**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 85874-45-9 |Benzyltriethylammonium borohydride | 96 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: F C
Risk Phrases: 15 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Contact with water liberates extremely flammable gases. Causes
burns.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
May cause irritation of the respiratory tract with burning pain in
the nose and throat, coughing, wheezing, shortness of breath and
pulmonary edema. Causes chemical burns to the respiratory tract. The
toxicological properties of this substance have not been fully
investigated. Inhalation may be fatal as a result of spasm,
inflammation, edema of the larynx and bronchi, chemical pneumonitis
and pulmonary edema.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Water Reactive. Material will react with water and
may release a flammable and/or toxic gas.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Contents may develop pressure upon prolonged storage. Do not breathe
dust, vapor, mist, or gas. Do not get in eyes, on skin, or on
clothing. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Keep under a nitrogen blanket. Water free area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 85874-45-9:
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 146 deg C (dec)
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 146 deg C
Solubility in water: Reacts.
Specific Gravity/Density:
Molecular Formula: C13H26BN
Molecular Weight: 207.17
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures, dust generation, exposure to moist air or water.
Incompatibilities with Other Materials:
Water, strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, oxides of boron,
borane, hydrogen gas.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 85874-45-9 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Benzyltriethylammonium borohydride -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: WATER-REACTIVE SOLID, CORROSIVE, N.O.S.*
Hazard Class: 4.3 (8)
UN Number: 3131
Packing Group: III
IMO
Shipping Name: WATER-REACTIVE SOLID, CORROSIVE, N.O.S.
Hazard Class: 4.3 (8)
UN Number: 3131
Packing Group: III
RID/ADR
Shipping Name: WATER-REACTIVE SOLID, CORROSIVE, N.O.S.
Hazard Class: 4.3
UN Number: 3131
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F C
Risk Phrases:
R 15 Contact with water liberates extremely
flammable gases.
R 34 Causes burns.
Safety Phrases:
S 7/8 Keep container tightly closed and dry.
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 85874-45-9: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 85874-45-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 85874-45-9 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 4/05/1997 Revision #2 Date: 3/20/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
P-Isopropylcalix[8]arene
| |
|
P-Isopropyldihomooxacalix[4]arene
| |
|
Maltitol, 95% (tlc)
| 585-88-6 |
|
Methanesulfonamide, 98% (hplc)
| 3144-09-0 |
|
3-(4-Methoxyphenyl)pyrazole, 99+%
| 27069-17-6 |
|
4'-Methylacetanilide
| 103-89-9 |
|
2-Methyl-1-Propanol, P.A.
| 78-83-1 |
|
5-Methyl-2-Pyrazinecarboxylic Acid, 99%
| 5521-55-1 |
|
2-(2,3,4,5,6-Pentafluorophenoxy)ethanol, 93% (gc)
| |
|
2-Amino-4-Hydroxy-6-Methylpyrimidine
| 3977-29-5 |
|
2,3,4,5,6-Pentafluorophenylacetonitrile
| 653-30-5 |
|
(1R,2R)-(-)-Pseudoephedrine
| 321-97-1 |
|
(s)-(-)-Amino-2-(1'-methoxy-1'-ethylpropyl )pyrrolidine
| 118535-62-9 |
|
(1S,2S)-(+)-Pseudoephedrine hydrochloride
| 345-78-8 |
|
Tetrafluorohydroquinone, 98%
| 771-63-1 |
|
2,2,3,3-Tetrafluoro-1-propanol
| 76-37-9 |
|
Alpha, alpha, alpha', alpha'-tetramethylhe ptanedioic acid
| 2941-45-9 |
|
3-(2-Thienyl) Pyrazole, 99+%
| 19933-24-5 |
|
3-(4-Tolyl)pyrazole, 99+%
| 59843-75-3 |
|
Tributyl(vinyl)tin
| 7486-35-3 |
|
Zeolite Without Alumina Acid Sites, Ratio SiO2/Al2O3 = 1000
| 1318-02-1 |
|
(1s,2s) - (+)- Pseudoephedrine
| 90-82-4 |
|
Tributylethynylstannane
| 994-89-8 |
|
(2S,3S)-2,3-Epoxybutan
| 21490-63-1 |
|
DL-2-Phenyl-3-Butyn-2-Ol, 98+%
| 127-66-2 |
|
2,6-Dimethoxyacetophenone, 99+%
| 2040-04-2 |
|
1-Bromo-N,N,2-Trimethylpropenylamine
| 73630-93-0 |
|
(R,R)-bis(2,2'-phenylthiomethyl)dihydropyran
| 0-00-0 |
|
(s,s)-bis(2,2'-phenylthiomethyl)dihydropyran
| |
|
2',4'-Dichloroacetophenone, 98.5% (GC)
| 2234-16-4 |
|
Phenoxy-2-Propanone, 97%
| 621-87-4 |
|
D,L-6-Hydroxy-1,2,3,4-tetrahydroisoquinoline-3-carboxylic acid
| 134388-87-7 |
|
erythro-D,L-beta-Methylphenylalanine hydrochloride
| |
|
N-BOC-erythro-D,L,beta-Methylphenylalanine
| |
|
N-BOC-erythro-D-beta-Methylphenylalanine
| |
|
N-BOC-erythro-L-beta-Methylphenylalanine
| |
|
D,L-2-Aminotetralin-2-Carboxylic Acid
| 6331-63-1 |
|
N-Boc-D,L-2-Aminotetralin-2-Carboxylic Acid
| |
|
2-Aminoindan-2-carboxylic acid hydrochlori de
| |
|
N-FMOC-2-Aminoindan-2-carboxylic acid
| 135944-07-9 |
|
4-AMINOINDANE
| 32202-61-2 |
|
Aminomethylcyclopropane, 97%
| 2516-47-4 |
|
2-Chloro-5-Fluorophenol, 98%
| 3827-49-4 |
|
L-7-Hydroxy-1,2,3,4-tetrahydroisoquinoline -3-carboxylic acid
| 128502-56-7 |
|
Ether, stabilized, c.p.
| 60-29-7 |
|
Ether, reagent ACS, anhydrous, stabilized
| 60-29-7 |
|
Benzyltriethylammonium borohydride, 96%
| 85874-45-9 |
|
2-Methyl-1,3-dioxolane
| 497-26-7 |
|
4-Methyl-1,3-dioxolane
| 1072-47-5 |
|
2,6-Di-tert. butyl-4-methylphenol
| 128-37-0 |
|
|