
California ic acid
(Hydrogen
Permissibl chloride;
e Exposure muriatic
Limits for acid)
Chemical
Contaminan
ts
US - Idaho hydrochlor 5 7
- Limits ic acid
for Air (Hydrogen
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FRESHWATER/SALTWATER NITRITE TEST SOLUTION
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Jun-7-2007 CHEMWATCH 4650-16
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CD 2007/2 Page 7 of 15
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Source Material TWA ppm TWA mg/m鲁 STEL ppm STEL mg/m鲁Peak ppm Peak mg/m鲁 TWA F/CC
_________ _________ _____ _____ _____ _____ _____ _____ _____
Contaminan chloride)
ts
US - hydrochlor 5 7
Hawaii Air ic acid
Contaminan (Hydrogen
t Limits chloride)
US OSHA hydrochlor 5 7
Permissibl ic acid
e Exposure (Hydrogen
Levels chloride)
(PELs) -
Table Z1
Canada - hydrochlor 7.5
Saskatchew ic acid
an (Hydrogen
Occupation chloride)
al Health
and Safety
Regulation
s-
Contaminat
ion Limits
Canada - hydrochlor 5 7 - -
Yukon ic acid
Permissibl (Hydrogen
e chloride)
Concentrat
ions for
Airborne
Contaminan
t
Substances
US - hydrochlor 5.0
Washington ic acid
(Hydrogen
Permissibl chloride)
e exposure
limits of
air
contaminan
ts
Canada - hydrochlor 5 7.5
Alberta ic acid
Occupation (Hydrogen
al chloride)
Exposure
Limits
Canada - hydrochlor 2
British ic acid
Columbia (Hydrogen
Occupation chloride
al (Revised
Exposure 2003))
Limits
US NIOSH hydrochlor 5 7
Recommende acid
ic
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FRESHWATER/SALTWATER NITRITE TEST SOLUTION
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Jun-7-2007 CHEMWATCH 4650-16
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CD 2007/2 Page 8 of 15
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Source Material TWA ppm TWA mg/m鲁 STEL ppm STEL mg/m鲁Peak ppm Peak mg/m鲁 TWA F/CC
_________ _________ _____ _____ _____ _____ _____ _____ _____
d Exposure (Hydrogen
Limits chloride)
(RELs)
US ACGIH hydrochlor 2
Threshold ic acid
Limit (Hydrogen
Values chloride)
(TLV)
EMERGENCY EXPOSURE LIMITS
Material Revised IDLH Value (mg/m3) Revised IDLH Value (ppm)
hydrochloric acid 50
ODOR SAFETY FACTOR (OSF)
OSF=1.3 (hydrochloric acid)
Exposed individuals are NOT reasonably expected to be warned, by smell, that the Exposure
Standard is being exceeded.
Odour Safety Factor (OSF) is determined to fall into either Class C, D or E.
The Odour Safety Factor (OSF) is defined as:
OSF= Exposure Standard (TWA) ppm/ Odour Threshold Value (OTV) ppm
Classification into classes follows:
Class OSF Description
A 550 Over 90% of exposed individuals
are aware by smell that the
Exposure Standard (TLV- TWA for
example) is being reached, even
when distracted by working
activities
B 26- 550 As " A" for 50- 90% of persons
being distracted
C 1- 26 As " A" for less than 50% of
persons being distracted
D 0.18- 1 10- 50% of persons aware of
being tested perceive by smell
that the Exposure Standard is
being reached
E <0.18 As " D" for less than 10% of
persons aware of being tested
.
MATERIAL DATA
INGREDIENT DATA
POLYETHYLENE GLYCOL:
For powdered forms:
The polyethylene glycols are extremely low in oral toxicity, are not
significantly irritating to the eyes or skin, and are not absorbed
through the skin in toxic amounts. vapour pressures are extremely low and
inhalation exposure is limited to mists. Based on experimental data and
human experience, these substances do not present significant hazards to
health in the workplace.
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Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
HYDROCHLORIC ACID:
Odour Threshold Value: 0.262 ppm (detection), 10.06 ppm (recognition)
NOTE: Detector tubes for hydrochloric acid, measuring in excess of 1 ppm,
are available commercially.
Hydrogen chloride is a strong irritant to the eyes, mucous membranes and
skin. Chronic exposure produces a corrosive action on the teeth. Reports
of respiratory irritation following short-term exposure at 5 ppm have lead
to the recommended TLV-C. There is no indication that skin contact with
hydrogen chloride elicits systemic poisoning and a skin designation has
not been applied.
Exposure of humans to hydrogen chloride at 50 to 100 ppm for 1 hour is
reported to be barely tolerable; 35 ppm caused irritation of the throat on
short exposure and 10 ppm was the maximal concentration for prolonged
exposure. It has been stated that hydrogen chloride at concentrations of
5 ppm is immediately irritating.
-
Toxic effects of hydrochloric acid
-------------------------------------------------------------------------
Concentration Clinical effects
-------------------------------------------------------------------------
0.067 - 0.267 ppm Reported range of odour thresholds and
changes in respiratory pattern
5 ppm No organic damage
10 ppm Irritation; work undisturbed
10-50 ppm Work difficult but possible
35 ppm Short exposure irritation of the throat
50-100 ppm Exposure for 1 h barely tolerable
1000-2000 ppm Brief exposure dangerous; laryngospasm
1300-2000 ppm Lethal after a few minutes
-------------------------------------------------------------------------
PERSONAL PROTECTION
EYE
路 Safety glasses with side shields
路 Chemical goggles.
路 Contact lenses may pose a special hazard; soft contact lenses may absorb and
concentrate irritants. A written policy document, describing the wearing of lens or
restrictions on use, should be created for each workplace or task. This should include a
review of lens absorption and adsorption for the class of chemicals in use and an account
of injury experience. Medical and first-aid personnel should be trained in their removal
and suitable equipment should be readily available. In the event of chemical exposure,
begin eye irrigation immediately and remove contact lens as soon as practicable. Lens
should be removed at the first signs of eye redness or irritation - lens should be
removed in a clean environment only after workers have washed hands thoroughly. [CDC
NIOSH Current Intelligence Bulletin 59].
HANDS/FEET
Wear general protective gloves, eg. light weight rubber gloves.
Suitability and durability of glove type is dependent on usage. Factors such as:
路 frequency and duration of contact,
路 chemical resistance of glove material,
路 glove thickness and
路 dexterity,
are important in the selection of gloves.
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CD 2007/2 Page 10 of 15
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
OTHER
No special equipment needed when handling small quantities.
OTHERWISE:
路 Overalls.
路 Barrier cream.
路 Eyewash unit.
RESPIRATOR
Selection of the Class and Type of respirator will depend upon the level of breathing
zone contaminant and the chemical nature of the contaminant. Protection Factors (defined
as the ratio of contaminant outside and inside the mask) may also be important.
Breathing Zone Level Maximum Protection Half- face Respirator Full- Face Respirator
ppm (volume) Factor
1000 10 B- AUS P -
1000 50 - B- AUS P
5000 50 Airline * -
5000 100 - B- 2 P
10000 100 - B- 3 P
100+ Airline**
* - Continuous Flow ** - Continuous-flow or positive pressure demand.
The local concentration of material, quantity and conditions of use determine the type of
personal protective equipment required.
Use appropriate NIOSH-certified respirator based on informed professional
judgement. In conditions where no reasonable estimate of exposure can be
made, assume the exposure is in a concentration IDLH and use NIOSH-certified
full face pressure demand SCBA with a minimum service life of 30 minutes, or
a combination full facepiece pressure demand SAR with auxiliary self-contained
air supply. Respirators provided only for escape from IDLH atmospheres shall be
NIOSH-certified for escape from the atmosphere in which they will be used.
ENGINEERING CONTROLS
General exhaust is adequate under normal operating conditions. If risk of overexposure
exists, wear SAA approved respirator. Correct fit is essential to obtain adequate
protection. Provide adequate ventilation in warehouse or closed storage areas.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL PROPERTIES
Liquid.
Mixes with water.
Molecular Weight: Not Applicable Boiling Range (掳 Not Av ailable
F):
Melting Range (掳 Not Available
F): Specific Gravity (water= 1): 1.128
Solubility in water (g/L): Miscible pH (as supplied): Not Available
pH (1% solution): Not Available Vapor Pressure (mmHg): Not Available
Volatile Component (%vol): Not Available Evaporation Rate: Not Available
Relative Vapor Density (air=1): Not Available Flash Point (掳 Not Applicable
F):
Lower Explosive Limit (%): Not Applicable Upper Explosive Limit (%): Not Applicable
Autoignition Temp (掳 Not Applicable
F): Decomposition Temp (掳 Not Available
F):
State: Liquid Viscosity: Not Available
APPEARANCE
Blue-green solution with no odour; mixes with water.
continued...
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Jun-7-2007 CHEMWATCH 4650-16
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CD 2007/2 Page 11 of 15
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
路 Presence of incompatible materials.
路 Product is considered stable.
路 Hazardous polymerisation will not occur.
STORAGE INCOMPATIBILITY
Avoid contamination of water, foodstuffs, feed or seed.
Avoid reaction with oxidising agents.
Section 11 - TOXICOLOGICAL INFORMATION
Freshwater/Saltwater Nitrite Test Solution
TOXICITY AND IRRITATION
The material may be irritating to the eye, with prolonged contact causing inflammation.
Repeated or prolonged exposure to irritants may produce conjunctivitis.
The material may cause skin irritation after prolonged or repeated exposure and may
produce a contact dermatitis (nonallergic). This form of dermatitis is often
characterised by skin redness (erythema) and swelling epidermis. Histologically there may
be intercellular oedema of the spongy layer (spongiosis) and intracellular oedema of the
epidermis.
POLYETHYLENE GLYCOL:
TOXICITY IRRITATION
Oral (rat) LD50: 33750 mg/kg Skin (rabbit): 500mg/24h - mild.
Eye (rabbit): 500mg/24h - mild.
for molecular weights (200-8000) *
Oral (rat) LD50: 31000->50000 mg/kg
Oral (mice) LD50: 38000->50000 mg/kg
Oral (g.pig) LD50: 17000->50000 mg/kg
Oral (rabbit) LD50: 14000->50000 mg/kg * AIHA WEEL Guides
Intraperitoneal (mice) LD50: 3100-12900 mg/kg
HYDROCHLORIC ACID:
TOXICITY IRRITATION
Unreported (man) LDLo: 81 mg/kg Eye (rabbit): 5mg/30s - Mild
Inhalation (human) LCLo: 1300 ppm/30 min
Inhalation (human) LCLo: 3000 ppm/5 min
Inhalation (rat) LC50: 3124 ppm/1h
Oral (rat) LD50: 900 mg/kg
The substance is classified by IARC as Group 3:
NOT classifiable as to its carcinogenicity to humans.
Evidence of carcinogenicity may be inadequate or limited in animal testing.
MATERIAL CARCINOGEN SENSITIZER SKIN MUTAGEN REPROTOXIN
______________________________ ____________ __________ __________ __________ __________
hydrochloric acid ACGIH:A4
CARCINOGEN
ACGIH: hydrochloric acid: A4
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CD 2007/2 Page 12 of 15
Section 12 - ECOLOGICAL INFORMATION
No data for Freshwater/Saltwater Nitrite Test Solution.
Refer to data for ingredients, which follows:
POLYETHYLENE GLYCOL:
BOD 5 if unstated: 0-0.02,1%
COD: 1.62-1.74,98%
Toxicity Fish: TLm(96)>10000mg/L
HYDROCHLORIC ACID:
Hazardous Air Pollutant: Yes
Fish LC50 (96hr.) (mg/l): 0.282
Prevent, by any means available, spillage from entering drains or water
courses.
DO NOT discharge into sewer or waterways.
Ecotoxicity
Fish LC100 (24 h): trout 10 mg/l
TLm (96 h): mosquito fish 282 ppm (fresh water)
LC50: goldfish 178 mg/l
Shrimp LC50 (48 h): 100 - 330 ppm (salt water)
Starfish LC50 (48 h): 100 - 330 mg/l
Cockle LC50 (48 h): 330 - 1000 mg/l
[Hach]
Hydrogen chloride in water dissociates almost completely, releasing
hydrogen and chloride ions; the hydrogen ions are captured by water to
produce hydronium ions.
Hydrochloric acid infiltrates soil, the rate dependent on moisture
content. During soil transport, hydrochloric acid dissolves soil
components.
Drinking water standard:
chloride: 400 mg/l (UK max.)
250 mg/l (WHO guideline)
Section 13 - DISPOSAL CONSIDERATIONS
Disposal Instructions
All waste must be handled in accordance with local, state and federal
regulations.
DO NOT allow wash water from cleaning or process equipment to enter drains.
It may be necessary to collect all wash water for treatment before disposal.
In all cases disposal to sewer may be subject to local laws and regulations and these
should be considered first. Where in doubt contact the responsible authority.
路 Recycle wherever possible or consult manufacturer for recycling options.
路 Consult State Land Waste Authority for disposal.
路 Bury or incinerate residue at an approved site.
路 Recycle containers if possible, or dispose of in an authorised landfill.
Legislation addressing waste disposal requirements may differ by country, state and/ or
territory. Each user must refer to laws operating in their area. In some areas, certain
wastes must be tracked.
A Hierarchy of Controls seems to be common - the user should investigate:
路 Reduction,
路 Reuse
路 Recycling
路 Disposal (if all else fails)
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CD 2007/2 Page 13 of 15
Section 13 - DISPOSAL CONSIDERATIONS
This material may be recycled if unused, or if it has not been contaminated so as to make
it unsuitable for its intended use. If it has been contaminated, it may be possible to
reclaim the product by filtration, distillation or some other means. Shelf life
considerations should also be applied in making decisions of this type. Note that
properties of a material may change in use, and recycling or reuse may not always be
appropriate.
Section 14 - TRANSPORTATION INFORMATION
NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS:UN, IATA,
IMDG
Section 15 - REGULATORY INFORMATION
REGULATIONS
US EPCRA Section 313 Chemical List For Reporting Year 2004
Ingredient CAS % de minimus
concentration
hydrochloric acid 7647- 01- 0 1.0
US CERCLA List of Hazardous Substances and Reportable Quantities
Ingredient CAS RQ (Pounds) RQ (KG)
hydrochloric acid 7647- 01- 0 5000 2270
polyethylene glycol (CAS: 25322-68-3) is found on the following regulatory lists;
Canada - British Columbia Occupational Exposure Limits
Canada - Saskatchewan Occupational Health and Safety Regulations - Contamination Limits
Canada Domestic Substances List (DSL)
IMO MARPOL 73/78 (Annex II) - List of Other Liquid Substances
US - Minnesota Hazardous Substance List
US Cosmetic Ingredient Review (CIR) Cosmetic ingredients found safe, with qualifications
US DOE Temporary Emergency Exposure Limits (TEELs)
US DOT Coast Guard Bulk Hazardous Materials - List of Flammable and Combustible Bulk
Liquid Cargoes
US EPA High Production Volume Program Chemical List
US Food Additive Database
US Premarket Notifications for Food Contact Substances
US Toxic Substances Control Act (TSCA) - Inventory
hydrochloric acid (CAS: 7647-01-0) is found on the following regulatory lists;
Canada - Alberta Ambient Air Quality Objectives
Canada - Alberta Occupational Exposure Limits
Canada - British Columbia Occupational Exposure Limits
Canada - Ontario Occupational Exposure Limits
Canada - Quebec Occupational Exposure Limits (French)
Canada - Saskatchewan Industrial Hazardous Substances
Canada - Saskatchewan Occupational Health and Safety Regulations - Contamination Limits
Canada - Yukon Permissible Concentrations for Airborne Contaminant Substances
Canada Controlled Drugs and Substances Act Schedule VI
Canada Domestic Substances List (DSL)
Canada Environmental Quality Guidelines (EQGs) Water: Community
Canada Ingredient Disclosure List (SOR/88-64)
Canada National Pollutant Release Inventory (NPRI)
Canada Prohibited Toxic Substances - Schedule 2: Concentration Limits (French)
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Section 15 - REGULATORY INFORMATION
Canada Prohibited Toxic Substances, Schedule 2, Concentration Limits (English)
CODEX General Standard for Food Additives (GSFA) - Additives Permitted for Use in Food
in General, Unless Otherwise Specified, in Accordance with GMP
IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk
International Agency for Research on Cancer (IARC) Carcinogens
International Council of Chemical Associations (ICCA) - High Production Volume List
International Maritime Dangerous Goods Requirements (IMDG Code) - Goods Forbidden for
Transport
Mexico Maximum Permissible Exposure Limits
OECD Representative List of High Production Volume (HPV) Chemicals
United Nations List of Precursors and Chemicals Frequently used in the Illicit
Manufacture of Narcotic Drugs and Psychotropic Substances Under International Control -
Table II
US - Arizona Ambient Air Quality Guidelines
US - California Air Toxics "Hot Spots" List (Assembly Bill 2588) Substances for which
emissions must be quantified
US - California Occupational Safety and Health Regulations (CAL/OSHA) - Hazardous
Substances List
US - California OEHHA/ARB - Acute Reference Exposure Levels and Target Organs (RELs)
US - California OEHHA/ARB - Chronic Reference Exposure Levels and Target Organs (CRELs)
US - California Permissible Exposure Limits for Chemical Contaminants
US - California Toxic Air Contaminant List Category II
US - Connecticut Hazardous Air Pollutants
US - Hawaii Air Contaminant Limits
US - Idaho - Limits for Air Contaminants
US - Minnesota Hazardous Substance List
US - Minnesota Permissible Exposure Limits (PELs)
US - New Jersey Right to Know Hazardous Substances
US - New Jersey Right to Know Hazardous Substances (Spanish)
US - Oregon Hazardous Materials
US - Rhode Island Hazardous Substance List
US - Tennessee Occupational Exposure Limits - Limits For Air Contaminants
US - Vermont Permissible Exposure Limits Table Z-1-A Final Rule Limits for Air
Contaminants
US - Vermont Permissible Exposure Limits Table Z-1-A Transitional Limits for Air
Contaminants
US - Washington Permissible exposure limits of air contaminants
US - Wisconsin Hazardous Air Contaminants With Acceptable Ambient Concentrations
US - Wyoming List of Highly Hazardous Chemicals, Toxics and Reactives
US ACGIH Carcinogens Listing
US ACGIH Threshold Limit Values (TLV)
US AIHA Emergency Response Planning Guides (ERPGs)
US CAA (Clean Air Act) 112 (r) List of Regulated Toxic & Flammable Substances and
Threshold Quantities for Accidental Release Prevention
US CERCLA List of Hazardous Substances and Reportable Quantities
US Clean Air Act - Hazardous Air Pollutants
US CWA (Clean Water Act) - List of Hazardous Substances
US CWA (Clean Water Act) - Reportable Quantities of Designated Hazardous Substances
US Department of Transportation (DOT) List of Hazardous Substances and Reportable
Quantities - Hazardous Substances Other Than Radionuclides
US DOE Temporary Emergency Exposure Limits (TEELs)
US Drug Enforcement Administration (DEA) List II or Essential Chemicals
US Drug Enforcement Administration (DEA) Thresholds for Regulated Transactions in List
II Chemicals
US EPA Acute Exposure Guideline Levels (AEGLs) - Final
US EPA Hazardous Substances
US EPA High Production Volume Chemicals Additional List
US EPA High Production Volume Program Chemical List
continued...
FRESHWATER/SALTWATER NITRITE TEST SOLUTION
Chemwatch Material Safety Data Sheet
Jun-7-2007 CHEMWATCH 4650-16
NB293ECP Version No:5
CD 2007/2 Page 15 of 15
Section 15 - REGULATORY INFORMATION
US EPA List of Regulated Toxic Substances and Threshold Quantities for Accidental
Release Prevention
US EPCRA Section 313 Chemical List For Reporting Year 2004
US Food Additive Database
US NFPA 45 Fire Protection for Laboratories Using Chemicals - Flammability
Characteristics of Common Compressed and Liquefied Gases
US NIOSH Recommended Exposure Limits (RELs)
US OSHA List of Highly Hazardous Chemicals, Toxics and Reactives
US OSHA Permissible Exposure Levels (PELs) - Table Z1
US SARA Section 302 Extremely Hazardous Substances
US Toxic Substances Control Act (TSCA) - Inventory
WHO Guidelines for Drinking-water Quality - Chemicals for which guideline values have
not been established
Section 16 - OTHER INFORMATION
Reasonable care has been taken in the preparation of this information, but the
author makes no warranty of merchantability or any other warranty, expressed or
implied, with respect to this information. The author makes no representations
and assumes no liability for any direct, incidental or consequential damages
resulting from its use. CHEMTREC: (800) 424- 9300
Issue Date: Jun-7-2007
Print Date: Jun-7-2007
Classification of the preparation and its individual components has drawn on official and
authoritative sources as well as independent review by the Chemwatch Classification
committee using available literature references.
This document is copyright. Apart from any fair dealing for the purposes of
private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from
CHEMWATCH. TEL (+61 3) 9572 4700.
LIQUID AMMONIA TEST SOLUTION #1
Chemwatch Material Safety Data Sheet
Jun-5-2007 CHEMWATCH 4650-12
NB293ECP Version No:4
CD 2007/2 Page 1 of 12
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
LIQUID AMMONIA TEST SOLUTION #1
STATEMENT OF HAZARDOUS NATURE
CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200.
SUPPLIER
Company: Aquarium Pharmaceuticals Inc Company: Aquarium Pharmaceuticals Inc
Address: Address:
PO Box 218 50 East Hamilton Street
Chalfont Chalfont
PA, 18914- 0218 PA, 18914
USA USA
Telephone: +1 215 822 8181 Telephone: +1 215 822 8181
Emergency Tel: +1800 222 1222 (US Only) Fax: +1 215 822 1906
PRODUCT USE
Ammonia test solution for product LR8600, 34 and 401M.
SYNONYMS
"Solution ID# 3335A"
Section 2 - HAZARDS IDENTIFICATION
CANADIAN WHMIS SYMBOLS
EMERGENCY OVERVIEW
RISK
Ingestion may produce health damage*.
Cumulative effects may result following exposure*.
Possible respiratory sensitizer*.
Possible skin sensitizer*.
May be harmful to the fetus/ embryo*.
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
Accidental ingestion of the material may be damaging to the health of the individual.
Large oral doses of salicylates may cause mild burning pain in the throat, stomach and
continued...
LIQUID AMMONIA TEST SOLUTION #1
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Section 2 - HAZARDS IDENTIFICATION
usually prompt vomiting. Several hours may elapse before the development of deep and
rapid breathing, lassitude, anorexia, nausea, vomiting, thirst and occasional diarrhoea.
Common derivatives of salicylic acid produce substantially the same toxic syndrome,
("salicylism"). Major signs and symptoms arise from stimulation and terminal depression
of the central nervous system. Stimulation produces vomiting, hyperpnea (abnormal
increase in rate and depth of respiration), headache, tinnitus (ringing in the ears)
confusion, bizarre behaviour or mania, generalised convulsions. Death is due to
respiratory failure or cardiovascular collapse. Severe sensory disturbances such as
deafness and dimness of vision are common. Less common features include sweating, skin
eruptions, gastrointestinal and other hemorrhages, renal failure and pancreatitis. A
tendency to bleed may be manifest by blood in the vomitus (haematemesis), bloody stools
(melena) or purplish-red spots (petechiae) on the skin. Many of the toxic effects
detailed here are due to or aggravated by severe disturbance of acid-base balance with
the chief cause being prolonged hyperventilation from central stimulation. An assessment
of acute salicylate intoxication based on dose suggests; 500 mg/mg: Potentially lethal.
EYE
Although the liquid is not thought to be an irritant (as classified by EC Directives),
direct contact with the eye may produce transient discomfort characterised by tearing or
conjunctival redness (as with windburn).
SKIN
The material is not thought to produce adverse health effects or skin irritation
following contact (as classified by EC Directives using animal models). Nevertheless,
good hygiene practice requires that exposure be kept to a minimum and that suitable
gloves be used in an occupational setting.
Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may
produce systemic injury with harmful effects. Examine the skin prior to the use of the
material and ensure that any external damage is suitably protected.
INHALED
The material is not thought to produce either adverse health effects or irritation of the
respiratory tract following inhalation (as classified by EC Directives using animal
models). Nevertheless, adverse systemic effects have been produced following exposure of
animals by at least one other route and good hygiene practice requires that exposure be
kept to a minimum and that suitable control measures be used in an occupational setting.
Not normally a hazard due to non-volatile nature of product.
Inhalation hazard is increased at higher temperatures.
CHRONIC HEALTH EFFECTS
Limited evidence suggests that repeated or long-term occupational exposure may produce
cumulative health effects involving organs or biochemical systems.
Limited evidence shows that inhalation of the material is capable of inducing a
sensitisation reaction in a significant number of individuals at a greater frequency than
would be expected from the response of a normal population.
Pulmonary sensitisation, resulting in hyperactive airway dysfunction and pulmonary
allergy may be accompanied by fatigue, malaise and aching. Significant symptoms of
exposure may persist for extended periods, even after exposure ceases. Symptoms can be
activated by a variety of nonspecific environmental stimuli such as automobile exhaust,
perfumes and passive smoking.
There exists limited evidence that shows that skin contact with the material is capable
either of inducing a sensitisation reaction in a significant number of individuals,
and/or of producing positive response in experimental animals.
There is some evidence that human exposure to the material may result in developmental
toxicity. This evidence is based on animal studies where effects have been observed in
the absence of marked maternal toxicity, or at around the same dose levels as other toxic
effects but which are not secondary non-specific consequences of the other toxic effects.
Chronic exposure to the salicylates (o-hydroxybenzoates) may produce metabolic and
central system disturbances or damage to the kidneys. Persons with pre-existing skin
continued...
LIQUID AMMONIA TEST SOLUTION #1
Chemwatch Material Safety Data Sheet
Jun-5-2007 CHEMWATCH 4650-12
NB293ECP Version No:4
CD 2007/2 Page 3 of 12
Section 2 - HAZARDS IDENTIFICATION
disorders, eye problems or impaired kidney function may be more susceptible to the
effects of these substances. Certain individuals (atopics), notably asthmatics, exhibit
significant hyper- sensitivity to salicylic acid derivatives. Reactions include urticaria
and other skin eruptions, rhinitis and severe (even fatal) bronchospasm and dyspnea.
Chronic exposure to the p-hydroxybenzoates (parabens) is associated with hypersensitivity
reactions following application of these to the skin. Hypersensitivity reactions have
also been reported following parenteral or oral administration. Cross-sensitivity occurs
between the p-hydroxybenzoates Hypersensitivity reactions may include by acute
bronchospasm, hives (urticaria), deep dermal wheals (angioneurotic oedema), running nose
(rhinitis) and blurred vision. Anaphylactic shock and skin rash (non- thrombocytopenic
purpura) may also occur. Any individual may be predisposed to such anti-body mediated
reaction if other chemical agents have caused prior sensitisation (cross-sensitivity).
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
polyethylene glycol 25322-68-3 <90
sodium salicylate 54-21-7 <10
Section 4 - FIRST AID MEASURES
SWALLOWED
路 If swallowed do NOT induce vomiting.
路 If vomiting occurs, lean patient forward or place on left side (head-down position, if
possible) to maintain open airway and prevent aspiration.
路 Observe the patient carefully.
路 Never give liquid to a person showing signs of being sleepy or with reduced awareness;
i.e. becoming unconscious.
路 Give water to rinse out mouth, then provide liquid slowly and as much as casualty can
comfortably drink.
路 Seek medical advice.
EYE
If this product comes in contact with the eyes:
路 Wash out immediately with fresh running water.
路 Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and
moving the eyelids by occasionally lifting the upper and lower lids.
路 If pain persists or recurs seek medical attention.
路 Removal of contact lenses after an eye injury should only be undertaken by skilled
personnel.
SKIN
If skin contact occurs:
路 Immediately remove all contaminated clothing, including footwear.
路 Flush skin and hair with running water (and soap if available).
路 Seek medical attention in event of irritation.
INHALED
路 If fumes or combustion products are inhaled remove from contaminated area.
路 Other measures are usually unnecessary.
NOTES TO PHYSICIAN
Treat symptomatically.
for salicylate intoxication:
路 Pending gastric lavage, use emetics such as syrup of Ipecac or delay gastric emptying
and absorption by swallowing a slurry of activated charcoal. Do not give ipecac after
continued...
LIQUID AMMONIA TEST SOLUTION #1
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Section 4 - FIRST AID MEASURES
charcoal.
路 Gastric lavage with water or perhaps sodium bicarbonate solution (3%-5%). Mild alkali
delays salicylate absorption from the stomach and perhaps slightly from the duodenum.
路 Saline catharsis with sodium or magnesium sulfate (15-30 gm in water).
路 Take an immediate blood sample for an appraisal of the patient's acid-base status. A pH
determination on an anaerobic sample of arterial blood is best. An analysis of the plasma
salicylate concentration should be made at the same time. Laboratory controls are almost
essential for the proper management of severe salicylism.
路 In the presence of an established acidosis, alkali therapy is essential, but at least
in an adult, alkali should be withheld until its need is demonstrated by chemical
analysis. The intensity of treatment depends on the intensity of acidosis. In the
presence of vomiting, intravenous sodium bicarbonate is the most satisfactory of all
alkali therapy.
路 Correct dehydration and hypoglycaemia (if present) by the intravenous administration of
glucose in water or in isotonic saline. The administration of glucose may also serve to
remedy ketosis which is often seen in poisoned children.
路 Even in patients without hypoglycaemia, infusions of glucose adequate to produce
distinct hyperglycaemia are recommended to prevent glucose depletion in the brain. This
recommendation is based on impressive experimental data in animals.
路 Renal function should be supported by correcting dehydration and incipient shock.
Overhydration is not justified. An alkaline urine should be maintained by the
administration of alkali if necessary with care to prevent a severe systemic alkalosis.
As long as urine remains alkaline (pH above 7.5), administration of an osmotic diuretic
such as mannitol or perhaps THAM is useful, but one must be careful to avoid
hypokalaemia. Supplements of potassium chloride should be included in parenteral fluids.
路 Small doses of barbiturates, diazepam, paraldehyde, or perhaps other sedatives (but
probably not morphine) may be required to suppress extreme restlessness and convulsions.
路 For hyperpyrexia, use sponge baths.
The presence of petechiae or other signs of haemorrhagic tendency calls for a large
Vitamin K dose and perhaps ascorbic acid. Minor transfusions may be necessary since
bleeding in salicylism is not always due to a prothrombin effect.
路 Haemodialysis and haemoperfusion have proved useful in salicylate poisoning, as have
peritoneal dialysis and exchange transfusions, but alkaline diuretic therapy is probably
sufficient except in fulminating cases.
[GOSSELIN, et.al.: Clinical Toxicology of Commercial Products]
The mechanism of the toxic effect involves metabolic acidosis, respiratory alkalosis,
hypoglycaemia, and potassium depletion. Salicylate poisoning is characterised by extreme
acid-base disturbances, electrolyte disturbances and decreased levels of consciousness.
There are differences between acute and chronic toxicity and a varying clinical picture
which is dependent on the age of the patient and their kidney function. The major feature
of poisoning is metabolic acidosis due to "uncoupling of oxidative phosphorylation" which
produces an increased metabolic rate, increased oxygen consumption, increased formation
of carbon dioxide, increased heat production and increased utilisation of glucose. Direct
stimulation of the respiratory centre leads to hyperventilation and respiratory
alkalosis. This leads to compensatory increased renal excretion of bicarbonate which
contributes to the metabolic acidosis which may coexist or develop subsequently.
Hypoglycaemia may occur as a result of increased glucose demand, increased rates of
tissue glycolysis, and impaired rate of glucose synthesis. NOTE: Tissue glucose levels
may be lower than plasma levels. Hyperglycaemia may occur due to increased
glycogenolysis. Potassium depletion occurs as a result of increased renal excretion as
well as intracellular movement of potassium.
Salicylates competitively inhibit vitamin K dependent synthesis of factors II, VII, IX, X
and in addition, may produce a mild dose dependent hepatitis. Salicylates are bound to
albumin. The extent of protein binding is concentration dependent (and falls with higher
blood levels). This, and the effects of acidosis, decreasing ionisation, means that the
volume of distribution increases markedly in overdose as does CNS penetration. The extent
of protein binding (50-80%) and the rate of metabolism are concentration dependent.
Hepatic clearance has zero order kinetics and thus the therapeutic half-life of 2-4.5
hours but the half-life in overdose is 18-36 hours. Renal excretion is the most important
continued...
LIQUID AMMONIA TEST SOLUTION #1
Chemwatch Material Safety Data Sheet
Jun-5-2007 CHEMWATCH 4650-12
NB293ECP Version No:4
CD 2007/2 Page 5 of 12
Section 4 - FIRST AID MEASURES
route in overdose. Thus when the salicylate concentrations are in the toxic range there
is increased tissue distribution and impaired clearance of the drug.
HyperTox 3.0 http://www.ozemail.com.au/-ouad/SALI0001.HTA.
Section 5 - FIRE FIGHTING MEASURES
Flash Point (掳 Not Applicable
F):
Lower Explosive Limit (%): Not Applicable
Upper Explosive Limit (%): Not Applicable
Autoignition Temp (掳 Not Applicable
F):
EXTINGUISHING MEDIA
路 Water spray or fog.
路 Foam.
路 Dry chemical powder.
路 BCF (where regulations permit).
路 Carbon dioxide.
FIRE FIGHTING
路 Alert Fire Brigade and tell them location and nature of hazard.
路 Wear full body protective clothing with breathing apparatus.
路 Prevent, by any means available, spillage from entering drains or water course.
路 Use water delivered as a fine spray to control fire and cool adjacent area.
路 Avoid spraying water onto liquid pools.
路 DO NOT approach containers suspected to be hot.
路 Cool fire exposed containers with water spray from a protected location.
路 If safe to do so, remove containers from path of fire.
GENERAL FIRE HAZARDS/HAZARDOUS COMBUSTIBLE PRODUCTS
路 Combustible.
路 Slight fire hazard when exposed to heat or flame.
路 Heating may cause expansion or decomposition leading to violent rupture of containers.
路 On combustion, may emit toxic fumes of carbon monoxide (CO).
路 May emit acrid smoke.
路 Mists containing combustible materials may be explosive.
Combustion products include: carbon dioxide (CO2), other pyrolysis products typical of
burning organic material.
May emit poisonous fumes.
May emit corrosive fumes.
FIRE INCOMPATIBILITY
Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine
bleaches, pool chlorine etc. as ignition may result.
PERSONAL PROTECTION
Glasses:
Safety Glasses.
Chemical goggles.
Gloves:
PVC chemical resistant type.
Respirator:
continued...
LIQUID AMMONIA TEST SOLUTION #1
Chemwatch Material Safety Data Sheet
Jun-5-2007 CHEMWATCH 4650-12
NB293ECP Version No:4
CD 2007/2 Page 6 of 12
Section 6 - ACCIDENTAL RELEASE MEASURES
MINOR SPILLS
路 Remove all ignition sources.
路 Clean up all spills immediately.
路 Avoid breathing vapours and contact with skin and eyes.
路 Control personal contact by using protective equipment.
路 Contain and absorb spill with sand, earth, inert material or vermiculite.
路 Wipe up.
路 Place in a suitable labelled container for waste disposal.
MAJOR SPILLS
Moderate hazard.
路 Clear area of personnel and move upwind.
路 Alert Fire Brigade and tell them location and nature of hazard.
路 Wear breathing apparatus plus protective gloves.
路 Prevent, by any means available, spillage from entering drains or water course.
路 No smoking, naked lights or ignition sources.
路 Increase ventilation.
路 Stop leak if safe to do so.
路 Contain spill with sand, earth or vermiculite.
路 Collect recoverable product into labelled containers for recycling.
路 Absorb remaining product with sand, earth or vermiculite.
路 Collect solid residues and seal in labelled drums for disposal.
路 Wash area and prevent runoff into drains.
路 If contamination of drains or waterways occurs, advise emergency services.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
DO NOT allow clothing wet with material to stay in contact with skin.
DO NOT USE brass or copper containers / stirrers.
路 Avoid all personal contact, including inhalation.
路 Wear protective clothing when risk of exposure occurs.
路 Use in a well-ventilated area.
路 Prevent concentration in hollows and sumps.
路 DO NOT enter confined spaces until atmosphere has been checked.
路 Avoid smoking, naked lights or ignition sources.
路 Avoid contact with incompatible materials.
路 When handling, DO NOT eat, drink or smoke.
路 Keep containers securely sealed when not in use.
路 Avoid physical damage to containers.
路 Always wash hands with soap and water after handling.
路 Work clothes should be laundered separately.
路 Use good occupational work practice.
路 Observe manufacturer's storing and handling recommendations.
路 Atmosphere should be regularly checked against established exposure standards to
ensure safe working conditions.
RECOMMENDED STORAGE METHODS
路 Metal can or drum
路 Packaging as recommended by manufacturer.
路 Check all containers are clearly labelled and free from leaks.
continued...
LIQUID AMMONIA TEST SOLUTION #1
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CD 2007/2 Page 7 of 12
Section 7 - HANDLING AND STORAGE
STORAGE REQUIREMENTS
路 Store in original containers.
路 Keep containers securely sealed.
路 No smoking, naked lights or ignition sources.
路 Store in a cool, dry, well-ventilated area.
路 Store away from incompatible materials and foodstuff containers.
路 Protect containers against physical damage and check regularly for leaks.
路 Observe manufacturer's storing and handling recommendations.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
Source Material TWA ppm TWA mg/m鲁 STEL ppm STEL mg/m鲁Peak ppm Peak mg/m鲁 TWA F/CC
_________ _________ _____ _____ _____ _____ _____ _____ _____
Canada - polyethyle 3 6
Saskatchew ne glycol
an (Respirabl
Occupation e size+)
al Health
and Safety
Regulation
s-
Contaminat
ion Limits
Canada - polyethyle 10 20
Saskatchew ne glycol
an (Particula
Occupation tes,
al Health NOC++)
and Safety
Regulation
s-
Contaminat
ion Limits
Canada - polyethyle 10
British ne glycol
Columbia (Particles
Occupation
al (Insoluble
Exposure or Poorly
Limits Soluble)
Not
Otherwise
Classified
(PNOC))
The following materials had no OELs on our records
鈥? sodium salicylate: CAS:54- 21- 7
MATERIAL DATA
Not available. Refer to individual constituents.
INGREDIENT DATA
POLYETHYLENE GLYCOL:
continued...
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Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
For powdered forms:
The polyethylene glycols are extremely low in oral toxicity, are not
significantly irritating to the eyes or skin, and are not absorbed
through the skin in toxic amounts. vapour pressures are extremely low and
inhalation exposure is limited to mists. Based on experimental data and
human experience, these substances do not present significant hazards to
health in the workplace.
SODIUM SALICYLATE:
CEL TWA: 5 mg/m3 [as analogue for asprin]
PERSONAL PROTECTION
EYE
路 Safety glasses with side shields.
路 Chemical goggles.
路 Contact lenses may pose a special hazard; soft contact lenses may absorb and
concentrate irritants. A written policy document, describing the wearing of lens or
restrictions on use, should be created for each workplace or task. This should include a
review of lens absorption and adsorption for the class of chemicals in use and an account
of injury experience. Medical and first-aid personnel should be trained in their removal
and suitable equipment should be readily available. In the event of chemical exposure,
begin eye irrigation immediately and remove contact lens as soon as practicable. Lens
should be removed at the first signs of eye redness or irritation - lens should be
removed in a clean environment only after workers have washed hands thoroughly. [CDC
NIOSH Current Intelligence Bulletin 59].
HANDS/FEET
Wear chemical protective gloves, eg. PVC.
Wear safety footwear or safety gumboots, eg. Rubber.
NOTE: The material may produce skin sensitisation in predisposed individuals. Care must
be taken, when removing gloves and other protective equipment, to avoid all possible skin
contact.
Suitability and durability of glove type is dependent on usage. Factors such as:
路 frequency and duration of contact,
路 chemical resistance of glove material,
路 glove thickness and
路 dexterity,
are important in the selection of gloves.
OTHER
路 Overalls.
路 P.V.C. apron.
路 Barrier cream.
路 Skin cleansing cream.
路 Eye wash unit.
The local concentration of material, quantity and conditions of use determine the type of
personal protective equipment required.
Use appropriate NIOSH-certified respirator based on informed professional
judgement. In conditions where no reasonable estimate of exposure can be
made, assume the exposure is in a concentration IDLH and use NIOSH-certified
full face pressure demand SCBA with a minimum service life of 30 minutes, or
a combination full facepiece pressure demand SAR with auxiliary self-contained
air supply. Respirators provided only for escape from IDLH atmospheres shall be
NIOSH-certified for escape from the atmosphere in which they will be used.
continued...
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Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS
General exhaust is adequate under normal operating conditions. If risk of overexposure
exists, wear SAA approved respirator. Correct fit is essential to obtain adequate
protection. Provide adequate ventilation in warehouse or closed storage areas.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL PROPERTIES
Liquid.
Mixes with water.
Molecular Weight: Not Applicable Boiling Range (掳 Not Av ailable
F):
Melting Range (掳 Not Available
F): Specific Gravity (water= 1): 1.152
Solubility in water (g/L): Miscible pH (as supplied): 8.3
pH (1% solution): Not Available Vapor Pressure (mmHg): Not Available
Volatile Component (%vol): Not Available Evaporation Rate: Not Available
Relative Vapor Density (air=1): Not Available Flash Point (掳 Not Applicable
F):
Lower Explosive Limit (%): Not Applicable Upper Explosive Limit (%): Not Applicable
Autoignition Temp (掳 Not Applicable
F): Decomposition Temp (掳 Not Available
F):
State: Liquid Viscosity: Not Available
APPEARANCE
Reddish-orange liquid with a mild odour; mixes with water.
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
路 Presence of incompatible materials.
路 Product is considered stable.
路 Hazardous polymerisation will not occur.
STORAGE INCOMPATIBILITY
Avoid reaction with oxidising agents.
Section 11 - TOXICOLOGICAL INFORMATION
Liquid Ammonia Test Solution #1
TOXICITY AND IRRITATION
The material may be irritating to the eye, with prolonged contact causing inflammation.
Repeated or prolonged exposure to irritants may produce conjunctivitis.
The material may cause skin irritation after prolonged or repeated exposure and may
produce a contact dermatitis (nonallergic). This form of dermatitis is often
characterised by skin redness (erythema) and swelling epidermis. Histologically there may
be intercellular oedema of the spongy layer (spongiosis) and intracellular oedema of the
epidermis.
POLYETHYLENE GLYCOL:
TOXICITY IRRITATION
Oral (rat) LD50: 33750 mg/kg Skin (rabbit): 500mg/24h - mild.
Eye (rabbit): 500mg/24h - mild.
for molecular weights (200-8000) *
continued...
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Section 11 - TOXICOLOGICAL INFORMATION
Oral (rat) LD50: 31000->50000 mg/kg
Oral (mice) LD50: 38000->50000 mg/kg
Oral (g.pig) LD50: 17000->50000 mg/kg
Oral (rabbit) LD50: 14000->50000 mg/kg * AIHA WEEL Guides
Intraperitoneal (mice) LD50: 3100-12900 mg/kg
SODIUM SALICYLATE:
TOXICITY IRRITATION
Oral (human) LDLo: 700 mg/kg Nil Reported
Oral (rat) LD50: 1200 mg/kg
Intraperitoneal (rat) LD50: 542 mg/kg
Subcutaneous (rat) LD50: 980 mg/kg
Exposure to the material for prolonged periods may cause physical defects in the
developing embryo (teratogenesis).
Section 12 - ECOLOGICAL INFORMATION
DO NOT discharge into sewer or waterways.
Refer to data for ingredients, which follows:
POLYETHYLENE GLYCOL:
BOD 5 if unstated: 0-0.02,1%
COD: 1.62-1.74,98%
Toxicity Fish: TLm(96)>10000mg/L
Section 13 - DISPOSAL CONSIDERATIONS
Disposal Instructions
All waste must be handled in accordance with local, state and federal
regulations.
DO NOT allow wash water from cleaning or process equipment to enter drains.
It may be necessary to collect all wash water for treatment before disposal.
In all cases disposal to sewer may be subject to local laws and regulations and these
should be considered first. Where in doubt contact the responsible authority.
路 Recycle wherever possible or consult manufacturer for recycling options.
路 Consult State Land Waste Authority for disposal.
路 Bury or incinerate residue at an approved site.
路 Recycle containers if possible, or dispose of in an authorised landfill.
Legislation addressing waste disposal requirements may differ by country, state and/ or
territory. Each user must refer to laws operating in their area. In some areas, certain
wastes must be tracked.
A Hierarchy of Controls seems to be common - the user should investigate:
路 Reduction,
路 Reuse
路 Recycling
路 Disposal (if all else fails)
This material may be recycled if unused, or if it has not been contaminated so as to make
it unsuitable for its intended use. If it has been contaminated, it may be possible to
reclaim the product by filtration, distillation or some other means. Shelf life
considerations should also be applied in making decisions of this type. Note that
properties of a material may change in use, and recycling or reuse may not always be
appropriate.
continued...
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CD 2007/2 Page 11 of 12
Section 14 - TRANSPORTATION INFORMATION
NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS:UN, IATA,
IMDG
Section 15 - REGULATORY INFORMATION
REGULATIONS
polyethylene glycol (CAS: 25322-68-3) is found on the following regulatory lists;
Canada - British Columbia Occupational Exposure Limits
Canada - Saskatchewan Occupational Health and Safety Regulations - Contamination Limits
Canada Domestic Substances List (DSL)
IMO MARPOL 73/78 (Annex II) - List of Other Liquid Substances
US - Minnesota Hazardous Substance List
US Cosmetic Ingredient Review (CIR) Cosmetic ingredients found safe, with qualifications
US DOE Temporary Emergency Exposure Limits (TEELs)
US DOT Coast Guard Bulk Hazardous Materials - List of Flammable and Combustible Bulk
Liquid Cargoes
US EPA High Production Volume Program Chemical List
US Food Additive Database
US Premarket Notifications for Food Contact Substances
US Toxic Substances Control Act (TSCA) - Inventory
sodium salicylate (CAS: 54-21-7) is found on the following regulatory lists;
Canada Domestic Substances List (DSL)
Canada Environmental Quality Guidelines (EQGs) Water: Aquatic life
IMO MARPOL 73/78 (Annex II) - List of Other Liquid Substances
US - California Occupational Safety and Health Regulations (CAL/OSHA) - Hazardous
Substances List
US Cosmetic Ingredient Review (CIR) Cosmetic ingredients found safe, with qualifications
US DOE Temporary Emergency Exposure Limits (TEELs)
US EPA High Production Volume Program Chemical List
US Toxic Substances Control Act (TSCA) - Inventory
Section 16 - OTHER INFORMATION
LIMITED EVIDENCE
Ingestion may produce health damage*.
Cumulative effects may result following exposure*.
Possible respiratory sensitiser*.
Possible skin sensitiser*.
May be harmful to the foetus/ embryo*.
* (limited evidence).
EXPOSURE STANDARD FOR MIXTURES
"Worst Case" computer-aided prediction of spray/ mist or fume/ dust components and
concentration:
Composite Exposure Standard for Mixture (TWA) :5 mg/m鲁.
Operations which produce a spray/mist or fume/dust, introduce particulates to the
breathing zone.
If the breathing zone concentration of ANY of the components listed below is exceeded,
continued...
LIQUID AMMONIA TEST SOLUTION #1
Chemwatch Material Safety Data Sheet
Jun-5-2007 CHEMWATCH 4650-12
NB293ECP Version No:4
CD 2007/2 Page 12 of 12
Section 16 - OTHER INFORMATION
"Worst Case" considerations deem the individual to be overexposed.
Component Breathing Zone ppm Breathing Zone mg/m3 Mixture Conc (%).
Component Breathing Zone Mixture Conc
(mg/m鲁) (%)
sodium salicylate 5.0000 10.0
Reasonable care has been taken in the preparation of this information, but the
author makes no warranty of merchantability or any other warranty, expressed or
implied, with respect to this information. The author makes no representations
and assumes no liability for any direct, incidental or consequential damages
resulting from its use. CHEMTREC: (800) 424- 9300
Issue Date: Jun-5-2007
Print Date: Jun-5-2007
This document is copyright. Apart from any fair dealing for the purposes of
private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from
CHEMWATCH. TEL (+61 3) 9572 4700.
LIQUID AMMONIA TEST SOLUTION #2
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-9
Issue Date: Mon 3-Oct-2005 CD 2005/3 Page 1 of 15
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
LIQUID AMMONIA TEST SOLUTION #2
STATEMENT OF HAZARDOUS NATURE
CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR
1910.1200.
SUPPLIER
Company: Aquarium Pharmaceuticals Incorporated Company: Aquarium Pharmaceuticals Incorporated
Address: Address:
50 East Hamilton Street PO Box 218
Chalfont Chalfont
PA, 18914 PA, 18914-0218
USA USA
Telephone: +1 215 822 8181 Telephone: +1 215 822 8181
Emergency Tel: +1800 222 1222 (US Only)
PRODUCT USE
Ammonia test solution for product LR8600, 34 and 401M.
SYNONYMS
"Solution ID# 3335B"
Section 2 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
sodium hydroxide 1310-73-2 <10
sodium hypochlorite 7681-52-9 <1
Section 3 - HAZARDS IDENTIFICATION
CANADIAN WHMIS SYMBOLS
EMERGENCY OVERVIEW
RISK
Causes severe burns.
Risk of serious damage to eyes.
Harmful to aquatic organisms.
Ingestion may produce health damage*.
*(limited evidence)
continued...
LIQUID AMMONIA TEST SOLUTION #2
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-9
Issue Date: Mon 3-Oct-2005 CD 2005/3 Page 2 of 15
Section 3 - HAZARDS IDENTIFICATION
Cumulative effects may result following exposure*.
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
Accidental ingestion of the material may be damaging to the health of the
individual.
The material can produce severe chemical burns within the oral cavity and
gastrointestinal tract following ingestion.
Ingestion of alkaline corrosives may produce burns around the mouth, ulcerations
and swellings of the mucous membranes, profuse saliva production, with an
inability to speak or swallow. Both the esophagus and stomach may experience
burning pain; vomiting and diarrhea may follow. Epiglottal swelling may result
in respiratory distress and asphyxia; shock can occur. Narrowing of the
esophagus, stomach or stomach valve may occur immediately or after a long delay
(weeks to years). Severe exposure can perforate the esophagus or stomach leading
to infections of the chest or abdominal cavity, with low chest pain, abdominal
stiffness and fever. All of the above can cause death.
EYE
The material can produce severe chemical burns to the eye following direct
contact. Vapors or mists may be extremely irritating.
If applied to the eyes, this material causes severe eye damage.
Direct eye contact with corrosive bases can cause pain and burns. There may be
swelling, epithelium destruction, clouding of the cornea and inflammation of the
iris. Mild cases often resolve; severe cases can be prolonged with complications
such as persistent swelling, scarring, permanent cloudiness, bulging of the eye,
cataracts, eyelids glued to the eyeball and blindness.
SKIN
The material can produce severe chemical burns following direct contact
with the skin.
Skin contact with alkaline corrosives may produce severe pain and burns;
brownish stains may develop. The corroded area may be soft, gelatinous and
necrotic; tissue destruction may be deep.
Entry into the blood-stream, through, for example, cuts, abrasions or lesions,
may produce systemic injury with harmful effects. Examine the skin prior to the
use of the material and ensure that any external damage is suitably protected.
INHALED
If inhaled, this material can irritate the throat and
lungs of some persons.
Inhaling corrosive bases may irritate the respiratory tract. Symptoms include
cough, choking, pain and damage to the mucous membrane. In severe cases, lung
swelling may develop, sometimes after a delay of hours to days. There may be low
blood pressure, a weak and rapid pulse, and crackling sounds.
CHRONIC HEALTH EFFECTS
Repeated or prolonged exposure to corrosives may result in the erosion of teeth,
inflammatory and ulcerative changes in the mouth and necrosis (rarely) of the
jaw. Bronchial irritation, with cough, and frequent attacks of bronchial
pneumonia may ensue. Gastrointestinal disturbances may also occur. Chronic
exposures may result in dermatitis and/or conjunctivitis. Substance
continued...
LIQUID AMMONIA TEST SOLUTION #2
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-9
Issue Date: Mon 3-Oct-2005 CD 2005/3 Page 3 of 15
Section 3 - HAZARDS IDENTIFICATION
accumulation, in the human body, may occur and may cause some concern following
repeated or long-term occupational exposure.
Section 4 - FIRST AID MEASURES
SWALLOWED
- For advice, contact a Poisons Information Center or a doctor at once.
- Urgent hospital treatment is likely to be needed.
- If swallowed do NOT induce vomiting.
- If vomiting occurs, lean patient forward or place on left side (head-down
position, if possible) to maintain open airway and prevent aspiration.
- Observe the patient carefully.
- Never give liquid to a person showing signs of being sleepy or with reduced
awareness; i.e. becoming unconscious.
- Give water to rinse out mouth, then provide liquid slowly and as much as
casualty can comfortably drink.
- Transport to hospital or doctor without delay.
EYE
If this product comes in contact with the eyes:
- Immediately hold eyelids apart and flush the eye continuously with running
water.
- Ensure complete irrigation of the eye by keeping eyelids apart and away from
eye and moving the eyelids by occasionally lifting the upper and lower lids.
- Continue flushing until advised to stop by the Poisons Information Center or a
doctor, or for at least 15 minutes.
- Transport to hospital or doctor without delay.
- Removal of contact lenses after an eye injury should only be undertaken by
skilled personnel.
SKIN
If skin or hair contact occurs:
- Immediately flush body and clothes with large amounts of water, using safety
shower if available.
- Quickly remove all contaminated clothing, including footwear.
- Wash skin and hair with running water. Continue flushing with water until
advised to stop by the Poisons Information Center.
- Transport to hospital, or doctor.
INHALED
- If fumes or combustion products are inhaled remove from contaminated area.
- Lay patient down. Keep warm and rested.
- Prostheses such as false teeth, which may block airway, should be removed,
where possible, prior to initiating first aid procedures.
- Apply artificial respiration if not breathing, preferably with a demand valve
resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if
necessary.
- Transport to hospital, or doctor, without delay.
NOTES TO PHYSICIAN
For acute or short-term repeated exposures to highly alkaline materials:
- Respiratory stress is uncommon but present occasionally because of soft tissue
edema.
- Unless endotracheal intubation can be accomplished under direct vision,
continued...
LIQUID AMMONIA TEST SOLUTION #2
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-9
Issue Date: Mon 3-Oct-2005 CD 2005/3 Page 4 of 15
Section 4 - FIRST AID MEASURES
cricothyroidotomy or tracheotomy may be necessary.
- Oxygen is given as indicated.
- The presence of shock suggests perforation and mandates an intravenous line
and fluid administration.
- Damage due to alkaline corrosives occurs by liquefaction necrosis whereby the
saponification of fats and solubilization of proteins allow deep penetration
into the tissue.
Alkalis continue to cause damage after exposure.
INGESTION:
- Milk and water are the preferred diluents
No more than 2 glasses of water should be given to an adult.
- Neutralizing agents should never be given since exothermic heat reaction may
compound injury.
* Catharsis and emesis are absolutely contra-indicated.
* Activated charcoal does not absorb alkali.
* Gastric lavage should not be used.
Supportive care involves the following:
- Withhold oral feedings initially.
- If endoscopy confirms transmucosal injury start steroids only within the first
48 hours.
- Carefully evaluate the amount of tissue necrosis before assessing the need for
surgical intervention.
- Patients should be instructed to seek medical attention whenever they develop
difficulty in swallowing (dysphagia).
SKIN AND EYE:
- Injury should be irrigated for 20-30 minutes.
- Eye injuries require saline. [Ellenhorn & Barceloux: Medical Toxicology].
Section 5 - FIRE FIGHTING MEASURES
Flash Point (掳F): Not Applicable
Lower Explosive Limit (%): Not Applicable
Upper Explosive Limit (%): Not Applicable
Autoignition Temp (掳F): Not Applicable
EXTINGUISHING MEDIA
- Water spray or fog.
- Foam.
- Dry chemical powder.
- BCF (where regulations permit).
- Carbon dioxide.
FIRE FIGHTING
- Alert Emergency Responders and tell them location and nature of hazard.
- Wear full body protective clothing with breathing apparatus.
- Prevent, by any means available, spillage from entering drains or water
course.
- Use fire fighting procedures suitable for surrounding area.
- DO NOT approach containers suspected to be hot.
- Cool fire exposed containers with water spray from a protected location.
- If safe to do so, remove containers from path of fire.
- Equipment should be thoroughly decontaminated after use.
continued...
LIQUID AMMONIA TEST SOLUTION #2
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-9
Issue Date: Mon 3-Oct-2005 CD 2005/3 Page 5 of 15
Section 5 - FIRE FIGHTING MEASURES
When any large container (including road and rail tankers) is involved in a fire,
consider evacuation by 2625 feet in all directions.
GENERAL FIRE HAZARDS/HAZARDOUS COMBUSTIBLE PRODUCTS
- Non combustible.
- Not considered to be a significant fire risk, however containers may burn.
May emit corrosive fumes.
FIRE INCOMPATIBILITY
None known.
Section 6 - ACCIDENTAL RELEASE MEASURES
MINOR SPILLS
- Clean up all spills immediately.
- Avoid breathing vapors and contact with skin and eyes.
- Control personal contact by using protective equipment.
- Contain and absorb spill with sand, earth, inert material or vermiculite.
- Wipe up.
- Place in a suitable labeled container for waste disposal.
MAJOR SPILLS
- Clear area of personnel and move upwind.
- Alert Emergency Responders and tell them location and nature of hazard.
- Wear full body protective clothing with breathing apparatus.
- Prevent, by any means available, spillage from entering drains or water
course.
- Consider evacuation.
- Stop leak if safe to do so.
- Contain spill with sand, earth or vermiculite.
- Collect recoverable product into labeled containers for recycling.
- Neutralize/decontaminate residue.
- Collect solid residues and seal in labeled drums for disposal.
- Wash area and prevent runoff into drains.
- After clean up operations, decontaminate and launder all protective clothing
and equipment before storing and re-using.
- If contamination of drains or waterways occurs, advise emergency services.
PROTECTIVE ACTIONS FOR SPILL
PROTECTIVE ACTION ZONE
half
evacuation
downwind
direction
distance
down wind distance
wind isolation
distance
direction
half
evacuation downwind
INITIAL direction distance
ISOLATION
ZONE
From IERG (Canada/Australia)
continued...
LIQUID AMMONIA TEST SOLUTION #2
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-9
Issue Date: Mon 3-Oct-2005 CD 2005/3 Page 6 of 15
Section 6 - ACCIDENTAL RELEASE MEASURES
Isolation Distance 25 meters
Downwind Protection Distance 250 meters
FOOTNOTES
1 PROTECTIVE ACTION ZONE is defined as the area in which people are at risk
of harmful exposure. This zone assumes that random changes in wind direction
confines the vapour plume to an area within 30 degrees on either side of the
predominant wind direction, resulting in a crosswind protective action distance
equal to the downwind protective action distance.
2 PROTECTIVE ACTIONS should be initiated to the extent possible, beginning with
those closest to the spill and working away from the site in the downwind
direction. Within the protective action zone a level of vapour concentration
may exist resulting in nearly all unprotected persons becoming incapacitated
and unable to take protective action and/or incurring serious or irreversible
health effects.
3 INITIAL ISOLATION ZONE is determined as an area, including upwind of the
incident, within which a high probability of localised wind reversal may
expose nearly all persons without appropriate protection to life-threatening
concentrations of the material.
4 SMALL SPILLS involve a leaking package of 200 litres (55 US gallons) or less,
such as a drum (jerrican or box with inner containers). Larger packages leaking
less than 200 litres and compressed gas leaking from a small cylinder are also
considered "small spills".
LARGE SPILLS involve many small leaking packages or a leaking package of
greater than 200 litres, such as a cargo tank, portable tank or a "one-tonne"
compressed gas cylinder.
5 Guide 154 is taken from the US DOT emergency response guide book.
6 IERG information is derived from CANUTEC - Transport Canada.
ACUTE EXPOSURE GUIDELINE LEVELS (AEGL) (in ppm)
AEGL 1: The airborne concentration of a substance above which it is predicted
that the general population, including susceptible individuals, could
experience notable discomfort, irritation, or certain asymptomatic nonsensory
effects. However, the effects are not disabling and are transient and
reversible upon cessation of exposure.
AEGL 2: The airborne concentration of a substance above which it is predicted
that the general population, including susceptible individuals, could
experience irreversible or other serious, long-lasting adverse health effects
or an impaired ability to escape.
AEGL 3: The airborne concentration of a substance above which it is predicted
that the general population, including susceptible individuals, could
experience life-threatening health effects or death.
EMERGENCY RESPONSE PLANNING GUIDELINES (ERPG)
The maximum airborne concentration below which it is believed that nearly all
individuals could be exposed for up to one hour WITHOUT experiencing or developing
life-threatening health effects is:
sodium hydroxide 50 mg/m鲁
sodium hypochlorite 500 mg/m鲁
irreversible or other serious effects or symptoms which could
impair an individual's ability to take protective action is:
continued...
LIQUID AMMONIA TEST SOLUTION #2
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-9
Issue Date: Mon 3-Oct-2005 CD 2005/3 Page 7 of 15
Section 6 - ACCIDENTAL RELEASE MEASURES
sodium hydroxide 5 mg/m鲁
sodium hypochlorite 500 mg/m鲁
other than mild, transient adverse effects
without perceiving a clearly defined odour is:
sodium hydroxide 0.5 mg/m鲁
sodium hypochlorite 75 mg/m鲁
The threshold concentration below which most people.
will experience no appreciable risk of health effects:
sodium hydroxide 0.5 mg/m鲁
sodium hypochlorite 25 mg/m鲁
American Industrial Hygiene Association (AIHA)
Ingredients considered according exceed the following cutoffs
Very Toxic (T+) >= 0.1% Toxic (T) >= 3.0%
R50 >= 0.25% Corrosive (C) >= 5.0%
R51 >= 2.5%
else >= 10%
where percentage is percentage of ingredient found in the mixture
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
- Avoid all personal contact, including inhalation.
- Wear protective clothing when risk of exposure occurs.
- Use in a well-ventilated area.
- WARNING: To avoid violent reaction, ALWAYS add material to water and NEVER
water to material.
- Avoid smoking, naked lights or ignition sources.
- Avoid contact with incompatible materials.
- When handling, DO NOT eat, drink or smoke.
- Keep containers securely sealed when not in use.
- Avoid physical damage to containers.
- Always wash hands with soap and water after handling.
- Work clothes should be laundered separately.
- Launder contaminated clothing before re-use.
- Use good occupational work practice.
- Observe manufacturer's storing and handling recommendations.
- Atmosphere should be regularly checked against established exposure standards
to ensure safe working conditions are maintained.
DO NOT allow clothing wet with material to stay in contact with skin.
RECOMMENDED STORAGE METHODS
- Lined metal can, Lined metal pail/drum
- Plastic pail
- Polyliner drum
- Packing as recommended by manufacturer.
- Check all containers are clearly labeled and free from leaks.
For low viscosity materials
- Drums and jerricans must be of the non-removable head type.
- Where a can is to be used as an inner package, the can must have a screwed
enclosure.
continued...
LIQUID AMMONIA TEST SOLUTION #2
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-9
Issue Date: Mon 3-Oct-2005 CD 2005/3 Page 8 of 15
Section 7 - HANDLING AND STORAGE
For materials with a viscosity of at least 2680 cSt. (23 deg. C) and solids
(between 15 C deg. and 40 deg C.):
- Removable head packaging;
- Cans with friction closures and
- low pressure tubes and cartridges may be used.
-
Where combination packages are used, and the inner packages are of glass,
porcelain or stoneware, there must be sufficient inert cushioning material in
contact with inner and outer packages unless the outer packaging is a close
fitting molded plastic box and the substances are not incompatible with the
plastic.
STORAGE REQUIREMENTS
- Store in original containers.
- Keep containers securely sealed.
- Store in a cool, dry, well-ventilated area.
- Store away from incompatible materials and foodstuff containers.
- Protect containers against physical damage and check regularly for leaks.
- Observe manufacturer's storing and handling recommendations.
DO NOT store near acids, or oxidizing agents.
Protect containers against physical damage.
Check regularly for spills and leaks.
No smoking, naked lights, heat or ignition sources.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
US OSHA Permissible Exposure Levels ( PELs)
Z Material TWA TWA STEL STEL Peak Peak Max Max Max
ppm mg/m鲁 ppm mg/m鲁 ppm mg/m鲁 excursion excursion excursion
ppm mg/m鲁 duration
(mins)
__ ______________ ____ ____ ____ ____ ____ ____ ________ ________ ________
Z1 Sodium 2
hydroxide
Source Material TWA TWA STEL STEL Peak Peak
ppm mg/m鲁 ppm mg/m鲁 ppm mg/m鲁
_________________________ ________________ _____ _____ _____ _____ _____ _____
US California Permissible Sodium -- 2
Exposure Limits for hydroxide;
Chemical Contaminants caustic soda
US Minnesota Permissible Sodium hydroxide 2
Exposure Limits (PELs)
US Vermont Permissible Sodium hydroxide 2
Exposure Limits Table
Z-1-A Transitional Limits
for Air Contaminants
US Vermont Permissible Sodium hydroxide 2
Exposure Limits Table
Z-1-A Final Rule Limits
for Air Contaminants
continued...
LIQUID AMMONIA TEST SOLUTION #2
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-9
Issue Date: Mon 3-Oct-2005 CD 2005/3 Page 9 of 15
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
US Tennessee Occupational Sodium hydroxide 2
Exposure Limits - Limits
For Air Contaminants
Canada Saskatchewan Sodium hydroxide 2.00000
Occupational Health and
Safety Regulations -
Contamination Limits
Canada Yukon Permissible Sodium hydroxide - 2 - -
Concentrations for
Airborne Contaminant
Substances
US Washington Permissible Sodium hydroxide 2
exposure limits of air
contaminants
Canadian British Columbia Sodium hydroxide 2
Occupational Exposure
Limits
NIOSH Recommended Sodium hydroxide 2
Exposure Limits for
Hazardous Agents in the
Workplace
US AIHA Workplace Sodium 2
Environmental Exposure Hypochlorite
Levels (WEELs)
No data available: sodium hypochlorite as (CAS: 10022-70-5)
Not available. Refer to individual constituents.
EXPOSURE STANDARDS FOR MIXTURE
"Worst Case" computer-aided prediction of vapour components/concentrations:
"Worst Case" computer-aided prediction of vapour components/concentrations:
Composite Exposure Standard for Mixture (TWA) (mg/m鲁): 1.5 mg/m鲁
"Worst Case" computer-aided prediction of vapour components/concentrations:
Composite Exposure Standard for Mixture (TWA) (mg/m鲁):
If the breathing zone concentration of ANY of the components listed below is
exceeded, "Worst Case" considerations deem the individual to be overexposed.
Component Breathing Zone ppm Breathing Zone mg/m鲁 Mixture Conc: (%).
Component Breathing zone Breathing Zone Mixture Conc
(ppm) (mg/m鲁) (%)
sodium hypochlorite 0.50 1.5000 1.0
INGREDIENT DATA
SODIUM HYDROXIDE:
The TLV-C is recommended based on concentrations that produce noticeable
but not excessive, ocular and upper respiratory tract irritation.
SODIUM HYPOCHLORITE:
available chlorine, as chlorine
TLV TWA: 0.5 ppm, 1.5 mg/m鲁: STEL: 1 ppm, 2.9 mg/m鲁
ES Peak: 1 ppm, 3 mg/m鲁
CEL TWA: 2 mg/m鲁 (compare WEEL TWA)
The odour threshold is likely to be similar to that of chlorine, 0.3 ppm.
Acute, subchronic, and chronic toxicity studies have shown no significant
treatment related effects. High concentrations may produce moderate to
continued...
LIQUID AMMONIA TEST SOLUTION #2
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-9
Issue Date: Mon 3-Oct-2005 CD 2005/3 Page 10 of 15
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
severe eye irritation, but not permanent injury. High doses also appear to
be embryotoxic. Since nearly all sodium hypochlorite is handled as aqueous
solution, airborne exposure is likely to be as an aerosol, or mist. Sodium
hypochlorite dissociates in water to form free hypochlorous acid in
equilibrium. The toxic effects are likely to be similar to those of
chlorine or sodium hydroxide.
PERSONAL PROTECTION
Glasses:
Full face- shield.
Gloves:
PE/EVAL/PE Gloves.
Respirator:
Type B-P Filter of sufficient capacity
EYE
- Chemical goggles.
- Full face shield.
- Contact lenses pose a special hazard; soft contact lenses may absorb irritants
and all lenses concentrate them.
HANDS/FEET
Elbow length PVC gloves.
When handling corrosive liquids, wear trousers or overalls outside of boots, to
avoid spills entering boots.
OTHER
- Overalls.
- PVC Apron.
- PVC protective suit may be required if exposure severe.
- Eyewash unit.
- Ensure there is ready access to a safety shower.
RESPIRATOR
Selection of the Class and Type of respirator will depend upon the level of
breathing zone contaminant and the chemical nature of the contaminant.
Protection Factors (defined as the ratio of contaminant outside and inside the
mask) may also be important.
Breathing Zone Maximum Protection Half-face Full-Face
Level ppm (volume) Factor Respirator Respirator
1000 10 B-1 P- -
1000 50 - B-1 P-
5000 50 Airline* -
5000 100 - B-2 P-
10000 100 - B-3 P-
100+ Airline* *
* - Continuous Flow ** - Continuous-flow or positive pressure demand.
The local concentration of material, quantity and
conditions of use determine the type of personal
protective equipment required.
Use appropriate NIOSH-certified respirator based on informed professional
judgement. In conditions where no reasonable estimate of exposure can be
made, assume the exposure is in a concentration IDLH and use NIOSH-certified
continued...
LIQUID AMMONIA TEST SOLUTION #2
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-9
Issue Date: Mon 3-Oct-2005 CD 2005/3 Page 11 of 15
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
full face pressure demand SCBA with a minimum service life of 30 minutes, or
a combination full facepiece pressure demand SAR with auxiliary self-contained
air supply. Respirators provided only for escape from IDLH atmospheres shall be
NIOSH-certified for escape from the atmosphere in which they will be used.
ENGINEERING CONTROLS
Local exhaust ventilation usually required. If risk of overexposure exists, wear
an approved respirator. Correct fit is essential to obtain adequate protection
an approved self contained breathing apparatus (SCBA) may be required in some
situations. Provide adequate ventilation in warehouse or closed storage area.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL PROPERTIES
Liquid.
Mixes with water.
Corrosive.
Alkaline.
Molecular Weight: Not Applicable Boiling Range (掳C): Not Available
Melting Range (掳C): Not Available Specific Gravity (water=1): 1.099
Solubility in water (g/L): Miscible pH (as supplied): 13.3-13.9
pH (1% solution): Not Available Vapor Pressure (kPa): Not Available
Volatile Component (%vol): Not Available Evaporation Rate: Not Available
Relative Vapor Density (air=1): Not Available Flash Point (掳C): Not Applicable
Lower Explosive Limit (%): Not Applicable Upper Explosive Limit (%): Not Applicable
Autoignition Temp (掳C): Not Applicable Decomposition Temp (掳C): Not Available
State: Liquid
APPEARANCE
Clear alkaline liquid with a chlorine odor; mixes with water.
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
- Presence of incompatible materials.
- Product is considered stable.
- Hazardous polymerization will not occur.
STORAGE INCOMPATIBILITY
Avoid strong acids.
Section 11 - TOXICOLOGICAL INFORMATION
Liquid Ammonia Test Solution #2
Not available. Refer to individual constituents.
unless otherwise specified data extracted from RTECS - Register of Toxic Effects
of Chemical Substances
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LIQUID AMMONIA TEST SOLUTION #2
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-9
Issue Date: Mon 3-Oct-2005 CD 2005/3 Page 12 of 15
Section 11 - TOXICOLOGICAL INFORMATION
SODIUM HYDROXIDE:
TOXICITY IRRITATION
Skin (rabbit): 500 mg/24h SEVERE
Eye (rabbit): 0.05 mg/24h SEVERE
Eye(rabbit):1 mg/24h SEVERE
Eye(rabbit):1 mg/30s rinsed-SEVERE
SODIUM HYPOCHLORITE:
TOXICITY IRRITATION
Oral (mouse) LD50: 5800 mg/kg Eye (rabbit): 10 mg - Moderate
Oral (woman) TDLo: 1000 mg/kg
as sodium hypochlorite pentahydrate
Oral (rat) LD50: 8910 mg/kg Skin (rabbit): 500 mg/24h-moderate
Eye (rabbit): 100 mg - moderate
The substance is classified by IARC as Group 3:
NOT classifiable as to its carcinogenicity to humans.
Evidence of carcinogenicity may be inadequate or limited in animal testing.
Section 12 - ECOLOGICAL INFORMATION
Prevent, by any means available, spillage from entering drains or water
courses.
DO NOT discharge into sewer or waterways.
Refer to data for ingredients, which follows:
SODIUM HYDROXIDE:
Toxicity Fish: LC50(96)43mg/L
SODIUM HYPOCHLORITE:
The material is classified as an ecotoxin* because the Fish LC50 (96 hours) is
less than or equal to 0.1 mg/l
* Classification of Substances as Ecotoxic (Dangerous to the Environment)
Appendix 8, Table 1
Compiler's Guide for the Preparation of International Chemical Safety Cards:
1993 Commission of the European Communities.
Section 13 - DISPOSAL CONSIDERATIONS
US EPA Waste Number & Descriptions
A. General Product Information
Corrosivity characteristic: use EPA hazardous waste number D002 (waste code C)
Disposal Instructions
All waste must be handled in accordance with local, state and federal
regulations.
- Recycle wherever possible.
- Consult manufacturer for recycling options or consult Waste Management
Authority for disposal if no suitable treatment or disposal facility can be
identified.
- Treat and neutralize at an approved treatment plant.
- Treatment should involve: Neutralization with suitable dilute acid followed
continued...
LIQUID AMMONIA TEST SOLUTION #2
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-9
Issue Date: Mon 3-Oct-2005 CD 2005/3 Page 13 of 15
Section 13 - DISPOSAL CONSIDERATIONS
by: Burial in a licensed land-fill or Incineration in a licensed apparatus
(after admixture with suitable combustible material).
- Decontaminate empty containers. Observe all label safeguards until containers
are cleaned and destroyed.
Puncture containers to prevent re-use and bury at an authorized landfill.
Section 14 - TRANSPORTATION INFORMATION
DOT Information
Shipping Name: CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S.
Hazard Class: 8
SubRisk: None
UN/NA Number: 3266
Packing Group: II
Labels Required: corrosive
Additional Shipping Information:
International Transport Regulations:
IMO: 3266
Section 15 - REGULATORY INFORMATION
RISK
Causes severe burns.
Risk of serious damage to eyes.
Harmful to aquatic organisms.
US Federal Regulations
A. General Product Information
In addition to Federal and State regulation, local regulations may
apply. Check with your local regulatory authorities.
B. Component Information
This material contains one or more of the following chemicals required
to be identified under SARA Section 302 (40 CFR 455 Appendix A)
SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4):
-------------------------------------------------------------------
sodium hydroxide (1310-73-2,<10% )
CERCLA: final RQ = 1000 pounds (454 kg)
-------------------------------------------------------------------
sodium hypochlorite (7681-52-9,<1% )
CERCLA: final RQ = 100 pounds (45.4 kg)
-------------------------------------------------------------------
Component TSCA
continued...
LIQUID AMMONIA TEST SOLUTION #2
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-9
Issue Date: Mon 3-Oct-2005 CD 2005/3 Page 14 of 15
Section 15 - REGULATORY INFORMATION
sodium hydroxide Y
sodium hypochlorite Y
State Regulations
A. General Product Information
B. Component Information
The following components appear on one or more of the following state
hazardous substance lists.
Component CAS No CA FL MA MN NJ PA
sodium hydroxide 1310-73-2 Y Y Y Y Y Y
sodium hypochlorite 7681-52-9 Y N Y Y N Y
Y=Yes this material appears on that state's hazardous substances list.
N=No this material does not appear on that state's hazardous substances list.
Other Regulations
A. General Product Information
All components are listed in the European Inventory of New and
Existing Chemical Substances (EINECS)
B. Component Information
CANADA
The following component(s) are identified under the Canadian
Hazardous Products Act Ingredient Disclosure List:
Component CAS No % Min Conc.
sodium hydroxide 1310-73-2 <10 1% item 1442 (998)
sodium hypochlorite 7681-52-9 <1 1% item 1443 (1013)
All of this product's components are on the Canadian Domestic
.
REGULATIONS
sodium hydroxide (CAS: 1310-73-2) is found on the following regulatory lists
Canadian Domestic Substances List (DSL)
US Toxic Substances Control Act (TSCA)
US EPA Hazardous Substances
US California Occupational Safety and Health Regulations (CAL/OSHA) - Hazardous
Substances List
US CWA (Clean Water Act) - List of Hazardous Substances
US CWA (Clean Water Act) - Reportable Quantities of Designated Hazardous
Substances
US Minnesota Hazardous Substance List
US EPA High Production Volume Chemicals Additional List
US Food Additive Database
Canada Yukon Permissible Concentrations for Airborne Contaminant Substances
US Connecticut Hazardous Air Pollutants
Canadian Ingredient Disclosure List (SOR/88-64)
sodium hypochlorite (CAS: 7681-52-9) is found on the following regulatory lists
Canadian Domestic Substances List (DSL)
US Toxic Substances Control Act (TSCA)
US California Occupational Safety and Health Regulations (CAL/OSHA) - Hazardous
Substances List
US CWA (Clean Water Act) - List of Hazardous Substances
US CWA (Clean Water Act) - Reportable Quantities of Designated Hazardous
Substances
continued...
LIQUID AMMONIA TEST SOLUTION #2
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-9
Issue Date: Mon 3-Oct-2005 CD 2005/3 Page 15 of 15
Section 15 - REGULATORY INFORMATION
US Minnesota Hazardous Substance List
Canadian Ingredient Disclosure List (SOR/88-64)
US AIHA Workplace Environmental Exposure Levels (WEELs)
US Food Additive Database
US EPA Hazardous Substances
Canadian National Pollutant Release Inventory (NPRI)
US EPA High Production Volume Chemicals Additional List
sodium hypochlorite (CAS: 10022-70-5) is found on the following regulatory lists
Canadian Domestic Substances List (DSL)
US Toxic Substances Control Act (TSCA)
US California Occupational Safety and Health Regulations (CAL/OSHA) - Hazardous
Substances List
US CWA (Clean Water Act) - List of Hazardous Substances
US CWA (Clean Water Act) - Reportable Quantities of Designated Hazardous
Substances
US Minnesota Hazardous Substance List
Canadian Ingredient Disclosure List (SOR/88-64)
US DOE Temporary Emergency Exposure Limits (TEELs)
US AIHA Workplace Environmental Exposure Levels (WEELs)
US Food Additive Database
US EPA Hazardous Substances
Canadian National Pollutant Release Inventory (NPRI)
US EPA High Production Volume Chemicals Additional List
Section 16 - OTHER INFORMATION
Reasonable care has been taken in the preparation of this information, but the
author makes no warranty of merchantability or any other warranty, expressed or
implied, with respect to this information. The author makes no representations
and assumes no liability for any direct, incidental or consequential damages
resulting from its use. For additional technical information please call our
toxicology department on +800 CHEMCALL.
Issue Date: Mon 3-Oct-2005
Print Date: Thu 6-Oct-2005
This document is copyright. Apart from any fair dealing for the purposes of
private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from
CHEMWATCH. TEL (+61 3) 9572 4700.
GENERAL HARDNESS (GH) TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-37
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 1 of 16
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
GENERAL HARDNESS (GH) TEST SOLUTION
STATEMENT OF HAZARDOUS NATURE
CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR
1910.1200.
SUPPLIER
Company: Aquarium Pharmaceuticals Incorporated Company: Aquarium Pharmaceuticals Incorporated
Address: Address:
50 East Hamilton Street PO Box 218
Chalfont Chalfont
PA, 18914 PA, 18914-0218
USA USA
Telephone: +1 215 822 8181 Telephone: +1 215 822 8181
Emergency Tel: +1800 222 1222 (US Only)
PRODUCT USE
Hardness test solution for products 58 and 34.
SYNONYMS
"Solution ID# 3338"
Section 2 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
triethanolamine 102-71-6 10-30
EDTA tetrasodium salt 64-02-8 1-5
water 7732-18-5 >60
Section 3 - HAZARDS IDENTIFICATION
CANADIAN WHMIS SYMBOLS
EMERGENCY OVERVIEW
RISK
Irritating to eyes.
Harmful by inhalation, in contact with skin and if swallowed.
Cumulative effects may result following exposure*.
continued...
GENERAL HARDNESS (GH) TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-37
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 2 of 16
Section 3 - HAZARDS IDENTIFICATION
Possible skin sensitizer*.
Exposure may produce irreversible effects*. *(limited evidence)
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
Accidental ingestion of the material may be harmful; animal experiments indicate
that ingestion of less than 150 gram may be fatal or may produce serious damage
to the health of the individual.
There is some evidence to suggest that this material can cause, if swallowed
once, irreversible damage of organs.
EYE
This material can cause eye irritation and damage in some persons.
SKIN
Skin contact with the material may be harmful; systemic effects may result
following absorption.
The material is not thought to be a skin irritant (as classified using animal
models). Temporary discomfort, however, may result from prolonged dermal
exposures. Good hygiene practice requires that exposure be kept to a minimum and
that suitable gloves be used in an occupational setting.
There is some evidence to suggest that this material, on a single contact with
skin, can cause irreversible damage of organs.
Toxic effects may result from skin absorption.
Entry into the blood-stream, through, for example, cuts, abrasions or lesions,
may produce systemic injury with harmful effects. Examine the skin prior to the
use of the material and ensure that any external damage is suitably protected.
INHALED
Harmful by inhalation.
The material is not thought to produce respiratory irritation (as classified
using animal models). Nevertheless inhalation of the material, especially for
prolonged periods, may produce respiratory discomfort and occasionally,
distress.
Inhalation of vapors or aerosols (mists, fumes), generated by the material
during the course of normal handling, may be harmful.
There is some evidence to suggest that this material can cause, if inhaled once,
irreversible damage of organs.
CHRONIC HEALTH EFFECTS
Substance accumulation, in the human body, may occur and may cause some concern
following repeated or long-term occupational exposure. There has been some
concern that this material can cause cancer or mutations but there is not enough
data to make an assessment. There is limited evidence that, skin contact with
this product is more likely to cause a sensitization reaction in some persons
compared to the general population. Prolonged or chronic exposure to
alkanolamines may result in liver, kidney or nervous system injury. Repeated
inhalation may aggravate asthma and inflammatory or fibrotic pulmonary disease.
Results of repeated exposure tests with diethanolamine (DEA) in laboratory
animals include anaemia (rats) and effects on the kidneys (rats and mice) and
liver (mice). DEA produces nervous system injury in dogs and rats. Heart and
salivary gland lesions have also been seen in mice treated cutaneously with DEA
continued...
GENERAL HARDNESS (GH) TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-37
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 3 of 16
Section 3 - HAZARDS IDENTIFICATION
and in mice receiving DEA in drinking water. Rats given high doses of DEA
developed anaemia and testicular lesions. Exaggerated doses of DEA produced
heart and nervous system effects in other animals. Changes in other organs were
judged to be secondary due to the poor health of animals subjected to extremely
high doses of DEA. Rats, rabbits and guinea pigs exposed to high vapour
concentrations of volatile monoethanolamine (MEA) (up to 1250 ppm) for periods
of up to 5 weeks developed pulmonary, hepatic and renal lesions. Dogs, rats and
guinea pigs exposed to 100 ppm MEA for 30 days, became apathetic and developed
poor appetites. Animal tests also indicate that inhalation exposure to MEA may
result in nervous system injury. All species exposed to airborne MEA experienced
dermal effects, varying from ulceration to hair loss probably resulting from
contact with the cage. An increased incidence of skeletal variations, suggestive
of a slight developmental delay was seen in the foetuses of rats given 1500
mg/kg/day DEA cutaneously; this also produced significant maternal toxicity. No
foetal malformations, however, were seen in rats nor in rabbits receiving
identical treatment. The foetus of rats given high doses of MEA by gavage,
showed an increased rate of embryofoetal death, growth retardation, and some
malformations including hydronephrosis and hydroureter. The high doses required
to produce these effects bring into question the relevance of this finding to
humans. There is some evidence that embryofoetotoxicity and teratogenicity does
not occur in rats when MEA is administered by dermal application to the mother.
The National Toxicology Program (NTP) concluded that there is clear evidence of
liver tumours and some evidence of kidney tumours in mice exposed dermally to
DEA over their lifetime. Chronic skin painting studies in mice of both sexes
produced liver tumours and an increased incidence of kidney tumours in male
mice. The significance of these findings to humans is unclear as DEA is neither
genotoxic, mutagenic nor clastogenic, and did not induce tumours in rats or
transgenic mice similarly treated. Alkanolamines (especially those containing a
secondary amine moiety) may react with nitrites or other nitrosating agents to
form carcinogenic N-nitrosamines. Alkanolamines are metabolised by biosynthetic
routes to ethanolamine and choline and incorporated into phospholipids. They are
excreted predominantly unchanged with a half-life of approximately one week. In
the absence of sodium nitrite, no conversion to carcinogenic N-nitrosamines was
observed. Diethanolamine competitively inhibits the cellular uptake of choline,
in vitro, and hepatic changes in choline homeostasis, consistent with choline
deficiency, are observed in vivo. Many amines are potent skin and respiratory
sensitisers and certain individuals especially those described as "atopic" (i.e.
those predisposed to asthma and other allergic responses) may show allergic
reactions when chronically exposed to alkanolamines. In a study with coconut
diethanolamide, the National Toxicology Program (Technical Report Series 479),
showed clear evidence of carcinogenic activity in male B6C3F1 mice based on
increased incidences of hepatic and renal tubule neoplasms and in female B6C3F1
mice based on increased incidences of hepatic neoplasms. There was equivocal
evidence of carcinogenic activity in female F344/N rats based on a marginal
increase in the incidence of renal tube neoplasms. These increases were
associated with the concentration of free diethanolamine present as a
contaminant in the diethanolamine condensate. Exposure to rats to coconut oil
diethanolamine condensate by dermal application in ethanol for 2 years resulted
in epidermal hyperplasia, sebaceous gland hyperplasia, hyperkeratosis and
parakeratosis in males and females and ulcer in females at the site of
application. There were increases in the incidences of chronic inflammation,
epithelial hyperplasia, and epithelial ulcer in the forestomach of female rats.
The severity of nephropathy in dosed female rats were increased. Exposure of
mice to coconut oil diethanolamine condensate by dermal application for 2 years
resulted in increased incidences of eosinophilic foci of the liver in males.
Increased incidences of epidermal hyperplasia, sebaceous gland hyperplasia, and
continued...
GENERAL HARDNESS (GH) TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-37
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 4 of 16
Section 3 - HAZARDS IDENTIFICATION
hyperkeratosis in males and females, ulcer in males, and parakeratosis and
inflammation in females at the site of application and of follicular cell
hyperplasia in the thyroid gland of males and females, were chemical related.
Injection of EDTA and it salts can cause severe kidney damage with tissue death
and internal bleeding, bone marrow depression and critically low levels of
calcium.
Section 4 - FIRST AID MEASURES
SWALLOWED
- IF SWALLOWED, REFER FOR MEDICAL ATTENTION, WHERE POSSIBLE, WITHOUT DELAY.
- Where Medical attention is not immediately available or where the patient is
more than 15 minutes from a hospital or unless instructed otherwise:
- For advice, contact a Poisons Information Center or a doctor.
- Urgent hospital treatment is likely to be needed.
- If conscious, give water to drink.
- INDUCE vomiting with fingers down the back of the throat, ONLY IF CONSCIOUS.
Lean patient forward or place on left side (head-down position, if possible) to
maintain open airway and prevent aspiration.
NOTE: Wear a protective glove when inducing vomiting by mechanical means.
- In the mean time, qualified first-aid personnel should treat the patient
following observation and employing supportive measures as indicated by the
patient's condition.
- If the services of a medical officer or medical doctor are readily available,
the patient should be placed in his/her care and a copy of the MSDS should be
provided. Further action will be the responsibility of the medical specialist.
- If medical attention is not available on the worksite or surroundings send the
patient to a hospital together with a copy of the MSDS.
EYE
If this product comes in contact with the eyes:
- Wash out immediately with fresh running water.
- Ensure complete irrigation of the eye by keeping eyelids apart and away from
eye and moving the eyelids by occasionally lifting the upper and lower lids.
- If pain persists or recurs seek medical attention.
- Removal of contact lenses after an eye injury should only be undertaken by
skilled personnel.
SKIN
If skin contact occurs:
- Immediately remove all contaminated clothing, including footwear
- Flush skin and hair with running water (and soap if available).
- Seek medical attention in event of irritation.
INHALED
- If fumes or combustion products are inhaled remove from contaminated area.
- Lay patient down. Keep warm and rested.
- Prostheses such as false teeth, which may block airway, should be removed,
where possible, prior to initiating first aid procedures.
- Apply artificial respiration if not breathing, preferably with a demand valve
resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if
necessary.
- Transport to hospital, or doctor.
continued...
GENERAL HARDNESS (GH) TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-37
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 5 of 16
Section 4 - FIRST AID MEASURES
NOTES TO PHYSICIAN
Treat symptomatically.
Section 5 - FIRE FIGHTING MEASURES
Flash Point (掳F): Not Applicable
Lower Explosive Limit (%): Not Applicable
Upper Explosive Limit (%): Not Applicable
Autoignition Temp (掳F): Not Applicable
EXTINGUISHING MEDIA
The product contains a substantial proportion of water, therefore there are no
restrictions on the type of extinguishing media which may be used. Choice of
extinguishing media should take into account surrounding areas.
Though the material is non-combustible, evaporation of water from the mixture,
caused by the heat of nearby fire, may produce floating layers of combustible
substances.
In such an event consider:
- foam
- dry chemical powder
- carbon dioxide.
FIRE FIGHTING
- Alert Emergency Responders and tell them location and nature of hazard.
- Wear breathing apparatus plus protective gloves for fire only.
- Prevent, by any means available, spillage from entering drains or water
course.
- Use fire fighting procedures suitable for surrounding area.
- Do not approach containers suspected to be hot.
- Cool fire exposed containers with water spray from a protected location.
- If safe to do so, remove containers from path of fire.
- Equipment should be thoroughly decontaminated after use.
GENERAL FIRE HAZARDS/HAZARDOUS COMBUSTIBLE PRODUCTS
- Non combustible.
- Not considered to be a significant fire risk.
- Expansion or decomposition on heating may lead to violent rupture of
containers.
- Decomposes on heating and may produce toxic fumes of carbon monoxide (CO).
- May emit acrid smoke.
Decomposition may produce toxic fumes of, carbon dioxide (CO2), nitrogen oxides
(NOx), other pyrolysis products typical of burning organic material.
May emit poisonous fumes.
May emit corrosive fumes.
FIRE INCOMPATIBILITY
None known.
Section 6 - ACCIDENTAL RELEASE MEASURES
MINOR SPILLS
- Clean up all spills immediately.
- Avoid breathing vapors and contact with skin and eyes.
continued...
GENERAL HARDNESS (GH) TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-37
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 6 of 16
Section 6 - ACCIDENTAL RELEASE MEASURES
- Control personal contact by using protective equipment.
- Contain and absorb spill with sand, earth, inert material or vermiculite.
- Wipe up.
- Place in a suitable labeled container for waste disposal.
MAJOR SPILLS
Moderate hazard.
- Clear area of personnel and move upwind.
- Alert Emergency Responders and tell them location and nature of hazard.
- Wear breathing apparatus plus protective gloves.
- Prevent, by any means available, spillage from entering drains or water
course.
- Stop leak if safe to do so.
- Contain spill with sand, earth or vermiculite.
- Collect recoverable product into labeled containers for recycling.
- Neutralize/decontaminate residue.
- Collect solid residues and seal in labeled drums for disposal.
- Wash area and prevent runoff into drains.
- After clean up operations, decontaminate and launder all protective clothing
and equipment before storing and re-using.
- If contamination of drains or waterways occurs, advise emergency services.
ACUTE EXPOSURE GUIDELINE LEVELS (AEGL) (in ppm)
AEGL 1: The airborne concentration of a substance above which it is predicted
that the general population, including susceptible individuals, could
experience notable discomfort, irritation, or certain asymptomatic nonsensory
effects. However, the effects are not disabling and are transient and
reversible upon cessation of exposure.
AEGL 2: The airborne concentration of a substance above which it is predicted
that the general population, including susceptible individuals, could
experience irreversible or other serious, long-lasting adverse health effects
or an impaired ability to escape.
AEGL 3: The airborne concentration of a substance above which it is predicted
that the general population, including susceptible individuals, could
experience life-threatening health effects or death.
EMERGENCY RESPONSE PLANNING GUIDELINES (ERPG)
The maximum airborne concentration below which it is believed that nearly all
individuals could be exposed for up to one hour WITHOUT experiencing or developing
life-threatening health effects is:
triethanolamine 500 mg/m鲁
water 500 mg/m鲁
irreversible or other serious effects or symptoms which could
impair an individual's ability to take protective action is:
triethanolamine 20 mg/m鲁
water 500 mg/m鲁
other than mild, transient adverse effects
without perceiving a clearly defined odour is:
triethanolamine 5 mg/m鲁
water 500 mg/m鲁
continued...
GENERAL HARDNESS (GH) TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-37
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 7 of 16
Section 6 - ACCIDENTAL RELEASE MEASURES
The threshold concentration below which most people.
will experience no appreciable risk of health effects:
triethanolamine 5 mg/m鲁
water 500 mg/m鲁
American Industrial Hygiene Association (AIHA)
Ingredients considered according exceed the following cutoffs
Very Toxic (T+) >= 0.1% Toxic (T) >= 3.0%
R50 >= 0.25% Corrosive (C) >= 5.0%
R51 >= 2.5%
else >= 10%
where percentage is percentage of ingredient found in the mixture
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
DO NOT allow clothing wet with material to stay in contact with skin.
DO NOT USE brass or copper containers / stirrers.
Alkanolamines and iron may produced unstable complexes. Monoethanolamine (MEA)
and iron form a trisethanolamino-iron complex. This material may spontaneously
decompose at temperatures between 130 and 160 degrees C. and is suspected of
causing a fire in a nearly empty storage tank containing a "heel" of MEA in
contact with carbon steel coils. If steam coil heating is used, low pressure
steam in stainless steel coils should be considered. Drum heating should also be
reviewed and, where possible, temperatures should be maintained below 130
degrees C.
- Avoid all personal contact, including inhalation.
- Wear protective clothing when risk of exposure occurs.
- Use in a well-ventilated area.
- Avoid contact with moisture.
- Avoid contact with incompatible materials.
- When handling, DO NOT eat, drink or smoke.
- Keep containers securely sealed when not in use.
- Avoid physical damage to containers.
- Always wash hands with soap and water after handling.
- Work clothes should be laundered separately. Launder contaminated clothing
before re-use.
- Use good occupational work practice.
- Observe manufacturer's storing and handling recommendations.
- Atmosphere should be regularly checked against established exposure standards
to ensure safe working conditions are maintained.
RECOMMENDED STORAGE METHODS
- Polyethylene or polypropylene container.
- Packing as recommended by manufacturer
- Check all containers are clearly labeled and free from leaks.
STORAGE REQUIREMENTS
- Store in original containers.
- Keep containers securely sealed.
- Store in a cool, dry, well-ventilated area.
continued...
GENERAL HARDNESS (GH) TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-37
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 8 of 16
Section 7 - HANDLING AND STORAGE
- Store away from incompatible materials and foodstuff containers.
- Protect containers against physical damage and check regularly for leaks.
- Observe manufacturer's storing and handling recommendations.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
Source Material TWA TWA STEL STEL Peak Peak
ppm mg/m鲁 ppm mg/m鲁 ppm mg/m鲁
_________________________ ________________ _____ _____ _____ _____ _____ _____
US California Permissible Triethanolamine -- 5
Exposure Limits for
Chemical Contaminants
Canada Saskatchewan Triethanolamine 5 10
Occupational Health and
Safety Regulations -
Contamination Limits
Canadian British Columbia Triethanolamine 5
Occupational Exposure
Limits
No data available: EDTA tetrasodium salt as (CAS: 64-02-8) / (CAS: 10378-23-1) / (CAS: 13235-36-4)
No data available: water as (CAS: 7732-18-5)
ODOUR SAFETY FACTOR (OSF)
OSF=0.77 (triethanolamine)
Exposed individuals are NOT reasonably expected to be warned, by smell, that the
Exposure Standard is being exceeded.
Odor Safety Factor (OSF) is determined to fall into either Class C, D or E.
The Odor Safety Factor (OSF) is defined as:
OSF= Exposure Standard (TWA) ppm/ Odor Threshold Value (OTV) ppm
Classification into classes follows:
Class OSF Description
A 550 Over 90% of exposed
individuals are aware by
smell that the Exposure
Standard (TLV-TWA for
example) is being
reached, even when
distracted by working
activities
B 26-550 Idem for 50-90% of
persons being distracted
C 1-26 Idem for less than 50% of
persons being distracted
D 0.18-1 0-50% of persons aware of
being tested perceive by
smell that the Exposure
Standard is being reached
E <0.18 Idem for less than 10% of
persons aware of being
tested
Amoore and Hautala * have determined that it is only at an OSF value of 26 that
continued...
GENERAL HARDNESS (GH) TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-37
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 9 of 16
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
50% of distracted persons can detect the substance at the Exposure Standard
value. In the case of alerted persons, an OSF of 26 means that 99% of them can
detect the odor at the Exposure Standard value. It is ONLY for substances
belonging to Class A and B that there is a reasonable chance of being warned in
time, that the Exposure Standard is being exceeded. * Journal Applied
Toxicology: Vol 3, 1983, p272
NOTE: The use of the OSF may be inappropriate for mixtures where substances mask
the odor of others.
EXPOSURE STANDARDS FOR MIXTURE
"Worst Case" computer-aided prediction of spray/ mist or fume/ dust components
and concentration:
"Worst Case" computer-aided prediction of spray/ mist or fume/ dust components
and concentration:
Composite Exposure Standard for Mixture (TWA) :100 mg/m鲁.
INGREDIENT DATA
TRIETHANOLAMINE:
Exposure at or below the TLV-TWA is thought to minimise the potential for
skin and eye irritation, and acute effects (including liver, kidney and
nerve damage) and chronic effects (including cancer and allergic contact
dermatitis).
EDTA TETRASODIUM SALT:
Dusts not otherwise classified, as inspirable dust;
ES TWA: 10 mg/m鲁.
WATER:
No exposure limits set by NOHSC or ACGIH.
PERSONAL PROTECTION
Glasses:
Chemical goggles.
Gloves:
PVC chemical resistant type.
Respirator:
Type AK-P Filter of sufficient capacity
EYE
- Safety glasses with side shields.
- Chemical goggles.
- Contact lenses pose a special hazard; soft lenses may absorb irritants and all
lenses concentrate them. DO NOT wear contact lenses.
HANDS/FEET
Wear chemical protective gloves, eg. PVC.
Wear safety footwear or safety gumboots, eg. Rubber.
NOTE: The material may produce skin sensitisation in predisposed individuals.
Care must be taken, when removing gloves and other protective equipment, to
avoid all possible skin contact.
OTHER
- Overalls.
- P.V.C. apron.
- Barrier cream.
continued...
GENERAL HARDNESS (GH) TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-37
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 10 of 16
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
- Skin cleansing cream.
- Eye wash unit.
RESPIRATOR
Selection of the Class and Type of respirator will depend upon the level of
breathing zone contaminant and the chemical nature of the contaminant.
Protection Factors (defined as the ratio of contaminant outside and inside the
mask) may also be important.
Breathing Zone Maximum Protection Half-face Full-Face
Level ppm (volume) Factor Respirator Respirator
1000 10 AK-1 P -
1000 50 - AK-1 P
5000 50 Airline* -
5000 100 - AK-2 P
10000 100 - AK-3 P
100+ Airline* *
* - Continuous Flow ** - Continuous-flow or positive pressure demand.
The local concentration of material, quantity and
conditions of use determine the type of personal
protective equipment required.
Use appropriate NIOSH-certified respirator based on informed professional
judgement. In conditions where no reasonable estimate of exposure can be
made, assume the exposure is in a concentration IDLH and use NIOSH-certified
full face pressure demand SCBA with a minimum service life of 30 minutes, or
a combination full facepiece pressure demand SAR with auxiliary self-contained
air supply. Respirators provided only for escape from IDLH atmospheres shall be
NIOSH-certified for escape from the atmosphere in which they will be used.
ENGINEERING CONTROLS
Local exhaust ventilation usually required. If risk of overexposure exists, wear
an approved respirator. Correct fit is essential to obtain adequate protection
an approved self contained breathing apparatus (SCBA) may be required in some
situations. Provide adequate ventilation in warehouse or closed storage area.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL PROPERTIES
Liquid.
Mixes with water.
Molecular Weight: Not Applicable Boiling Range (掳C): Not Available
Melting Range (掳C): Not Available Specific Gravity (water=1): 1.056
Solubility in water (g/L): Miscible pH (as supplied): 10.7-11.3
pH (1% solution): Not Available Vapor Pressure (kPa): Not Available
Volatile Component (%vol): Not Available Evaporation Rate: Not Available
Relative Vapor Density (air=1): Not Available Flash Point (掳C): Not Applicable
Lower Explosive Limit (%): Not Applicable Upper Explosive Limit (%): Not Applicable
Autoignition Temp (掳C): Not Applicable Decomposition Temp (掳C): Not Available
State: Liquid
continued...
GENERAL HARDNESS (GH) TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-37
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 11 of 16
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Dark green alkaline solution with a slight odor; mixes with water.
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
- Presence of incompatible materials.
- Product is considered stable.
- Hazardous polymerization will not occur.
STORAGE INCOMPATIBILITY
Avoid strong acids, bases.
Section 11 - TOXICOLOGICAL INFORMATION
General Hardness (GH) Test Solution
Not available. Refer to individual constituents.
unless otherwise specified data extracted from RTECS - Register of Toxic Effects
of Chemical Substances
TRIETHANOLAMINE:
TOXICITY IRRITATION
Oral (rat) LD50: 8000 mg/kg Skin (human): 15 mg/3d (int)-mild
Oral (rat) LD50: 4920 ul/kg Skin (rabbit): 560 mg/24 hr- mild
Oral (rat) LD50: 5560 mg/kg (calc.) Eye (rabbit): 5.62 mg - SEVERE
Oral (rat) LD50: 4.92 ml/kg (female) * Eye (rabbit): 10 mg - mild
Oral (rat) LD50: 8.57 ml/kg (male) * Eye (rabbit): 0.1 ml -
Dermal (rat) LD50: >16000 mg/kg minor iritis,
Dermal (rabbit) LD50: 16 ml/kg * minor conjunctival irritation
Intraperitoneal (rat) LD50: 1510 mg/kg Skin (rabbit): 4 h occluded
Oral (mouse) LD50: 5846 mg/kg no irritation *
Intraperitoneal (mouse) LD50: 1450 mg/kg
Oral (rabbit) LD50: 2200 mg/kg
Dermal (rabbit) LD50: >20000 mg/kg
Oral (g.pig) LD50: 2200 mg/kg
(occluded, male or female) with significant discharge;
Kill rate 1/5 * no corneal injury *
Lachrymation, diarrhoea, convulsions, urinary tract changes, changes in
bladder weight, changes in testicular weight, changes in thymus weight,
changes in liver weight, dermatitis after systemic exposure, kidney,
ureter, bladder tumours recorded.
Equivocal tumourigen by RTECS criteria.
* Union Carbide
The substance is classified by IARC as Group 3:
NOT classifiable as to its carcinogenicity to humans.
Evidence of carcinogenicity may be inadequate or limited in animal testing.
NOTE: Substance has been shown to be mutagenic in at least one assay, or belongs
to a family of chemicals producing damage or change to cellular DNA.
Limited evidence of a carcinogenic effect*.
EDTA TETRASODIUM SALT:
continued...
GENERAL HARDNESS (GH) TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-37
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 12 of 16
Section 11 - TOXICOLOGICAL INFORMATION
TOXICITY IRRITATION
Oral (rat) LD50: 2000-3200 mg/kg* Skin (rabbit):500 mg/24h-Moderate
Eyes (rabbit): 1.9 mg
Eyes (rabbit):100 mg/24h-Moderate
*[BASF]
WATER:
TOXICITY IRRITATION
No significant acute toxicological data identified in literature search.
Section 12 - ECOLOGICAL INFORMATION
DO NOT discharge into sewer or waterways.
Refer to data for ingredients, which follows:
TRIETHANOLAMINE:
Fish LC50 (96hr.) (mg/l): 3500 (24hr
Daphnia magna EC50 (48hr.) (mg/l): 2.5
Algae IC50 (72hr.) (mg/l): 1.8-47
log Kow (Sangster 1997): -1
log Pow (Verschueren 1983): 0.75428571
BOD20: 6.20%
ThOD: 2.04
log Kow : -1.32- -1.75
Koc : 3
Half-life (hr) air :4
Henry's atm m鲁 /mol: 3.38E-19
BOD 5 if unstated: nil-0.17
COD : 1.5
ThOD : 2.04; 1.61 p/p
ThOD (measured) 1.52 mg/mg (Union Carbide)
ThOD (calculated) 1.61 mg/mg (Union Carbide)
BCF : <1
Biodegradability:
96% DOC reduction (OECD Method 301E)
BOD
Day 5: 8%
Day 10: 9%
Day 20: 66%
Passes Sturm, AFNOR tests for biodegradability.
Reaches more than 70% mineralisation in OECD test for inherent
biodegradability (Zahn-Wellens test)
Theoretical oxygen demand ThOD) is calculated at 1.61 p/p. Degradation is
expected in the atmospheric environment within minutes to hours.
Material is practically non-toxic to aquatic organisms on an acute basis
(LC50 >100 mg/l in most sensitive species)
Fish LC50 (96 h): fathead minnow (Pimephales promelas) 1800-11800 mg/l
fathead minnow 5600 mg/l (Union Carbide)
bluegill (Leuciscus idus) 7930 mg/l
goldfish (Carrassius auratus) 5000 mg/l
Daphnia magna LC50 (24 h): 1390 - 2038 mg/l
Daphnia magna LC50 (48 h): 947 mg/l (Union Carbide)
Algae LC50 (48 h): 750 mg/l
Brine shrimp LC50: (Artemia salina) 5600 mg/l
continued...
GENERAL HARDNESS (GH) TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-37
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 13 of 16
Section 12 - ECOLOGICAL INFORMATION
Maximum aceeptable toxicant concentration (MATC): 22 mg/l
Algal growth inhibition (Scenedesmus subspicatus) EC50: 470-750 mg/l
Inhibition of bacteria in effluent: 50% inhibition: >10000 mg/l
Inhibitory concentration (IC50) is OECD "Activated Sludge, Respiration
Inhibition Test" (Guideline 209) is >1000 mg/l. Material has shown a
potential to biodegrade. Attains >99% degradation in activated sludge in
24 hours. Attains >99% degradation in soil is 1-14 days.
Bioconcentration potential is low (BCF less than 100 or log Kow less
than 3). Log octanol/ water partition coefficient (log Kow) is estimated
using the Pomona-Medchem structural fragment to be -1.746. Potential for
the mobility in soil is very high (Koc betweeen 0 and 50).
Henry's Law Constant (H) is estimated to be 3.38E-19 atm.m鲁/mol (25 C)
Log soil organic carbon partition coefficient (log Koc) is estimated to be
0.48.
When released into soil the material is expected to degrade without
significant evaporation. A half-life of between 1 to 10 days is expected.
When released into water, the material is expected to degrade with a
half-life of about 1 to 10 days. Beacuse the material has a log
octanol-water coefficient of less than 3 it is not expected to
bioaccumulate. Release to air is expected to produce photolytic
degradation resulting in hydroxyl radicals. The material is expected to be
removed from the atmosphere by dry and wet deposition (half-life between
1 and 10 days).
EDTA TETRASODIUM SALT:
Not readily biodegradable. Harmful to aquatic organisms.
May cause long term adverse effects in the aquatic environment. [ORICA]
Toxicity to fish: LC50 (96h): >500 mg/l (Leuciscus idus)
Toxicity to daphnae (acute): EC50 (48h): >100 mg/l
Toxicity to algae EC50 (72h): 10-100 mg/l
COD Value: 570 mg O2/g
BOD5-Value: 20 mg O2/g
Toxicity to bacteria: 50 mg/l Warburg test
Section 13 - DISPOSAL CONSIDERATIONS
Disposal Instructions
All waste must be handled in accordance with local, state and federal
regulations.
- Recycle wherever possible.
- Consult manufacturer for recycling options or consult Waste Management
Authority for disposal if no suitable treatment or disposal facility can be
identified.
- Dispose of by: Burial in a licensed land-fill or Incineration in a licensed
apparatus (after admixture with suitable combustible material)
- Decontaminate empty containers. Observe all label safeguards until containers
are cleaned and destroyed.
Puncture containers to prevent re-use and bury at an authorized landfill.
continued...
GENERAL HARDNESS (GH) TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-37
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 14 of 16
Section 14 - TRANSPORTATION INFORMATION
DOT Information
Shipping Name: None
Hazard Class: None
SubRisk: None
UN/NA Number: None
Packing Group: None
Additional Shipping Information:
International Transport Regulations:
IMO: None
Section 15 - REGULATORY INFORMATION
RISK
Harmful by inhalation, in contact with skin and if swallowed.
Irritating to eyes.
US Federal Regulations
A. General Product Information
In addition to Federal and State regulation, local regulations may
apply. Check with your local regulatory authorities.
B. Component Information
This material contains one or more of the following chemicals required
to be identified under SARA Section 302 (40 CFR 455 Appendix A)
SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4): None
-------------------------------------------------------------------
Component TSCA
triethanolamine Y
EDTA tetrasodium salt Y
State Regulations
A. General Product Information
B. Component Information
The following components appear on one or more of the following state
hazardous substance lists.
Component CAS No CA FL MA MN NJ PA
triethanolamine 102-71-6 N Y Y Y N Y
EDTA tetrasodium salt 64-02-8 N N N N N N
Y=Yes this material appears on that state's hazardous substances list.
N=No this material does not appear on that state's hazardous substances list.
continued...
GENERAL HARDNESS (GH) TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-37
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 15 of 16
Section 15 - REGULATORY INFORMATION
Other Regulations
A. General Product Information
All components are listed in the European Inventory of New and
Existing Chemical Substances (EINECS)
B. Component Information
CANADA
The following component(s) are identified under the Canadian
Hazardous Products Act Ingredient Disclosure List:
Component CAS No % Min Conc.
triethanolamine 102-71-6 10-30 1% item 1621 (1663)
All of this product's components are on the Canadian Domestic
.
REGULATIONS
triethanolamine (CAS: 102-71-6) is found on the following regulatory lists
Canadian Domestic Substances List (DSL)
US Toxic Substances Control Act (TSCA)
US TSCA Section 8 (d) - Health and Safety Data Reporting
US EPA Other (Inert) Pesticide Ingredients in Pesticide Products, List 2:
Potentially Toxic Other Ingredients/High Priority for Testing inerts
US Minnesota Hazardous Substance List
US EPA High Production Volume Program Chemical List
Canadian Ingredient Disclosure List (SOR/88-64)
US DOE Temporary Emergency Exposure Limits (TEELs)
US Food Additive Database
Canada Saskatchewan Occupational Health and Safety Regulations - Contamination
Limits
US California OEHHA/ARB - Acute Reference Exposure Levels and Target Organs
(RELs) - Respiratory
EDTA tetrasodium salt (CAS: 64-02-8) is found on the following regulatory lists
Canadian Domestic Substances List (DSL)
US Toxic Substances Control Act (TSCA)
US EPA High Production Volume Program Chemical List
US DOE Temporary Emergency Exposure Limits (TEELs)
US Food Additive Database
US California OEHHA/ARB - Acute Reference Exposure Levels and Target Organs
(RELs) - Respiratory
EDTA tetrasodium salt (CAS: 10378-23-1) is found on the following regulatory
lists
US DOE Temporary Emergency Exposure Limits (TEELs)
US California OEHHA/ARB - Acute Reference Exposure Levels and Target Organs
(RELs) - Respiratory
water (CAS: 7732-18-5) is found on the following regulatory lists
Canadian Domestic Substances List (DSL)
US Toxic Substances Control Act (TSCA)
US DOE Temporary Emergency Exposure Limits (TEELs)
US Californian Proposition 65 - Priority List for the Development of MADLs for
Chemicals Causing Reproductive Toxicity
No data available for EDTA tetrasodium salt as CAS: 13235-36-4.
continued...
GENERAL HARDNESS (GH) TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-37
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 16 of 16
Section 16 - OTHER INFORMATION
Reasonable care has been taken in the preparation of this information, but the
author makes no warranty of merchantability or any other warranty, expressed or
implied, with respect to this information. The author makes no representations
and assumes no liability for any direct, incidental or consequential damages
resulting from its use. For additional technical information please call our
toxicology department on +800 CHEMCALL.
Issue Date: Tue 4-Oct-2005
Print Date: Thu 6-Oct-2005
This document is copyright. Apart from any fair dealing for the purposes of
private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from
CHEMWATCH. TEL (+61 3) 9572 4700.
CARBONATE HARDNESS (KH) TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-3
Issue Date: Mon 3-Oct-2005 CD 2005/3 Page 1 of 7
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
CARBONATE HARDNESS (KH) TEST SOLUTION
STATEMENT OF HAZARDOUS NATURE
Not considered a hazardous substance according to OSHA 29
CFR 1910.1200.
SUPPLIER
Company: Aquarium Pharmaceuticals Incorporated Company: Aquarium Pharmaceuticals Incorporated
Address: Address:
50 East Hamilton Street PO Box 218
Chalfont Chalfont
PA, 18914 PA, 18914-0218
USA USA
Telephone: +1 215 822 8181 Telephone: +1 215 822 8181
Emergency Tel: +1800 222 1222 (US Only)
PRODUCT USE
Test solution for products 34P, 58 and 59.
SYNONYMS
"Solution ID# 3339"
Section 2 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
non hazardous ingredients 100
Section 3 - HAZARDS IDENTIFICATION
CANADIAN WHMIS SYMBOLS
None
EMERGENCY OVERVIEW
RISK
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
The material has NOT been classified as "harmful by ingestion". This is because
of the lack of corroborating animal or human evidence. The material may still be
damaging to the health of the individual, following ingestion, especially where
pre-existing organ (e.g. liver, kidney) damage is evident. Present definitions
of harmful or toxic substances are generally based on doses producing mortality
continued...
CARBONATE HARDNESS (KH) TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-3
Issue Date: Mon 3-Oct-2005 CD 2005/3 Page 2 of 7
Section 3 - HAZARDS IDENTIFICATION
(death) rather than those producing morbidity (disease, ill-health).
Gastrointestinal tract discomfort may produce nausea and vomiting. In an
occupational setting however, unintentional ingestion is not thought to be cause
for concern.
EYE
Although the liquid is not thought to be an irritant, direct contact with the
eye may produce transient discomfort characterized by tearing or conjunctival
redness (as with windburn).
SKIN
The material is not thought to produce adverse health effects or skin irritation
following contact (as classified using animal models). Nevertheless, good
hygiene practice requires that exposure be kept to a minimum and that suitable
gloves be used in an occupational setting.
INHALED
The material is not thought to produce adverse health effects or irritation of
the respiratory tract (as classified using animal models). Nevertheless, good
hygiene practice requires that exposure be kept to a minimum and that suitable
control measures be used in an occupational setting.
CHRONIC HEALTH EFFECTS
Long-term exposure to the product is not thought to produce chronic effects
adverse to the health (as classified using animal models); nevertheless exposure
by all routes should be minimized as a matter of course.
Section 4 - FIRST AID MEASURES
SWALLOWED
- Immediately give a glass of water.
- First aid is not generally required. If in doubt, contact a Poisons
Information Center or a doctor.
EYE
If this product comes in contact with eyes:
- Wash out immediately with water.
- If irritation continues, seek medical attention.
- Removal of contact lenses after an eye injury should only be undertaken by
skilled personnel.
SKIN
If skin or hair contact occurs:
- Flush skin and hair with running water (and soap if available).
- Seek medical attention in event of irritation.
INHALED
- If fumes or combustion products are inhaled remove from contaminated area.
- Other measures are usually unnecessary.
NOTES TO PHYSICIAN
Treat symptomatically.
continued...
CARBONATE HARDNESS (KH) TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-3
Issue Date: Mon 3-Oct-2005 CD 2005/3 Page 3 of 7
Section 5 - FIRE FIGHTING MEASURES
Flash Point (掳F): Not Applicable
Lower Explosive Limit (%): Not Applicable
Upper Explosive Limit (%): Not Applicable
Autoignition Temp (掳F): Not Applicable
EXTINGUISHING MEDIA
- There is no restriction on the type of extinguisher which may be used.
Use extinguishing media suitable for surrounding area.
FIRE FIGHTING
- Use water delivered as a fine spray to control fire and cool adjacent area.
- DO NOT approach containers suspected to be hot.
- Cool fire exposed containers with water spray from a protected location.
- If safe to do so, remove containers from path of fire.
- Equipment should be thoroughly decontaminated after use.
GENERAL FIRE HAZARDS/HAZARDOUS COMBUSTIBLE PRODUCTS
- Non combustible.
- Not considered to be a significant fire risk.
- Expansion or decomposition on heating may lead to violent rupture of
containers.
- Decomposes on heating and may produce toxic/ irritating fumes.
- May emit acrid smoke.
FIRE INCOMPATIBILITY
None known.
Section 6 - ACCIDENTAL RELEASE MEASURES
MINOR SPILLS
- Clean up all spills immediately.
- Avoid breathing vapors and contact with skin and eyes.
- Control personal contact by using protective equipment.
- Contain and absorb spill with sand, earth, inert material or vermiculite.
- Wipe up.
- Place in a suitable labeled container for waste disposal.
MAJOR SPILLS
- Clear area of personnel and move upwind.
- Alert Emergency Responders and tell them location and nature of hazard.
- Control personal contact by using protective equipment.
- Prevent spillage from entering drains, sewers or water courses.
- Recover product wherever possible.
- Put residues in labeled containers for disposal.
- If contamination of drains or waterways occurs, advise emergency services.
ACUTE EXPOSURE GUIDELINE LEVELS (AEGL) (in ppm)
AEGL 1: The airborne concentration of a substance above which it is predicted
that the general population, including susceptible individuals, could
continued...
CARBONATE HARDNESS (KH) TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-3
Issue Date: Mon 3-Oct-2005 CD 2005/3 Page 4 of 7
Section 6 - ACCIDENTAL RELEASE MEASURES
experience notable discomfort, irritation, or certain asymptomatic nonsensory
effects. However, the effects are not disabling and are transient and
reversible upon cessation of exposure.
AEGL 2: The airborne concentration of a substance above which it is predicted
that the general population, including susceptible individuals, could
experience irreversible or other serious, long-lasting adverse health effects
or an impaired ability to escape.
AEGL 3: The airborne concentration of a substance above which it is predicted
that the general population, including susceptible individuals, could
experience life-threatening health effects or death.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
- Limit all unnecessary personal contact.
- Wear protective clothing when risk of exposure occurs.
- Use in a well-ventilated area.
- When handling DO NOT eat, drink or smoke.
- Always wash hands with soap and water after handling.
- Avoid physical damage to containers.
- Use good occupational work practice.
- Observe manufacturer's storing and handling recommendations.
RECOMMENDED STORAGE METHODS
- Polyethylene or polypropylene container.
- Packing as recommended by manufacturer
- Check all containers are clearly labeled and free from leaks.
STORAGE REQUIREMENTS
- Store in original containers.
- Keep containers securely sealed.
- Store in a cool, dry, well-ventilated area.
- Store away from incompatible materials and foodstuff containers.
- Protect containers against physical damage and check regularly for leaks.
- Observe manufacturer's storing and handling recommendations.
Segregate from alkalis, oxidizing agents and chemicals readily decomposed by
acids, i.e. cyanides, sulfides, carbonates.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
Not available. Refer to individual constituents.
PERSONAL PROTECTION
Glasses:
Chemical goggles.
Gloves:
When handling larger quantities:
General purpose rubber glove.
Respirator:
continued...
CARBONATE HARDNESS (KH) TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-3
Issue Date: Mon 3-Oct-2005 CD 2005/3 Page 5 of 7
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EYE
- Safety glasses with side shields; or as required,
- Chemical goggles.
- Contact lenses pose a special hazard; soft lenses may absorb irritants and all
lenses concentrate them.
HANDS/FEET
Wear general protective gloves, e.g.. light weight rubber gloves.
OTHER
No special equipment needed when handling small quantities.
OTHERWISE:
- Overalls.
- Barrier cream.
- Eyewash unit.
The local concentration of material, quantity and
conditions of use determine the type of personal
protective equipment required.
Use appropriate NIOSH-certified respirator based on informed professional
judgement. In conditions where no reasonable estimate of exposure can be
made, assume the exposure is in a concentration IDLH and use NIOSH-certified
full face pressure demand SCBA with a minimum service life of 30 minutes, or
a combination full facepiece pressure demand SAR with auxiliary self-contained
air supply. Respirators provided only for escape from IDLH atmospheres shall be
NIOSH-certified for escape from the atmosphere in which they will be used.
ENGINEERING CONTROLS
General exhaust is adequate under normal operating conditions. If risk of
overexposure exists, wear an approved respirator. Correct fit is essential to
obtain adequate protection. Provide adequate ventilation in warehouse or closed
storage areas.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL PROPERTIES
Liquid.
Mixes with water.
Molecular Weight: Not Applicable Boiling Range (掳C): Not Available
Melting Range (掳C): Not Available Specific Gravity (water=1): 0.997 approx.
Solubility in water (g/L): Miscible pH (as supplied): 1.20-1.45
pH (1% solution): Not Available Vapor Pressure (kPa): Not Available
Volatile Component (%vol): Not Available Evaporation Rate: Not Available
Relative Vapor Density (air=1): Not Available Flash Point (掳C): Not Applicable
Lower Explosive Limit (%): Not Applicable Upper Explosive Limit (%): Not Applicable
Autoignition Temp (掳C): Not Applicable Decomposition Temp (掳C): Not Available
State: Liquid
APPEARANCE
Reddish orange solution with no odor; mixes with water.
continued...
CARBONATE HARDNESS (KH) TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-3
Issue Date: Mon 3-Oct-2005 CD 2005/3 Page 6 of 7
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
- Presence of incompatible materials.
- Product is considered stable.
- Hazardous polymerization will not occur.
STORAGE INCOMPATIBILITY
Avoid contamination of water, foodstuffs, feed or seed.
Avoid storage with highly alkaline solutions.
Section 11 - TOXICOLOGICAL INFORMATION
Carbonate Hardness (KH) Test Solution
Not available. Refer to individual constituents.
unless otherwise specified data extracted from RTECS - Register of Toxic Effects
of Chemical Substances
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Disposal Instructions
All waste must be handled in accordance with local, state and federal
regulations.
- Recycle wherever possible.
- Consult manufacturer for recycling options or consult Waste Management
Authority for disposal if no suitable treatment or disposal facility can be
identified.
- Dispose of by: Burial in a licensed land-fill or Incineration in a licensed
apparatus (after admixture with suitable combustible material)
- Decontaminate empty containers. Observe all label safeguards until containers
are cleaned and destroyed.
Section 14 - TRANSPORTATION INFORMATION
DOT Information
Shipping Name: None
Hazard Class: None
SubRisk: None
UN/NA Number: None
Packing Group: None
Additional Shipping Information:
International Transport Regulations:
IMO: None
continued...
CARBONATE HARDNESS (KH) TEST SOLUTION
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-3
Issue Date: Mon 3-Oct-2005 CD 2005/3 Page 7 of 7
Section 15 - REGULATORY INFORMATION
RISK
US Federal Regulations
A. General Product Information
In addition to Federal and State regulation, local regulations may
apply. Check with your local regulatory authorities.
B. Component Information
This material contains one or more of the following chemicals required
to be identified under SARA Section 302 (40 CFR 455 Appendix A)
SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4): None
-------------------------------------------------------------------
Component TSCA
State Regulations
A. General Product Information
B. Component Information
The following components appear on one or more of the following state
hazardous substance lists.
Component CAS No CA FL MA MN NJ PA
Y=Yes this material appears on that state's hazardous substances list.
N=No this material does not appear on that state's hazardous substances list.
Other Regulations
A. General Product Information
All components are listed in the European Inventory of New and
Existing Chemical Substances (EINECS)
B. Component Information
CANADA
All of this product's components are on the Canadian Domestic
.
Section 16 - OTHER INFORMATION
Reasonable care has been taken in the preparation of this information, but the
author makes no warranty of merchantability or any other warranty, expressed or
implied, with respect to this information. The author makes no representations
and assumes no liability for any direct, incidental or consequential damages
resulting from its use. For additional technical information please call our
toxicology department on +800 CHEMCALL.
Issue Date: Mon 3-Oct-2005
Print Date: Thu 6-Oct-2005
This document is copyright. Apart from any fair dealing for the purposes of
private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from
CHEMWATCH. TEL (+61 3) 9572 4700.
|