acrylic acid, 2-cyano-, methyl ester; (methyl 2-cyanoacrylate) polymethylmethacrylate; (poly(methyl methacrylate)) hydroquinone (sara iii) volatile organic compounds: 92.6%, 1009.34 g/l supp data: hrs. this will cause periods of weeping until clearance is ing 5:vision may be experienced together w/a lachrymatory eft, & it ing 6:realize that disassoc will normally occur within a matter of hrs, ing 7:accidentally stuck together, apply lots of warm water to lips & ing 8:inside mouth. peel/roll lips apart. do not try to pull lips ing 9:swallow cyanoacrylate. adhesive solidfies & adheres in mouth. ing 10: in case a lump forms in the mouth, position the patient to ing 11:detaches. burns: cyanoacrylates give off heat on solidification. ing 12:temperature enough to cause a burn. burns should be treated ing 13: released from the tissue as described above. surgery: it should ing 14: method to separate accidentally bonded skin.
LOCTITE CORPORATION -- SUPERBONDER 496 INSTANT ADHESIVE 49650
=======================================================
Material Safety Data Sheet
=======================================================
NIIN: 00-164-1359
MSDS Num: BDDRV
MSDS NAME: SUPERBONDER 496 INSTANT ADHESIVE 49650
Responsible Party
Name: LOCTITE CORPORATION
Address: 705 NORTH MOUNTAIN ROAD
City: NEWINGTON CT 06111
Info Phone: 203-278-1280
Emergency Phone Number: (203)278-1280 X287
Preparer's Name: STEPHEN REPETTO
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: LOCTITE CORPORATION
Address: 1001 TROUT BROOK CROSSING
City: ROCKY HILL CT 06067-3910
Phone: 860-571-5100
=======================================================
Item Description Information
=======================================================
Item Manager: GSA
Item Name: ADHESIVE
Unit of Issue: OZ
UI Container Qty: 0
=======================================================
Ingredients
=======================================================
Cas: 137-05-3
RTECS #: AS7000000
Name: ACRYLIC ACID, 2-CYANO-, METHYL ESTER; (METHYL 2-CYANOACRYLATE)
% Wt: 90-95
OSHA PEL: 2 PPM;4 STEL
ACGIH TLV: 2 PPM;4 STEL
------------------------------
Cas: 9011-14-7
RTECS #: TR0400000
Name: POLYMETHYLMETHACRYLATE; (POLY(METHYL METHACRYLATE))
% Wt: 5-10
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 123-31-9
RTECS #: MX3500000
Name: HYDROQUINONE (SARA III)
% Wt: 0.1-0.5
OSHA PEL: 2 MG/M3
ACGIH TLV: 2 MG/M3; 9192
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
------------------------------
RTECS #: 9999999VO
Name: VOLATILE ORGANIC COMPOUNDS: 92.6%, 1009.34 G/L
-----------------------------
Name: SUPP DATA: HRS. THIS WILL CAUSE PERIODS OF WEEPING UNTIL CLEARANCE IS
ACHIEVED. DURING PERIOD OF CONTAM, DOUBLE
-----------------------------
Name: ING 5:VISION MAY BE EXPERIENCED TOGETHER W/A LACHRYMATORY EFT, & IT
IS IMPORTANT TO UNDERSTAND THE CAUSE &
-----------------------------
Name: ING 6:REALIZE THAT DISASSOC WILL NORMALLY OCCUR WITHIN A MATTER OF HRS,
EVEN W/GROSS CONTAM. MOUTH: IF LIBS ARE
-----------------------------
Name: ING 7:ACCIDENTALLY STUCK TOGETHER, APPLY LOTS OF WARM WATER TO LIPS &
ENCOURAGE MAX WETTING & PRESS FROM SALIVA
-----------------------------
Name: ING 8:INSIDE MOUTH. PEEL/ROLL LIPS APART. DO NOT TRY TO PULL LIPS
W/OPPOSING ACTION. IT IS ALMOST IMPOSSIBLE TO
-----------------------------
Name: ING 9:SWALLOW CYANOACRYLATE. ADHESIVE SOLIDFIES & ADHERES IN MOUTH.
SALIVA WILL LIFT ADHESIVE IN 1/2 TO 2 DAYS.
-----------------------------
Name: ING 10: IN CASE A LUMP FORMS IN THE MOUTH, POSITION THE PATIENT TO
PREVENT INGESTION OF THE LUMP WHEN IT
-----------------------------
Name: ING 11:DETACHES. BURNS: CYANOACRYLATES GIVE OFF HEAT ON SOLIDIFICATION.
IN RARE CASES A LARGE DROP WILL INCR
-----------------------------
Name: ING 12:TEMPERATURE ENOUGH TO CAUSE A BURN. BURNS SHOULD BE TREATED
NORMALLY AFTER THE LUMP OF CYANOACRYLATE IS
-----------------------------
Name: ING 13: RELEASED FROM THE TISSUE AS DESCRIBED ABOVE. SURGERY: IT SHOULD
NEVER BE NEC TO USE SUCH A DRASTIC
-----------------------------
Name: ING 14: METHOD TO SEPARATE ACCIDENTALLY BONDED SKIN.
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: LD50:(ORAL,RAT) 5000 MG/KG
Route Of Entry Inds - Inhalation: NO
Skin: NO
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: BONDS SKIN RAPIDLY AND STRONGLY. SKIN AND EYE IRRITANT.
EXPOS SYMPS: VAPOR IS IRRITAING TO EYES AND MUCOUS MEMBRANES ABOVE TLV.
PROLONGED AND REPEATED OVEREXPOSURE TO VAPORS MAY PRODUCE ALLERGIC REACT ION
WITH ASTHMA-LIKE SYMPTOMS IN SENSITIVE INDIVIDUALS.
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS.
Medical Cond Aggravated By Exposure: NONE KNOWN.
First Aid: SKIN:FIRST IMMERSE BONDED SURFACES IN WARM SOAPY WATER. PEEL/ROLL
THE SURFS APART W/THE AID OF BLUNT EDGE, E.G., A SPATULA OR A TEASPOON
HANDLE; THEN REMOVE ADHESIVE FROM SKIN W/SOAP & WATER. DO NOT T RY TO
PULL SURFACES APART W/DIRECT OPPOSING ACTION. EYE: IN THE EVENT THAT EYELIDS
ARE STUCK TOGETHER OR BONDED TO THE EYBALL WASH THORO W/WARM WATER &
APPLY A GAUZE PATCH. THE EYE WILL (SUPP DATA)
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: FLOOD WITH WATER TO POLYMERIZE. SOAK UP WITH AN INERT
ABSORBENT.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: FLOOD WITH WATER TO POLYMERZIE. LANDFILL OR INCINERATE
IN ACCORDANCE WITH EPA AND LOCAL REGULATIONS.
Handling And Storage Precautions: STORE AT OR BELOW 75F/23.89C TO MAXIMIZE
SHELF LIFE. AVOID CONTACT WITH SKIN AND EYES. AVOID BREATHING VAPORS.
Other Precautions: NONE SPECIFIED BY MANUFACTURER.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: TCC
Flash Point Text: >150F,>66C
Extinguishing Media: CO*2, FOAM; DRY CHEMICAL
Fire Fighting Procedures: USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: IRRITATING ORGANIC FRAGMENTS FORMED BY FIRE OR
THERMAL DECOMPOSITION.
=======================================================
Control Measures
=======================================================
Respiratory Protection: NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE
OF CONCERN (FP N)
Ventilation: POSITIVE DOWN-DRAFT EXHAUST VENT SHOULD BE PROVIDED TO MAINTAIN
VAPOR CONENTRATION BELOW TLV.
Protective Gloves: POLYETHYLENE GLOVES. DO NOT USE COTTON.
Eye Protection: SAFETY GLASSES/GOGGLES.
Other Protective Equipment: NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: FIRST AID PROC: OPEN WITHOUT FURTHER ACTION,
TYPICALLY IN 1-4 DAYS. THERE WILL BE NO RESIDUAL DMG. DO NOT TRY TO PEN THE
EYES BY MANIPULATION. EYEBALL: CYANOACRYLATE INTRODUCED INTO THE EYES WILL
ATTA CH ITSELF TO THE EYE PROTEIN & WILL DISASSOCIATE FROM IT OVER
INTERMITTENT PERIODS, GENERALLY COVERING SEVERAL
=======================================================
Physical/Chemical Properties
=======================================================
HCC: N1
B.P. Text: >300F,>149C
M.P/F.P Text: N/K (FP N)
Decomp Text: N/K (FP N)
Vapor Pres: <0.2
Vapor Density: 3
Spec Gravity: 1.09 AT 75F
Evaporation Rate & Reference: N/K (FP N)
Solubility in Water: POLYMERIZED BY WATER
Appearance and Odor: CLEAR LIQUID, SHARP IRRITATING ODOR
Percent Volatiles by Volume: N/K-FP
Corrosion Rate: N/K-FP N
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: POLYMERIZED BY WATER, ALCOHOLS, AMINES, ALKALIES
Hazardous Decomposition Products: NONE
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
MSDS Transport Information
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
Transportation Information
=======================================================
Trans ID NO: 52433
MSDS NAME: SUPERBONDER 496 INSTANT ADHESIVE 49650
MSDS Prepared Date: 03/01/1992
Review Date: 06/14/1995
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: OZ
Container QTY: 0
Additional Data: NOT REGULATED FOR SHIPPING.
=======================================================
Detail DOT Information
=======================================================
DOT PSN Code: ZZZ
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
Detail IMO Information
=======================================================
IMO PSN Code: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
=======================================================
Detail IATA Information
=======================================================
IATA PSN Code: ZZZ
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
Detail AFI Information
=======================================================
AFI PSN Code: ZZZ
AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: SUPERBONDER 496 INSTANT ADHESIVE 49650
Company: LOCTITE CORPORATION
Street: 1001 TROUT BROOK CROSSING
City: ROCKY HILL CT
Zipcode: 06067-3910
Health Emergency Phone: (203)278-1280 X287
Label Required IND: Y
Date Of Label Review: 04/20/1994
Status Code: C
Label Date: 04/20/1994
Origination Code: G
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Moderate
Reactivity Hazard: Slight
Hazard And Precautions: POLYMERIZED BY CONTACT WITH WATER, ALCOHOLS, AMINES,
ALKALIES. AVOID SKIN AND EYE CONTACT. AVOID BREATHING VAPORS. STORE AT OR
BELOW 75F. ACUTE: BONDS SKIN RAPIDLY AND STRONGLY. SKIN AND EYE IRRITANT.
VAPOR IS IRRITATING TO EYES AND MUCOUSMEMBRANES ABOVE TLV. PROLONGED AND
REPEATED OVEREXPOSURE TO VAPORS MAY PRODUCE ALLERGIC REACTIONS. CHRONIC: NONE
LISTED BY MANUFACTURER.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.