**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 506-93-4 |Guanidine Nitrate | 98 | 208-060-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: O
Risk Phrases: 8
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Contact with combustible material may cause fire.
Potential Health Effects
Eye:
May cause conjunctivitis. May cause permanent corneal
opacification.
Skin:
May cause severe irritation and possible burns.
Ingestion:
May cause burns to the gastrointestinal tract. May be harmful if
swallowed. May cause nausea, vomiting, and diarrhea, possibly with
blood.
Inhalation:
May cause acute pulmonary edema, asphyxia, chemical pneumonitis, and
upper airway obstruction caused by edema.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Strong oxidizer. Contact with other material may
cause fire. During a fire, irritating and highly toxic gases may be
generated by thermal decomposition or combustion. Use water with
caution and in flooding amounts. Some oxidizers may react explosively
with hydrocarbons(fuel). May accelerate burning if involved in a
fire. Containers may explode when heated.
Extinguishing Media:
Contact professional fire-fighters immediately. For small fires, do
NOT use dry chemicals, carbon dioxide, halon or foams. USE WATER
ONLY. For large fires flood fire with water from a distance.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up, then place into a suitable container for
disposal. Avoid generating dusty conditions. Remove all sources of
ignition. Provide ventilation. Do not use combustible materials such
as paper towels to clean up spill.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid contact with eyes,
skin, and clothing. Keep container tightly closed. Avoid contact with
clothing and other combustible materials. Avoid ingestion and
inhalation.
Storage:
Keep away from heat, sparks, and flame. Do not store near
combustible materials. Store in a tightly closed container. Store in
a cool, dry, well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 506-93-4:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear a chemical apron. Wear appropriate protective
clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: white
Odor: None reported.
pH: 5.5 0.5
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 213.00 - 215.00 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: >250 deg C
Solubility in water: 130 G/L WATER (20 C)
Specific Gravity/Density:
Molecular Formula: CH5N3.HNO3
Molecular Weight: 122.08
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, dust generation, excess
heat, combustible materials, reducing agents.
Incompatibilities with Other Materials:
Reducing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 506-93-4: MF4350000
LD50/LC50:
CAS# 506-93-4: Draize test, rabbit, eye: 92 mg Mild; Draize test,
rabbit, skin: 500 mg Severe; Oral, mouse: LD50 = 1028 mg/kg; Oral,
rat: LD50 = 730 mg/kg.
Carcinogenicity:
Guanidine Nitrate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: GUANIDINE NITRATE
Hazard Class: 5.1
UN Number: 1467
Packing Group: III
IMO
Shipping Name: GUANIDINE NITRATE
Hazard Class: 5.1
UN Number: 1467
Packing Group: III
RID/ADR
Shipping Name: GUANIDINE NITRATE
Hazard Class: 5.1
UN Number: 1467
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: O
Risk Phrases:
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
S 15 Keep away from heat.
S 17 Keep away from combustible material.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 506-93-4: 1
Canada
CAS# 506-93-4 is listed on Canada's DSL List.
CAS# 506-93-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 506-93-4 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Methyl acetoacetate, 98% (gc)
| 105-45-3 |
|
(2R,3R)-4-Bromo-1-Carboxy-2,3-Dihydroxycyclohexa-4,6-Diene, 95%
| 0-01-1 |
|
O-Tolylacetic Acid, 99%
| 644-36-0 |
|
2,4-Dichloro-5-Fluoroacetophenone, 99%
| 0-00-1 |
|
5-Bromouridine, 99+%
| 957-75-5 |
|
1,6-Diiodohexane, 99+%
| 629-09-4 |
|
1-Chloro-2-isopropyliminomethyl-4-nitrobenzene, 99% (uv-vis)
| 71173-78-9 |
|
2-Methoxyethylamine, p.a.
| 109-85-3 |
|
Methylene green
| 2679-01-8 |
|
4-Hydroxyphenylpyruvic acid, 98%
| 156-39-8 |
|
5,7-Dimethoxy-3-(1-naphthoyl)coumarin
| 86548-40-5 |
|
Citric Acid, Disodium Salt Sesquihydrate, 99%
| 144-33-2 |
|
4-Acryloylamidobenzo-15-Crown-5, 99%
| 0-00-1 |
|
1-Methyl-3-Pyrrolidinol
| 13220-33-2 |
|
Sulfoacetic Acid Disodium Salt, 99% (Titr.)
| 5462-60-2 |
|
4-Methylaminophenol sulfate
| 55-55-0 |
|
3,4-Epoxytetrahydrofuran
| 285-69-8 |
|
3-Aminopropyltriethoxysilane, 99%
| 919-30-2 |
|
4,6-Dichloro-2-methylthio-5-phenylpyrimidine, 95%
| 64415-11-8 |
|
Phenylethylthiourea, 98%
| 3955-58-6 |
|
Tyramine, 97%
| 51-67-2 |
|
N-Carbobenzyloxy-L-Isoleucine, 99+%
| 3160-59-6 |
|
1-Decyne, 98%
| 764-93-2 |
|
5-Chloro-2-Hydroxy-4-Methylbenzophenone, 99%
| 68751-90-6 |
|
4-Ketopimelic acid, 98%
| 502-50-1 |
|
2-Hexyl-2,3,4,5,5-pentamethyl-3-imidazolin ium-1-oxyl-methyl
| |
|
9-Anthraldehyde, 99%
| 642-31-9 |
|
1,2,4,5-Benzenetetracarboxylic acid, 96%
| 89-05-4 |
|
trans-4-Hydroxy-l-proline, 99+%
| 51-35-4 |
|
2,2-Dichlorohexanal, 90%
| 57024-78-9 |
|
d-Glucuronic acid, sodium salt monohydrate 99%
| 14984-34-0 |
|
n-Thionylaniline, 98%
| 1122-83-4 |
|
Hexamethonium bromide hydrate, 98+%
| 55-97-0 |
|
Styrallyl acetate, 99%
| 93-92-5 |
|
4-Cyanobenzoyl Chloride, 98%
| 6068-72-0 |
|
Tricyclohexylmethanol
| 17687-74-0 |
|
Tetrahydrofurfurylamine, 97%
| 4795-29-3 |
|
2-Methylanthracene, 97%
| 613-12-7 |
|
2-Thiophene glyoxylic acid ethyl ester, 96%
| 4075-58-5 |
|
4-Methoxybenzaldehyde-3-Sulfonic Acid Sodium Salt
| 5393-59-9 |
|
Alpha,alpha,alpha-trifluoroacetophenone, 99%
| 434-45-7 |
|
Guanidine Nitrate, 98%
| 506-93-4 |
|
4-Ethyl-4-Formylhexanenitrile , 95%
| 2938-48-9 |
|
3-Furoic acid, 99%
| 488-93-7 |
|
Phthalocyanine, 99% (uv-vis)
| 574-93-6 |
|
(Z)-(2-(Chloroacetamido)thiazole-4-y)-methoxyiminoacetic acid, 96%
| 64486-18-6 |
|
3-Amino-1-Phenyl-2-Pyrazolin-5-One, 93% (HPLC)
| 4149-06-8 |
|
3-Methylbenzyl Alcohol, 97%
| 587-03-1 |
|
2-Hydroxybenzimidazole, 97%
| 615-16-7 |
|
4-Amino-3-Nitrobenzophenone, 98+%
| 31431-19-3 |
|
|