**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 98-29-3 |4-tert-Butylcatechol | 0.01 | 202-653-9 |
|----------------|--------------------------------------|----------|-----------|
| 2039-85-2 |3-Chlorostyrene | 98 | 218-024-7 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.The toxicological
properties of this material have not been fully investigated.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. The toxicological properties of this substance have not
been fully investigated.
Inhalation:
Causes respiratory tract irritation. The toxicological properties of
this substance have not been fully investigated.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Hazardous polymerization may occur under fire
conditions.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Scoop up
with a nonsparking tool, then place into a suitable container for
disposal.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Use with
adequate ventilation. Avoid breathing dust, vapor, mist, or gas. Keep
away from heat, sparks and flame. Do not get on skin or in eyes.
Avoid ingestion and inhalation. Pure vapor will be uninhibited and
may polymerize in vents or other confined spaces.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Keep refrigerated. (Store below
4C/39F.)
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local explosion-proof ventilation to keep
airborne levels to acceptable levels.
Exposure Limits
CAS# 98-29-3:
CAS# 2039-85-2:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: 0.981 mm Hg @ 25 deg C
Viscosity: Not available.
Boiling Point: 60 - 62 deg C @ 6.00mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 62 deg C ( 143.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Insoluble.
Specific Gravity/Density: 1.0900g/cm3
Molecular Formula: C8H7Cl
Molecular Weight: 138.60
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable. However, it may undergo explosive polymerization if
uninhibited.
Conditions to Avoid:
Light, ignition sources, temperatures above 65C.
Incompatibilities with Other Materials:
Polymerizing initiators, strong oxidizing agents, acids, metal salts.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide.
Hazardous Polymerization: May occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 98-29-3: UX1400000
CAS# 2039-85-2 unlisted.
LD50/LC50:
CAS# 98-29-3: Draize test, rabbit, skin: 750 ug/24H Severe; Oral,
rat: LD50 = 2820 mg/kg; Skin, rabbit: LD50 = 630 uL/kg.
CAS# 2039-85-2.
Carcinogenicity:
4-tert-Butylcatechol -
Not listed by ACGIH, IARC, or NTP.
3-Chlorostyrene -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 98-29-3: No information available.
CAS# 2039-85-2: No information available.
Canada
CAS# 98-29-3 is listed on Canada's DSL List.
CAS# 2039-85-2 is listed on Canada's NDSL List.
CAS# 98-29-3 is listed on Canada's Ingredient Disclosure List.
CAS# 2039-85-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 98-29-3 is listed on the TSCA inventory.
CAS# 2039-85-2 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 9/02/1997 Revision #3 Date: 5/30/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Cyclopropyl 4-fluorophenyl ketone, 97%
| 772-31-6 |
|
N-[4-(2-Benzoxazolyl)phenyl]maleimide
| 16707-41-8 |
|
5-Bromo-5-Deoxy-2,3-O-Isopropylidene-D-Ribonolactone, 99%
| 94324-23-9 |
|
2-Methylmercaptobenzimidazole, 99%
| 7152-24-1 |
|
2-Azacyclooctanone, 97%
| 673-66-5 |
|
Diethyl 2-(2-Cyanoethyl)-Malonate, 98%
| 17216-62-5 |
|
2,6-Dimethylcyclohexanone (mixture of isomers), 99%
| 2816-57-1 |
|
4-[Bis(4-fluorophenyl)methylene]piperidinehydrobromide
| 111627-29-3 |
|
Pentafluorobenzoyl chloride, 98%
| 2251-50-5 |
|
1-(4-Chlorophenyl)-2-pyrrolidinone 99+%
| 7661-33-8 |
|
Dirhenium Decacarbonyl, made from 99.99% Pure Raw Material, Sublimed.
| 14285-68-8 |
|
2-Mercaptopyridine-N-Oxide , 99%
| 1121-31-9 |
|
Poly(Ethylene Glycol), Average M.W 1450
| 25322-68-3 |
|
Poly(Ethylene Glycol), Average M.W. 1,500
| 25322-68-3 |
|
Poly(Ethylene Oxide) Approximate M.W.200.000
| 25322-68-3 |
|
Poly(Ethylene Glycol), Average M.W. 300
| 25322-68-3 |
|
Poly(Ethylene Oxide), Approximate M.W.100.000
| 25322-68-3 |
|
Poly(Ethylene Oxide) Approximate M.W.900.000
| 25322-68-3 |
|
Trans 2, trans 6-nonadienal, 95%
| 17587-33-6 |
|
5-Bromoindole, 99%
| 10075-50-0 |
|
Sodium Molybdate Dihydrate
| 7631-95-0 |
|
Dipropylamine, 99%
| 142-84-7 |
|
1-(3,4-Dimethylphenyl)piperazine, 98+%
| 1014-05-7 |
|
Poly(ethylene Glycol), Type 6000 (Average m.w. 5600 to 7000)
| 25322-68-3 |
|
Poly(Ethylene Glycol), Average M.W. 1,000
| 25322-68-3 |
|
4-Chloro-2-Phenylquinoline, 99%
| |
|
Glutaric Dialdehyde (8% in Water)
| 111-30-8 |
|
p-tert-Butoxycarbonyloxystyrene
| 87188-51-0 |
|
Tryptamine, 98%
| 61-54-1 |
|
Fast Blue RR
| 6268-05-9 |
|
p-Amidinobenzamide hydrochloride 99%
| 59855-11-7 |
|
4-Methoxystyrene, 96%, Stabilized with 0.01% 4-Tert.-Butylcatechol
| |
|
4-Pentenenitrile, 98%
| 592-51-8 |
|
2-Hexene, 97+%, mixture of cis and trans
| 592-43-8 |
|
Palladium Black, 98% Pd
| 7440-05-3 |
|
Palladium on calcium carbonate, 5% Pd
| 471-34-1 |
|
Alizarin Violet 3R
| 6408-63-5 |
|
Nonanoyl chloride, 98%
| 764-35-2 |
|
Glycol dimercaptoacetate, 97%
| 123-81-9 |
|
2-(2-Formamidothiazole-4-yl)-2-methoxyimin o acetic acid, 95%
| 65872-43-7 |
|
4,4'-Methylenebis-(2,6-diisopropylaniline) 90-95%
| 19900-69-7 |
|
11-Phenoxyundecanoic acid, 99%
| 7170-44-7 |
|
(+)-Diethyl L-tartrate, 99+%
| 87-91-2 |
|
Indium, powder, 99.999%
| 7440-74-6 |
|
1,4-Dimethoxy-2-Fluorobenzene, 99%
| 82830-49-7 |
|
Uridine 5'-monophosphate, disodium salt
| 3387-36-8 |
|
Pentolinium Tartrate, 99%
| 52-62-0 |
|
Rubidium nitrate, 99.99%
| 13126-12-0 |
|
Dioctyl phthalate
| 117-81-7 |
|
3-Chlorostyrene, 98%, stabilized with 100 ppm tert-butylcatechol
| 98-29-3 |
|
|