Material Safety Data Sheet
HMIS
NFPA Personal Protective Equipment
Health Hazard
2
1 Fire Hazard
1
0 0
Reactivity
0 See Section 15.
Section 1. Chemical Product and Company Identification Page Number: 1
Catalog
Salicylic acid XX068, S1005, SA125,
Common Name/
Number(s). SA130
Trade Name
69-72-7
CAS#
Manufacturer VO0525000
RTECS
SPECTRUM LABORATORY PRODUCTS INC.
14422 S. SAN PEDRO STREET TSCA 8(b) inventory: No
TSCA
products were found.
GARDENA, CA 90248
Not available.
Commercial Name(s) Not available.
CI#
2-hydroxybenzoic acid; Benzoic acid, 2-hydroxy-;
Synonym
IN CASE OF EMERGENCY
Orthohydroxybenzoic acid; o-Hydroxybenzoic acid
CHEMTREC (24hr) 800-424-9300
Salicylic Acid
Chemical Name
Not available. CALL (310) 516-8000
Chemical Family
C7-H6-O3
Chemical Formula
SPECTRUM LABORATORY PRODUCTS INC.
Supplier
14422 S. SAN PEDRO STREET
GARDENA, CA 90248
Section 2.Composition and Information on Ingredients
Exposure Limits
TWA (mg/m3) STEL (mg/m3) CEIL (mg/m3)
Name CAS # % by Weight
1) Salicylic acid 69-72-7 100
Salicylic acid:
Toxicological Data
ORAL (LD50): Acute: 891 mg/kg [Rat]. 480 mg/kg [Mouse]. 1300 mg/kg [Rabbit].
on Ingredients
DERMAL (LD50): Acute: >2000 mg/kg [Rat]. >10000 mg/kg [Rabbit].
Acute: 900 mg/m3 1 hours [Rat].
DUST (LC50):
Section 3. Hazards Identification
Potential Acute Health Effects Hazardous in case of eye contact (irritant), of ingestion. Slightly hazardous in case of skin contact (irritant,
permeator), of inhalation . Severe over-exposure can result in death.
CARCINOGENIC EFFECTS: Not available.
Potential Chronic Health
MUTAGENIC EFFECTS: Mutagenic for bacteria and/or yeast.
Effects
TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Classified Reproductive system/toxin/female, Development toxin [POSSIBLE].
Repeated exposure to a highly toxic material may produce general deterioration of health by an accumulation in
one or many human organs.
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Salicylic acid
Section 4. First Aid Measures
Eye Contact Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at
least 15 minutes. Cold water may be used. Get medical attention immediately.
Skin Contact In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove
contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get
medical attention.
Serious Skin Contact Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate
medical attention.
Inhalation If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
medical attention immediately.
Serious Inhalation Not available.
Ingestion Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight
clothing such as a collar, tie, belt or waistband.
Serious Ingestion Notes to Physician:
Treatment is largely symptomatic. Methods to rid the body rapidly of the Salicylic acid should be undertaken.
Absorption of the salicylic acid from the gastrointestinal tract can be reduced by gastric lavage, administration of
activated charcoal or a combination of these. If patient has acidosis, correction of blood pH is essential.
Section 5. Fire and Explosion Data
May be combustible at high temperature.
Flammability of the Product
545掳C (1013掳F)
Auto-Ignition Temperature
CLOSED CUP: 157掳C (314.6掳F).
Flash Points
LOWER: 1.1%
Flammable Limits
These products are carbon oxides (CO, CO2).
Products of Combustion
Slightly flammable to flammable in presence of heat.
Fire Hazards in Presence of
Various Substances
Explosion Hazards in Presence Risks of explosion of the product in presence of mechanical impact: Not available.
Risks of explosion of the product in presence of static discharge: Not available.
of Various Substances
SMALL FIRE: Use DRY chemical powder.
Fire Fighting Media
LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
and Instructions
As with most organic solids, fire is possible at elevated temperatures
Special Remarks on
Fire Hazards
Special Remarks on Explosion Dust-Air mixtures may pose an explosion hazard.
Hazards
Section 6. Accidental Release Measures
Small Spill Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by
spreading water on the contaminated surface and dispose of according to local and regional authority
requirements.
Large Spill Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray to
reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Eliminate all ignition
sources. Call for assistance on disposal. Finish cleaning by spreading water on the contaminated surface and
allow to evacuate through the sanitary system.
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Salicylic acid
Section 7. Handling and Storage
Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not
Precautions
ingest. Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable
respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid
contact with skin and eyes. Keep away from incompatibles such as oxidizing agents
Keep container tightly closed. Keep container in a cool, well-ventilated area. Moisture sensitive. Sensitive to light.
Storage
Store in light-resistant containers.
Section 8. Exposure Controls/Personal Protection
Engineering Controls Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below
recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to
airborne contaminants below the exposure limit.
Personal Protection Safety glasses. Lab coat. Dust respirator. Use a dust respirator if ventilation is inadequate and handling of
material results in visible dust clouds. Be sure to use an approved/certified respirator or equivalent. Gloves
(impervious).
Personal Protection in Case of Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used
a Large Spill to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist
BEFORE handling this product.
Exposure Limits Not available.
Section 9. Physical and Chemical Properties
Physical state and appearance Solid. (Crystalline granules ) Odorless.
Odor
sweetish , afterward acrid
Taste
138.12 g/mole
Molecular Weight
White.
Color
Not available.
pH (1% soln/water)
Decomposition temperature: 211掳C (411.8掳F)
Boiling Point
159掳C (318.2掳F)
Melting Point
Not available.
Critical Temperature
1.443 (Water = 1)
Specific Gravity
Not applicable.
Vapor Pressure
4.8 (Air = 1)
Vapor Density
Not available.
Volatility
Not available.
Odor Threshold
The product is more soluble in oil; log(oil/water) = 2.3
Water/Oil Dist. Coeff.
Not available.
Ionicity (in Water)
See solubility in water, acetone.
Dispersion Properties
Soluble in acetone.
Solubility
Partially soluble in cold water.
Very slightly soluble in hot water.
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Salicylic acid
Section 10. Stability and Reactivity Data
The product is stable.
Stability
Not available.
Instability Temperature
Excessive heat, excessive dust generation, Incompatible materials.
Conditions of Instability
Dust-Air mixtures
Reactive with oxidizing agents.
Incompatibility with various
substances
Non-corrosive in presence of glass.
Corrosivity
Light, moisture, Iron salts, spirt nitrous ether, lead acetate, iodine
Special Remarks on
Reactivity
Not available.
Special Remarks on
Corrosivity
Will not occur.
Polymerization
Section 11. Toxicological Information
Routes of Entry Absorbed through skin. Inhalation. Ingestion.
Toxicity to Animals Acute oral toxicity (LD50): 480 mg/kg [Mouse].
Acute toxicity of the dust (LC50): 900 mg/m3 1 hours [Rat].
Chronic Effects on Humans MUTAGENIC EFFECTS: Mutagenic for bacteria and/or yeast.
DEVELOPMENTAL TOXICITY: Classified Reproductive system/toxin/female, Development toxin [POSSIBLE].
Other Toxic Effects on Hazardous in case of ingestion.
Humans Slightly hazardous in case of skin contact (irritant, permeator), of inhalation.
Special Remarks on Not available.
Toxicity to Animals
Special Remarks on May affect genetic material (mutagenicity) based on animal studies. May cause adverse reproductive effects.
Chronic Effects on Humans Teratorgenic, Embryotoxic and/or foetotoxic in animal studies. Human: Transferred into maternal breast milk.
Special Remarks on other Acute Potential Health Efffects:
Toxic Effects on Humans Skin: Can cause mild skin irritation. It may be absorbed through the skin. If absorbed through the skin, it may
affect the cardiovascular system (increase in pulse rate), liver, and metabolism (body temperature increase), and
cause other symptoms similar to those from ingestion.
Eye: Causes eye irritation, temporary injury.
Inhalation: Inhalation of dust can cause respiratory tract irritation, coughing, sneezing, and shortness of
breath/rapid breathing.
Ingestion: May be harmful if swallowed in large amounts. Causes irritation of the gastrointestinal tract (nausea,
vomiting abdominal pains). Ingestion of a sizable amount can cause "Salicylism" as evidenced by nausea,
abdominal pain, vomiting, increased respiration/rapid breathing, ringing in the ears/difficulty hearing, dimness of
vision, sweating, thrist, skin erruptions, and alteration in the acid-base balance. Severe salicylate intoxication may
also affect behavior/central nervous system with symptoms such as muscle weakness, general depressed activity
(somnolence), sleepiness, tremor, confusion, dizziness, agitation, irritability, disorientation, slurred speech, ataxia,
restlessness, hyperactivity, hallucinations, convulsions, central nervous system depression, coma. It may also
affect the cardiovascular system (hypotension, increased or decreased heart rate), liver. Fatalities resulting from
respiratory or cardiovascular failure are known. The mean lethal adult dose of salicylates is between 20 and 30
grams.
Chronic Potential Heath Effects:
Possible hypersensitization.
Ingestion: Prolonged ingestion may cause kidney damage, liver damage, damage to stomach, involuntary
shaking, anemia, internal bleeding, and other symptoms similar to acute ingestion. The pancreas may also be
affected by prolonged ingestion of salicylic acid.
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Salicylic acid
Section 12. Ecological Information
Not available.
Ecotoxicity
Not available.
BOD5 and COD
Possibly hazardous short term degradation products are not likely. However, long term degradation products may
Products of Biodegradation
arise.
The products of degradation are less toxic than the product itself.
Toxicity of the Products
of Biodegradation
Not available.
Special Remarks on the
Products of Biodegradation
Section 13. Disposal Considerations
Waste Disposal
Section 14. Transport Information
DOT Classification Not a DOT controlled material (United States).
Not applicable.
Identification
Not applicable.
Special Provisions for
Transport
DOT (Pictograms)
Section 15. Other Regulatory Information and Pictograms
TSCA 8(b) inventory: Salicylic acid
Federal and State
Regulations
California prop. 65: This product contains the following ingredients for which the State of California has found
California
to cause cancer which would require a warning under the statute: No products were found.
Proposition 65
Warnings California prop. 65: This product contains the following ingredients for which the State of California has found
to cause birth defects which would require a warning under the statute: No products were found.
Other Regulations EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances (EINECS No.
200-712-3).
Canada: Listed on Canadian Domestic Substance List (DSL).
China: Listed on National Inventory.
Japan: Listed on National Inventory (ENCS).
Korea: Listed on National Inventory (KECI).
Philippines: Listed on National Inventory (PICCS).
Australia: Listed on AICS.
CLASS D-2A: Material causing other toxic effects (VERY TOXIC).
Other Classifications WHMIS (Canada)
DSCL (EEC) R22- Harmful if swallowed. S26- In case of contact with eyes, rinse
R37/38- Irritating to respiratory system immediately with plenty of water and seek
and skin. medical advice.
R41- Risk of serious damage to eyes. S37/39- Wear suitable gloves and eye/face
protection.
S46- If swallowed, seek medical advice
immediately and show this container or label.
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Salicylic acid
Health Hazard
HMIS (U.S.A.) 2 National Fire Protection Flammability
1
Association (U.S.A.)
Fire Hazard
1
0
0
Health Reactivity
Reactivity
0
Specific hazard
Personal Protection
E
WHMIS (Canada)
(Pictograms)
DSCL (Europe)
(Pictograms)
TDG (Canada)
(Pictograms)
ADR (Europe)
(Pictograms)
Protective Equipment Gloves.
Lab coat.
Dust respirator. Be sure to use an
approved/certified respirator or
equivalent. Wear appropriate respirator
when ventilation is inadequate.
Safety glasses.
Continued on Next Page
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Salicylic acid
Section 16. Other Information
S3080
MSDS Code
Not available.
References
Other Special Major uses: Medication; manufacture of other salicylates; chemical intermediate for sythesis of aspirin, rubber retarders;
Considerations in dyestuff
Validated by Sonia Owen on 10/3/2007. Verified by Sonia Owen.
Printed 1/16/2008.
CALL (310) 516-8000
Notice to Reader
All chemicals may pose unknown hazards and should be used with caution. This Material Safety Data Sheet (MSDS) applies only to the material as packaged. If this product is
combined with other materials, deteriorates, or becomes contaminated, it may pose hazards not mentioned in this MSDS. It shall be the user's responsibility to develop proper
methods of handling and personal protection based on the actual conditions of use. While this MSDS is based on technical data judged to be reliable, Spectrum Quality Products,
Inc. assumes no responsibility for the completeness or accuracy of the information contained herein.
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