**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 7440-28-0 |Thallium | 0.1 | 231-138-1 |
|----------------|--------------------------------------|----------|-----------|
| 7697-37-2 |Nitric acid | 2 | 231-714-2 |
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | 97.9 | 231-791-2 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: XI
Risk Phrases: 33 37/38 41 53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Danger of cumulative effects. Irritating to respiratory system and
skin. Risk of serious damage to eyes. May cause long-term adverse
effects in the aquatic environment.
Potential Health Effects
Eye:
Causes eye irritation and possible burns. May cause chemical
conjunctivitis and corneal damage.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
Ingested thallium compounds are extremely toxic, causing
convulsions, coma, conjunctivitis, runny nose, polyneuritis, motor
and sensory peripheral neuropathy, encephalopathy, arterial
hypertension, rapid heart rate, and skin eruptions Most
characteristic symptom of thallium intoxication among survivors of
acute episode is complete loss of scalp & facial hair within 8 days
of exposure. Thallium is a cumulative poison. Smaller doses can
cause hair loss within weeks & death in months.
Inhalation:
Causes respiratory tract irritation. May cause cardiac damage. May
cause systemic effects.
Chronic:
Exposure to high concentrations of nitric acid vapor may cause
pneuomonitis and pulmonary edema which may be fatal. Symptoms may or
may not be delayed. Continued exposure to the vapor & mist of nitric
acid may result in a chronic bronchitis, & more severe exposure
results in a chemical pneumonitis. The vapor & mists of nitric acid
may erode the teeth, particularly affecting the canines & incisors.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Vapors may
accumulate in confined spaces Contact with metals may evolve
flammable hydrogen gas. Containers may explode when heated. Contact
with water forms corrosive vapors. Non-combustible, substance itself
does not burn but may decompose upon heating to produce irritating,
corrosive and/or toxic fumes. Runoff from fire control or dilution
water may cause pollution.
Extinguishing Media:
Do NOT get water inside containers. For large fires, use water
spray, fog or alcohol-resistant foam. For small fires, use carbon
dioxide, dry chemical, dry sand, or alcohol-resistant foam. Most
foams will react with the material and release corrosive/toxic
gases. Cool containers with flooding quantities of water until well
after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on
skin, or on clothing. Keep container tightly closed. Do not ingest or
inhale. Use with adequate ventilation. Wash clothing before reuse.
Discard contaminated shoes.
Storage:
Keep container closed when not in use. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 7440-28-0:
United States OSHA: 0.1 mg/m3 TWA
Belgium - TWA: 0.1 mg/m3 VLE
France - VME: 0.1 mg/m3 VME
Malaysia: 0.1 mg/m3 TWA
Netherlands: 0.1 mg/m3 MAC
Spain: 0.1 mg/m3 VLA-ED
CAS# 7697-37-2:
United Kingdom, WEL - TWA: 2 ppm TWA; 5.2 mg/m3 TWA
United Kingdom, WEL - STEL: 4 ppm STEL; 10 mg/m3 STEL
United States OSHA: 2 ppm TWA; 5 mg/m3 TWA
Belgium - TWA: 2 ppm VLE; 5.3 mg/m3 VLE
Belgium - STEL: 4 ppm VLE; 10 mg/m3 VLE
France - VME: 2 ppm VME; 5 mg/m3 VME
France - VLE: 4 ppm VLE; 10 mg/m3 VLE
Germany: 2 ppm TWA; 5.2 mg/m3 TWA
Japan: 2 ppm OEL; 5.2 mg/m3 OEL
Malaysia: 2 ppm TWA; 5.2 mg/m3 TWA
Netherlands: 0.5 ppm STEL; 1.3 mg/m3 STEL
Russia: 2 mg/m3 TWA
Spain: 2 ppm VLA-ED; 5.2 mg/m3 VLA-ED
Spain: 4 ppm VLA-EC; 10 mg/m3 VLA-EC
CAS# 7732-18-5:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: not available
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: miscible
Specific Gravity/Density:
Molecular Formula: Solution
Molecular Weight: 0
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, excess heat, oxidizers.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, irritating and toxic fumes and gases, nitrogen.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7440-28-0: XG3425000
CAS# 7697-37-2: QU5775000 QU5900000
CAS# 7732-18-5: ZC0110000
LD50/LC50:
Not available.
CAS# 7697-37-2: Inhalation, rat: LC50 = 260 mg/m3/30M; Inhalation,
rat: LC50 = 130 mg/m3/4H; Inhalation, rat: LC50 = 67 ppm(NO2)/4H.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
Thallium -
Not listed by ACGIH, IARC, or NTP.
Nitric acid -
Not listed by ACGIH, IARC, or NTP.
Water -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
Thallium has been detected in fish and plants and monitoring data
suggest it may bioconcentrate in aquatic organisms.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: THALLIUM COMPOUND, N.O.S.
Hazard Class: 6.1
UN Number: 1707
Packing Group: II
IMO
Shipping Name: THALLIUM COMPOUND, N.O.S.
Hazard Class: 6.1
UN Number: 1707
Packing Group: II
RID/ADR
Shipping Name: THALLIUM COMPOUND, N.O.S.
Hazard Class: 6.1
UN Number: 1707
Packing group: II
USA RQ: CAS# 7440-28-0: 1000 lb final RQ (no reporting of releases of this hazar
USA RQ: CAS# 7697-37-2: 1000 lb final RQ; 454 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 33 Danger of cumulative effects.
R 37/38 Irritating to respiratory system and skin.
R 41 Risk of serious damage to eyes.
R 53 May cause long-term adverse effects in the
aquatic environment.
Safety Phrases:
S 13 Keep away from food, drink and animal feeding
stuffs.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37/39 Wear suitable gloves and eye/face
protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 7440-28-0: No information available.
CAS# 7697-37-2: 1
CAS# 7732-18-5: No information available.
Canada
CAS# 7440-28-0 is listed on Canada's DSL List.
CAS# 7697-37-2 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 7440-28-0 is listed on Canada's Ingredient Disclosure List.
CAS# 7697-37-2 is listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7440-28-0 is listed on the TSCA inventory.
CAS# 7697-37-2 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 9/02/1997 Revision #5 Date: 9/22/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Chloramphenicol
| 56-75-7 |
|
(+/-)-5,5',6,6',7,7',8,8'-Octahydro-1,1'-bi-2-naphthol
| 39648-74-3 |
|
(+/-)-2,2'-Diamino-1,1'-binaphthalene, 98%
| 4488-22-6 |
|
Thallium atomic absorption standard solution, 1 mg/ml Tl in 2% HNO3
| 7440-28-0 |
|
2-Amino-6-Methoxybenzothiazole, 98%
| 1747-60-0 |
|
4-Ethoxy-2-Nitroaniline
| 616-86-4 |
|
1,6-Diaminohexane-N,N,N',N'-Tetraacetic Acid
| 1633-00-7 |
|
Alpha-Oxo-2-Furanacetonitrile
| 6047-91-2 |
|
N,N-Dimethyl-4-oxo-4-p-tolylbutyramide
| 402470-91-1 |
|
N-(P-Aminobenzoyl)-Beta-Alanine, 98%
| 7377-08-4 |
|
2,6-Dimethyl-1,4-hydroquinone
| 654-42-2 |
|
Bis(trimethylsilyl)acetylene, 99%
| 14630-40-1 |
|
3-(Trifluoromethyl)phenethyl alcohol, 97%
| 455-01-6 |
|
Chloroplatinic acid hydrate
| 16941-12-1 |
|
6,13-Pentacenequinone, 99%
| 3029-32-1 |
|
(2-Methylphenoxy)acetic acid, 99%
| 1878-49-5 |
|
4-Fluoro-o-phenylenediamine
| 367-31-7 |
|
2-Nitro-9-fluorenone
| 3096-52-4 |
|
Coconut oil, refined
| 8001-31-8 |
|
Dicalite Speed Plus, Diatomaceous Filter-Aid
| 0-01-1 |
|
Ethyl 2-cyano-4,4-diethoxybutanoate
| 52133-67-2 |
|
Indoine blue
| 4569-88-4 |
|
2-Bromo-4'-cyanoacetophenone, 97%
| 20099-89-2 |
|
Thymol iodide
| 552-22-7 |
|
Methyl-6-bromo-2-naphthoate, 98%
| 33626-98 -1 |
|
4-Phenylpyridine-N-Oxide,97%
| 1131-61-9 |
|
5-Chlorovaleric acid, 98%
| 1119-46-6 |
|
L-Carnitine L-tartrate
| 36687-82-8 |
|
Thulium(III)-Sulfate Octahydrate, 99.99%
| 13778-40-0 |
|
Chlorosulfonic acid
| 7647-01-0 |
|
4-Aminodibenzo-18-Crown-8, Hydrochloride, 97%
| 0-00-1 |
|
N-Ethyl-o-toluidine, 98%
| 94-68-8 |
|
N-Ethyl-3,4-(methylenedioxy)aniline, 99%
| 32953-14-3 |
|
N,N'-Bis(3-aminopropyl)piperazine
| 7209-38-3 |
|
2-Chloro-3,4-dimethoxybenzaldehyde, 98%
| 5417-17-4 |
|
L-Homophenylalanine ethyl ester hydrochloride
| 90891-21-7 |
|
2,3-Dichlorophenylacetic acid
| 10236-60-9 |
|
1,1,1-Trichlorotrifluoroethane, 99%
| 354-58-5 |
|
Methyl cyclobutanecarboxylate, 98%
| 765-85-5 |
|
Methyl 3-(trifluoromethyl)phenylacetate, 97%
| 62451-84-7 |
|
2,4-Dimethylbenzyl cyanide
| 68429-53-8 |
|
2,4-Dimethylbenzyl bromide, 98%
| 78831-87-5 |
|
2,4-Dimethylbenzylamine
| 94-98-4 |
|
2,3-Dichlorobenzylamine, 98%
| 39226-95-4 |
|
3-(Trifluoromethyl)phenethylamine
| 52516-30-0 |
|
N,N-Dimethyl-m-anisidine, 97%
| 15799-79-8 |
|
2-(4-Chlorobenzyl)benzimidazole
| 5468-66-6 |
|
N-Phenyl-2,3-naphthalimide, 98%
| 21815-18-9 |
|
Acetyl isothiocyanate
| 13250-46-9 |
|
Ada, 99%
| 26239-55-4 |
|
|