**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 111-92-2 |Di-n-butylamine | 99 | 203-921-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 10 20/21/22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Harmful by inhalation, in contact with skin and if
swallowed.
Potential Health Effects
Eye:
Contact with liquid or vapor causes severe burns and possible
irreversible eye damage. Lachrymator (substance which increases the
flow of tears). Low vapor concentrations may cause a temporary
visual disturbance known as 'blue haze' or 'halo vision'.
Skin:
Harmful if absorbed through the skin. Causes skin burns.
Ingestion:
Harmful if swallowed. Causes gastrointestinal tract burns.
Inhalation:
Harmful if inhaled. May cause irritation of the respiratory tract
with burning pain in the nose and throat, coughing, wheezing,
shortness of breath and pulmonary edema.
Chronic:
Chronic exposure may cause effects similar to those of acute
exposure.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water for
at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do NOT induce vomiting. Get medical aid immediately.
If victim is fully conscious, give a cupful of water. Never give
anything by mouth to an unconscious person.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Use water spray to keep fire-exposed containers
cool. Flammable liquid and vapor. Vapors are heavier than air and may
travel to a source of ignition and flash back. Vapors can spread
along the ground and collect in low or confined areas.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Provide ventilation. Approach spill
from upwind. Use water spray to cool and disperse vapors and protect
personnel.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Ground and bond containers when transferring
material. Do not get in eyes, on skin, or on clothing. Empty
containers retain product residue, (liquid and/or vapor), and can be
dangerous. Keep container tightly closed. Do not ingest or inhale. Do
not pressurize, cut, weld, braze, solder, drill, grind, or expose
empty containers to heat, sparks or open flames. Use only with
adequate ventilation. Keep away from heat, sparks and flame.
Storage:
Keep away from sources of ignition. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 111-92-2:
Germany: 5 ppm TWA; 29 mg/m3 TWA
Germany: Skin absorber
Personal Protective Equipment
Eyes:
Wear chemical splash goggles and face shield.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: amine-like - malodorous
pH: 12.2 (0.1M aq soln)
Vapor Pressure: 2.59 mm Hg @ 25 deg C
Viscosity: 0.9 mPa s 20 C
Boiling Point: 159 deg C
Freezing/Melting Point: -62 deg C
Autoignition Temperature: 260 deg C ( 500.00 deg F)
Flash Point: 39 deg C ( 102.20 deg F)
Explosion Limits, lower: .60
Explosion Limits, upper: 6.80
Decomposition Temperature: Not available.
Solubility in water: Slightly soluble.
Specific Gravity/Density: 0.76
Molecular Formula: C8H19N
Molecular Weight: 129.24
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Amines absorb carbon
dioxide from the air to form carbamate salts.
Conditions to Avoid:
Ignition sources.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 111-92-2: HR7780000
LD50/LC50:
CAS# 111-92-2: Oral, mouse: LD50 = 290 mg/kg; Oral, rat: LD50 = 189
mg/kg; Skin, rabbit: LD50 = 770 mg/kg.
Inhalation, rats LC50: > 2.0 mg/l/1H (Mortality was not observed.)
Air Products & Chemicals.
(Mortality was not observed.) Huntingdon Research
Centre.
Centre.
Carcinogenicity:
Di-n-butylamine -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Di-n-BUTYLAMINE
Hazard Class: 8 (3)
UN Number: 2248
Packing Group: II
IMO
Shipping Name: DI-(normal-BUTYL)AMINE
Hazard Class: 8 (3)
UN Number: 2248
Packing Group: II
RID/ADR
Shipping Name: Di-n-BUTYLAMINE
Hazard Class: 8
UN Number: 2248
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 10 Flammable.
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 111-92-2: 1
Canada
CAS# 111-92-2 is listed on Canada's DSL List.
CAS# 111-92-2 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 111-92-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 12/12/1997 Revision #4 Date: 6/16/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
4-Methyl-2-phenyl-5-pyrimidinecarbaldehyde, 97%
| 342405-36-1 |
|
(4-Methyl-2-phenyl-5-pyrimidinyl)methanol, 97%
| 342405-27-0 |
|
4-Methyl-2-phenyl-5-pyrimidinecarbohydrazide, 97%
| 100517-70-2 |
|
3-Methyl-5-phenyl-4-isoxazolecarboxylic acid, 97%
| 17153-21-8 |
|
3-Methyl-5-phenyl-4-isoxazolecarbonyl chloride, 97%
| 91182-77-3 |
|
3-Methyl-5-phenyl-4-isoxazolecarbaldehyde, 95+%
| 89479-66-3 |
|
4-Isocyanato-3-methyl-5-phenylisoxazole
| 352018-89-4 |
|
4-(Bromomethyl)-3-methyl-5-phenylisoxazole, 95+%
| 113841-59-1 |
|
(3-Methyl-5-phenyl-4-isoxazolyl)methanol, 97%
| 113826-87-2 |
|
4-Iodo-3-methyl-5-phenylisoxazole, 97%
| 16114-53-7 |
|
[1-(2-Pyrimidinyl)-4-piperidinyl]methanol, 97%
| 111247-61-1 |
|
1-Methyl-1h-imidazole-2-carboxylic acid, tech
| 20485-43-2 |
|
1-Methyl-1h-imidazole-2-carbonyl chloride, 97%
| 62366-45-4 |
|
2-Methylnaphtho[1,2-d]thiazole, 97%(titr.)
| 2682-45-3 |
|
1-Methyl-1H-imidazole-2-carbaldehyde, 97%
| 13750-81-7 |
|
2-(Bromomethyl)-1-methyl-1h-imidazole, 97%
| 131671-69-7 |
|
(1-Methyl-1H-imidazol-2-yl)methanol, 97%
| 17334-08-6 |
|
(1-Methyl-1H-imidazol-2-yl)methylamine, 97%
| 124312-73-8 |
|
2-(Chloromethyl)-1-methyl-1h-imidazole hydrochloride, 97%
| 78667-04-6 |
|
6-Phenylnicotinic acid, 90+%
| 29051-44-3 |
|
6-Phenylnicotinoyl chloride, 90+%
| 257876-10-1 |
|
Cyclohexenylethylamine, 99%
| 3399-73-3 |
|
3-(4-Bromophenoxy)-6-methylpyridazine, 97%
| 368869-96-9 |
|
Ethyl 4-[(6-methyl-3-pyridazinyl)oxy]benzoate, 90+%
| 423768-61-0 |
|
4-Phenyl-1,2,3-thiadiazole-5-carboxylic acid, 97%
| 78875-63-5 |
|
(4-Phenyl-1,2,3-thiadiazol-5-yl)methanol, 97%
| 423768-62-1 |
|
(4-Phenyl-1,2,3-thiadiazol-5-yl)methylamine, 90+%
| 499770-68-2 |
|
2,4,4,6-Tetrabromo-2,5-Cyclohexadien-1-One 95%
| 20244-61-5 |
|
3-Methyl-5-(4-methyl-1,2,3-thiadiazol-5-yl)isoxazole-4-carboxylic
| 263385-59-7 |
|
3-Methyl-5-(4-methyl-1,2,3-thiadiazol-5-yl)-4-isoxazolecarbonyl
| 423768-48-3 |
|
3-(1h-pyrrol-1-yl)benzoic acid, 97%
| 61471-45-2 |
|
3-(1h-pyrrol-1-yl)benzaldehyde, 95+%
| 129747-77-9 |
|
1-[3-(Bromomethyl)phenyl]-1h-pyrrole, 97%
| 112596-36-8 |
|
[3-(1h-pyrrol-1-yl)phenyl]methanol, 97%
| 83140-94-7 |
|
Di-n-butylamine
| 111-92-2 |
|
1-(3-Bromophenyl)-1h-pyrrole, 95+%
| 107302-22-7 |
|
1,12-Dodecanediol, 99%
| 5675-51-4 |
|
Magnesium bromide, anhydrous
| 7789-48-2 |
|
3-(1H-Pyrrol-1-yl)benzylamine, 97%
| 368869-95-8 |
|
3-(1H-Pyrrol-1-yl)aniline, 97%
| 89353-42-4 |
|
1-(3-Nitrophenyl)-1h-pyrrole, 97%
| 4310-42-3 |
|
3-(1H-pyrrol-1-yl)thiophene-2-carboxylic acid, 97%
| 74772-17-1 |
|
3-(1H-pyrrol-1-yl)-2-thiophenecarbaldehyde, 95+%
| 107073-28-9 |
|
tert-Butyl bromoacetate, 97% (gc)
| 5292-43-3 |
|
[3-(1h-pyrrol-1-yl)-2-thienyl]methanol, 97%
| 107073-27-8 |
|
4-Chloro-4'-methylbutyrophenone, 95%
| 38425-26-2 |
|
Methyl 4-formyl-1,2,5-trimethyl-1h-pyrrole-3-carboxylate, 95+%
| 175276-49-0 |
|
Methyl 4-(hydroxymethyl)-1,2,5-trimethyl-1h-pyrrole-3-carboxylate,
| 368869-98-1 |
|
4,5,6,7-Tetrahydro-2-benzothiophene-1-carboxylic acid, 97%
| 6435-75-2 |
|
1,3-Dimethyl-1h-thieno[2,3-c]pyrazole-5-carboxylic acid, 95+%
| 25252-46-4 |
|
|