**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 13446-18-9 |Magnesium nitrate hexahydrate | >98 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: O
Risk Phrases: 8
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Contact with combustible material may cause fire.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause methemoglobinemia, cyanosis (bluish discoloration of skin
due to deficient oxygenation of the blood), convulsions, and death.
May cause nausea, vomiting, and diarrhea, possibly with blood.
Inhalation:
May cause respiratory tract irritation. May cause methemoglobinemia,
cyanosis (bluish discoloration of skin due to deficient oxygenation
of the blood), convulsions, tachycardia, dyspnea (labored breathing),
and death. May cause effects similar to those described for
ingestion.
Chronic:
May cause methemoglobinemia, which is characterized by
chocolate-brown colored blood, headache, weakness, dizziness, breath
shortness, cyanosis (bluish skin due to deficient oxygenation of
blood), rapid heart rate, unconsciousness and possible death.
Repeated exposure may cause kidney damage and digestive tract
abnormalities. Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
Treat symptomatically and supportively.
Antidote:
The use of Calcium disodium EDTA as a chelating agent should be
determined by qualified medical personnel.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Strong oxidizer. Contact with other material may
cause fire. During a fire, irritating and highly toxic gases may be
generated by thermal decomposition or combustion. Use water with
caution and in flooding amounts. Some oxidizers may react explosively
with hydrocarbons(fuel). May accelerate burning if involved in a
fire. Containers may explode when heated.
Extinguishing Media:
Use water only! Contact professional fire-fighters immediately. For
small fires, do NOT use dry chemicals, carbon dioxide, halon or
foams. USE WATER ONLY. For large fires flood fire with water from a
distance.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up, then place into a suitable container for
disposal. Remove all sources of ignition. Provide ventilation. Do not
use combustible materials such as paper towels to clean up spill.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Minimize dust generation and accumulation. Avoid
contact with eyes, skin, and clothing. Keep container tightly closed.
Avoid contact with clothing and other combustible materials. Avoid
ingestion and inhalation. Use with adequate ventilation.
Storage:
Keep away from heat, sparks, and flame. Do not store near
combustible materials. Store in a cool, dry, well-ventilated area
away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 10377-60-3:
CAS# 13446-18-9:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear a chemical apron. Wear appropriate protective
clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: colorless or white
Odor: none reported
pH: 5.0-8.2; 5% solution
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 89 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 330 deg C
Solubility in water: Soluble.
Specific Gravity/Density: 1.46 (water=1)
Molecular Formula: MgN2O6.6 H2O
Molecular Weight: 1216.3592
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions. Deliquescent (tending to absorb atmospheric
water vapor and become liquid).
Conditions to Avoid:
Dust generation, excess heat.
Incompatibilities with Other Materials:
Reducing agents, combustible materials, organic materials.
Hazardous Decomposition Products:
Nitrogen oxides, oxides of magnesium.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 10377-60-3 unlisted.
CAS# 13446-18-9: OM3756000
LD50/LC50:
Not available.
CAS# 13446-18-9: Draize test, rabbit, eye: 500 mg/24H Mild; Draize
test, rabbit, skin: 500 mg/24H Mild; Oral, rat: LD50 = 5440 mg/kg.
Carcinogenicity:
Magnesium nitrate anhydrous -
Not listed by ACGIH, IARC, or NTP.
Magnesium nitrate hexahydrate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: MAGNESIUM NITRATE
Hazard Class: 5.1
UN Number: 1474
Packing Group: III
IMO
Shipping Name: MAGNESIUM NITRATE
Hazard Class: 5.1
UN Number: 1474
Packing Group: III
RID/ADR
Shipping Name: MAGNESIUM NITRATE
Hazard Class: 5.1
UN Number: 1474
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: O
Risk Phrases:
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
S 17 Keep away from combustible material.
WGK (Water Danger/Protection)
CAS# 10377-60-3: 1
CAS# 13446-18-9: 1
Canada
CAS# 10377-60-3 is listed on Canada's DSL List.
CAS# 10377-60-3 is not listed on Canada's Ingredient Disclosure List.
CAS# 13446-18-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 10377-60-3 is listed on the TSCA inventory.
CAS# 13446-18-9 is not on the TSCA Inventory because it is a hydrate.
It is considered to be listed if the CAS number for the anhydrous form
is on the inventory (40CFR720.3(u)(2)).
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 9/02/1997 Revision #6 Date: 8/11/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
1,1',3,3,3',3'-Hexamethyl-4,4',5,5'-dibenzo-2,2'-indotricarbocyanine
| 23178-67-8 |
|
1-Bromooctane, 97% (gc)
| 111-83-1 |
|
n-Octyl 4-chloroacetoacetate, tech. 85%
| 41051-21-2 |
|
Magnesium Hydroxide
| 1309-42-8 |
|
5-Nitrosalicylic Acid, 99%
| 96-97-9 |
|
Quinaldine red, 99% (uv-vis)
| 117-92-0 |
|
Silver nitrite, 99%
| 7783-99-5 |
|
Magnesium nitrate hexahydrate
| 10377-60-3 |
|
2,4-Dichloronitrobenzene, 97%
| 611-06-3 |
|
Magnesium Oxide
| 1309-48-4 |
|
Magnesium Perchlorate Anhydrous
| 10034-81-8 |
|
Pyrrole, 99%
| 109-97-7 |
|
Dextro,levo-10-camphorsulfonic acid, sodium salt, 98%
| 34850-66-3 |
|
2-Amino-4,6-Dihydroxy-5-Methylpyrimidine 99%
| 55477-35-3 |
|
N-Carbobenzyloxy-L-Valine, 99+%
| 1149-26-4 |
|
Calcium bromide dihydrate, 99+%
| 7789-41-5 |
|
Phenyl Acridine-9-Carboxylate
| 109392-90-7 |
|
(R,R)-(-)-2,3-Dimethoxy-1,4-Bis(Dimethylamino)Butane, 96%
| 26549-22-4 |
|
Magnesium sulfate anhydrous
| 7487-88-9 |
|
Guanidine carbonate, 97% (titr.)
| 593-85-1 |
|
4-Ethoxy-3-Methoxybenzaldehyde, 95%
| 120-25-2 |
|
Magnesium sulfate heptahydrate
| 7487-88-9 |
|
3-(N-Benzyl-N-methylamino)-1,2-propanediol 96+%
| 60278-98-0 |
|
Maleic acid
| 110-16-7 |
|
Malonic acid
| 141-82-2 |
|
Oil for Heat Transfer
| 0-01-1 |
|
D-(+)-Maltose Monohydrate
| 69-79-4 |
|
Manganese(II) chloride tetrahydrate
| 7773-01-5 |
|
2-Aminobenzimidazole, 95% (titr.)
| 934-32-7 |
|
Manganese (IV) Dioxide
| 1313-13-9 |
|
Cesium Fluoride, 99%
| 13400-13-0 |
|
2,2'-Dipyridylamine, 99%
| 1202-34-2 |
|
Manganese (II) Nitrate Solution
| 7697-37-2 |
|
Methylglyoxal bis-(guanyl-hydrazone) dihydrochloride monohydrate,
| 24968-67-0 |
|
N-Methyl-D-Glucamine, 99%
| 6284-40-8 |
|
1,5-Dibromopentane, 97%
| 111-24-0 |
|
Manganese(II) sulfate monohydrate
| 7785-87-7 |
|
Pentachloropyridine, 98%
| 2176-62-7 |
|
Mannitol
| 69-65-8 |
|
N,N-Dimethyl-O-Phenylenediamine Dihydrochloride, 99% (Titr.)
| 62654-07-3 |
|
Trimethyltin chloride, 99%
| 1066-45-1 |
|
Salicylamide, 99%
| 65-45-2 |
|
5-alpha-Cholestane, 98+%
| 481-21-0 |
|
2-Methyl-5-nitroimidazole, 99%
| 88054-22-2 |
|
2-Mercaptoethanol
| 60-24-2 |
|
Mercury(II) acetate
| 1600-27-7 |
|
Cytidine-2'(3')-Monophosphoric Acid, 99+%
| 84-52-6 |
|
Cis-2-Hydroxy-1-Cyclopentanecarboxamide 99+%
| 40481-98-9 |
|
Fast Blue B Salt
| 14263-94-6 |
|
M-Nitrocinnamic Acid, 99%, Predominantly Trans
| 555-68-0 |
|
|