**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 53874-66-1 |3-Phenoxybenzyl Chloride | ca. 100 | 258-831-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to eyes, respiratory system and
skin.
Potential Health Effects
Eye:
Causes eye irritation. Lachrymator (substance which increases the
flow of tears). May cause chemical conjunctivitis.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. Can produce delayed pulmonary
edema.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Vapors may
be heavier than air. They can spread along the ground and collect
in low or confined areas. Runoff from fire control or dilution water
may cause pollution.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes,
skin, and clothing. Keep container tightly closed. Avoid ingestion
and inhalation. Use with adequate ventilation. Wash clothing before
reuse.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 53874-66-1:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 141 - 142 deg C @ 5 mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C13H11ClO
Molecular Weight: 218.69
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 53874-66-1: CZ0790000
LD50/LC50:
CAS# 53874-66-1: Oral, mouse: LD50 = 1666 mg/kg; Oral, mouse: LD50 =
1660 mg/kg; Oral, rat: LD50 = 1224 mg/kg; Oral, rat: LD50 = 1220
mg/kg; Skin, rat: LD50 = 5720 mg/kg.
Carcinogenicity:
3-Phenoxybenzyl Chloride -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 53874-66-1: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 53874-66-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 53874-66-1 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 1/16/2002 Revision #1 Date: 5/01/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
4-Hydroxy-3-methoxybenzylamine hydrochloride, 98%
| 7149-10-2 |
|
Ethyl acetimidate hydrochloride, 97%
| 2208-07-3 |
|
Methanephosphonic acid, 98%
| 993-13-5 |
|
Meso-Tetraphenylporphine
| 917-23-7 |
|
Hydroquinone sulfonic acid potassium salt, tech.
| 21799-87-1 |
|
p-Carboxycinnamic Acid
| 19675-63-9 |
|
4'-Chloro-3'-Nitroacetophenone
| 5465-65-6 |
|
N-Ethyl-p-menthane-3-carboxamide, 99%
| 39711-79-0 |
|
Chromone-3-Carboxylic Acid
| 39079-62-4 |
|
Chromone-3-Carboxaldehyde
| 17422-74-1 |
|
5-Methylbenzo[b]thiophene
| 14315-14-1 |
|
3-Methyl-2-pyridone
| 1003-56-1 |
|
2',4',6'-Triisopropylacetophenone, 98%
| 2234-14-2 |
|
Thianaphthene-1,1-Dioxide
| 825-44-5 |
|
6-Chloro-5-Fluorobenzimidazole-2-Thiol
| 142313-30-2 |
|
3-Methylbenzo[b]thiophene
| 1455-18-1 |
|
2-(Methylthio)benzothiazole, 98% (gc)
| 615-22-5 |
|
4,5-Dibromothiophene-2-carboxaldehyde
| 38071-22-6 |
|
Ethyl 2,4-dimethylthiazole-5-carboxylate
| 7210-77-7 |
|
4-Methyl(thiobenzamide)
| 2362-62-1 |
|
4-(Trifluoromethyl)thiophenol
| 825-83-2 |
|
2,5-Dimethylfuran, 99%
| 625-86-5 |
|
4-Isopropoxybenzaldehyde
| 18962-05-5 |
|
Tris(4-trifluoromethylphenyl)phosphine
| 13406-29-6 |
|
5-Chlorothiophene-2-sulfonamide
| 53595-66-7 |
|
4-Chloro-2,6-Dimethylphenol
| 1123-63-3 |
|
2-Amino-4-tert-butylthiazole
| 74370-93-7 |
|
2-(3,4-Dimethoxyphenylthio)acetic acid
| 95735-63-0 |
|
4-Chloromethyl-2-Methylthiazole Hydrochloride
| 39238-07-8 |
|
4,5-Dibromothiophene-2-sulfonyl chloride
| 81606-31-7 |
|
4-(Trifluoromethyl)-1,2-phenylenediamine
| 368-71-8 |
|
1,2,3,4,5,6-Hexachloro-7-Methoxy-Naphthalene, Tech.
| 1506-15-6 |
|
1,3:2,5:4,6-tri-o-methylene-d-mannitol, 98%
| 5434-31-1 |
|
2-Chlorobenzoylacetonitrile
| 40018-25-5 |
|
3,5-Bis(Trifluoromethyl)Thiophenol
| 130783-02-7 |
|
3-Chloro-4-fluorophenylisothiocyanate
| 137724-66-4 |
|
Eugenol, 99%
| 97-53-0 |
|
4-Chloro-5-Fluoro-o-Phenylendiamine
| 132942-81-5 |
|
4-Methoxy-o-phenylenediamine
| 102-51-2 |
|
3-Phenoxybenzyl Chloride
| 53874-66-1 |
|
Abies Sibirica, Essential Oil
| 0-00-1 |
|
3-Chloro-4-Iodoaniline, 98%
| 135050-44-1 |
|
2-Chloro-6-fluoroaniline
| 363-51-9 |
|
5-Chloro-4-Fluoro-2-Nitroaniline
| 104222-34-6 |
|
n-Butyric acid, 99+%
| 107-92-6 |
|
2-Isopropyl-2-Phenylacetic Acid
| 3508-94-9 |
|
Nonyltrimethylammonium Bromide, 96%
| 1943-11-9 |
|
9,10-Diethoxyanthracene
| 68818-86-0 |
|
[(1S)-endo]-(+)-3-Bromo-10-camphorsulfonic acid monohydrate
| 209736-59-4 |
|
4-Biphenylcarboxamide
| 3815-20-1 |
|
|