**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 108-86-1 |Bromobenzene | 100.0 | 203-623-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI N
Risk Phrases: 10 38 51/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Irritating to skin. Toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.Dangerous for
the environment.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be absorbed through the skin in harmful
amounts. If absorbed, may cause liver injury.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause central nervous system depression.
Inhalation:
Inhalation of high concentrations may cause central nervous system
effects characterized by nausea, headache, dizziness, unconsciousness
and coma. Causes respiratory tract irritation. May cause narcotic
effects in high concentration. May cause liver abnormalities. Vapors
may cause dizziness or suffocation. May cause blood changes.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Will burn
if involved in a fire. Use water spray to keep fire-exposed
containers cool. Containers may explode in the heat of a fire. This
chemical poses an explosion hazard. Flammable liquid and vapor.
Vapors may be heavier than air. They can spread along the ground
and collect in low or confined areas. Containers may explode when
heated.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. Do NOT use straight streams of
water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. A
vapor suppressing foam may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Ground and bond
containers when transferring material. Use spark-proof tools and
explosion proof equipment. Avoid contact with eyes, skin, and
clothing. Empty containers retain product residue, (liquid and/or
vapor), and can be dangerous. Keep container tightly closed. Keep
away from heat, sparks and flame. Avoid ingestion and inhalation. Do
not pressurize, cut, weld, braze, solder, drill, grind, or expose
empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 108-86-1:
Russia: 3 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Always use
a NIOSH or European Standard EN 149 approved
respirator when necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: aromatic odor
pH: Not available.
Vapor Pressure: 3.3 mm Hg @ 20
Viscosity: 1.124 cP 20 C
Boiling Point: 155 deg C
Freezing/Melting Point: -31 deg C
Autoignition Temperature: 565 deg C ( 1,049.00 deg F)
Flash Point: 51 deg C ( 123.80 deg F)
Explosion Limits, lower: .5%
Explosion Limits, upper: 2.5%
Decomposition Temperature: Not available.
Solubility in water: Insoluble in water.
Specific Gravity/Density: 1.495
Molecular Formula: C6H5Br
Molecular Weight: 156.939
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Bromobutane + sodium, strong oxidizing agents, alkali metals.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide, hydrogen bromide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 108-86-1: CY9000000
LD50/LC50:
CAS# 108-86-1: Inhalation, mouse: LC50 = 21 gm/m3/2H; Inhalation,
rat: LC50 = 20411 mg/m3; Oral, mouse: LD50 = 2700 mg/kg; Oral,
rabbit: LD50 = 3300 mg/kg; Oral, rat: LD50 = 2383 mg/kg.
Carcinogenicity:
Bromobenzene -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Bacteria: Phytobacterium phosphoreum: EC50 = 9.46 mg/L; 30 minutes;
Microtox test; 15 degrees C
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: BROMOBENZENE
Hazard Class: 3
UN Number: 2514
Packing Group: III
IMO
Shipping Name: BROMOBENZENE
Hazard Class: 3.3
UN Number: 2514
Packing Group: III
RID/ADR
Shipping Name: BROMOBENZENE
Hazard Class: 3
UN Number: 2514
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI N
Risk Phrases:
R 10 Flammable.
R 38 Irritating to skin.
R 51/53 Toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 33 Take precautionary measures against static
discharges.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 108-86-1: 2
Canada
CAS# 108-86-1 is listed on Canada's DSL List.
CAS# 108-86-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 108-86-1 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 5/20/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Hepes Sodium Salt, DNase, RNase and Protease Free, 99+%
| 75277-39-3 |
|
DL-alpha-Methylbenzylisothiocyanate, 98%
| 32393-32-1 |
|
Isopropanol, DNase, RNase, Protease free
| 67-63-0 |
|
Bromobenzene, 99%
| 108-86-1 |
|
Isopropyl-??-D-thiogalactopyranoside, DNase, RNase, Protease free,
| 123-91-1 |
|
Acetic Acid, Sodium Salt, Anhydrous, DNase, RNase, Protease Free
| 127-09-3 |
|
Bromoform, 99+%, Stabil. With 1 wt.% Ethanol
| 64-17-5 |
|
Buffer Solution pH 4
| 50-00-0 |
|
Sodium chloride, DNase, RNase, Protease free
| 7647-14-5 |
|
2-Butoxyethanol, 97%
| 111-76-2 |
|
Dodecyl sulfate, sodium salt, DNase, RNase, Protease free
| 151-21-3 |
|
Tris(hydroxymethyl)aminomethane,DNase,RNase,Protease free
| 77-86-1 |
|
Triton?? X-100, DNase, RNase, Protease free, peroxides free
| 9002-93-1 |
|
Cadmium chloride hemipentahydrate, reagent ACS, crystals
| 7790-78-5 |
|
Urea, DNase RNase and Protease free
| 57-13-6 |
|
25-Ethoxycalix[4]arene
| 138240-24-1 |
|
Cadmium nitrate tetrahydrate, reagent, crystals, 99%
| 10022-68-1 |
|
(S)-(+)-Tetrahydro-5-Oxo-2-Furanecarboxylic Acid, 98%
| 21461-84-7 |
|
25,27-Dipropoxycalix[4]Arene, 95%
| 162301-48-6 |
|
25,26,27,28-Tetrapropoxycalix[4]Arene, 98%
| 0-01-1 |
|
Cadmium sulfate, 8/3-hydrate, reagent acs, crystals
| 7790-84-3 |
|
5-Bromo-25,26,27,28-Tetrapropoxycalix[4]Arene, 97%
| 0-01-1 |
|
Caffeine, 98% (Titr.)
| 58-08-2 |
|
5,11,17,23-Tetrabromo-25,26,27,28-tetrapropoxycalix[4]arene, 98%
| 181640-72-2 |
|
Calcium hydride, CA. 93%, 0-2 mm Grain size
| 7789-78-8 |
|
Acrylamide
| 79-06-1 |
|
5,11-Dibromo-25,27-Dipropoxycalix[4]arene, 99%
| 176098-88-7 |
|
25-Ethoxy-27-Diethoxyphosphoryloxycalix[4]Arene
| 0-01-1 |
|
5,11,17,23-Tetrakis-dimethylaminomethylcalix[4]arene
| 115421-52-8 |
|
Trifluoroacetylisocyanate
| 14565-32-3 |
|
C-Undecylcalix[4]resorcinarene Monohydrate
| 0-01-1 |
|
Sodium tert-Pentoxide, 95%
| 14593-46-5 |
|
2-Phenylpropyl butyrate, 98%
| 80866-83-7 |
|
Diisopropyl Azodicarboxylate, 94%
| 2446-83-5 |
|
5-Fluoroorotic Acid Hydrate, 98%
| 703-95-7 |
|
Poly-L-leucine
| 0-01-1 |
|
2-Nitrochalcone
| 7473-93-0 |
|
Calcium hydroxide, reagent ACS
| 1305-62-0 |
|
4-Methoxychalcone
| 959-33-1 |
|
Calcium lactacte pentahydrate (powder), 98% (titr.)
| 5743-47-5 |
|
Ethyl stearate, mixture 1:1 with ethyl palmitate
| 111-61-5 |
|
MOPS, DNase, RNase, Protease Free
| 1132-61-2 |
|
(R)-(+)-Carbobenzyloxyamino-3-Phenyl-1-Propanol
| 58917-85-4 |
|
Bafilomycin A1
| 88899-55-2 |
|
2,6-Dichloro-5-Fluoronicotinoyl Chloride, 90%
| 96568-02-4 |
|
Methyl Indole-4-Carboxylate
| 39830-66-5 |
|
2134800 Phosphate, dibasic, anhydrous, 97+%
| 7757-93-9 |
|
N-BOC Ethyl Oxamate
| 0-01-1 |
|
3-(4-Methylbenzoyl)Propionic Acid, 98%
| 4619-20-9 |
|
4-(4-Methylphenyl)Butyric Acid, 98%
| 4521-22-6 |
|
|