**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 99-86-5 |1,3-Cyclohexadiene, 1-methyl-4-(1-meth| 85-90 | 202-795-1 |
| |ylethyl)- | | |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 10 22 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Harmful if swallowed. Irritating to eyes, respiratory
system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. Heated or misted substance may
cause headache, irregular eye movements, and possible coma. Vapors
may cause dizziness or suffocation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. If irritation
develops, get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Antidote:
None reported.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Will burn
if involved in a fire. Use water spray to keep fire-exposed
containers cool. Containers may explode in the heat of a fire.
Flammable liquid and vapor.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. Do NOT use straight streams of
water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. A
vapor suppressing foam may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Ground and bond containers when
transferring material. Use spark-proof tools and explosion proof
equipment. Avoid breathing dust, vapor, mist, or gas. Avoid contact
with eyes, skin, and clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Keep container
tightly closed. Keep away from heat, sparks and flame. Avoid
ingestion and inhalation. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 99-86-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective gloves and clothing to
prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: Not available.
Odor: Pleasant odor of lemon
pH: Not available.
Vapor Pressure: .8 mm Hg @ 20 deg C
Viscosity: Not available.
Boiling Point: 173 - 175 deg C @ 760.00mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 46 deg C ( 114.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: miscible with alcohol,ether
Specific Gravity/Density: .8370g/cm3
Molecular Formula: C10H16
Molecular Weight: 136.24
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 99-86-5: OS8060000
LD50/LC50:
CAS# 99-86-5: Draize test, rabbit, skin: 15%/24H Mild; Oral, rat:
LD50 = 1680 mg/kg.
Carcinogenicity:
1,3-Cyclohexadiene, 1-methyl-4-(1-methylethyl)- -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TERPENE HYDROCARBONS, N.O.S.
Hazard Class: 3
UN Number: 2319
Packing Group: III
IMO
Shipping Name: TERPENE HYDROCARBONS, N.O.S.
Hazard Class: 3.3
UN Number: 2319
Packing Group: III
RID/ADR
Shipping Name: TERPENE HYDROCARBONS, N.O.S.
Hazard Class: 3
UN Number: 2319
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 10 Flammable.
R 22 Harmful if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 33 Take precautionary measures against static
discharges.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 99-86-5: No information available.
Canada
CAS# 99-86-5 is listed on Canada's DSL List.
CAS# 99-86-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 99-86-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 2/03/1999 Revision #2 Date: 1/24/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
1-(2,3-Dihydrobenzo[b]furan-5-yl)ethan-1-one, 97%
| 90843-31-5 |
|
alpha-Terpinene, tech. 85-90%
| 99-86-5 |
|
3-Acetyl-1,3-thiazolane-2-carbohydrazide, 97%
| 175203-18-6 |
|
1-Bromo-2-(2-chloroethoxy)-3,5-difluorobenzene, 97%
| 175203-19-7 |
|
5,7-Difluoro-2,3-dihydrobenzo[b]furan, 97%
| 175203-20-0 |
|
Ethyl 2-mercapto-1H-imidazole-4-carboxylate, 97%
| 64038-64-8 |
|
5-({[5-(Trifluoromethyl)-2-pyridyl]thio}methyl)-2-furoic acid, 97%
| 238742-86-4 |
|
3-(2-Methyl-3-furyl)-3-oxopropanenitrile, 97%
| 158386-97-1 |
|
4-Fluoro-2-nitrobenzonitrile, 97%
| 80517-21-1 |
|
Methyl 3-[(4-bromo-3,5-dimethyl-1h-pyrazol-1-yl)methyl]benzoate, 97%
| 175203-23-3 |
|
3-[(4-Bromo-3,5-dimethyl-1h-pyrazol-1-yl)methyl]benzoic acid, 97%
| 175203-24-4 |
|
N4-(2-hydrazino-2-oxoethyl)-2,1,3-benzothiadiazole-4-sulfonamide, 97%
| 175203-26-6 |
|
4-Bromo-2-nitroaniline, 97%
| 875-51-4 |
|
2-[(2,4-Dichlorophenyl)sulfonyl]acetonitrile, 97%
| 87475-64-7 |
|
2-Fluoro-6-[4-(methylthio)phenoxy]benzonitrile, 97%
| 148901-52-4 |
|
2,4-Dichloro-1-[(2-chloroethyl)sulfonyl]benzene, 97%
| 175203-30-2 |
|
N1-phenylbenzene-1-carboximidamide, 97%
| 1527-91-9 |
|
4-[(1,1-Dimethylprop-2-ynyl)oxy]benzonitrile, 97%
| 33143-92-9 |
|
2,2-Dimethyl-2h-chromene-6-carbonitrile, 97%
| 33143-29-2 |
|
5-Chloro-4-nitro-2,1,3-benzothiadiazole, 97%
| 2274-89-7 |
|
2-[(2-Phenoxyethyl)thio]acetic acid, 97%
| 75434-70-7 |
|
1-(3,4-Dimethoxyphenyl)ethan-1-one oxime, 97%
| 88920-78-9 |
|
5-Chloro-2,1,3-benzoxadiazole, 95+%
| 19155-86-3 |
|
2,1,3-Benzoxadiazole-5-carbonitrile, 97%
| 54286-62-3 |
|
3-[({[1-(3,4-Dichlorophenyl)ethylidene]amino}oxy)methyl]benzoic acid,
| 175203-32-4 |
|
3-[({[1-(4-Chlorophenyl)ethylidene]amino}oxy)methyl]benzoic acid, 97%
| 175203-33-5 |
|
4,4'-Dimethoxybenzophenone, 97%
| 90-96-0 |
|
2-(Methylthio)-6-nitro-1,3-benzothiazole, 97%
| 3621-99-6 |
|
2,1,3-Benzoxadiazole-5-carbothioamide, 97%
| 306935-24-0 |
|
5-Nitrovanillin, 99%
| 6635-20-7 |
|
Ethyl 2-(3-thioxo-3,4-dihydro-2h-1,4-benzothiazin-2-yl)acetate, 97%
| 2832-87-3 |
|
2,1,3-Benzoxadiazol-5-ol, 97%
| 768-09-2 |
|
N-(2-Cyanoethyl)pyrrole, 99+%
| 43036-06-2 |
|
2-(3-Oxo-1,3-dihydroisobenzofuran-1-yliden)acetic acid, 97%
| 4743-57-1 |
|
Trans-2-Hepten-1-Ol, 99+%
| 33467-76-4 |
|
2-(Methylthio)-1,3-benzothiazol-6-amine, 97%
| 25706-29-0 |
|
2-(4-Oxo-3,4-dihydrophthalazin-1-yl)acetic acid, 95+%
| 25947-11-9 |
|
6-(Bromomethyl)-4-chloro-2-(trifluoromethyl)quinoline, 95+%
| 123637-51-4 |
|
4-Chloro-8-(trifluoromethoxy)-2-(trifluoromethyl)quinoline,97%
| 306935-27-3 |
|
Diethyl 1,2,3,6-tetrahydropyridazine-1,2-dicarboxylate, 97%
| 35691-30-6 |
|
5,7-Dichloro-2-(trifluoromethyl)quinolin-4-ol, 97%
| 59108-13-3 |
|
4,5,7-Trichloro-2-(trifluoromethyl)quinoline, 97%
| 175203-41-5 |
|
7-Chloro-2-(trifluoromethyl)quinolin-4-ol, 97%
| 57124-20-6 |
|
5-[(4-Bromo-3,5-dimethyl-1H-pyrazol-1-yl)methyl]-2-furoic acid, 97%
| 306935-28-4 |
|
4-Chloro-2-(trifluoromethyl)quinoline, 97%
| 1701-24-2 |
|
Methyl 2-{[2-(trifluoromethyl)-4-quinolyl]thio}acetate, 97%
| 175203-42-6 |
|
2-Methylbenzhydrol, 98+%
| 5472-13-9 |
|
2-{[2-(trifluoromethyl)-4-quinolyl]thio]ethanohydrazide, 95+%
| 175203-43-7 |
|
Difurfuryldisulfide, 96%
| 4437-20-1 |
|
Ethyl N-(2-cyano-3-ethoxyacryloyl)carbamate, 97%
| 1187-34-4 |
|
|