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MSDS  : Ligroine
CAS  : 8032-32-4
SYNONYMS  : * Benzine (light petroleum distillate) * Benzoline * Canadol * Ligroin * Painters naphtha * Petroleum ether * Refined solvent naphtha * Skellysolve F * Skellysolve G * Varnish marker's naphtha * VM and P Naphtha * VM & P Naphtha
*** CHEMICAL IDENTIFICATION ***

RTECS NUMBER : OI6180000
CHEMICAL NAME : Ligroine
CAS REGISTRY NUMBER : 8032-32-4
OTHER CAS REGISTRY NOS. : 8031-06-9
LAST UPDATED : 199712
DATA ITEMS CITED : 18
COMPOUND DESCRIPTOR : Reproductive Effector
Primary Irritant
SYNONYMS/TRADE NAMES :
* Benzine (light petroleum distillate)
* Benzoline
* Canadol
* Ligroin
* Painters naphtha
* Petroleum ether
* Refined solvent naphtha
* Skellysolve F
* Skellysolve G
* Varnish marker's naphtha
* VM and P Naphtha
* VM & P Naphtha

*** HEALTH HAZARD DATA ***

** SKIN/EYE IRRITATION DATA **

TYPE OF TEST : Standard Draize test
ROUTE OF EXPOSURE : Administration into the eye
SPECIES OBSERVED : Human
DOSE/DURATION : 880 ppm/15M
REFERENCE :
TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E.
First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year:
32,263,1975

** ACUTE TOXICITY DATA **

TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE : Inhalation
SPECIES OBSERVED : Rodent - rat
DOSE/DURATION : 3400 ppm/4H
TOXIC EFFECTS :
Behavioral - convulsions or effect on seizure threshold
Behavioral - muscle weakness
REFERENCE :
TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E.
First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year:
32,263,1975

TYPE OF TEST : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE : Inhalation
SPECIES OBSERVED : Rodent - mouse
DOSE/DURATION : 153 gm/m3/31M
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity)
Behavioral - changes in motor activity (specific assay)
REFERENCE :
BIZEA2 Biochemische Zeitschrift. (Berlin, Ger.) V.1-346, 1906-67. For
publisher information, see EJBCAI. Volume(issue)/page/year: 115,235,1921

TYPE OF TEST : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE : Intravenous
SPECIES OBSERVED : Rodent - mouse
DOSE/DURATION : 40 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PCJOAU Pharmaceutical Chemistry Journal (English Translation). Translation
of KHFZAN. (Plenum Pub. Corp., 233 Spring St., New York, NY 10013) No.1-
1967- Volume(issue)/page/year: 7,765,1973

** REPRODUCTIVE DATA **

TYPE OF TEST : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE : Inhalation
SPECIES OBSERVED : Rodent - rat
DOSE : 300 mg/m3/4H
SEX/DURATION : female 1-19 day(s) after conception
TOXIC EFFECTS :
Reproductive - Specific Developmental Abnormalities - musculoskeletal system
Reproductive - Effects on Newborn - behavioral
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O
Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936-
Volume(issue)/page/year: 56(9),35,1991

*** REVIEWS ***

ACGIH TLV-Animal carcinogen
DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices
(BEIs) booklet issues by American Conference of Governmental Industrial
Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year:
TLV/BEI,1997

ACGIH TLV-TWA 1370 mg/m3 (300 ppm)
DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices
(BEIs) booklet issues by American Conference of Governmental Industrial
Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year:
TLV/BEI,1997

*** U.S. STANDARDS AND REGULATIONS ***

EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION
FEREAC Federal Register. (U.S. Government Printing Office, Supt. of
Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year:
54,7740,1989

*** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA ***

NIOSH RECOMMENDED EXPOSURE LEVEL (REL) :
NIOSH REL TO VM & P NAPHTHA-air:10H TWA 350 mg/m3;CL 1800 mg/m3/15M
REFERENCE :
NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of
Health, Education, and Welfare, Reports and Memoranda.
Volume(issue)/page/year: DHHS #92-100,1992

NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA :
NOHS - National Occupational Hazard Survey (1974)
NOHS Hazard Code - M0630
No. of Facilities: 1437 (estimated)
No. of Industries: 21
No. of Occupations: 22
No. of Employees: 10998 (estimated)

NOHS - National Occupational Hazard Survey (1974)
NOHS Hazard Code - M2829
No. of Facilities: 182022 (estimated)
No. of Industries: 459
No. of Occupations: 231
No. of Employees: 2414497 (estimated)

NOHS - National Occupational Hazard Survey (1974)
NOHS Hazard Code - T0180
No. of Facilities: 1133 (estimated)
No. of Industries: 16
No. of Occupations: 12
No. of Employees: 3524 (estimated)

NOES - National Occupational Exposure Survey (1983)
NOES Hazard Code - M0630
No. of Facilities: 5 (estimated)
No. of Industries: 1
No. of Occupations: 2
No. of Employees: 1674 (estimated)
No. of Female Employees: 109 (estimated)

NOES - National Occupational Exposure Survey (1983)
NOES Hazard Code - T0180
No. of Facilities: 93614 (estimated)
No. of Industries: 337
No. of Occupations: 196
No. of Employees: 1319179 (estimated)
No. of Female Employees: 164513 (estimated)

*** STATUS IN U.S. ***

EPA TSCA Section 8(b) CHEMICAL INVENTORY

EPA TSCA Section 8(d) unpublished health/safety studies

EPA TSCA TEST SUBMISSION (TSCATS) DATA BASE, JUNE 1998

NIOSH Analytical Method, 1994: Naphthas, 1550


*** END OF RECORD ***
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