Search   
MSDS 
:
 Ammonium cerium(iv) nitrate, reagent acs, 98.5% (titr.)
CAS 
:
 16774-21-3
SYNONYMS 
:
 Ceric ammonium nitrate; Ammonium hexanitratocerate(IV); ammonium     nitratocerate(IV).
**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****

+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 16774-21-3 |Ceric ammonium nitrate | 98.0 | 240-827-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI O
Risk Phrases: 36 8

**** SECTION 3 - HAZARDS IDENTIFICATION ****

EMERGENCY OVERVIEW
Irritating to eyes. Contact with combustible material may cause
fire.The toxicological properties of this material have not been
fully investigated.

Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. If absorbed, causes symptoms similar to
those of ingestion.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause methemoglobinemia, cyanosis (bluish discoloration
of skin due to deficient oxygenation of the blood), convulsions, and
death. The toxicological properties of this substance have not been
fully investigated. Methemoglobinemia is characterized by dizziness,
drowsiness, headache, breath shortness, cyanosis with bluish skin,
rapid heart rate and chocolate-brown colored blood.
Inhalation:
Causes respiratory tract irritation. May cause effects similar to
those described for ingestion. The toxicological properties of this
substance have not been fully investigated.
Chronic:
No information found.

**** SECTION 4 - FIRST AID MEASURES ****

Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of soap and water for at
least 15 minutes while removing contaminated clothing and shoes. Wash
clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure to fresh air immediately. If not breathing,
give artificial respiration. If breathing is difficult, give oxygen.
Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Antidote:
None reported.

**** SECTION 5 - FIRE FIGHTING MEASURES ****

General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Strong oxidizer. Contact with combustible materials
may cause a fire. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
with caution and in flooding amounts.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use water only!
Contact professional fire-fighters immediately. Use water spray, dry
chemical, carbon dioxide, or appropriate foam.

**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****

General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Remove all sources of ignition. Provide ventilation.

**** SECTION 7 - HANDLING and STORAGE ****

Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Material is heat, shock and/or friction
sensitive. Use care in handling and storage. Avoid contact with
eyes, skin, and clothing. Keep container tightly closed. Avoid
contact with clothing and other combustible materials. Avoid
ingestion and inhalation. Wash clothing before reuse.
Storage:
Keep away from heat, sparks, and flame. Do not store near
combustible materials. Store in a tightly closed container. Store in
a cool, dry, well-ventilated area away from incompatible substances.

**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****

Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Personal Protective Equipment

Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR ??1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant a respirator's use. Follow the OSHA
respirator regulations found in 29CFR 1910.134 or
European Standard EN 149. Always use a NIOSH or
European Standard EN 149 approved respirator when
necessary.

**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****

Physical State: Solid
Appearance: Not available.
Odor: Very slight characteristic
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 107 - 108 deg C
Autoignition Temperature: Not available.
Flash Point: 87 deg C ( 188.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 87 deg C
Solubility in water: soluble
Specific Gravity/Density:
Molecular Formula: H8CeN8O18
Molecular Weight: 548.21

**** SECTION 10 - STABILITY AND REACTIVITY ****

Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, dust generation, excess
heat, combustible materials, reducing agents.
Incompatibilities with Other Materials:
Reducing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.

**** SECTION 11 - TOXICOLOGICAL INFORMATION ****

RTECS#:
CAS# 16774-21-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Ceric ammonium nitrate -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.

**** SECTION 12 - ECOLOGICAL INFORMATION ****



**** SECTION 13 - DISPOSAL CONSIDERATIONS ****

Dispose of in a manner consistent with federal, state, and local regulations.

**** SECTION 14 - TRANSPORT INFORMATION ****

IATA
Shipping Name: NITRATES, INORGANIC, N.O.S.
Hazard Class: 5.1
UN Number: 1477
Packing Group: II
IMO
Shipping Name: NITRATES, INORGANIC, N.O.S.
Hazard Class: 5.1
UN Number: 1477
Packing Group: II
RID/ADR
Shipping Name: NITRATES, INORGANIC, N.O.S.
Dangerous Goods Code: 5.1(22B)
UN Number: 1477

**** SECTION 15 - REGULATORY INFORMATION ****

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI O
Risk Phrases:
R 36 Irritating to eyes.
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
S 17 Keep away from combustible material.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 39 Wear eye/face protection.
WGK (Water Danger/Protection)
CAS# 16774-21-3: 1
United Kingdom Occupational Exposure Limits

Canada
CAS# 16774-21-3 is listed on Canada's DSL List.
CAS# 16774-21-3 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
US FEDERAL
TSCA
CAS# 16774-21-3 is listed on the TSCA inventory.

**** SECTION 16 - ADDITIONAL INFORMATION ****

MSDS Creation Date: 4/12/1999 Revision #1 Date: 8/02/2000

The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
Search More   
ALL MSDS PAGES IN THIS GROUP
NAMECAS
p-Xylylenediamine, 99% 539-48-0
3-(4-Chlorobenzoyl)Propionic Acid, 99% 3984-34-7
trans-1,2-Diaminocyclohexane-N,N,N',N'-tetraacetic acid monohydrate, 125572-95-4
2,5-Dimercapto-1,3,4-Thiadiazole, Dipotassium Salt, 98% 4628-94-8
1,1-Dibromoethane, stabilized with potassium carbonate, 99% 557-91-5
n-Octadecyl mercaptan, 98% 2885-00-9
Nile Blue A Perchlorate, Laser Grade, 99+% (UV-Vis) 53340-16-2
DL-2-Hydroxyvaleric Acid, Sodium Salt, Hydrate, 98% 57768-94-2
1-Bromo-2-methylnaphthalene 90-95% (GC) 2586-62-1
Benzyltrimethylammonium Methoxide, 40 wt% Solution in Methanol 67-56-1
2,2'-bis(4,5-dimethylimidazole) tech., 70% remainder 4,5-dimethyl... 69286-06-2
2,5-Dimethylbenzenesulfonic acid, dihydrate, 99% (titr.) 609-54-1
1,3,3-Trimethyl-2-methyleneindoline, 95% (titr.) 118-12-7
2,6-Diaminopyridine, 98% 141-86-6
2,2,4-Trimethyl-1,3-pentanediolmono (2-methylpropanoate) 25265-77-4
3,4-Diaminothiophene dihydrobromide, 99% 78637-85-1
3-Carbamoyl-2,2,5,5-Tetramethylpyrrolidin-1-Yloxy, Free Radical, 97% 4399-55-7
2,6-Dichloro-4-Fluorophenol, 99% 392-56-3
L(-)-Citronellal, 97% 5949-05-3
1,2,3-Trichloro-5-Nitrobenzene, 98% 20098-48-0
Copper cyclohexanebutyrate 2218-80-6
Copper(II) Benzoylacetonate 14128-84-8
Trans-2-Hexenoic Acid, 99% 13419-69-7
4-Hydroxymethyl-4-Methyl-1-Phenyl-3-Pyrazolidone, 98% 13047-13-7
Adenosine-5'-Diphosphate, Disodium Salt Hydrate, 98% 16178-48-6
(+)-Cis-2-Oxabicyclo(3.3.0)Oct-6-En-3-One, 97% 54483-22-6
p-Benzoquinone dioxime, 94% (dry state) moistened with ca.30% water 105-11-3
5-Chloro-2-Nitrobenzoic Acid, 99% 2516-95-2
(R)-(-)-2-Phenylglycinol, 98% 56613-80-0
1,2,3,4,6-Penta-O-acetyl-beta-D-glucopyranose, 99+% 604-69-3
8-Pentadecanone, 98% 818-23-5
Sym.-Dicarbethoxyhydrazine, 97% 4114-28-7
Sulfamide 7803-58-9
n-Phenyldiethanolamine, 90-95% (gc), remainder n-phenylethanolamine 120-07-0
Tetrakis(Trimethylsilyl)Silane, 93% (GC) 4098-98-0
1,1,2-Trimethyl-1H-Benz(e)indole, 96% (UV-VIS) 41532-84-7
4-Nitrobenzaldoxime, 99% 1129-37-9
Galactan, EX Gum Arabic 39280-09-6
Magnesium Phthalocyanine 1661-03-6
Titanium atomic absorption standard solution, 1 mg/ml Ti in 5% HF 7440-32-6
4-Penten-1-Yl Acetate, 98% 1576-85-8
Ammonium cerium(iv) nitrate, reagent acs, 98.5% (titr.) 16774-21-3
n-Omega-methyltryptamine, 99% 61-49-4
4-Nitrobenzenesulfonic Acid (Pract), 85% (UV-Vis) 138-42-1
2-Methylpentane, 99+% 107-83-5
Arachidonic Acid, From Porcine Liver 99% 506-32-1
4-Bromo-2-chlorothiophene,95% 32431-93-9
4-Aminopyrazolo[3,4-D]Pyrimidine, 98% 2380-63-4
Azure a Eosinate 62298-43-5
4-Hydroxy-2-methylquinoline, 98.5% 607-67-0

Free MSDS Search ( Providing 250,000+ Material Properties )
Chemcas.com| Ads link:todaystock.net