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MSDS  : Stibine
CAS  : 7803-52-3
SYNONYMS  : * Antimonwasserstoffes * Antimony hydride * Antimony trihydride * Antymonowodor * Hydrogen antimonide * Stibine
*** CHEMICAL IDENTIFICATION ***

RTECS NUMBER : WJ0700000
CHEMICAL NAME : Stibine
CAS REGISTRY NUMBER : 7803-52-3
LAST UPDATED : 199712
DATA ITEMS CITED : 13
MOLECULAR FORMULA : H3-Sb
MOLECULAR WEIGHT : 124.78
WISWESSER LINE NOTATION : H3 SB
SYNONYMS/TRADE NAMES :
* Antimonwasserstoffes
* Antimony hydride
* Antimony trihydride
* Antymonowodor
* Hydrogen antimonide
* Stibine

*** HEALTH HAZARD DATA ***

** ACUTE TOXICITY DATA **

TYPE OF TEST : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE : Inhalation
SPECIES OBSERVED : Rodent - mouse
DOSE/DURATION : 100 ppm/1H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
28ZLA8 "Toxicity of Industrial Metals," Browning, E., London, Butterworths,
1961 Volume(issue)/page/year: -,30,1961

TYPE OF TEST : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE : Inhalation
SPECIES OBSERVED : Mammal - dog
DOSE/DURATION : 40 ppm/1H
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - acute pulmonary edema
REFERENCE :
JIHTAB Journal of Industrial Hygiene and Toxicology. (Cambridge, MA)
V.18-31, 1936-49. For publisher information, see AEHLAU.
Volume(issue)/page/year: 28,167,1946

TYPE OF TEST : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE : Inhalation
SPECIES OBSERVED : Mammal - cat
DOSE/DURATION : 40 ppm/1H
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - acute pulmonary edema
REFERENCE :
JIHTAB Journal of Industrial Hygiene and Toxicology. (Cambridge, MA)
V.18-31, 1936-49. For publisher information, see AEHLAU.
Volume(issue)/page/year: 28,167,1946

TYPE OF TEST : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE : Inhalation
SPECIES OBSERVED : Rodent - guinea pig
DOSE/DURATION : 92 ppm/1H
TOXIC EFFECTS :
Kidney, Ureter, Bladder - changes in tubules (including acute renal failure,
acute tubular necrosis)
REFERENCE :
28ZLA8 "Toxicity of Industrial Metals," Browning, E., London, Butterworths,
1961 Volume(issue)/page/year: -,30,1961

*** REVIEWS ***

ACGIH TLV-TWA 0.51 mg/m3 (0.1 ppm)
DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices
(BEIs) booklet issues by American Conference of Governmental Industrial
Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year:
TLV/BEI,1997

*** U.S. STANDARDS AND REGULATIONS ***

MSHA STANDARD-air:TWA 0.1 ppm (0.5 mg/m3)
DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices
(BEIs) booklet issues by American Conference of Governmental Industrial
Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year:
3,233,1971

OSHA PEL (Gen Indu):8H TWA 0.1 ppm (0.5 mg/m3)
CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt.
of Documents, Washington, DC 20402) Volume(issue)/page/year:
29,1910.1000,1994

OSHA PEL (Construc):8H TWA 0.1 ppm (0.5 mg/m3)
CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt.
of Documents, Washington, DC 20402) Volume(issue)/page/year:
29,1926.55,1994

OSHA PEL (Shipyard):8H TWA 0.1 ppm (0.5 mg/m3)
CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt.
of Documents, Washington, DC 20402) Volume(issue)/page/year:
29,1915.1000,1993

OSHA PEL (Fed Cont):8H TWA 0.1 ppm (0.5 mg/m3)
CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt.
of Documents, Washington, DC 20402) Volume(issue)/page/year:
41,50-204.50,1994

*** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA ***

NIOSH RECOMMENDED EXPOSURE LEVEL (REL) :
NIOSH REL TO STIBINE-air:10H TWA 0.1 ppm
REFERENCE :
NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of
Health, Education, and Welfare, Reports and Memoranda.
Volume(issue)/page/year: DHHS #92-100,1992

NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA :
NOES - National Occupational Exposure Survey (1983)
NOES Hazard Code - X5764
No. of Facilities: 23 (estimated)
No. of Industries: 1
No. of Occupations: 1
No. of Employees: 23 (estimated)

*** STATUS IN U.S. ***

NIOSH Analytical Method, 1994: Stibine, 6008


*** END OF RECORD ***
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Spiro(6H-4,9a-methanocyclopent(d)-oxocin-6,3'-oxetane)-2,2'(1H)-dione, hexahydro-5-(methoxymethyl)-9-methyl-1,5,6a-trihydroxy-,(1R-(1-alpha,4-beta,5-beta,6-beta,6a-beta,9-alpha,9a-beta))- 153445-92-2
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Stibine 7803-52-3
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Stibine, diphenyl-, 2-ethylhexanoate 5035-58-5
Stibine oxide, dihydroxy-p-tolyl- 5450-68-0
Stibine oxide, hydroxy(2-thiazolyl)-, sodium salt 5450-68-0
Stibine oxide, triphenyl- 4756-75-6
Stibine sulfide, triphenyl- 3958-19-8
Stibine, trimethyl- 594-10-5
Stibine, triphenyl- 603-36-1
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Stibine, tri-p-tolyl- 5395-43-7
Stibnite 1317-86-8
Stibonium, tetramethyl-, iodide 2185-78-6
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Stibonium, tetraphenyl-,chlorotriphenyl(thiocyanato-N)plumbate(1-) 158882-78-1
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