Product # (s)_7670
MATERIAL SAFETY DATA SHEET
Section 1. Company Identification and Product Information
Product Name or Identity: PALCAM Broth
Acumedia Manufacturers, Inc. 517/372-9200
Manufacturer鈥檚 Name: Emergency Phone No.:
740 East Shiawassee 517/372-0108
Fax No.:
Lansing, Michigan 48912 foodsafety@neogen.com
e-mail:
Date Prepared or Revised: November 2007
Section 2. Composition / Information on Hazardous Ingredients
Hazardous Components CAS-No. % EG-Number Hazard
Specific Chemical Identity: Symbol
Lithium Chloride 7447-41-8 21.3% 231-212-3 Xn (Harmful)
Ferric Ammonium Citrate 1185-57-5 1.1% 214-686-6 Xi (Irritant)
Section 3. Health Hazard Identification
Inhalation? Yes Skin? Yes Ingestion? Yes
Route(s) of Entry:
Harmful. Harmful if swallowed, inhaled, or absorbed through the skin. Irritating to eyes, respiratory
Health Hazards:
system, and skin. Skin irritation may be severe. Lithium Chloride may affect central nervous
(Acute and Chronic)
system.
IARC Monographs? No OSHA Regulated? No
Carcinogenicity:
Signs and Symptoms of Exposure: Lithium Chloride can affect the central nervous system, respiratory system, muscles
and kidneys. Irritant to skin and mucous membranes. Irritating effect on the eyes, can cause redness and pain. Dermatitis
may develop after long exposure with this product.
Medical Conditions Generally Aggravated by Exposure: Lithium Chloride causes irritation to the gastrointestinal tract.
Symptoms may include nausea, vomiting, and diarrhea. Pink urine discoloration is a strong indicator of iron poisoning. Liver
damage has been recorded. Overdose of iron compounds may have a corrosive effect on the gastrointestinal mucosa and
be followed by necrosis. Persons with pre-existing skin disorders, impaired liver, kidney, or respiratory function may be
more susceptible to the effects of the substance.
Section 4. First Aid Measures
Ingestion: If swallowed, wash out mouth with water, provided person is conscious. Never give anything
Emergency /
by mouth to an unconscious person. Seek medical attention.
First Aid
Procedures: Inhalation: If inhaled, supply fresh air or oxygen. Seek medical attention. If not breathing, apply artificial
respiration. If breathing is difficult, give oxygen.
Eye Contact: Rinse opened eye for at least 15 minutes under running water, lifting lower and upper
eyelids occasionally. Seek medical attention.
Skin Contact: Remove contaminated clothing. Immediately wash with plenty of soap and water for at
least 15 minutes. Seek medical attention. Wash clothing before reuse.
Section 5. Fire and Explosion Hazard Data
Flash Point (Method Used): N/A Flammable Limits: LEL 鈥? N/A
UEL 鈥? N/A
Extinguishing Media: Use alcohol foam, dry chemical, or carbon dioxide. Water may be effective for cooling, but may not
effect extinguishment.
Special Fire Fighting Procedures: Firefighters should wear protective equipment and self-contained breathing apparatus.
Emits toxic fumes under fire conditions.
Unusual Fire and Explosion Hazards: During heating or in case of fire, poisonous gases are produced. Fine dust
dispersed in air in sufficient concentrations, and in the presence of an ignition source, is a potential dust explosion hazard.
Page 1 of 3
Product # (s)_7670
Section 6. Accidental Release Measures
Personal Precautions: Shut off all sources of ignition, ventilate spill area. Wear suitable protective clothing, gloves, and
eye protection. Wear self-containing breathing apparatus, rubber boots, and heavy rubber gloves. Place contaminated
material in a chemical waste container. Prevent direct contact with skin, eyes, or clothing.
Environmental Precautions: Prevent dispersion of material. Do not allow to enter drains or water courses. Water runoff
can cause environmental damage.
Clean-up Methods: Contact safety officer and ventilate area. Absorb spill with inert material, including dry-lime, sand, or
soda ash, then place into a chemical waste container using non-sparking tools. Wash spill site.
Section 7. Handling and Storage
Handling: Protect against physical damage. Ensure good ventilation / exhaustion. Avoid contact with eyes, skin, and
clothing. Avoid prolonged or repeated exposure. Do not use if skin is cut or scratched.
Storage: Keep container tightly closed. Keep away from incompatible material. Storage area should be cool, dry and well
ventilated. Containers of this material may be hazardous when empty since they retain product residues.
Other Precautions: Remove contaminated clothing immediately. Ensure good ventilation. Prevent dust formation.
Section 8. Exposure Controls / Personal Protection
ACGIH TLV: 1 mg/m3 (soluble iron salt) (Ferric Ammonium Citrate)
OSHA-PEL: 15 mg (total dust) (Lithium Chloride)
Engineering Measures: Where protection from nuisance levels of dusts are desired, use type N95 (US) or type P1 (EN
143) dust masks. Use respirators and components tested and approved under appropriate government standards such as
NIOSH (US) or CEN (EU). Proper ventilation, safety shower, and eye bath required.
Respiratory Protection (Specify Type): With sufficient ventilation, breathing apparatus is not necessary. In the event of
possible spill / exposure, use dust mask to EN 149 FFP2S.
Local Exhaust: 50 鈥? 100 CFM Special: Safety shower and eye wash.
Ventilation:
Protective Gloves: Compatible chemical-resistant Eye Protection: Safety glasses or chemical goggles to EN 166, 167,
gloves. and 168.
Other Protective Clothing or Equipment: Uniform, lab coat, or disposable lab wear.
Work / Hygienic Practices: Follow the usual precautionary measure for handling chemicals / powder. Keep away from
food and beverages. Immediately remove all soiled and contaminated clothing. Avoid contact with eyes, skin, and clothing.
Section 9. Physical and Chemical Properties
Specific Gravity: 2.070 g/cm3 (Lithium Chloride)
Boiling Point: 1360掳C (Lithium Chloride)
Vapor Pressure: 1 mm @ 547掳C (Lithium Chloride) Melting Point: 605掳C (Lithium Chloride)
Vapor Density (AIR = 1): N/A Solubility in Water: Soluble (Lithium Chloride)
Soluble (Ferric Ammonium Citrate)
Appearance and Odor: Crystalline, white, odorless (Lithium Chloride)
Green or red-brown powder, odorless to slight ammonia odor (Ferric Ammonium Citrate).
Section 10. Stability and Reactivity
Unstable
Stability:
Stable X Conditions to Avoid: Moisture and air sensitive. Ferric Ammonium Citrate is reduced to
ferrous salt by exposure to light. Very deliquescent, forms a solution on prolonged
exposure to air.
Incompatibility (Materials to Avoid): Incompatible with strong acids, metals, iodides, Bromine trifluoride, and oxidizers.
Hazardous Decomposition or Byproducts: Hydrogen chloride gas, Lithium oxides, Carbon monoxide, Carbon dioxide,
Nitrogen oxides, Ammonia iron and iron salts.
May Occur
Hazardous Polymerization:
Will Not Occur X Conditions to Avoid: Moisture, light, and incompatible materials.
Page 2 of 3
Product # (s)_7670
Section 11. Toxicological Information
LD50: ORL-RAT, 526 mg/kg, Investigated as a tumorigen, mutagen, and reproductive effector, (Lithium Chloride)
LD50: N/A (Ferric Ammonium Citrate)
Section 12. Ecological Information
Ecotoxicity Tests: LC50 鈥? 96 hrs, 17 mg/L, Ptychocheilus lucius, (Lithium Chloride)
LC50 鈥? 7 days, 200 mg/L, Fundulus heteroclitus (Ferric Ammonium Citrate)
Section 13. Disposal Considerations
Waste Disposal Method: Dispose in accordance with all applicable federal, state, and local environmental regulations.
Keep waste separate. Contact a licensed professional waste disposal service to dispose of this material if questions arise.
Do not allow product to reach ground water, water bodies, or sewage system.
Container Information: Do not remove labels from containers until they have been cleaned.
Section 14. Transport Information
Lithium Chloride:* Ferric Ammonium Citrate:*
UN # --- UN # 3077
Class:-- Class: 9
Packing Group: -- Packing Group: III
Hazard Class: -- Hazard Class: Environmentally hazardous substance
IATA: Non-Hazardous for air transport IATA: Non-Hazardous for air transport
*Lithium Chloride is not regulated for transportation. * Information reported for product/size: 25 kg
Section 15. Regulatory Information
EU Regulations
Hazard Symbol(s):
Lithium Chloride: Xn (Harmful)
Ferric Ammonium Citrate: Xi (Irritant)
Risk Phrases:
Lithium Chloride: R 22 / 36 / 37 / 38, Harmful if swallowed. Irritating to eyes, respiratory system, and skin.
Ferric Ammonium Citrate: R 36 / 37 / 38, Irritating to eyes, respiratory system, and skin.
Safety Phrases:
Lithium Chloride: S 26 / 36 / 37 / 39, In case of contact with eyes, rinse immediately with plenty of water and seek medical
advice. Wear suitable protective clothing, gloves, and eye protection.
Ferric Ammonium Citrate: S 26 / 36, In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice. Wear suitable protective clothing.
Section 16. Other Information
This document is believed to be correct, but does not purport to be all inclusive and shall be used only as a guide.
Acumedia Manufacturers, Inc. shall not be held liable for any damage resulting from handling or from contact with the above
product. These suggestions should not be confused with state, municipal or insurance requirements, and constitute NO
WARRANTY.
Page 3 of 3
Rev 04, November 07
|