LCI (LUCIER CHEMICAL INDUSTRIE -- SODIUM FLUOROSILICATE
=======================================================
Material Safety Data Sheet
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NIIN: 00-088-7252
MSDS Num: BNBQF
MSDS NAME: SODIUM FLUOROSILICATE
Responsible Party
Name: LCI (LUCIER CHEMICAL INDUSTRIES) LTD
Box: 49000
City: JACKSONVILLE BEACH FL 32240-9000
Info Phone: 904-241-1200
Emergency Phone Number: 904-241-1200
Preparer's Name: GUSTAVO R. NAVAR
Chemtrec IND/Phone: (800)424-9300
Published: Y
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Contractor Summary
=======================================================
Name: LOS ANGELES CHEMICAL CO
Address: 4545 ARDINE ST
Box: 1987
City: SOUTH GATE CA 90280
Phone: 213-562-9500
Name: LUCIER CHEMICAL INDUSTRY DBA LCI LTD
Address: 415 PABLO AVE N
Box: 49000
City: JACKSONVILLE BEACH FL 32240-9000
Phone: 904-241-1200
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Item Description Information
=======================================================
Item Manager: S9G
Item Name: SODIUM SILICOFLUORIDE,TECHNICAL
Specification Number: AWWA STD B 702-89
Type/Grade/Class: NONE
Unit of Issue: DR
Quantitative Expression: 00000000050LB
UI Container Qty: 1
Type of Container: 1A2
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Ingredients
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Cas: 16893-85-9
RTECS #: VV8410000
Name: SODIUM SILICOFLUORIDE/FLUOROSILICATE
% Wt: 99
Other REC Limits: NONE RECOMMENDED
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
------------------------------
Name: WATER INSOLUBLES/INSOLUBLE MATERIALS
% Wt: 0.5
Other REC Limits: NONE RECOMMENDED
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
-----------------------------
Name: NAF.HF
% Wt: 0.50
Other REC Limits: NONE RECOMMENDED
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: ORAL LD50 (RAT) IS 125 MG/KG
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: MAY CAUSE IRRITATION OF EYES, SKIN AND REPIRATORY
TRACT. INGESTION MAY CAUSE KIDNEY DAMAGE, SEVERE DIGESTIVE SYSTEM DISTRESS
AND TOXIC EFFECTS. CHRONIC: MAY CAUSE SCLEROSIS. MAY CAUSE MAY ENZYM E SYSTEM
EFFECTS.
Explanation Of Carcinogenicity: NO INGREDIENT OF A CONCENTRATION OF 0.1% OR
GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN. (PER MFG MSDS)
Signs And Symptions Of Overexposure: INHALATION: COUGHING, WHEEZING, CHEST
PAIN, SHORTNESS OF BREATH. EYES: REDNESS, PAIN, DISCOMFORT, ITCHING, TEARING.
SKIN: RASH, DISCOMFORT, ITCHING. INGESTION: ABDOMINAL PAIN, DIARRHEA, NAUSEA,
VOMITI NG, THIRST, DISTURBED COLOR VISION, MUSCULAR WEAKNESS, CONVULSIONS,
LOSS OF CONSCIOUSNESS.
Medical Cond Aggravated By Exposure: PRE-EXISTING RESPIRATORY DISORDERS SUCH AS
ASTHMA AND EMPHYSEMA.
First Aid: INHALATION: REMOVE PERSON TO FRESH AIR. IF NEEDED, RESUSCITATE.
EYES: FLUSH WITH LOTS OF WATER FOR 15 MINUTES. SEE DOCTOR. SKIN: REMOVE
CONTAMINATED CLOTHES AND WASH AREA WITH SOAP AND WATER. INGESTIO N: DO NOT
INDUCE VOMITING! IF CONSCIOUS, GIVE SEVERAL GLASSES OF MILK OR WATER. GET
IMMEDIATE MEDICAL ATTENTION.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: EVAACUATE AREA & ISOLATE HAZARD AREA. CAREFULLY
SHOVEL MATERIAL & PLACE IN CLEAN DRY CONTAINER & COVER. REMOVE
CONTAINER FROM SPILL SITE & DISPOSE. CHEMTREC MAY BE CONTACTED FOR
24-HOUR ASSISTANCE
Neutralizing Agent: MFR GAVE NO INFORMATION OF MSDS.
Waste Disposal Methods: DISPOSE OF I/A/W FEDERAL, STATE & LOCAL
REGULATIONS.
Handling And Storage Precautions: STORE IN A COOL, DRY PLACE AWAY FROM IACIDS.
USE ONLY W/ADEQUATE VENTILATION, DUST MASK OR SCBA. ALWAYS WEAR PROTECTIVE
CLOTHING.
Other Precautions: AVOID CONTACT W/EYES, SKIN & CLOTHING. KEEP BAG OR
CONTAINER CLOSED WHEN NOT IN USE. AVOID BREATHING DUST OR MIST. DO NOT GET ON
SKIN, CLOTHING OR IN EYES. WASH OFF W/WATER. DO NOT TAKE INTERNALLY. DO NOT
BREATHE DUST.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Text: N/A.
Lower Limits: N/A.
Upper Limits: N/A.
Extinguishing Media: CHEMICAL IS NOT FLAMMABLE. FOAM, DRY CHEMICALS OR CARBON
DIOXIDE MAY BE USED WHERE IT IS STORED.
Fire Fighting Procedures: WHEN THIS PRODUCT IS HEATED TO DECOMPOSITION
(>500C) IT WILL GENERATE HIGHLY TOXIC GASES SUCH AS HYDROGEN FLUORIDE.
Unusual Fire/Explosion Hazard: EXTREME TEMPERATURES WILL CAUSE DECOMPOSITION
& FORMATION OF NITROGEN OXIDES & FLUORINE. FIRE FIGHTERS SHOULD SEAR
FULL PROTECTIVE CLOTHING & SCBA.
=======================================================
Control Measures
=======================================================
Respiratory Protection: WEAR A NIOSH APPROVED RESPIRATOR. SELF-CONTAINED
BREATHING APPARATUS MAY BE REQUIRED WHEN CHEMICAL IS HEATED TO DECOMPOSITION.
Ventilation: ADEQUATE VENTILATION TO MAINTAIN FLUORIDE CONCENTRATIONS BELOW
APPLICABLE STANDARDS.
Protective Gloves: IMPERVIOUS GLOVES
Eye Protection: SPLASH PROOF GOGGLES
Other Protective Equipment: PROTECTIVE IMPERVIOUS CLOTHING TO PREVENT CONTACT
W/SKIN.
Work Hygienic Practices: MFR GAVE NO INFORMATION OF MSDS.
Supplemental Safety and Health: MSDS WAS MISSING PAGE 2 WHICH COVERED HEALTH
RISKS AND FIRST AID. INFORMATION FROM PREVIOUS MSDS WAS LEFT IN THOSE FIELDS.
=======================================================
Physical/Chemical Properties
=======================================================
HCC: T4
NRC/State LIC No: NOT RELEVANT
B.P. Text: DECOMPOSES
M.P/F.P Text: DECOMPOSES
Decomp Temp: =500.C, 932.F
Vapor Pres: N/A.
Vapor Density: N/A.
Spec Gravity: 2.679
Viscosity: UNKNOWN
Evaporation Rate & Reference: N/A.
Solubility in Water: 0.44%
Appearance and Odor: WHITE ODORLESS GRANULAR CRYSTALLINE MATERIAL - PH 1% SOLN
= 3.1
Corrosion Rate: UNKNOWNN
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: CONTACT WITH STRONG ACIDS & ALKALIES WILL CAUSE
FORMATION OF HYDROGEN FLUORIDE GAS.
Materials To Avoid: STRONG ACIDS, ALKALIES
Hazardous Decomposition Products: MAY FORM HYDROGEN FLUORIDE, FLUORINE AND
NITROGEN OXIDES.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: WILL NOT OCCUR.
=======================================================
Toxicological Information
=======================================================
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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Transportation Information
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Trans ID NO: 47125
MSDS NAME: SODIUM FLUOROSILICATE
MSDS Prepared Date: 05/01/1994
Review Date: 02/28/2001
Net Unit Weight: 50 POUNDS
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: DR
Container QTY: 1
Type Of Container: 1A2
Additional Data: MFR SUPPLIED THE PROPER SHIPPING NAME.
=======================================================
Detail DOT Information
=======================================================
DOT PSN Code: NFM
DOT Proper Shipping Name: SODIUM FLUOROSILICATE
Hazard Class: 6.1
UN ID Num: UN2674
DOT Packaging Group: III
Label: KEEP AWAY FROM FOOD
Packaging Exception: 153
Non Bulk Pack: 213
Bulk Pack: 240
Max Qty Pass: 100 KG
Max Qty Cargo: 200 KG
Vessel Stow Req: A
Water/Ship/Other Req: 26
=======================================================
Detail IMO Information
=======================================================
IMO PSN Code: NRZ
IMO Proper Shipping Name: SODIUM FLUOROSILICATE
IMDG Page Number: 6250
UN Number: 2674
UN Hazard Class: 6.1
IMO Packaging Group: III
Subsidiary Risk Label: -
EMS Number: 6.1-04
MED First Aid Guide NUM: 750
=======================================================
Detail IATA Information
=======================================================
IATA PSN Code: WQL
IATA UN ID Num: 2674
IATA Proper Shipping Name: SODIUM FLUOROSILICATE
IATA UN Class: 6.1
IATA Label: TOXIC
UN Packing Group: III
Packing Note Passenger: 619
Max Quant Pass: 100KG
Max Quant Cargo: 200KG
Packaging Note Cargo: 619
=======================================================
Detail AFI Information
=======================================================
AFI PSN Code: WQL
AFI Proper Shipping Name: SODIUM FLUOROSILICATE
AFI Hazard Class: 6.1
AFI UN ID NUM: UN2674
AFI Packing Group: III
Special Provisions: P5
Back Pack Reference: A10.6
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: SODIUM FLUOROSILICATE
Company: LUCIER CHEMICAL INDUSTRY DBA LCI LTD
Street: 415 PABLO AVE N
PO Box: 49000
City: JACKSONVILLE BEACH FL
Zipcode: 32240-9000
Health Emergency Phone: 904-241-1200
Label Required IND: Y
Date Of Label Review: 05/03/1997
Status Code: C
MFG Label NO: NONE
Label Date: 05/03/1997
Year Procured: 1997
Origination Code: F
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: TARGET ORGANS:EYE, SKIN, RESPIRATORY & GI TRACTS.
ACUTE- FLUORIDE DUST MAY CAUSE IRRITATION TO EYES & RESPIRATORY TRACT.
SWALLOWING MAY CAUSE ABDOMINAL PAIN/BURNING. CHRONIC- SKIN RASH, PULMONARY
FIBR OSIS. STORE AWAY FROM INCOMPATIBLES. SWEEP UP & PLACE IN A SUITABLE
CONTAINER FOR DISPOSAL. FIRST AID- GET MEDICAL HELP IF SYMPTOMS PERSIST.
INHALED:REMOVE TO FRESH AIR. PROVIDE CPR/OXYGEN IF NEEDED. EYES: FLUSH WITH
WATER FOR 15 MINUTES. HOLD EYELIDS OPEN. SKIN:WASH WITH SOAP &WATER.
ORAL:IF CONSCIOUS, DRINK SEVERAL GLASSES OF MILK (CALCIUM) OR LARGE AMOUNT OF
WATER. GET MEDICAL ATTENTION IMMEDIA TELY. DO NOT INDUCE VOMITING.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
*** END OF RECORD *** |
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