LILLY INDUSTRIES INC -- POLYESTER GEL COAT, 3665506 BROWN
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: CBJWB
MSDS NAME: POLYESTER GEL COAT, 3665506 BROWN
Responsible Party
Name: LILLY INDUSTRIES INC
Address: 210 EAST ALONDRA BLVD
City: GARDENA CA 90248
Info Phone: 310-352-3087
Emergency Phone Number: 800-424-9300 (CHEMTREC)
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: LILLY IND INC
Address: 210 E ALONDRA BLVD
City: GARDENA CA 90248
Phone: 310-352-3087
Name: LILLY INDUSTRIES INC
Address: 210 E ALONDRA BLVD
City: GARDENA CA 90248
Phone: 213-321-0710
=======================================================
Ingredients
=======================================================
Cas: 7758-97-6
RTECS #: GB2975000
Name: CHROMIC ACID, LEAD (2+) SALT (1:1); (LEAD CHROMATE PIG)
% Wt: 0.52
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 1344-37-2
Name: LEAD SULFOCHROME; (LEAD CHROMATE PIG)
% Wt: 0.31
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Name: POLYESTER RESIN (UNSATURATED)
% Wt: 1-5
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Cas: 100-42-5
RTECS #: WL3675000
Name: STYRENE (SARA 313) VP: 4.50
% Wt: 26.46
OSHA PEL: 100 PPM
ACGIH TLV: 50PPM/100STEL, S
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
Name: POLYESTER RESIN (UNSATURATED)
% Wt: 50-60
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Name: POLYESTER ALKYD VP: 5.00
% Wt: 1-5
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Name: SUP DAT: CONTRS. THIS PROD CONTAINS EXTREMELY FLAM SOLV WHOSE VAPS MAY
FORM EXPLO MIX W/AIR.
-----------------------------
Name: MATLS TO AVOID: AVOID CONT WITH FREE RADICAL FORMERS (PEROXIDES,
HYDRAZIDES, ALKALI METALS, STRONG LEWIS ACIDS).
-----------------------------
Name: EFTS OF OVEREXP: SPRAY MIST MAY RSLT IN LEAD POIS. SYMP INCL FATG,
ANEMIA, HDCH, NAUS, ANXIETY & HYPERTENSION.
-----------------------------
Name: ING 9: DMG TO KIDNEYS, LUNGS & NERV SYS MAY OCCUR. CHRONIC EXPOS MAY
PRODUCE DEPRESS, GEN WEAK, & POSS LIVER DAMAGE.
-----------------------------
Name: RESP PROT: BECOME AIRBORNE AS VAP/DUST. USE VENT AS REQUIRED TO CTL VAP
CONCS, AVOID PRLNG/RPTD BRTHG OF VAPS.
-----------------------------
Name: VENT: ACCEPTABLE LIMIT, & TO REMOVE DECOMP PRODUCTS DURING
WELDING/FLAME CUTTING ON SURFACES COATED WITH THIS PRODUCT.
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: NO
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: YES
OSHA: NO
Effects of Exposure: ACUTE: SKIN: MAY CAUSE IRRIT/BLISTERING. EYE: MAY CAUSE
MOD IRRIT, TEARING, BURNING/REDNESS. INGEST: MAY CAUSE INTESTINAL IRRIT,
NAUS/DIZZ. INHAL: OVEREXP MAY CAUSE RESP IRRIT/NAUS, EVEN UNCON/DEATH.
CHRONIC: REPORTS HAVE ASSOC RPTD & PRLNG OVEREXP TO SOLV W/PERM BRAIN
& NERV SYS DMG. INTENTIONAL (EFTS OF OVEREXPOSURE)
Explanation Of Carcinogenicity: STYRENE & CHROMIUM (VI): IARC MONOGRAPHS,
SUPPLEMENT, VOL 7, PG 345, 1987: GROUP 2B. ANIMAL: NERVOUS SYSTEM.
Signs And Symptions Of Overexposure: HLTH HAZ: MISUSE BY DELIBERATELY
CONCENTRATING & INHALING CONTENTS MAY BE HARMFUL/FATAL. AVOID BRTHG
VAPS/SPRAY MIST. LEAD APPEARS ON NAVY LIST OF OCCUP CHEM REPRO HAZ. SEEK
CONSULT FROM APPROP HLTH P ROFESSIONALS CONCERNING LATEST HAZ LISTINFO &
SAFE HNDLG & EXPOS INFO (FP N). PRLNG/RPTD INGEST/INHAL OF DUST/
Medical Cond Aggravated By Exposure: CONJUNCTIVITIS OF THE EYE, DERMATITIS,
ASTHMA, PREEXISTING RESPIRATORY DISEASES.
First Aid: EYES: FLUSH WITH LUKEWARM WATER FOR AT LEAST 15 MINUTES AND OBTAIN
MEDICAL ATTENTION. SKIN: WASH WITH COPIOUS AMOUNTS OF LUKEWARM WATER AND
SOAP. REMOVE CONTAMINATED CLOTHING PROMPTLY. INGESTION: DO N OT INDUCE
VOMITING. OBTAIN EMERGENCY MEDICAL HELP. VOMITING MAY LEAD TO CHEMICAL
PNEUMONITIS, WHICH CAN BE FATAL. INHALATION: REMOVE TO FRESH AIR.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: REMOVE SOURCES OF IGNITION. PREVENT FLOW INTO SEWERS
OR WATERWAYS. CLEAN UP WITH AN INERT ABSORBENT USING NON-SPARKING TOOLS.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: FOLLOW APPLICABLE REGULATIONS ON DISPOSAL OF WASTE.
RESIDUES ARE HAZARDOUS DUE TO THEIR IGNITABILITY. HEAVY METAL COMPOUNDS ARE
CONSIDERED HAZARDOUS BASED ON BASIS OF EP TOXICITY. DISPOSE OF IN ACCORD ANCE
W/LOCAL, STATE & FEDERAL REGULATIONS (FP N).
Handling And Storage Precautions: KEEP PRODUCT CONTAINERS COOL, DRY, AND AWAY
FROM SOURCES OF IGNITION. USE AND STORE THIS PRODUCT WITH ADEQUATE
VENTILATION.
Other Precautions: DO NOT SMOKE IN STORAGE AREAS. KEEP CONTAINERS CLOSED WHEN
NOT IN USE. KEEP FROM CONTACT WITH OXIDIZING MATERIALS. DO NOT TAKE
INTERNALLY. FOR INDUSTRIAL USE ONLY. KEEP AWAY FROM FOOD PRODUCTS.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: TCC
Flash Point Text: 88.0F,31.1C
Lower Limits: 1.1%
Upper Limits: 6.1%
Extinguishing Media: USE DRY CHEMICAL, CARBON DIOXIDE, OR FOAM.
Fire Fighting Procedures: WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP(FP
N). WATER SPRAY MAY BE INEFFECTIVE. WATER SPRAY MAY BE USED TO COOL CLSD
CONTRS TO PVNT PRESS BUILD UP(SUP DAT)
Unusual Fire/Explosion Hazard: VAPS MAY BE HVR/AIR & MAY TRAVEL ALONG
GROUND BEFORE IGNIT/FLASHING BACK TO VAP SOURCE. WATER/FOAM SPRAYED INTO
CONTR OF HOT BURNING LIQ MAY CAUSE A (SUP DAT)
=======================================================
Control Measures
=======================================================
Respiratory Protection: WHEN SPRAYING IN OPEN AREAS, USE NIOSH/MSHA APPRVD MECH
FILTER RESP TO REMOVE AIRBORNE OVERSPRAY. IN CONFINED AREAS USE NIOSH/MSHA
APPRVD, POS PRESS, SCBA. RESP PROT MAY ALSO BE NEC IN ANY LATER MFG O
PERATION IN WHICH PROD MAY
Ventilation: LOC VENT SHOULD BE SUFFICIENT. PROVIDE GEN DILUTION/LOC EXHAUST
VENT IN VOL & PATTERN TO KEEP TLV BELOW
Protective Gloves: NEOPRENE OR RUBBER GLOVES.
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGS (FP N).
Other Protective Equipment: PROTECTIVE CLOTHING SHOULD BE WORN. EMERGENCY
EYEWASH & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA (FP N).
Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING. FOLLOW PRUDENT HYGIENE
PRACTICE.
Supplemental Safety and Health: FIRE FIGHT PROC: & POSS AUTOIGNIT/EXPLO
WHEN EXPOSED TO EXTREME HEAT. IF WATER IS USED, FOG NOZZ ARE PREFERABLE. CLSD
CONTRS MAY BE COOLED W/WATER SPRAY. EXPLO HAZ: VIOLENT ERUPTION. CONT W/FREE
RADIC AL FORMERS SUCH AS PEROXIDES MAY RLST IN SPONT EXOTHERMIC
POLYMERIZATION. EXPOS TO HEAT BUILDS UP PRESS IN CLSD
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: >293F,>145C
Vapor Pres: 5 @ 68F
Vapor Density: HVR/AIR
Spec Gravity: 1.212 (FP N)
Evaporation Rate & Reference: SLOWER THAN ETHER
Appearance and Odor: LIQUID
Percent Volatiles by Volume: 34.18
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: AVOID EXPOSURE TO SPARKS, OPEN FLAMES, HOT
SURFACES, AND ALL SOURCES OF HEAT AND IGNITION.
Materials To Avoid: AVOID STRONG MINERAL ACIDS & OXIDIZING AGENTS, STRONG
ACIDS, ALKALIES, OXIDIZERS, AMINES, POLYM ACCELERATORS.
Hazardous Decomposition Products: NONE SPECIFIED BY MANUFACTURER.
Hazardous Polymerization Indicator: YES
Conditions To Avoid Polymerization: HAZARDOUS POLYMERIZATION MAY OCCUR WITH
CATALYST OR HEAT.
=======================================================
Toxicological Information
=======================================================
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Ecological Information
=======================================================
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MSDS Transport Information
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Regulatory Information
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Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: POLYESTER GEL COAT, 3665506 BROWN
Assigned IND: Y
Company: LILLY INDUSTRIES INC
Street: 210 E ALONDRA BLVD
City: GARDENA CA
Zipcode: 90248
Health Emergency Phone: 800-424-9300 (CHEMTREC)
Label Required IND: Y
Date Of Label Review: 01/25/1996
Status Code: C
Label Date: 01/25/1996
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: FLAMMABLE LIQUID CLASS IC. ACUTE: SKIN: MAY CAUSE
IRRIT/BLISTERING. EYE: MAY CAUSE MODERATE IRRIT, TEARING, BURNING/REDNESS.
INGEST: MAY CAUSE INTESTINAL IRRIT, NAUSEA/DIZZINESS. INHAL: OVEREXPOSURE M
AY CAUSE RESPIRATORY IRRIT/NAUSEA, EVENUNCONSCIOUSNESS/DEATH. CHRONIC: CANCER
HAZARD. CONTAINS STYRENE & CHROMIUM (VI), WHICH IS LISTED AS AN ANIMAL
NERVOUS SYSTEM CARCINOGEN (FP N). REPORTS HAVE ASSO CIATED RPTD &
PROLONGED OVEREXPOSURE TO SOLVENTS W/PERMANENT BRAIN & NERVOUS SYSTEM
DAMAGE. LEAD APPEARS ON THE NAVY OCCUPATIONAL CHEMICAL REPRODUCTIVE HAZARDS
LIST (FP N). PROLONGED INGESTION/INHALAT ION OF DUST/SPRAY MIST MAY CAUSE
LEAD POISONING.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
*** END OF RECORD *** |
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