**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 120-78-5 |2,2'-Dithio(bis)benzothiazole | 94% | 204-424-9 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI N
Risk Phrases: 31 43 50/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Contact with acids liberates toxic gas. May cause sensitization by
skin contact. Very toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause sensitization by skin contact.
Ingestion:
May cause nausea and vomiting. May cause allergic reaction.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. Get medical
aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Will burn if involved in a fire.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin
and eyes. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear a chemical apron.
Respirators:
A NIOSH/MSHA approved air purifying dust or mist
respirator or European Standard EN 149.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: yellow
Odor: unpleasant odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 177 - 180 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Insoluble.
Specific Gravity/Density:
Molecular Formula: C14H8N2S4
Molecular Weight: 332.49
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, oxides of sulfur, carbon
dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 120-78-5: DL4550000
LD50/LC50:
CAS# 120-78-5: Oral, mouse: LD50 = 7 gm/kg; Oral, rat: LD50 = >12
gm/kg; Skin, rabbit: LD50 = >7940 mg/kg.
Carcinogenicity:
2,2'-Dithio(bis)benzothiazole -
Not listed by ACGIH, IARC, or NTP.
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
log Pow = 4.66
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
*
Hazard Class: 9
UN Number: 3077
Packing Group: III
IMO
Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Hazard Class: 9
UN Number: 3077
Packing Group: III
RID/ADR
Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Hazard Class: 9
UN Number: 3077
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI N
Risk Phrases:
R 31 Contact with acids liberates toxic gas.
R 43 May cause sensitization by skin contact.
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 36/37 Wear suitable protective clothing and
gloves.
S 60 This material and its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 120-78-5: 2
United Kingdom Occupational Exposure Limits
United Kingdom Maximum Exposure Limits
Canada
CAS# 120-78-5 is listed on Canada's DSL List.
CAS# 120-78-5 is listed on Canada's Ingredient Disclosure List.
Exposure Limits
US FEDERAL
TSCA
CAS# 120-78-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/10/2003 Revision #0 Date: Original.
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
6-Tert-Butyl-M-Cresol (Techn)
| 88-60-8 |
|
3-(Methylsulfonyl)-5-(2-thienyl)isoxazole-4-carbonitrile, 97%
| 499771-08-3 |
|
5-[(2-Methyl-4-quinolyl)thio]-1,3,4-thiadiazol-2-amine, 97%
| 219719-19-4 |
|
5-(Thien-2-yl)thiophene-2-carbonitrile, 97%
| 16278-99-2 |
|
Methyl 3-amino-4-cyano-5-piperidinothiophene-2-carboxylate, 97%
| 499771-09-4 |
|
4-Amino-2-(4-methylphenyl)-6-(methylthio)pyrimidine-5-carbonitrile,
| 287922-40-1 |
|
6-(2-furyl)-2-oxo-4-(2-thienyl)-1,2-dihydro-3-pyridinecarbonitrile,
| 111121-81-4 |
|
6-Bromo-8-methoxy-2-oxo-2H-chromene-3-carboxylic acid, 97%
| 119686-34-9 |
|
2-Heptylamine, 99%
| 123-82-0 |
|
3-Amino-2-[(4-chlorophenyl)sulfonyl]acrylonitrile, 97%
| 32083-31-1 |
|
3-Chloro-5-phenylisothiazole-4-carbonitrile, 97%
| 28989-23-3 |
|
1-(6-Chloro-1,3-benzothiazol-2-yl)hydrazine, 97%
| 51011-54-2 |
|
5-(2-Chloroanilino)-3-hydroxyisothiazole-4-carbonitrile, 97%
| 287196-71-8 |
|
Phenyltrimethylammonium bromide, 98%
| 16056-11-4 |
|
Benzhydryl isothiocyanate, 90%+
| 3550-21-8 |
|
2-Butyl-4-chloro-5-formylimidazole
| 83857-96-9 |
|
D-(-)-Ornithine hydrochloride, 98%
| 16682-12-5 |
|
D-Fructose-1,6-diphosphate trisodium salt hydrate
| 00-01-1 |
|
Methyl thiosalicylate
| 4892-02-8 |
|
Ethylene Carbonate, 99+%
| 96-49-1 |
|
Cis-9-Tetradecenyl Acetate, 95%
| 16725-53-4 |
|
Ammonium titanyl oxalate monohydrate
| 10580-03-7 |
|
2-(2-Aminoethyl)pyridine
| 2706-56-1 |
|
Pinacolborane
| 25015-63-8 |
|
2,5-Dichlorothiophene-3-carbaldehyde, 97%
| 61200-60-0 |
|
3-Formyl-6-methylchromone
| 42059-81-4 |
|
3-Azetidinecarboxylic acid
| 36476-78-5 |
|
Sand, 40-100 mesh
| 14808-60-7 |
|
Sephadex??-SP C-25
| 61840-62-8 |
|
Diethyl 1-naphthylmethylphosphonate
| 53575-08-9 |
|
N-Lauroylsarcosine
| 97-78-9 |
|
N-BOC-N,2-Dimethylalanine
| 146000-39-7 |
|
Cytosine, 99+%
| 71-30-7 |
|
P-Amino-DL-Phenylalanine Hydrate, 97%
| 2922-41-0 |
|
alpha,alpha,alpha',alpha'-Tetrabromo-o-xylene, 97%
| 13209-15-9 |
|
5-Phenyl-1-pentanol
| 10521-91-2 |
|
4-Nitro-L-phenylalanine monohydrate
| 207591-86-4 |
|
2-tert-Butylbenzimidazole
| 24425-13-6 |
|
2,3-Dichlorophenethylalcohol
| 114686-85-0 |
|
4-tert-Butylanisole
| 5396-38-3 |
|
Methyl 2,3-dichlorophenylacetate
| 10328-87-7 |
|
2,3-Dichlorophenylacetone
| 102052-39-1 |
|
3-O-Acetyl-4-fluoro-L-fucal
| 402832-08-0 |
|
2,2'-Dithio(bis)benzothiazole, 94%
| 120-78-5 |
|
4-O-Benzyl-D-galactal
| 157380-76-2 |
|
4-O-Benzyl-D-glucal
| 58871-11-7 |
|
6-O-Benzyl-D-glucal
| 165524-85-6 |
|
4-O-Benzyl-L-rhamnal
| 117249-16-8 |
|
3,4-Di-O-acetyl-L-arabinal
| 3945-18-4 |
|
3,6-Di-O-acetyl-4-O-benzyl-D-galactal
| 165524-90-3 |
|
|