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MSDS  : Sulfide, bis(dimethylthiocarbamoyl)
CAS  : 97-74-5
SYNONYMS  : * Aceto TMTM * Bis(dimethylthiocarbamoyl)sulfide * Bis(dimethylthiocarbamyl) monosulfide * Carbamic acid, dimethyldithio-, anhydrosulfide * Carbamic anhydride, tetramethyltrithio- * CP 2113 * Formamide, 1,1'-thiobis(N,N-dimethylthio- * Monosulfure de tetramethylthiurame * Mono-thiurad * Monothiuram * Pennac MS * Tetramethylthiurammonium sulfide * Tetramethylthiuram monosulfide * Tetramethylthiuramonosulfide * Tetramethylthiuram sulfide * Thionex rubber accelerator * Thiuram monosulfide, tetramethyl- * TMTM * TMTMS * Unads * USAF B-32 * USAF EK-P-6255 * Vulkacit MS * Vulkacit thiuram MS/C
*** CHEMICAL IDENTIFICATION ***

RTECS NUMBER : WQ1750000
CHEMICAL NAME : Sulfide, bis(dimethylthiocarbamoyl)
CAS REGISTRY NUMBER : 97-74-5
BEILSTEIN REFERENCE NO. : 1775650
REFERENCE : 4-04-00-00238 (Beilstein Handbook Reference)
LAST UPDATED : 199806
DATA ITEMS CITED : 21
MOLECULAR FORMULA : C6-H12-N2-S3
MOLECULAR WEIGHT : 208.38
WISWESSER LINE NOTATION : 1N1&YUS&SYUS&N1&1
COMPOUND DESCRIPTOR : Agricultural Chemical
Tumorigen
Mutagen
Reproductive Effector
SYNONYMS/TRADE NAMES :
* Aceto TMTM
* Bis(dimethylthiocarbamoyl)sulfide
* Bis(dimethylthiocarbamyl) monosulfide
* Carbamic acid, dimethyldithio-, anhydrosulfide
* Carbamic anhydride, tetramethyltrithio-
* CP 2113
* Formamide, 1,1'-thiobis(N,N-dimethylthio-
* Monosulfure de tetramethylthiurame
* Mono-thiurad
* Monothiuram
* Pennac MS
* Tetramethylthiurammonium sulfide
* Tetramethylthiuram monosulfide
* Tetramethylthiuramonosulfide
* Tetramethylthiuram sulfide
* Thionex rubber accelerator
* Thiuram monosulfide, tetramethyl-
* TMTM
* TMTMS
* Unads
* USAF B-32
* USAF EK-P-6255
* Vulkacit MS
* Vulkacit thiuram MS/C

*** HEALTH HAZARD DATA ***

** ACUTE TOXICITY DATA **

TYPE OF TEST : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE : Oral
SPECIES OBSERVED : Rodent - rat
DOSE/DURATION : 450 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
FATOAO Farmakologiya i Toksikologiya (Moscow). For English translation, see
PHTXA6 and RPTOAN. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.2-
1939- Volume(issue)/page/year: 32,356,1969

TYPE OF TEST : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE : Intraperitoneal
SPECIES OBSERVED : Rodent - rat
DOSE/DURATION : 383 mg/kg
TOXIC EFFECTS :
Behavioral - changes in motor activity (specific assay)
Nutritional and Gross Metabolic - body temperature decrease
REFERENCE :
JNPHAG Journal de Pharmacologie. (SPPIF, B.P.22, F-41353 Vineuil, France)
V.1- 1970- Volume(issue)/page/year: 9,35,1978

TYPE OF TEST : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE : Oral
SPECIES OBSERVED : Rodent - mouse
DOSE/DURATION : 818 mg/kg
TOXIC EFFECTS :
Liver - other changes
Kidney, Ureter, Bladder - changes in tubules (including acute renal failure,
acute tubular necrosis)
Blood - changes in cell count (unspecified)
REFERENCE :
ENVRAL Environmental Research. (Academic Press, Inc., 1 E. First St.,
Duluth, MN 55802) V.1- 1967- Volume(issue)/page/year: 28,199,1982

TYPE OF TEST : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE : Intraperitoneal
SPECIES OBSERVED : Rodent - mouse
DOSE/DURATION : 300 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161)
Formerly U.S. Clearinghouse for Scientific & Technical Information.
Volume(issue)/page/year: AD277-689

TYPE OF TEST : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE : Oral
SPECIES OBSERVED : Mammal - dog
DOSE/DURATION : 100 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
RCTEA4 Rubber Chemistry and Technology. (American Chemical Soc., Rubber
Division, c/o Mrs. M.E. Bauer, Univ. of Akron, Akron, OH 44325) V.1- 1928-
Volume(issue)/page/year: 44,512,1971

TYPE OF TEST : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE : Oral
SPECIES OBSERVED : Mammal - cat
DOSE/DURATION : 100 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
RCTEA4 Rubber Chemistry and Technology. (American Chemical Soc., Rubber
Division, c/o Mrs. M.E. Bauer, Univ. of Akron, Akron, OH 44325) V.1- 1928-
Volume(issue)/page/year: 44,512,1971

TYPE OF TEST : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE : Oral
SPECIES OBSERVED : Rodent - rabbit
DOSE/DURATION : 100 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
RCTEA4 Rubber Chemistry and Technology. (American Chemical Soc., Rubber
Division, c/o Mrs. M.E. Bauer, Univ. of Akron, Akron, OH 44325) V.1- 1928-
Volume(issue)/page/year: 44,512,1971

TYPE OF TEST : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE : Oral
SPECIES OBSERVED : Rodent - guinea pig
DOSE/DURATION : 850 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
FATOAO Farmakologiya i Toksikologiya (Moscow). For English translation, see
PHTXA6 and RPTOAN. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.2-
1939- Volume(issue)/page/year: 32,356,1969

TYPE OF TEST : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE : Intraperitoneal
SPECIES OBSERVED : Rodent - guinea pig
DOSE/DURATION : 20 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
RCTEA4 Rubber Chemistry and Technology. (American Chemical Soc., Rubber
Division, c/o Mrs. M.E. Bauer, Univ. of Akron, Akron, OH 44325) V.1- 1928-
Volume(issue)/page/year: 44,512,1971

TYPE OF TEST : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE : Oral
SPECIES OBSERVED : Mammal - species unspecified
DOSE/DURATION : 10 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
IPSTB3 International Polymer Science and Technology. (Rapra Technology
Ltd., Shawbury, Shrewsbury, Shropshire SY4 4NR, UK) Volume(issue)/page/year:
3,93,1976

** OTHER MULTIPLE DOSE TOXICITY DATA **

TYPE OF TEST : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE : Oral
SPECIES OBSERVED : Rodent - rat
DOSE/DURATION : 520 mg/kg/4W-I
TOXIC EFFECTS :
Liver - changes in liver weight
Blood - pigmented or nucleated red blood cells
Blood - changes in erythrocyte (RBC) count
REFERENCE :
ENVRAL Environmental Research. (Academic Press, Inc., 1 E. First St.,
Duluth, MN 55802) V.1- 1967- Volume(issue)/page/year: 28,199,1982

** TUMORIGENIC DATA **

TYPE OF TEST : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE : Subcutaneous
SPECIES OBSERVED : Rodent - mouse
DOSE/DURATION : 100 mg/kg
TOXIC EFFECTS :
Tumorigenic - equivocal tumorigenic agent by RTECS criteria
Lungs, Thorax, or Respiration - tumors
Blood - tumors
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161)
Formerly U.S. Clearinghouse for Scientific & Technical Information.
Volume(issue)/page/year: PB223-159

** REPRODUCTIVE DATA **

TYPE OF TEST : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE : Subcutaneous
SPECIES OBSERVED : Rodent - mouse
DOSE : 900 mg/kg
SEX/DURATION : female 6-14 day(s) after conception
TOXIC EFFECTS :
Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
e.g., stunted fetus)
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161)
Formerly U.S. Clearinghouse for Scientific & Technical Information.
Volume(issue)/page/year: PB223-160

** MUTATION DATA **

TYPE OF TEST : Mutation in microorganisms
TEST SYSTEM : Bacteria - Salmonella typhimurium
DOSE/DURATION : 100 ug/plate
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE
Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 68,313,1979

TYPE OF TEST : Micronucleus test
ROUTE OF EXPOSURE : Intraperitoneal
TEST SYSTEM : Rodent - hamster
DOSE/DURATION : 250 mg/kg
REFERENCE :
SWEHDO Scandinavian Journal of Work, Environment and Health. (Haartmaninkatu
1, SF-00290 Helsinki, 29, Finland) V.1- 1975- Volume(issue)/page/year:
9(Suppl 2),27,1983

TYPE OF TEST : Sister chromatid exchange
TEST SYSTEM : Rodent - hamster Ovary
DOSE/DURATION : 100 nmol/L
REFERENCE :
SWEHDO Scandinavian Journal of Work, Environment and Health. (Haartmaninkatu
1, SF-00290 Helsinki, 29, Finland) V.1- 1975- Volume(issue)/page/year:
9(Suppl 2),27,1983

*** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA ***

NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA :
NOHS - National Occupational Hazard Survey (1974)
NOHS Hazard Code - 80220
No. of Facilities: 376 (estimated)
No. of Industries: 7
No. of Occupations: 23
No. of Employees: 6032 (estimated)

NOES - National Occupational Exposure Survey (1983)
NOES Hazard Code - 80220
No. of Facilities: 803 (estimated)
No. of Industries: 18
No. of Occupations: 31
No. of Employees: 40683 (estimated)
No. of Female Employees: 5320 (estimated)

*** STATUS IN U.S. ***

EPA TSCA Section 8(b) CHEMICAL INVENTORY

EPA TSCA Section 8(d) unpublished health/safety studies

EPA TSCA TEST SUBMISSION (TSCATS) DATA BASE, JUNE 1998


*** END OF RECORD ***
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